CN106835698B - Softener composition - Google Patents
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- CN106835698B CN106835698B CN201710078407.XA CN201710078407A CN106835698B CN 106835698 B CN106835698 B CN 106835698B CN 201710078407 A CN201710078407 A CN 201710078407A CN 106835698 B CN106835698 B CN 106835698B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/477—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having six-membered heterocyclic rings
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to a softener composition which comprises the following components in percentage by weight: 3-7% of quaternary ammonium salt active substance, 0.02-0.5% of cationic starch, 0.01-1.5% of thickening agent, 0-2% of additive and the balance of water; the cationic starch is prepared from starch and 2, 3-epoxypropyltrimethylammonium chloride, 3-chloro-2-hydroxypropyltrimethylammonium chloride, 3-chloro-2-hydroxypropyldimethyl-dodecylammonium chloride or 3-chloro-2-hydroxypropyldimethyl-octadecylammonium chloride. According to the softener composition, the cationic starch and the quaternary ammonium salt active substance are compounded, and the cationic starch is used in combination with the quaternary ammonium salt under the condition of a small addition amount (0.02-0.5% by weight of the composition), so that the fabric softening effect is superior to that of the single quaternary ammonium salt, and meanwhile, the greasy hand feeling caused by the quaternary ammonium salt with high saturation can be reduced to a certain extent, and more smooth experience is brought.
Description
Technical Field
the invention relates to the technical field of daily chemicals, in particular to a softener composition.
background
In the process of repeated use and repeated washing of the fabric, fibers, especially fine fibers in the fabric are often intertwined and intertwined together and even broken and fall off according to different materials and textile processes. The appearance of the fabric is influenced, the fabric becomes hard and rough, and the overall hand feeling is influenced. The fabric softener can form a cation protective film on the surface of fabric fibers, reduce fiber friction and make clothes soft and smooth.
The raw materials of the fabric softener are mainly quaternary ammonium salt cationic surfactants, and the cationic products are more, but the fabric softener can be really used for fabric softening and also can be quaternary ammonium salt products with double long chain groups, such as dioctadecyl dimethyl ammonium chloride (D1821), alkyl ester quaternary ammonium salt (TE), imidazoline quaternary ammonium salt (OM) and the like. The problem of low biodegradation of typical D1281 is a major factor limiting the development thereof. With the increasing environmental awareness, alkyl ester quaternary ammonium salts and imidazoline quaternary ammonium salts are becoming popular trends in the market. More and more manufacturers use it as a major ingredient in fabric softening. The compatibility, dispersibility, biodegradability, non-yellowing property and rewettability of the representative alkyl ester quaternary ammonium salt are all stronger than those of D1281, but the softness is different from that of D1281.
according to the invention, by combining the use condition of domestic market, the cationic starch with higher substitution degree and the specific quaternary ammonium salt are applied to the softener in a matching way, and more detailed research is carried out on the auxiliary softening effect of the softener. The cationic starch addition range is optimized and a better combination is preferred.
Patent CN200910242913.3 discloses a fabric care softener containing cationic polymer and quaternary ammonium salt, which only shows a structural formula of modified starch and does not describe the degree of substitution, starch source and other aspects in detail.
Patent 201510960094.1 discloses an environment-friendly fabric softener containing ester quaternary ammonium salt, thickener, etc. The cationic starch only contains esterquat cationic surfactant and is not compounded with cationic starch.
Disclosure of Invention
Based on this, the object of the present invention is to provide a softener composition.
The specific technical scheme is as follows:
A softener composition is characterized by comprising the following components in percentage by weight:
In some of these embodiments, the quaternary ammonium salt active is selected from:
a. Has the following chemical structural formula:
{R4-m-N+-[(CH2)n-Y-R1]m}A-
Wherein m is 1, 2, or 3;
n is 2 or 3;
R 1 is C12-C22 alkyl which is unsaturated or saturated, straight chain or branched chain, R is C1-C6 alkyl or hydroxyalkyl;
y is-COO-or-CONH-;
A - is selected from chloride, bromide, sulfate or methylsulfate;
b. Has the following chemical structural formula:
A - , R and R 1 are as defined above, R 2 is C1-C6 alkylene, G is O or-NR-, c. has the following chemical formula:
R 1, R 2 and a - are as defined above;
d. Has the following chemical structural formula:
R 1 and a - are as defined above;
e. Has the following chemical structural formula:
Wherein R 3 is selected from C1-C2 alkyl, R 4, R 5 and R 6 are respectively and independently selected from C1-C2 alkyl, CH 2 CH (COOC n H 2n-1) CH 3, CH 2 CH (COOC n H 2n) CH 3, CH (CH 2 COOC n H 2n-1) CH 3 or CH (CH 2 COOC n H 2n) CH 3, wherein n is less than or equal to 5 and less than or equal to 17, and A - is defined as above.
in some of these embodiments, the quaternary ammonium salt active is selected from: fatty acid diethyl hydroxyethyl methyl ammonium methosulfate, fatty acid diethyl dimethyl ammonium methosulfate or fatty acid isopropyl dimethyl ammonium methosulfate.
In some of these embodiments, the cationic starch is prepared from starch and 2, 3-epoxypropyltrimethylammonium chloride, 3-chloro-2-hydroxypropyltrimethylammonium chloride, 3-chloro-2-hydroxypropyldimethyl-dodecylammonium chloride, or 3-chloro-2-hydroxypropyldimethyl-octadecylammonium chloride.
In some of the embodiments, the cationic starch comprises 20-50 wt% of amylose.
In some of the embodiments, the cationic starch comprises 20-30 wt% of amylose.
In some of these embodiments, the cationic starch has the following properties: the degree of substitution is 0.07 to 0.5, and the viscosity of a 20wt% aqueous solution is 20 to 500 mPas.
In some of these embodiments, the cationic starch is one or more of starch hydroxypropyltrimethyl ammonium chloride, dimethyl stearyl hydroxypropylammonium chloride, or dimethyl dodecyl hydroxypropylammonium chloride.
In some of these embodiments, the starch is selected from one or more of tapioca starch, potato starch, sweet potato starch, corn starch, wheat starch, sago starch, waxy corn starch, or rice starch.
In some of these embodiments, the thickening agent is selected from one or more of cationic cellulose ethers, cationic guar, chitosan, polyacrylamide homopolymers, polyacrylamide copolymers, polyquaterniums, polyvinylamines, or polyethyleneimines.
In some embodiments, the additive is selected from one or more of silicone oil, essence, encapsulated essence, preservative, and pigment.
According to the softener composition, the cationic starch and the quaternary ammonium salt active substance are compounded, and the fabric softening capacity of single quaternary ammonium salt can be improved by matching with the quaternary ammonium salt under the condition of a small addition amount (0.05-0.5% by weight of the composition) of the cationic starch. Meanwhile, the smooth hand feeling of the fabric is considered, the greasy hand feeling caused by the quaternary ammonium salt with higher saturation is reduced to a certain extent, and more smooth hand feeling experience is brought.
Detailed Description
in order that the invention may be more fully understood, reference will now be made to the following description. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.
Examples 1 to 8
See tables 1 and 2.
TABLE 1
The quaternary ammonium salt active substance is ethyl dipalmitate hydroxyethyl methyl sulfate methyl amine;
The thickening agent is: acrylamide/acryloyloxyethyltrimethyl ammonium chloride copolymer;
The cationic starch is starch hydroxypropyl trimethyl ammonium chloride. The specific parameters are shown in Table 2.
TABLE 2
The softener compositions were formulated according to the raw material ratios in Table 1, according to methods well known to those skilled in the art.
Comparative example 1
The comparative example is a softener composition, the raw material ratio is the same as that of example 5, except that no cationic starch is added.
Comparative example 2
This comparative example is a softener composition having the same raw material ratio as in example 5, except that the degree of substitution in the cationic starch used therein is 0.03.
And (3) effect testing:
(1) The test cotton towel was washed with ordinary washing powder, and then prepared into 5% solutions with the softener compositions prepared in example 5, comparative example 1 and comparative example 2, respectively, and then soaked and dried.
(2) The softening effect of the clothes is detected, and the softening effect is evaluated in a way of comparing the touch of 50 groups of hands, wherein the highest softening effect is 5 points, and the lowest softening effect is 1 point. The slippery effect is best 5 points, and the lowest is 1 point.
Table 3 results of performance testing
| Evaluation index | Example 5 | Comparative example 1 | comparative example 2 |
| softening effect | 4.6 | 3.6 | 3.8 |
| Slippery feel | 3.7 | 2.9 | 3.1 |
From the test results, the fabric softener composition compounded by the cationic starch and the quaternary ammonium salt active agent has a softening effect superior to that of a single quaternary ammonium salt softening agent, and compared with the cationic starch with low substitution degree, the cationic starch has a better auxiliary softening effect.
Examples 9 to 13
the softener composition of this example has the same raw material ratio as example 5, but the quaternary ammonium salt active is different. See table 4 for details.
TABLE 4
The cationic starch is starch hydroxypropyl trimethyl ammonium chloride. The degree of substitution is 0.25, the viscosity of a 20wt% aqueous solution is 200mPa · s, the amylose content is 25 wt%;
Comparative examples 3 to 7
TABLE 5
And (3) testing the comparative performance:
TABLE 6
| Evaluation index | comparative example 3 | Example 9 | Comparative example 4 | Example 10 | Comparative example 5 |
| softening effect | 3.6 | 4.6 | 3.6 | 4.7 | 3.3 |
| Slippery feel | 2.9 | 3.8 | 2.8 | 3.6 | 2.6 |
TABLE 7
| Evaluation index | Example 11 | Comparative example 6 | Example 12 | Comparative example 7 | Example 13 |
| softening effect | 4.5 | 3.7 | 4.5 | 4.7 | 4.8 |
| Slippery feel | 3.2 | 2.8 | 3.4 | 3.7 | ]3.8 |
From the test results, the cationic starch of the invention can be compounded with quaternary ammonium salts such as dipalmitate ethyl hydroxyethyl methyl sulfate amine, dipalmitate ethyl dimethyl methyl ammonium sulfate and dipalmitate ethyl dimethyl ammonium methyl sulfate to obviously improve the fabric softening performance.
The compound also has a certain softening effect when being compounded with di (tallow ethyl amide) polyethoxy methyl ammonium methyl sulfate and 1-methyl-2-tallow-3-ethyl amide-imidazoline ammonium methyl sulfate.
Although dioctadecyldimethylammonium chloride (D1821) has superior flexibility, it is not easy to prepare a high-concentration product due to its poor biodegradability and antistatic property, and its production cost is high, and it is easily adsorbed by sludge to cause environmental pollution in sewage treatment, and it has been stopped in western european countries such as germany. D1821 is gradually replaced by the quaternary ammonium salt which is easy to biodegrade at home and abroad especially, and the alkyl ester quaternary ammonium salt (difatty ethyl hydroxyethyl methyl ammonium sulfate, difatty ethyl dimethyl ammonium methyl sulfate or difatty isopropyl dimethyl ammonium methyl sulfate) adopted by the invention has better compatibility, dispersibility, biodegradability, non-yellowing property and rewettability than D1281. According to the invention, the high-substitution cationic starch is compounded with the quaternary ammonium salt, so that the softening effect of the softener can be obviously improved, and the softness is close to that of D1281.
The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above-mentioned embodiments only express several embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (10)
1. The softener composition is characterized by comprising the following components in percentage by weight:
Quaternary ammonium salt active 3 ~ 7%
cationic starch 0.02 ~ 0.5.5%
thickener 0.01 ~ 1.5.5%
Additive 0 ~ 2%
The balance of water;
The cationic starch is prepared from starch and 2, 3-epoxypropyltrimethylammonium chloride, 3-chloro-2-hydroxypropyltrimethylammonium chloride, 3-chloro-2-hydroxypropyldimethyl-dodecylammonium chloride or 3-chloro-2-hydroxypropyldimethyl-octadecylammonium chloride, and has the following properties that the substitution degree is 0.15 ~ 0.3.3, the viscosity of 20wt% aqueous solution is 200 ~ 400 mPa & s, and the thickening agent is polyacrylamide copolymer;
The quaternary ammonium salt active is selected from: fatty acid diethyl hydroxyethyl methyl ammonium methosulfate, fatty acid diethyl dimethyl ammonium methosulfate or fatty acid isopropyl dimethyl ammonium methosulfate.
2. The softener composition of claim 1 wherein the cationic starch has the following properties: the degree of substitution was 0.15, and the viscosity of a 20wt% aqueous solution was 400 mPas.
3. the softener composition of claim 1 wherein the quaternary ammonium salt active is selected from the group consisting of: ethyl dipalmitate hydroxyethyl methyl ammonium methyl sulfate, ethyl dipalmitate dimethyl ammonium methyl sulfate.
4. The softener composition of claim 1 wherein the cationic starch comprises 20 ~ 50wt% amylose.
5. the softener composition of claim 4 wherein the cationic starch comprises 20 ~ 30wt% amylose.
6. The softener composition of claim 5 wherein the cationic starch comprises 25wt% amylose.
7. The softener composition of claim 1 wherein the cationic starch is starch hydroxypropyltrimonium chloride.
8. Softener composition according to any one of claims 1-7, characterized in that the starch is selected from one or more of tapioca starch, potato starch, sweet potato starch, corn starch, wheat starch, sago starch or rice starch.
9. The softener composition of any one of claims 1-7 wherein the thickener is an acrylamide/acryloyloxyethyltrimethyl ammonium chloride copolymer.
10. The softener composition of any one of claims 1 to 7, wherein the additive is selected from one or more of silicone oil, perfume, preservative and pigment.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108755114A (en) * | 2018-04-30 | 2018-11-06 | 安徽恒益纺织科技有限公司 | A kind of care agent for textile fabric |
| CN108914592A (en) * | 2018-07-02 | 2018-11-30 | 汪涛 | A kind of dacron afterfinish softening agent |
| CN113417142A (en) * | 2021-06-22 | 2021-09-21 | 杭州萧山凤凰纺织有限公司 | Antibacterial non-woven fabric and preparation method thereof |
| CN113980744A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color fixing softener and preparation method thereof |
| CN113980745A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color-locking care laundry detergent and preparation method thereof |
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| US7135451B2 (en) * | 2003-03-25 | 2006-11-14 | The Procter & Gamble Company | Fabric care compositions comprising cationic starch |
| CN101736580B (en) * | 2009-12-21 | 2013-08-14 | 北京绿泽宇和科技有限公司 | Fabric maintenance softener |
| KR102254335B1 (en) * | 2014-06-18 | 2021-05-24 | 로디아 오퍼레이션스 | Method of use of composition comprising a quaternary ammonium compound, a cationic polysaccharide and a nonionic polysaccharide |
| CN104193839B (en) * | 2014-09-05 | 2016-08-17 | 广州天赐高新材料股份有限公司 | Cationic starch and its preparation method and application |
| US20160244698A1 (en) * | 2015-02-20 | 2016-08-25 | The Procter & Gamble Company | Fabric care composition comprising metathesized unsaturated polyol esters |
| CN105421054A (en) * | 2015-12-16 | 2016-03-23 | 天津兰黛采妆环保科技开发有限公司 | Environment-friendly fabric softener |
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