CN106865986A - A kind of brilliant just alabaster material and preparation method and application - Google Patents
A kind of brilliant just alabaster material and preparation method and application Download PDFInfo
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- CN106865986A CN106865986A CN201710077104.6A CN201710077104A CN106865986A CN 106865986 A CN106865986 A CN 106865986A CN 201710077104 A CN201710077104 A CN 201710077104A CN 106865986 A CN106865986 A CN 106865986A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
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Abstract
The present invention provides a kind of brilliant just alabaster material and preparation method and application, and brilliant just alabaster material includes following composition and its mass fraction：SiO250~54 parts, Al2O315~19 parts, Li20~0.5 part of O, K23.5~5.5 parts of O, Na21~2 part of O, 6~9 parts of CaO, 1.5~3 parts of MgO, 4~7 parts of ZnO, 8~10 parts of BaO, 0~2 part of SrO, 0~0.5 part of ZrO, V2O50~0.2 part, by raw material is blended, calcining, crush or polishing is formed, mix with moulded pottery not yet put in a kiln to bake and be fabricated to brilliant firm alabaster ceramic tile.Brilliant just alabaster ceramic tile of the invention has good satin texture, thoroughly hardness, sense, resistance to acids and bases, color emissivity.
Description
Technical field
The present invention relates to ceramic tile ornament materials manufacturing technology field, and in particular to a kind of brilliant just alabaster material and its preparation side
Method and application.
Background technology
The tile product of matte surface has in the market：The overglaze colors such as traditional Antique Imitation Tiles, wood grain tile, entire body sandstone ashlar brick
The glazed tile series of technique.The incrustation pattern of this kind of product, if without glaze layer protection, it is easy in use,
It is thin out because of abrasion, even lose pattern color.Meanwhile, such product is also not suitable for applying inkjet technology, so as to lead
Pattern pattern is caused not enough to enrich, fidelity is low.
The underglaze colour for occurring in the recent period, the tile product for protecting glaze have：The dumb light products, this kind of product such as disconnected light glaze, satin glaze
Inkjet technology can be applied, simulative material can be accomplished.Although having certain improvement in terms of the pattern protection of brick face,
But because its hardness is usually less than 5 grades of Mohs' hardness, its later stage processing characteristics is not ideal, is not suitable for most of occasion, spy
It is not the use functional requirement of the big outdoor occasion of flow of the people.
For the use function of tile product, the glossiness visual sense effect of tile product be important decorative art and
One of expressive force of decoration functions.The possible post-production of tile product, can give a stone multiaspect, a kind of various glossiness of material
Texture, the decoration expressive force of surface tactile sensation, this will be a direction of following tile product decorative art development.On current glaze
Although the ceramic tile of color technique may burn out the finished product of various luster degree in production, post-production is not applied for.
And current underglaze colour dumb light product, it is again simultaneous in the presence of being difficult in terms of luminosity, hardness, saturating sense, acid and alkali-resistance, color development, post-production
The defect of Gu.
The content of the invention
It is an object of the invention to provide a kind of brilliant just alabaster material and preparation method and application, with silica, three oxygen
Change two aluminium, calcium oxide, zinc oxide, potassium oxide, barium monoxide for primary raw material is prepared into brilliant just alabaster material, then with the material such as moulded pottery not yet put in a kiln to bake
Brilliant just alabaster ceramic tile is processed into, finished product has good luminosity, thoroughly hardness, sense, resistance to acids and bases, color emissivity.
To achieve these goals, the technical solution adopted by the present invention is as follows：
A kind of brilliant just alabaster material, including following composition and its mass fraction：SiO250~54 parts, Al2O315~19 parts,
Li20~0.5 part of O, K23.5~5.5 parts of O, Na21~2 part of O, 6~9 parts of CaO, 1.5~3 parts of MgO, 4~7 parts of ZnO,
8~10 parts of BaO, 0~2 part of SrO, 0~0.5 part of ZrO, V2O50~0.2 part.
According to above scheme, the composition of the brilliant just alabaster material respectively by following raw material be mixed into loss on ignition for 12%~
16% compound, obtains after calcining：
SiO2：Silica flour, potassium feldspar, calcined kaolin or kaolin
Al2O3：Alumina powder, calcined kaolin, kaolin or aluminium hydroxide
Li2O：Lithium carbonate, lepidolite, petalite or spodumene
K2O：Feldspar in powder, potash or potassium nitrate
Na2O：Sodium oxide molybdena
CaO：Calcite, lime stone, dolomite, wollastonite, gypsum
MgO：Dolomite or talcum powder
ZnO：Calcining zinc oxide, Zinc Oxide (raw oxide powder and zinc), smithsonite
BaO：Barium carbonate, barium sulfate or blanc fixe
SrO：Strontium carbonate
ZrO：Zirconium English powder
V2O5：Ammonium metavanadate.
A kind of preparation method of brilliant just alabaster material, comprises the following steps：
1) each raw material is weighed according to the target component of the brilliant just alabaster material, dry stirring is well mixed；
2) compound input high temperature Cinker clew furnace is melting into parent glass, direct water-cooling quenching turns into cullet pellet during discharging；
3) after cullet pellet is dried, dry pulverization process is simultaneously obtained pure dry granular, or be polished into 100~200 through the screening of 150 mesh sieves
Purpose fundamental particle is the dry granular of spherical shape, that is, obtain brilliant just alabaster material powder.
A kind of brilliant just alabaster ceramic tile, is processed with brilliant just alabaster material by moulded pottery not yet put in a kiln to bake through following steps：Moulded pottery not yet put in a kiln to bake slurrying or system
Powder；Press punch forming；Kiln is dried；Drench ground-coat enamel；Inkjet printing imitates natural patterns；Glaze line heat drying；Print protection glaze；Spray or
Drench brilliant just alabaster material slurry, or the brilliant just alabaster material dry powder of printing；Dried before kiln；Kiln is fired；Thrown after edging, or edging
Light.
According to above scheme, the moulded pottery not yet put in a kiln to bake includes following composition and its mass fraction：SiO266~69 parts, Al2O319~
21 parts, K22.8~3.5 parts of O, Na21.6~2.0 parts of O, 0.8~1.2 part of MgO, 0~0.4 part of CaO, loss on ignition be 4%~
5%.
According to above scheme, the brilliant just alabaster material slurry is the slurry suitable for glaze spraying, by brilliant just alabaster material powder
Material is mixed with the stirring of suspension stamp-pad ink；The brilliant just alabaster material dry powder is printing glaze, by brilliant just alabaster material powder with
Printing print cream stirring is mixed into.
According to above scheme, the firing time that the kiln is fired is 45~90min, and kiln is test with import firing ring
Firing temperature is 1165~1200 DEG C.
According to above scheme, the ground-coat enamel uses the ground-coat enamel cosmetic soil of following quality：Whiteness：80~90 degree, gloss after burning
Degree：4~8 degree, comprising composition and its mass fraction be：K2O：0~1 part, Na2O：2~3 parts, SiO2：55~60 parts, Al2O3：
26~31 parts, CaO：0.9~1.5 part, MgO：0.6~1.2 part, ZrO2：6~12 parts, loss on ignition is less than or equal to 3%.
According to above scheme, the protection glaze uses the matting glaze of following quality：Glossiness after burning：20~60 degree, bag
The composition and its mass fraction for containing be：K2O：2~4 parts, Na2O：1~3 part, SiO2：50~60 parts, Al2O3：10~15 parts, CaO：
6~11 parts, MgO：1~3 part, ZnO：2~7 parts, BaO：6~9 parts, loss on ignition is less than or equal to 10%.This layer protection glaze is centre
Layer, there is 2 functions：One is that pit when doing effect net product plays soiling protective effect, and two is that to meet some special
Colorant color development requirement, with according to color development requirement can be in interior adjustment in a big way.If not having the demand of these two aspects, it is possible to
Do not use, the brilliant slurry that just alabaster material powder and suspension stamp-pad ink are mixed directly is drenched or sprayed after ground-coat enamel, print pattern.
The beneficial effects of the invention are as follows：
1) glossiness after brilliant firm alabaster material of the invention burns till has wax visual experience between 8~15 degree, has and silk
The same gloss of silks and satins and feel；
2) sense is adapted to underglaze colour decoration to brilliant just alabaster material of the invention thoroughly, and high temperature once-firing fuses into one with porcelain base；
3) brilliant just alabaster ceramic tile surface Mohs' hardness of the invention, near or above six grades, meets or exceeds traditional porcelain without glaze
The hardness level of abrasive brick, and pattern very abundant, imitative natural material effect are true to nature, wherein the brilliant just alabaster material dry granular of printing
Technique can also do anti-skidding series of products, can be used for the outdoor locations such as square, corridor, supermarket, kitchen surface, and indoor wall ground
Face is decorated.
4) brilliant just alabaster ceramic tile acid and alkali resistance of the invention meets or higher than National Standard of the People's Republic of China GB/
The standard requirement of T4100-2006；
5) the protection glazed thickness of brilliant just alabaster ceramic tile of the invention is between 0.1~0.2mm, and natural luminosity is up to 12 when not polished
Degree left and right, can reach 29 degree, 55 degree, 75 degree, 95 degree of any ranks after polishing；It is a brick multiaspect of product, decoration uses function,
More more options and marvellous combination of decorations are provided.
6) the protection glaze layer of brilliant just alabaster ceramic tile of the invention can print, can spray (or pouring), can kinds of processes mixing use, can
Integrate the tile product for using function and decoration functions to develop anti-skidding, degerming, anion etc..
Specific embodiment
Technical scheme is illustrated with reference to embodiment.
Embodiment 1：
The present invention provides a kind of brilliant just alabaster material, including following composition and its mass fraction：SiO251 parts, Al2O318 parts,
Li20.2 part of O, K24.1 parts of O, Na21.2 parts of O, 6.8 parts of CaO, 2 parts of MgO, 6 parts of ZnO, 9.1 parts of BaO, 1.5 parts of SrO,
V2O50.1 part, preparation method comprises the following steps：
1) each raw material is weighed according to the target component of the brilliant just alabaster material, dry stirring is well mixed；
2) compound input high temperature Cinker clew furnace is melting into parent glass, direct water-cooling quenching turns into cullet pellet during discharging；
3) after cullet pellet is dried, dry pulverization process is simultaneously obtained pure dry granular through the screening of 150 mesh sieves, that is, obtain brilliant just alabaster material
Feed powder material.
Further, it is 12%~16% that the composition of the brilliant just alabaster material is mixed into loss on ignition by following raw material respectively
Compound, obtained after calcining：
SiO2：Silica flour, Al2O3：Alumina powder, Li2O：Lithium carbonate, K2O：Feldspar in powder, Na2O：Sodium oxide molybdena, CaO：Calcite,
MgO：Dolomite, ZnO：Calcining zinc oxide, BaO：Barium carbonate, SrO：Strontium carbonate, ZrO：Zirconium English powder, V2O5：Ammonium metavanadate.
The present invention also provides a kind of brilliant just alabaster ceramic tile, is processed through following steps with brilliant just alabaster material by moulded pottery not yet put in a kiln to bake：
Moulded pottery not yet put in a kiln to bake slurrying or powder processed；Press punch forming；Kiln is dried；Drench ground-coat enamel；Inkjet printing imitates natural patterns；Glaze line heat drying；
Print protection glaze；The brilliant just alabaster material slurry of spray；Dried before kiln；Kiln is fired；Edging.
Further, the moulded pottery not yet put in a kiln to bake includes following composition and its mass fraction：SiO267 parts, Al2O320 parts, K2O 3.0
Part, Na21.8 parts of O, 1.0 parts of MgO, 0.2 part of CaO, loss on ignition are 4%~5%；The brilliant just alabaster material slurry is applicable
In the slurry of glaze spraying, mixed by brilliant just alabaster material powder and the stirring of suspension stamp-pad ink.
Further, the firing time that the kiln is fired is 60min, and kiln import firing ring test firing temperature is
1175~1180 DEG C.
Further, the ground-coat enamel uses the ground-coat enamel cosmetic soil of following quality：Whiteness：80~90 degree, glossiness after burning：4
~8 degree, comprising composition and its mass fraction be：K2O：0.8 part, Na2O：2.5 parts, SiO2：58 parts, Al2O3：29 parts, CaO：
1.1 parts, MgO：0.9 part, ZrO2：9 parts, loss on ignition is less than or equal to 3%.
Further, the protection glaze uses the matting glaze of following quality：Glossiness after burning：40~50 degree, comprising
Composition and its mass fraction are：K2O：3 parts, Na2O：2 parts, SiO2：55 parts, Al2O3：14 parts, CaO：8 parts, MgO：2 parts, ZnO：5
Part, BaO：7 parts, loss on ignition is less than or equal to 10%.
Embodiment 2：
The present invention provides a kind of brilliant just alabaster material, including following composition and its mass fraction：SiO250 parts, Al2O319 parts,
Li20.5 part of O, K25.5 parts of O, Na22 parts of O, 7.3 parts of CaO, 3 parts of MgO, 4 parts of ZnO, 8 parts of BaO, 0.5 part of SrO,
V2O50.2 part, preparation method comprises the following steps：
1) each raw material is weighed according to the target component of the brilliant just alabaster material, dry stirring is well mixed；
2) compound input high temperature Cinker clew furnace is melting into parent glass, direct water-cooling quenching turns into cullet pellet during discharging；
3) after cullet pellet is dried, dry pulverization process is simultaneously obtained pure dry granular through the screening of 150 mesh sieves, that is, obtain brilliant just alabaster material
Feed powder material.
Further, it is 12%~16% that the composition of the brilliant just alabaster material is mixed into loss on ignition by following raw material respectively
Compound, obtained after calcining：
SiO2：Potassium feldspar, Al2O3：Calcined kaolin, Li2O：Lepidolite, K2O：Potash, Na2O：Sodium oxide molybdena, CaO：Lime stone,
MgO：Talcum powder, ZnO：Zinc Oxide, BaO：Barium sulfate, SrO：Strontium carbonate, ZrO：Zirconium English powder, V2O5：Ammonium metavanadate.
With embodiment 1, difference is not to be using the brilliant just alabaster material slurry of spray to the preparation method of brilliant just alabaster ceramic tile
Body, but use the brilliant just alabaster material dry powder of printing.
Embodiment 3：
The present invention provides a kind of brilliant just alabaster material, including following composition and its mass fraction：SiO254 parts, Al2O316 parts,
Li20.1 part of O, K23.5 parts of O, Na21 part of O, 6.7 parts of CaO, MgO1.5 parts, 7 parts of ZnO, 10 parts of BaO, 0.1 part of ZrO,
V2O50.1 part, preparation method comprises the following steps：
1) each raw material is weighed according to the target component of the brilliant just alabaster material, dry stirring is well mixed；
2) compound input high temperature Cinker clew furnace is melting into parent glass, direct water-cooling quenching turns into cullet pellet during discharging；
3) after cullet pellet is dried, the fundamental particle for being polished into 100~200 mesh is the dry granular of spherical shape, that is, obtain brilliant firm
Alabaster material powder.
Further, it is 12%~16% that the composition of the brilliant just alabaster material is mixed into loss on ignition by following raw material respectively
Compound, obtained after calcining：
SiO2：Kaolin, Al2O3：Aluminium hydroxide, Li2O：Spodumene, K2O：Potassium nitrate, Na2O：Sodium oxide molybdena, CaO：Wollastonite,
MgO：Talcum powder, ZnO：Smithsonite, BaO：Blanc fixe, ZrO：Zirconium English powder, V2O5：Ammonium metavanadate.
The preparation method of brilliant just alabaster ceramic tile is with embodiment 1.
To the crystalline substance of embodiment 1 to 3, just alabaster ceramic tile is sampled be analyzed respectively, and the index of quality is as follows：
1) brick shape：The adobe morphological data of -0.15~+0.45mm, it is generally flat；
2) product surface glossiness：Between 11 to 13 degree, a little do not seen visually between different ceramic tiles, but the data difference for detecting
Not；3) porcelain base surface transparent material thickness after burning：It is unglazed, transparent between 0.1~0.2mm, compare and be adapted to do lower crackle texture
Marble and have mould pattern half throwing brick, and 29 degree of gloss below plane sheen, dumb light product；
4) case hardness, 6 grades of Mohs' hardness and more than；
5) acidproof B grades, alkaline-resisting A grades of performance.
Material of the invention and methods and applications provide new material for the pigment fibre, decorative of tile product, functionalization
Material and technology mode.
Above example is only used to illustrative and not limiting technical scheme, although above-described embodiment enters to the present invention
Detailed description is gone, the person skilled of this area should be understood：The present invention can be modified or replaced on an equal basis, but
Any modification and local replacement for not departing from spirit and scope of the invention all should be covered in scope of the presently claimed invention.
Claims (9)
1. a kind of brilliant just alabaster material, it is characterised in that including following composition and its mass fraction：SiO250~54 parts, Al2O3
15~19 parts, Li20~0.5 part of O, K23.5~5.5 parts of O, Na21~2 part of O, 6~9 parts of CaO, 1.5~3 parts of MgO, ZnO
4~7 parts, 8~10 parts of BaO, 0~2 part of SrO, 0~0.5 part of ZrO, V2O50~0.2 part.
2. brilliant just alabaster material according to claim 1, it is characterised in that the composition of the brilliant just alabaster material respectively by
Following raw material is mixed into the compound that loss on ignition is 12%~16%, is obtained after calcining：
SiO2：Silica flour, potassium feldspar, calcined kaolin or kaolin
Al2O3：Alumina powder, calcined kaolin, kaolin or aluminium hydroxide
Li2O：Lithium carbonate, lepidolite, petalite or spodumene
K2O：Feldspar in powder, potash or potassium nitrate
Na2O：Sodium oxide molybdena
CaO：Calcite, lime stone, dolomite, wollastonite, gypsum
MgO：Dolomite or talcum powder
ZnO：Calcining zinc oxide, Zinc Oxide (raw oxide powder and zinc), smithsonite
BaO：Barium carbonate, barium sulfate or blanc fixe
SrO：Strontium carbonate
ZrO：Zirconium English powder
V2O5：Ammonium metavanadate.
3. a kind of preparation method of brilliant just alabaster material, it is characterised in that comprise the following steps：
1) each raw material is weighed according to the target component of the brilliant just alabaster material, dry stirring is well mixed；
2) compound input high temperature Cinker clew furnace is melting into parent glass, direct water-cooling quenching turns into cullet pellet during discharging；
3) after cullet pellet is dried, dry pulverization process is simultaneously obtained pure dry granular, or be polished into 100~200 through the screening of 150 mesh sieves
Purpose fundamental particle is the dry granular of spherical shape, that is, obtain brilliant just alabaster material powder.
4. a kind of brilliant just alabaster ceramic tile, it is characterised in that processed through following steps with brilliant firm alabaster material by moulded pottery not yet put in a kiln to bake：Moulded pottery not yet put in a kiln to bake
Slurrying or powder processed；Press punch forming；Kiln is dried；Drench ground-coat enamel；Inkjet printing imitates natural patterns；Glaze line heat drying；Print is protected
Shield glaze；Brilliant just alabaster material slurry is drenched in spray, or the brilliant just alabaster material dry powder of printing；Dried before kiln；Kiln is fired；Edging, or
Polished after edging.
5. ceramic tile according to claim 4, it is characterised in that the moulded pottery not yet put in a kiln to bake includes following composition and its mass fraction：SiO2
66~69 parts, Al2O319~21 parts, K22.8~3.5 parts of O, Na21.6~2.0 parts of O, 0.8~1.2 part of MgO, CaO 0~
0.4 part, loss on ignition is 4%~5%.
6. ceramic tile according to claim 4, it is characterised in that the brilliant just alabaster material slurry is the slurry suitable for glaze spraying
Material, is mixed by brilliant just alabaster material powder and the stirring of suspension stamp-pad ink；The brilliant just alabaster material dry powder is printing glaze, by
Brilliant just alabaster material powder is mixed with printing print cream stirring.
7. ceramic tile according to claim 4, it is characterised in that the firing time that the kiln is fired is 45~90min, kiln
The firing temperature that stove is test with import firing ring is 1165~1200 DEG C.
8. ceramic tile according to claim 4, it is characterised in that the ground-coat enamel using following quality ground-coat enamel cosmetic soil：In vain
Degree：80~90 degree, glossiness after burning：4~8 degree, comprising composition and its mass fraction be：K2O：0~1 part, Na2O：2~3 parts,
SiO2：55~60 parts, Al2O3：26~31 parts, CaO：0.9~1.5 part, MgO：0.6~1.2 part, ZrO2：6~12 parts, loss on ignition
Less than or equal to 3%.
9. ceramic tile according to claim 4, it is characterised in that the protection glaze using following quality matting glaze：Burn
Glossiness afterwards：20~60 degree, comprising composition and its mass fraction be：K2O：2~4 parts, Na2O：1~3 part, SiO2：50~60
Part, Al2O3：10~15 parts, CaO：6~11 parts, MgO：1~3 part, ZnO：2~7 parts, BaO：6~9 parts, loss on ignition is less than or equal to
10%.
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| CN113845357A (en) * | 2021-10-22 | 2021-12-28 | 新明珠集团股份有限公司 | Rock plate and preparation method thereof |
| CN114149246A (en) * | 2021-12-28 | 2022-03-08 | 四川美术学院 | Production method of ceramic with cosmetic clay decoration |
| CN115448756A (en) * | 2022-10-19 | 2022-12-09 | 江西新明珠建材有限公司 | Waxy glaze ceramic tile and preparation method thereof |
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