CN106927604A - Sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit - Google Patents
Sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit Download PDFInfo
- Publication number
- CN106927604A CN106927604A CN201710345243.2A CN201710345243A CN106927604A CN 106927604 A CN106927604 A CN 106927604A CN 201710345243 A CN201710345243 A CN 201710345243A CN 106927604 A CN106927604 A CN 106927604A
- Authority
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- China
- Prior art keywords
- sodium
- salt wastewater
- processing unit
- discharge processing
- zero discharge
- Prior art date
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- Pending
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 36
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 title claims abstract description 31
- 239000011734 sodium Substances 0.000 title claims abstract description 29
- 229910052708 sodium Inorganic materials 0.000 title claims abstract description 29
- 238000004064 recycling Methods 0.000 title claims abstract description 17
- 230000008929 regeneration Effects 0.000 title abstract description 25
- 238000011069 regeneration method Methods 0.000 title abstract description 25
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 42
- 239000007788 liquid Substances 0.000 claims abstract description 24
- 230000001172 regenerating effect Effects 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 21
- 239000012267 brine Substances 0.000 claims abstract description 14
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 14
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims abstract description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 13
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 11
- 239000011780 sodium chloride Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 18
- 239000012528 membrane Substances 0.000 claims description 14
- 239000013505 freshwater Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 7
- 238000001471 micro-filtration Methods 0.000 claims description 5
- 239000011347 resin Substances 0.000 abstract description 10
- 229920005989 resin Polymers 0.000 abstract description 10
- 150000002500 ions Chemical class 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 7
- 239000002699 waste material Substances 0.000 abstract description 7
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical group [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 abstract description 6
- 239000010808 liquid waste Substances 0.000 abstract description 6
- 229910001425 magnesium ion Inorganic materials 0.000 abstract description 5
- 239000000243 solution Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 2
- 239000011575 calcium Substances 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229940096405 magnesium cation Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- -1 salt ion Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/04—Chlorides
- C01D3/06—Preparation by working up brines; seawater or spent lyes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The present invention relates to a kind of sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit, it is related to high-salt wastewater processing technology field, solves the technical problem that high-salt wastewater recovery difficult is big, recovering effect is poor produced in resin regeneration process present in prior art.Sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit of the invention includes passing sequentially through waste water tank, regenerative agent conversion unit and the concentration reuse unit of pipeline connection, mouth and liquid caustic soda is added to add mouth by setting sodium carbonate on regenerative agent conversion unit, you can to successively introducing OH in sodium bed regeneration liquid waste‑And CO3 2‑Ion, makes the divalent ion Ca in waste liquid2+、Mg2+Form aggregate, you can the divalent ion in removal sodium bed regeneration liquid waste, remaining sodium chloride solution is concentrated, continues resin regeneration, realizes the recycling of regeneration effluent brine, realize the zero-emission of sodium bed regeneration liquid waste and recycle.
Description
Technical field
The present invention relates to high-salt wastewater processing technology field, a kind of particularly sodium bed regeneration high-salt wastewater resource zero
Discharging processing device.
Background technology
Sodium bed regenerative wastewater refer to:During sodium ionomer resin swap tank soft water preparation, produced when sodium form positive resin regenerates
Raw waste water.When softened water is prepared, while resin constantly exchanges calcium, magnesium cation, gradually tend to saturation, when resin saturation
When just lose water-making ability, at this moment resin is regenerated with sodium chloride brine, and sodium ion displaces calcium, magnesium ion, resin regeneration
The a large amount of high-salt wastewaters of Cheng Zhongyou produce (mainly calcium, magnesium and chlorion), these waste water containing salt ion, if by its direct row
Put, it will environmental pollution, and waste a large amount of water sources;If reclaimed, technical difficulty is very big, is not molded also in the prior art
Process the processing unit of sodium form resin regeneration waste water.
The content of the invention
The present invention provides a kind of sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit, for solving in the prior art
The technical problem that high-salt wastewater recovery difficult is big, recovering effect is poor produced in the resin regeneration process of presence.
The present invention provides a kind of sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit, including passes sequentially through pipeline company
Waste water tank, regenerative agent conversion unit and the concentration reuse unit for connecing, sodium carbonate is provided with the regenerative agent conversion unit
Mouth and liquid caustic soda is added to add mouth.
In one embodiment, the regenerative agent conversion unit includes mixing reactor, the sodium carbonate add mouth and
The liquid caustic soda adds mouth to be respectively positioned on the top of the mixing reactor, and the mixing reactor is internally provided with agitator.
In one embodiment, the regenerative agent conversion unit also includes plate and frame filter press, the plate and frame filter press point
It is not connected with the mixing reactor and the concentration reuse unit, solid precipitation is provided with the plate and frame filter press
Mouthful.
In one embodiment, it is in series with screw rod on the pipeline between the mixing reactor and the plate and frame filter press
Pump.
In one embodiment, it is in series with pipeline on the pipeline between the waste water tank and the regenerative agent conversion unit
Blender, dosing mouth is provided with the pipe-line mixer.
In one embodiment, the concentration reuse unit includes concentration membrane stack, on the concentration membrane stack respectively
Fresh water output end and strong brine output end be set, the fresh water output end and sodium chloride strong brine output end respectively with the fresh water
Case is connected with strong brine case.
In one embodiment, connected on the pipeline being connected between the concentration membrane stack and the regenerative agent conversion unit
There are booster pump and micro-filtration.
Compared with prior art, the advantage of the invention is that:
(1) mouth and liquid caustic soda is added to add mouth by setting sodium carbonate on regenerative agent conversion unit, you can be regenerated to sodium bed
OH- and CO is successively introduced in waste liquid3 2-Ion, makes the divalent ion Ca in waste liquid2+、Mg2+Form aggregate, you can removal sodium bed
Divalent ion in regeneration liquid waste, realizes the process continuous of abraum salt water process, and realizes the zero-emission of sodium bed regeneration liquid waste
And cyclic regeneration.
(2) Ca is eliminated2+、Mg2+Waste water by after concentration reuse unit, further separating concentration, obtain
Fresh water may be recovered utilization, the sodium chloride strong brine of acquisition can be used as regenerated liquid and use, therefore to the concentration point of waste water
From treatment more thoroughly, utilization rate is higher.
Brief description of the drawings
The invention will be described in more detail below based on embodiments and refering to the accompanying drawings.
Fig. 1 is the schematic diagram of the sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit in embodiments of the invention.
In the accompanying drawings, identical part uses identical reference.Accompanying drawing is not drawn according to actual ratio.
Reference:
1- waste water tanks;2- regenerative agents convert list 3- concentration reuse lists
4- pipe-line mixers;5- fresh-water tanks;6- strong brine casees;
7- booster pumps;8- micro-filtrations;21- sodium carbonate adds mouth;
22- liquid caustic soda adds mouth;23- mixing reactors;24- agitators;
25- plate and frame filter press;26- screw pumps;31- concentrates membrane stack;
41- dosing mouths;251- solids separate out 311- fresh water output ends;
312- sodium chloride strong brine output ends.
Specific embodiment
Below in conjunction with accompanying drawing, the invention will be further described.
Fig. 1 is that a kind of structure of sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit in the embodiment of the present invention is shown
It is intended to;As shown in figure 1, the present invention provides a kind of sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit, pipe is passed sequentially through
Waste water tank 1, regenerative agent conversion unit 2 and concentration reuse unit 3 that road connects, carbon is provided with regenerative agent conversion unit 2
Sour sodium adds mouth 21 and liquid caustic soda to add mouth 22.Wherein, it is sodium hydroxide solution that liquid caustic soda adds the liquid caustic soda added in mouth 22.
Add mouth 21 and liquid caustic soda to add mouth 22 by setting sodium carbonate on regenerative agent conversion unit 2, you can to sodium bed again
OH is successively introduced in raw waste liquid-And CO3 2-Ion, makes the divalent ion Ca in waste liquid2+、Mg2+Form aggregate, you can removal sodium
Divalent ion in bed regeneration liquid waste, realizes the process continuous of abraum salt water process, and realizes the zero-emission of sodium bed regeneration liquid waste
Put and cyclic regeneration.
In one embodiment, regenerative agent conversion unit 2 includes mixing reactor 23, and sodium carbonate adds mouth 21 and liquid caustic soda to add
Entrance 22 is respectively positioned on the top of mixing reactor 23, and mixing reactor 23 is internally provided with agitator 24.Agitator 24 can
Liquid agitation in mixing reactor 23 is uniform, waste liquid is fully contacted and is reacted with sodium carbonate and liquid caustic soda.
Specifically, the equation for being reacted in mixing reactor 23 is:
CaCl2+MgCl2+Na2CO3+ 2NaOH=CaCO3↓+Mg(OH)2↓+4NaCl
In the present embodiment, regenerative agent conversion unit 2 also include plate and frame filter press 25, plate and frame filter press 25 respectively with mix
Reactor 23 is connected with concentration reuse unit 3, solid is provided with plate and frame filter press 25 and separates out mouth 26.
In the present embodiment, it is in series with screw pump 26 on the pipeline between mixing reactor 23 and plate and frame filter press 25.
Turbid solution after being reacted in mixing reactor 23 is input in plate and frame filter press 25 by screw pump 26, is led to
Cross the press filtration of plate and frame filter press 25 carries out separation of solid and liquid by turbid solution, makes the solids of sedimentation such as calcium carbonate and magnesium hydroxide in turbid solution
Emitted from solid precipitation mouth 26 in the form of filter residue, and the press filtration clear liquid isolated is input into concentration by clear liquid pipeline
It is further processed in treatment for reuse unit 3.
In the present embodiment, pipe-line mixer 4 is in series with the pipeline between waste water tank 1 and regenerative agent conversion unit 2, is managed
Dosing mouth 41 is provided with road blender 4.By dosing mouth 41 to poly-aluminium (PAC) is added in pipe-line mixer 4, it is to high concentrtion
The purified treatment effect of water and low temperature and low turbidity water is particularly evident, can be not added with alkaline assistant or other flocculation aids.
In one embodiment, concentration reuse unit 3 includes concentration membrane stack 31, is respectively provided with concentration membrane stack 31 light
Water output end 311 and strong brine output end 312, fresh water output end 311 and sodium chloride strong brine output end 312 respectively with fresh-water tank
5 are connected with strong brine case 6.Wherein, concentration membrane stack 31 can select electrodialysis membrane stack.
In one embodiment, supercharging is in series with the pipeline being connected between concentration membrane stack 31 and regenerative agent conversion unit 2
Pump 7 and micro-filtration 8.Before micro-filtration 8 can carry out Ion transfer concentration in concentration reuse unit 3, to raw water
Filtration treatment is carried out, is prevented impurity from entering and is caused ionic membrane dirty stifled in concentration membrane stack 31.
Although by reference to preferred embodiment, invention has been described, is not departing from the situation of the scope of the present invention
Under, various improvement can be carried out to it and part therein can be replaced with equivalent.Especially, as long as in the absence of structure punching
Prominent, the every technical characteristic being previously mentioned in each embodiment can combine in any way.The invention is not limited in text
Disclosed in specific embodiment, but all technical schemes including falling within the scope of the appended claims.
Claims (7)
1. a kind of sodium bed regenerates high-salt wastewater recycling and zero discharge processing unit, it is characterised in that connect including passing sequentially through pipeline
Waste water tank (1), regenerative agent conversion unit (2) and concentration reuse unit (3) for connecing, on the regenerative agent conversion unit (2)
Being provided with sodium carbonate adds mouth (21) and liquid caustic soda to add mouth (22).
2. sodium bed according to claim 1 regenerates high-salt wastewater recycling and zero discharge processing unit, it is characterised in that described
Regenerative agent conversion unit (2) includes mixing reactor (23), and the sodium carbonate adds mouth (21) and the liquid caustic soda to add mouth (22)
It is respectively positioned on the top of the mixing reactor (23), the mixing reactor (23) is internally provided with agitator (24).
3. sodium bed according to claim 2 regenerates high-salt wastewater recycling and zero discharge processing unit, it is characterised in that described
Regenerative agent conversion unit (2) also include plate and frame filter press (25), the plate and frame filter press (25) respectively with the mixing reactor
(23) it is connected with the concentration reuse unit (3), solid is provided with the plate and frame filter press (25) and separates out mouth (251).
4. sodium bed according to claim 3 regenerates high-salt wastewater recycling and zero discharge processing unit, it is characterised in that described
Screw pump (26) is in series with pipeline between mixing reactor (23) and the plate and frame filter press (25).
5. the sodium bed according to any one in claim 2-4 regenerates high-salt wastewater recycling and zero discharge processing unit, its
It is characterised by, pipe-line mixer (4) is in series with the pipeline between the waste water tank (1) and the regenerative agent conversion unit (2),
Dosing mouth (41) is provided with the pipe-line mixer (4).
6. the sodium bed according to any one in claim 1-4 regenerates high-salt wastewater recycling and zero discharge processing unit, its
It is characterised by, the concentration reuse unit (3) includes concentration membrane stack (31), is respectively provided with concentration membrane stack (31) light
Water output end (311) and strong brine output end (312), the fresh water output end (311) and sodium chloride strong brine output end (312)
It is connected with the fresh-water tank (5) and strong brine case (6) respectively.
7. sodium bed according to claim 6 regenerates high-salt wastewater recycling and zero discharge processing unit, it is characterised in that described
Booster pump (7) and micro-filtration are in series with the pipeline being connected between concentration membrane stack (31) and the regenerative agent conversion unit (2)
(8)。
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CN201710345243.2A CN106927604A (en) | 2017-05-16 | 2017-05-16 | Sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit |
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CN201710345243.2A CN106927604A (en) | 2017-05-16 | 2017-05-16 | Sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit |
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Publication Number | Publication Date |
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Family
ID=59430436
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CN201710345243.2A Pending CN106927604A (en) | 2017-05-16 | 2017-05-16 | Sodium bed regeneration high-salt wastewater recycling and zero discharge processing unit |
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---|---|---|---|---|
US4207397A (en) * | 1978-09-15 | 1980-06-10 | Water Refining Company, Inc. | Method for recovering and treating brine from water softener regeneration |
US20110077144A1 (en) * | 2006-07-14 | 2011-03-31 | Rayne Dealership Corporation | Regeneration of ion exchange resin and recovery of regenerant solution |
CN103319042A (en) * | 2013-07-16 | 2013-09-25 | 北京倍杰特国际环境技术有限公司 | High-salt complex wastewater reuse and zero discharge integrated equipment and technology |
CN104478133A (en) * | 2014-09-05 | 2015-04-01 | 陕西省石油化工研究设计院 | Method and system for recycling regenerated waste liquid of sodium bed |
CN104628186A (en) * | 2015-01-30 | 2015-05-20 | 西安聚方环境科技有限公司 | Method for treating sodium ion exchanger regenerated waste liquor in wastewater zero emission process and recycling system |
CN105540974A (en) * | 2015-12-25 | 2016-05-04 | 东华工程科技股份有限公司 | Processing method of high-hardness wastewater generated by ion exchange regeneration in high-concentration salt water treatment system |
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JP2016198747A (en) * | 2015-04-14 | 2016-12-01 | 王子ホールディングス株式会社 | Method for regenerating ion exchange resin, method for treating paper mill waste water, apparatus for regenerating ion exchange resin and apparatus for treating paper mill waste water |
CN106396210A (en) * | 2016-12-06 | 2017-02-15 | 淄博格瑞水处理工程有限公司 | Anion/cation resin regeneration wastewater zero-discharge recycling device |
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2017
- 2017-05-16 CN CN201710345243.2A patent/CN106927604A/en active Pending
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---|---|---|---|---|
US4207397A (en) * | 1978-09-15 | 1980-06-10 | Water Refining Company, Inc. | Method for recovering and treating brine from water softener regeneration |
US20110077144A1 (en) * | 2006-07-14 | 2011-03-31 | Rayne Dealership Corporation | Regeneration of ion exchange resin and recovery of regenerant solution |
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