CN106818808A - Pesticidal combination containing second azoles mite nitrile and diafenthiuron - Google Patents
Pesticidal combination containing second azoles mite nitrile and diafenthiuron Download PDFInfo
- Publication number
- CN106818808A CN106818808A CN201710080024.6A CN201710080024A CN106818808A CN 106818808 A CN106818808 A CN 106818808A CN 201710080024 A CN201710080024 A CN 201710080024A CN 106818808 A CN106818808 A CN 106818808A
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- China
- Prior art keywords
- diafenthiuron
- azoles mite
- pesticidal combination
- mite nitrile
- nitrile
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of second azoles mite nitrile and the Pesticidal combination of diafenthiuron, show by the screening of substantial amounts of toxicity and field control effectiveness test, the Pesticidal combination is 1 in compound proportion in second azoles mite nitrile and diafenthiuron:20‑20:Preventive effect when 1 to citrus red mite shows obvious synergistic function.Pesticidal combination prevention effect of the invention is good, consumption is low, to crop and beneficial natural enemies security, is worth the popularization and application in production.
Description
Technical field
The invention belongs to agricultural insecticide compositions field, and in particular to be a kind of mite nitrile of azoles containing second and diafenthiuron desinsection
Composition and application thereof.
Background technology
Mite class is commonly called as red spider, belongs to arachnoide pest, is various cause harm fruit tree, cotton, Solanaceae, vegetables and ornamental flower etc.
One of important pests of crop, belong to Acariformes and Acarina common evil mite more.Mite class mainly causes harm leaf, stem and the flower of plant
Deng, the cauline leaf for inhaling plant is pierced, there is the yellowish-brown dot of a large amount of needle point size chlorosis in initial stage leaf front, and anaphase blade is opened from the bottom up
Beginning chlorosis is crispaturaed, is even come off.Sometimes from plant middle part, blade takes place, and blade gradually turns yellow, comes off.Evil mite occurs from generation to generation
Many, fertility is strong, under suitable temperature and humidity conditions, mite population can be doubled and redoubled rapidly within a short period of time, to agriculture
Crop causes very big harm.Evil mite is also easy to produce the resistance to the action of a drug to mite killing medicament, if do not prevented and treated in time in serious generation, aggrieved work
The blade meeting chlorosis of thing is turned white, and is withered and fallen in advance.Under the torrid zone and greenhouse experiment, whole year can all occur.The height of temperature is determined
The number of the growth cycle, reproduction speed and egg laying amount of each worm state of mite class.It is big that the weather conditions of extreme arid torrid climate frequently can lead to its
Amount occurs.
The new acaricide of second Zuo Manjingshi China independent intellectual property right, Shenyang Sciencreat Chemicals Co., Ltd. develops
30% second azoles mite nitrile suspending agent product.Second azoles mite nitrile quite tires out such as panonychus citri, oranges and tangerines to phytophagous and embroiders mite, apple tetranychus, cotton
Tetranychid, eggplant tetranychid etc. show high activity, have preferable therapeutic effect to each period of acarid.
Diafenthiuron is a kind of new sulfur ureas efficient insecticide, acaricide, with tagging, stomach toxicity, interior suction and fumigation action, and
With certain ovicidal effect.It is changed into the material with insecticidal activity under ultraviolet light, to having produced serious anti-medicine on vegetables
Property insect have stronger activity.Aphid, aleyrodid, leafhopper, the noctuidae pests in various crop and ornamental plant can be prevented and treated
And evil mite.
Chemical prevention medicament should also need to the lasting period more long with quick-acting, and single medicament continuously uses appearance
Pest resistance to insecticide generation is easily caused, so that prevention effect declines substantially.Rational pest control with insecticide acaricide compounding or mixture have
Expansion prevents spectrum, improves prevention effect, extension optimum period for applying fertilizer, reduces dosage, reduce poisoning, reduce residual, delay insect resistance to
The positive feature such as the property of medicine and drug-fast generation and development, insecticidal/acaricidal agent compounding or mixture are having the most of solving the above problems
One of method of effect.Develop new product insecticide price constantly rises, and by contrast, exploitation is efficient with research, low toxicity, low-residual
Compounding there is small investment with mixture, the lead time is short and paid attention to both at home and abroad, numerous and confused increasing develops dynamics.
Present inventor is had found second azoles mite nitrile on the basis of the screening of a large amount of toxicities and field controling test
After diafenthiuron compounding, there is obvious synergistic effect to various crop pests, the present invention completed after further research,
The relevant report on second azoles mite nitrile and diafenthiuron are compounded is there is no at present.
The content of the invention
The invention aims to solve the deficiencies in the prior art, there is provided a kind of miticidal effect is good, evil mite resistance is low, property
The agricultural insecticide composition of matter stabilization, the Pesticidal combination active component includes second azoles mite nitrile and diafenthiuron, the desinsection group
Compound compounding has obvious synergistic effect.
Application another object of the present invention is to provide the Pesticidal combination, the Pesticidal combination is widely used in
The insect pests such as preventing and treating citrus red mite, European red mite, apple Tetranychus urticae, cotton red spider.
To achieve these goals, the present invention adopts the following technical scheme that scheme：
A kind of Pesticidal combination, its main active is second azoles mite nitrile and diafenthiuron, wherein, second azoles mite nitrile and diafenthiuron
Weight ratio is 1:20-20:1, preferably 1:10-5：1.
Further, the weight percentage of active component is 1-90%, preferably 8-60% in the Pesticidal combination.
Further, composition pesticide of the invention can be aided with auxiliary element conventional during the formulations of pesticide are processed and be prepared into
It is adapted to any one formulation for agriculturally using, including it is wettable powder, water dispersible granules, aqueous emulsion, microemulsion, missible oil, outstanding
Floating agent, suspension emulsion.
Further, described agricultural chemicals auxiliary element includes dispersant, wetting agent, emulsifying agent, antifreezing agent, defoamer, increasing
Thick dose, stabilizer, disintegrant, film forming agent, colouring agent, filler and solvent.
Further, the compound that composition pesticide of the invention can have desinsection, weeding, bactericidal property with other is mixed
Conjunction is used, also can be mixed with nematicide, fertilizer, plant growth regulator, nutrient for plants, soil conditioner or biostimulant
Conjunction is used.
The frequency of administration and usage amount of the present composition change and small variations with crops, insect, weather condition,
The purpose of effective preventing and treating can be reached by using appropriate dosage.
Each material is blended during Pesticidal combination of the invention can be directly prepared into finished product preparation form, i.e. composition,
It is directly used in mite killing；The composition of composition can also be provided by independent preparation, using preceding in bucket（Tank）In directly mix.The present invention
Concentrate the concentration of the active material is generally mixed to get with water.
Compared with prior art, agricultural insecticide composition of the invention has the beneficial effect that：（1）Insecticidal combinations of the invention
Active component second azoles mite nitrile and diafenthiuron are compounded in certain scope in thing, and the preventing and treating to various crop insect pest has significantly
Synergistic function, can reduce pesticide activity component usage amount, improve prevention effect；（2）In Pesticidal combination of the invention
The active component mechanism of action is different, and both can overcome and/or delay the drug-fast generation of pathogen compounding；（3）This hair
Bright Pesticidal combination is to crop safety, and environmental pollution is small.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.As described below is only the present invention preferably embodiment, is used only for explaining
The present invention, but can not be therefore understands that being the limitation to the scope of the claims of the present invention.It should be pointed out that it is all it is of the invention spirit and
Any modification, equivalent or improvement for being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be determined by the appended claims.
First, example of formulations
1st, embodiment 1:33% second azoles mite nitrile diafenthiuron suspension agent（1:10）
Second azoles mite nitrile 3%
Diafenthiuron 30%
Alkylbenzenesulfonate 6%
AEO 4%
Lauryl sodium sulfate 2%
Aluminium-magnesium silicate 3%
Silicone oil 1%
Formaldehyde 1%
Ethylene glycol 3%
Deionized water surplus
The preparation technology of the suspending agent is：First active compound is mixed, is then helped with wetting agent, dispersant, thickener, defoamer etc.
Agent and water are supplied to be well mixed and are prepared into mixed system, are ground 2 hours with sand mill after active compound is added, you can the present invention is obtained
Described suspending agent.
2nd, embodiment 2:24% second azoles mite nitrile diafenthiuron wettable powder（1:5）
Second azoles mite nitrile 4%
Diafenthiuron 20%
Sodium lignin sulfonate 4%
APES sulfate 5%
White carbon 10%
Precipitated calcium carbonate surplus
The preparation technology of the wettable powder is：Active ingredient and dispersant, wetting agent and filler are mixed by above-mentioned formula
Close, stirred in stirred tank, remixed after being crushed through airslide disintegrating mill uniform, you can wettable of the present invention is obtained
Pulvis.
3rd, embodiment 3:50% second azoles mite nitrile diafenthiuron water dispersible granule（1:1）
Second azoles mite nitrile 25%
Diafenthiuron 25%
NPE 5%
Alkyl sulfo succinate 7%
Dispersant MF -5 3%
Urea 4%
Polyvinylpyrrolidone 3%
Talcum powder surplus
The preparation technology of the water dispersible granules is：By above-mentioned formula by active ingredient and dispersant, wetting agent, disintegrant and
Filler is well mixed, and is crushed with micro jet, through mediating, be subsequently adding in fluidized-bed granulation dryer granulated,
Through sampling analysis after dry, screening, you can water dispersible granules of the present invention are obtained.
4th, embodiment 4:6% second azoles mite nitrile diafenthiuron microemulsion（5:1）
Second azoles mite nitrile 5%
Diafenthiuron 1%
Castor oil polyoxyethylene ether 5%
EO-PO block polyethers 4%
Ethylene glycol 3%
Ethyl acetate 5%
1-METHYLPYRROLIDONE 10%
Isopropanol 4%
Deionized water surplus
The preparation technology of the microemulsion is：Pesticide original medicine solvent, cosolvent are dissolved, emulsifying agent, antifreezing agent, steady is added
Determine other auxiliary elements such as agent, uniform mixing adds deionized water, micro emulsion of the present invention is can be prepared by after being sufficiently stirred for
Agent.
5th, embodiment 5:13% second azoles mite nitrile diafenthiuron emulsion in water（8:5）
Second azoles mite nitrile 8%
Diafenthiuron 5%
Solvent naphtha 18%
1- tetradecanols 7%
Polyoxyethylene fatty alcohol 3%
Di-2-ethylhexylphosphine oxide naphthalene sulfonate 4%
Castor oil polyoxyethylene ether 4%
Deionized water surplus
The preparation technology of the aqueous emulsion is：First pesticide original medicine, solvent, cosolvent and emulsifying agent are added together, it is dissolved
It is homogeneous oil phase；Then by part water, antifreeze etc., other auxiliary agents mix to form homogeneous aqueous phase；In a kettle. at a high speed
Oil phase is added into water phase while stirring, is slowly added water until reaching phase inversion point, opening cutter carries out high speed shear, and adds
Remaining water, shearing about half an hour, forms the aqueous emulsion of oil-in-water type, you can aqueous emulsion of the present invention is obtained.
2nd, Toxicity Determination
1st, controlling object：Citrus red mite；
2nd, test method：Experiment uses infusion process, second azoles mite nitrile and diafenthiuron mother liquor is made into different series concentrations, with clear
Water is control.Citrus leaf with red spider is taken back into interior, being cut into 3cm slide one end that is attached to long with two-sided tape chooses
The red spider that Individual Size is basically identical is selected, its back is pasted onto viscose glue with small writing brush, per slide 30, if 4 repetitions, first
Placed 4 hours under the conditions of moisturizing, spectroscopy is dissected with the bitubular, dead red spider chosen and is abandoned, then supply.Then will be stained with
The slide leaching of red spider is into the liquid to be shaken gently for, and is soaked and is taken out for 5 seconds or so, and the medicine of adhesive surface and surrounding is sucked with blotting paper
Liquid, often treatment is repeated 3 times.The survival number of each treatment red spider is checked within 24 hours after medicine, the death rate is calculated, least square method meter is used
Calculate virulence equation and lethal final concentration LC50, the toxicity index and mixed co-toxicity coefficient CTC of medicament are calculated according to the abundant methods of Sun Yun
Value.Result of the test is as shown in table 1.
Toxicity Determination result shows that second azoles mite nitrile and diafenthiuron are 1:20-20:Citrus red mite is prevented in the range of 1
Control and show synergistic function, wherein, it is 8 when both match:When 5, synergistic function is most obvious.
3rd, field control effectiveness test
In order to preferably verify practical application effect of the invention, preventing and treating oranges and tangerines are carried out using complex insecticidal composition of the invention
Red spider field control effectiveness test, is comparison medicament with 30% second azoles mite nitrile suspending agent and 25% diafenthiuron wettable powder.Using work
The type knapsack sprayer of agriculture -16 is sprayed, and insect population numbers were counted respectively at 7,14 days before medicine, after medicine and preventive effect is calculated, experiment knot
Fruit is as shown in table 2.
As shown in Table 2, the preventing and treating after second azoles mite nitrile and diafenthiuron are compounded to citrus red mite shows preferable lasting effect
And quick-acting, the composition pesticide preparation of embodiment 1-5 is 60 g.ai/hm in effective ingredient consumption2When to citrus red mite
Preventive effect more than 80%, wherein, the composite preparation prevention effect of embodiment 5 preferably, can substantially be prevented and treated for 14 days after medicine completely
The generation of citrus red mite.In addition, in scope of medication, do not it is found that composition pesticide of the invention has poisoning to produce oranges and tangerines crop
It is raw, the influence to beneficial natural enemy is not observed yet.
Claims (7)
1. a kind of Pesticidal combination, it is characterised in that active ingredient includes second azoles mite nitrile and diafenthiuron.
2. composition pesticide according to claim 1, it is characterised in that the weight ratio of the second azoles mite nitrile and diafenthiuron is
1:20-20:1。
3. composition pesticide according to claim 2, it is characterised in that the weight ratio of the second azoles mite nitrile and diafenthiuron is
1:10-5:1, more preferably 8：5.
4. the composition pesticide according to any one of claim 1-3 claim, it is characterised in that the pesticide combination
The auxiliary element that thing is aided with routine in formulations of pesticide processing is prepared into any one formulation for being adapted to agriculturally use.
5. composition pesticide according to claim 4, it is characterised in that the formulation be WP, water dispersible granules,
In aqueous emulsion, microemulsion, missible oil, suspending agent, suspension emulsion it is any in.
6. the composition pesticide according to claim 1-5 is used to prevent and treat the purposes of crop pests.
7. purposes according to claim 6, it is characterised in that the crop pests are evil mite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710080024.6A CN106818808A (en) | 2017-02-15 | 2017-02-15 | Pesticidal combination containing second azoles mite nitrile and diafenthiuron |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710080024.6A CN106818808A (en) | 2017-02-15 | 2017-02-15 | Pesticidal combination containing second azoles mite nitrile and diafenthiuron |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106818808A true CN106818808A (en) | 2017-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710080024.6A Pending CN106818808A (en) | 2017-02-15 | 2017-02-15 | Pesticidal combination containing second azoles mite nitrile and diafenthiuron |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108041061A (en) * | 2017-12-10 | 2018-05-18 | 广东中迅农科股份有限公司 | A kind of miticide composition containing diflubenzuron and second azoles mite nitrile |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1895046A (en) * | 2006-06-22 | 2007-01-17 | 深圳诺普信农化股份有限公司 | Insecticide composition containing butyether urea and bromoinsect-diazane |
| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
| CN104663704A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing ATP synthetase inhibitor acaricide |
-
2017
- 2017-02-15 CN CN201710080024.6A patent/CN106818808A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1895046A (en) * | 2006-06-22 | 2007-01-17 | 深圳诺普信农化股份有限公司 | Insecticide composition containing butyether urea and bromoinsect-diazane |
| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
| CN104663704A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing ATP synthetase inhibitor acaricide |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108041061A (en) * | 2017-12-10 | 2018-05-18 | 广东中迅农科股份有限公司 | A kind of miticide composition containing diflubenzuron and second azoles mite nitrile |
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Application publication date: 20170613 |
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