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CN106893379A - A kind of transparent flame-retarding coating - Google Patents

A kind of transparent flame-retarding coating Download PDF

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Publication number
CN106893379A
CN106893379A CN201710098731.8A CN201710098731A CN106893379A CN 106893379 A CN106893379 A CN 106893379A CN 201710098731 A CN201710098731 A CN 201710098731A CN 106893379 A CN106893379 A CN 106893379A
Authority
CN
China
Prior art keywords
parts
agent
transparent flame
retarding coating
thickener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710098731.8A
Other languages
Chinese (zh)
Inventor
韩小宁
裴志明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amgain Holdings Co Ltd
Shenyang Huajin Traffic Technology Co Ltd
Original Assignee
Amgain Holdings Co Ltd
Shenyang Huajin Traffic Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Amgain Holdings Co Ltd, Shenyang Huajin Traffic Technology Co Ltd filed Critical Amgain Holdings Co Ltd
Priority to CN201710098731.8A priority Critical patent/CN106893379A/en
Publication of CN106893379A publication Critical patent/CN106893379A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Fireproofing Substances (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of transparent flame-retarding coating, belong to fire proofing technical field.The invention includes carbon forming agent, adhesive, fire retardant, crosslinking agent, thickener, moistening flatting agent and deionized water, counts by weight, and the weight portion of each composition is respectively:18 22 parts of carbon forming agent, 38 42 parts of adhesive, 14 16 parts of fire retardant, 7.5 8.5 parts of crosslinking agent, 1.8 2.2 parts of thickener, 0.3 0.5 parts of moistening flatting agent, 14 16 parts of deionized water.A kind of transparent flame-retarding coating of the present invention is mainly used in motor vehicle seat set weaving face fabric surface, constituent is simple and environmentally friendly, the anti-flaming dope is fully transparent, aesthetics can be increased when fabric face is coated on, and the anti-flaming dope fire resistance is good, and oxygen index (OI) is significantly improved, the coating gain in weight of fabric face is reduced, smoke density is relatively low in combustion, the need for meeting use.

Description

A kind of transparent flame-retarding coating
Technical field
The invention belongs to fire proofing technical field, more particularly to a kind of transparent flame-retarding coating, motor-car seat is mainly used in Chair cover weaving face fabric surface.
Background technology
Anti-flaming dope is, for flammable substrates surface, can to reduce by the combustibility of painting material surface, and retardance fire is fast Speed spreads, and is used to improve by a kind of feature coating of painting material fire endurance.Chinese railroad industry standard TB/T3237-2010 is moved Car group is required with built-in material flame-retarded technology condition:The oxygen index (OI) of GB/T5454-1997 textile combustion performance tests needs More than 32% is reached, possesses combustibility in itself for the seat webbing weaving face fabric of motor-car, it is therefore desirable in seat webbing textile fabric Surface coats anti-flaming dope, because existing anti-flaming dope fire resistance is poor, in order to reach corresponding oxygen index (OI) performance requirement, Need to coat substantial amounts of anti-flaming dope on seat webbing weaving face fabric surface, increased the weightening of seat webbing weaving face fabric, also directly The weight of motor-car is increased, existing anti-flaming dope typically uses flour as carbon forming agent, therefore the anti-flaming dope being made It is nontransparent white and black, if anti-flaming dope to be directly coated on seat webbing weaving face fabric surface, influences U.S. of fabric Sight degree, thus by anti-flaming dope fabric face coating before, it is necessary to the need for according to use using suitable color stuffing general Anti-flaming dope is mixed colours, and existing anti-flaming dope smoke density in combustion process is heated is higher, it is difficult to meet GB/ Requirements of the T8323.2-2008 to smoke density, it is impossible to the need for meeting use.
The content of the invention
The technical problems to be solved by the invention are to overcome the above-mentioned deficiency in the presence of prior art, and provide a kind of group It is simple and environmentally friendly into composition, aesthetics can be increased when being coated on fabric face, and fire resistance is good, and oxygen index (OI) is obtained significantly Lifting, reduces the coating gain in weight of fabric face, in combustion the relatively low transparent flame-retarding coating of smoke density.
The present invention is for the solution technical scheme that is used of its technical problem:
A kind of transparent flame-retarding coating, it is comprising carbon forming agent, adhesive, fire retardant, crosslinking agent, thickener, moistening flatting agent and goes Ionized water, counts by weight, and the weight portion of each composition is respectively:It is carbon forming agent 18-22 parts, adhesive 38-42 parts, fire-retardant Agent 14-16 parts, crosslinking agent 7.5-8.5 parts, thickener 1.8-2.2 parts, moistening flatting agent 0.3-0.5 parts, deionized water 14-16 Part.
Further, the weight portion of each composition that the transparent flame-retarding coating is included is respectively:20 parts of carbon forming agent, adhesive 40 parts, 15 parts of fire retardant, 8 parts of crosslinking agent, 2 parts of thickener, 0.4 part of moistening flatting agent, 15 parts of deionized water.
Further, the carbon forming agent is silane resin.
Further, described adhesive is cationic acrylate, and fire retardant is phosphate, and crosslinking agent is end-blocking acedic acid Ester, thickener is methylhydroxypropylcellulose, and moistening flatting agent is Block polyoxyethylene-polyethenoxy ether.
The present invention compared with prior art, with advantages below and effect:
A kind of constituent of transparent flame-retarding coating of the present invention is simple and environmentally friendly, and fire resistance is good, and oxygen index (OI) is significantly improved, In the case where same fire resistance is reached, transparent flame-retarding coating of the present invention is far smaller than existing same in the coated weight of fabric face , in the coated weight of fabric face, and smoke density is relatively low in combustion for class anti-flaming dope, by using silane resin as Carbon forming agent, it can be ensured that the anti-flaming dope is fully transparent, when the anti-flaming dope is coated on fabric face, can avoid this fire-retardant Coating is covered fabric, and enabling increases aesthetics, and by carbon forming agent silane resin and fire retardant phosphate phase interworking Cooperation is used so that the transparent flame-retarding coating can quickly form layer of charcoal during heated combustion in fabric face, so as to prevent Fabric further burns, the need for meeting use.
Using silane resin as carbon forming agent, silane resin has flexible network structure to the present invention, in combustion heating Under the conditions of, the presence of network structure reduces the combustibility of material, and the growing amount of combustible also accordingly reduces, and prevents entering for material One step is burnt and is aoxidized, and under the high temperature conditions, remains to keep preferable mechanical property, and fire retardant phosphate and carbon forming agent silicon Alkane resin has flame retardant synergistic effect, and under the conditions of combustion heating, fire retardant phosphate facilitates the generation of layer of charcoal, carbon forming agent silane tree Fat increases the heat endurance of these layer of charcoal so that fire resistance is further enhanced.
A kind of transparent flame-retarding coating of the present invention is mainly used in motor vehicle seat set weaving face fabric surface, but range of application is not limited In this, it is also possible to be widely used in the multiple fields for having fire retardant performance requirement.
Specific embodiment
For the ease of understanding the present invention, the present invention enumerates that embodiment is as follows, and the embodiment can be made into one to the present invention The supplement of step and explanation, but the present invention is not limited to these embodiments.
Embodiment 1
The transparent flame-retarding coating of the present embodiment includes 20 parts of silane resin, 40 parts of cationic acrylate, 15 parts of phosphate, end-blocking 8 parts of acetonitrile acid esters, 2 parts of methylhydroxypropylcellulose, 0.4 part of Block polyoxyethylene-polyethenoxy ether, 15 parts of deionized water will Said components are uniformly mixed and made into transparent flame-retarding coating of the invention by weight.
Embodiment 2
The transparent flame-retarding coating of the present embodiment includes 18 parts of silane resin, 42 parts of cationic acrylate, 14 parts of phosphate, end-blocking 8.5 parts of acetonitrile acid esters, 1.8 parts of methylhydroxypropylcellulose, 0.5 part of Block polyoxyethylene-polyethenoxy ether, deionized water 14 Part, said components are uniformly mixed transparent flame-retarding coating of the invention by weight.
Embodiment 3
The transparent flame-retarding coating of the present embodiment includes 22 parts of silane resin, 38 parts of cationic acrylate, 16 parts of phosphate, end-blocking 7.5 parts of acetonitrile acid esters, 2.2 parts of methylhydroxypropylcellulose, 0.3 part of Block polyoxyethylene-polyethenoxy ether, deionized water 16 Part, said components are uniformly mixed transparent flame-retarding coating of the invention by weight.
Embodiment 4
The transparent flame-retarding coating of the present embodiment includes 18 parts of silane resin, 38 parts of cationic acrylate, 14 parts of phosphate, end-blocking 7.5 parts of acetonitrile acid esters, 1.8 parts of methylhydroxypropylcellulose, 0.3 part of Block polyoxyethylene-polyethenoxy ether, deionized water 14 Part, said components are uniformly mixed transparent flame-retarding coating of the invention by weight.
Embodiment 5
The transparent flame-retarding coating of the present embodiment includes 22 parts of silane resin, 42 parts of cationic acrylate, 16 parts of phosphate, end-blocking 8.5 parts of acetonitrile acid esters, 2.2 parts of methylhydroxypropylcellulose, 0.5 part of Block polyoxyethylene-polyethenoxy ether, deionized water 16 Part, said components are uniformly mixed transparent flame-retarding coating of the invention by weight.
The anti-flaming dope that embodiment 1- embodiments 5 are made is evenly applied into fabric face carries out fire resistance and smoke density Test, test result is as follows:
As can be seen from the above table, a kind of transparent flame-retarding coating of the invention, when fabric face coating gain in weight reaches 45g/ ㎡, knits The oxygen index (OI) of thing is 34%, and the oxygen index (OI) needs for meeting GB/T5454-1997 textile combustion performance tests reach more than 32% It is required that, needing to reach 85g/ ㎡ in fabric face coating gain in weight compared to existing anti-flaming dope, the oxygen index (OI) of fabric could reach To 32%, fire resistance of the invention will be far superior to the fire resistance of existing product, and burning smoke density of the invention meets The requirement of DS1.5min≤100 and DS4.0min≤200 in GB/T8323.2-2008, the need for meeting use.
Above content described in this specification is only illustration made for the present invention.Technology belonging to of the invention The technical staff in field can make various modifications or supplement to described specific embodiment or use similar mode Substitute, content without departing from description of the invention or surmount scope defined in the claims, this all should be belonged to The protection domain of invention.

Claims (4)

1. a kind of transparent flame-retarding coating, it is characterised in that:The transparent flame-retarding coating includes carbon forming agent, adhesive, fire retardant, friendship Connection agent, thickener, moistening flatting agent and deionized water, count by weight, and the weight portion of each composition is respectively:Carbon forming agent 18-22 parts, adhesive 38-42 parts, fire retardant 14-16 parts, crosslinking agent 7.5-8.5 parts, thickener 1.8-2.2 parts, soak levelling Agent 0.3-0.5 parts, deionized water 14-16 parts.
2. a kind of transparent flame-retarding coating according to claim 1, it is characterised in that:It is each that the transparent flame-retarding coating is included The weight portion of composition is respectively:20 parts of carbon forming agent, 40 parts of adhesive, 15 parts of fire retardant, 8 parts of crosslinking agent, 2 parts of thickener, wetting 0.4 part of levelling agent, 15 parts of deionized water.
3. a kind of transparent flame-retarding coating according to claim 2, it is characterised in that:The carbon forming agent is silane resin.
4. a kind of transparent flame-retarding coating according to claim 2, it is characterised in that:Described adhesive is cation acrylic Ester, fire retardant is phosphate, and crosslinking agent is end-blocking acetonitrile acid esters, and thickener is methylhydroxypropylcellulose, and moistening flatting agent is Block polyoxyethylene-polyethenoxy ether.
CN201710098731.8A 2017-02-23 2017-02-23 A kind of transparent flame-retarding coating Pending CN106893379A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710098731.8A CN106893379A (en) 2017-02-23 2017-02-23 A kind of transparent flame-retarding coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710098731.8A CN106893379A (en) 2017-02-23 2017-02-23 A kind of transparent flame-retarding coating

Publications (1)

Publication Number Publication Date
CN106893379A true CN106893379A (en) 2017-06-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710098731.8A Pending CN106893379A (en) 2017-02-23 2017-02-23 A kind of transparent flame-retarding coating

Country Status (1)

Country Link
CN (1) CN106893379A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1922252A (en) * 2004-02-18 2007-02-28 亨斯迈先进材料(瑞士)有限公司 Fire retardant compositions using siloxanes

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1922252A (en) * 2004-02-18 2007-02-28 亨斯迈先进材料(瑞士)有限公司 Fire retardant compositions using siloxanes

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Application publication date: 20170627