CN106804599A - A kind of bactericidal composition of novel pesticide - Google Patents
A kind of bactericidal composition of novel pesticide Download PDFInfo
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- CN106804599A CN106804599A CN201710029079.4A CN201710029079A CN106804599A CN 106804599 A CN106804599 A CN 106804599A CN 201710029079 A CN201710029079 A CN 201710029079A CN 106804599 A CN106804599 A CN 106804599A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
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Abstract
The invention discloses a kind of bactericidal composition of novel pesticide, its active ingredient includes compound a and at least one bactericide b, described compound a is to contain pyridyl pyrazoles acid amides female ring structure, described bactericide b is azoles mepanipyrim, amisulbrom, smart M 9834, benzene metsulfovax, chloronaphthalene pyrrole bacterium amine, Ben Sai Evil bacterium piperazines, biphenyl pyrrole bacterium amine or ring propionyl bacterium amine etc., compound a of the invention and existing conventional bactericide no interactions resistance, and with hypotoxicity, it is environment-friendly, use safety, wide sterilization spectrum, the advantage that drug effect is rapid and the duration is long, oranges and tangerines Penicillium notatum can be killed, Pear scab, the major part germ such as Puccinia recondita；The bactericidal composition of novel pesticide of the invention belongs to low-toxin farm chemicals, and the consumption to crop can play good bactericidal effect less, and the injury to crop is small, and noresidue, environmental safety is high.
Description
Technical field
The present invention relates to technical field of pesticide, the specifically bactericidal composition of novel pesticide.
Background technology
It is the important means for improving crop quality and yield to the preventing and treating of harmful bacteria in agricultural production, pathogenic bacteria can not only
Infringement plant growth, and the storage effect of crops in storage can be influenceed, so as to cause yield and Quality Down, cause cost
Waste；For non-agricultural, such as forestry, ornamental plant, storage food and fiber product, room and public health, preventing and treating is harmful to be caused
Germ is also and its necessary.
At present, a large amount of of bactericide use, and urging has made the generation of resistance, greatly reduces the prevention effect to harmful bacteria,
Therefore research, with different action sites, reduces interaction anti-to producing more effective, more economical, more low toxicity, environmentally safe close friend
Property disinfecting composition turn into current agricultural chemicals the task of top priority.
The content of the invention
To solve the above problems, it is an object of the invention to provide a kind of bactericidal composition of novel pesticide.
The present invention to achieve the above object, is achieved through the following technical solutions：
A kind of bactericidal composition of novel pesticide, its active ingredient includes that structural formula is the compound a of I and at least one bactericide b；
The structural formula of described compound a is as follows：
Structural formula I；
Described bactericide b is azoles mepanipyrim, amisulbrom, smart M 9834, benzene metsulfovax, chloronaphthalene pyrrole bacterium amine, benzene thiophene Evil bacterium
Piperazine, biphenyl pyrrole bacterium amine, ring propionyl bacterium amine, cyflufenamid, double chlorine zarilamid, fenhexamid, zarilamid, pyrazoles urethane, fluorine bacterium mite
Ester, flumorph, fluopicolide, fluopyram, fluorine thiazole bacterium nitrile, fluxapyroxad, iprovalicarb, thiophene acyl bacterium ketone, naphthalene pyrrole
Bacterium amine, isotianil, the mite that disappears are more, orysastrobin, Evil thiophene piperazine bacterium Ling, Evil imidazoles, penflufen-containing, pyrrole metsulfovax, the third oxygen quinoline azoles
It is quinoline, azoles amine bacterium ester, benzyl nalidixic bacterium ester, pyriminostrobin, benzene pyridine bacterium ketone, SYP-Z048, ring benzene pyrrole bacterium amine, Silthiopham, volution bacterium amine, different
Fourth ethoxyquin, trifluoro methoxy prestige, figured silk fabrics ammonia bacterium ester, fluorine ether bacterium acid amides, Boscalid, prothioconazoles, fluoxastrobin, the phonetic bacterium of fluorine
Amine, metrafenone, Metalaxyl-M, pyraclostrobin, figured silk fabrics bacterium amine, penta ring azoles, benomyl, bicarbonate, MBAMT, biphenyl triazole
Alcohol, bromuconazole, sulphur carboxylic fourth pyrimidine, difoltan, carboxin, ring propionyl bacterium amine, chloroneb, SYP-3375, cyazofamid, white urea
Cyanogen, cyproconazole, debacarb, Euparen, botran, olefin conversion, diphenylamines, Delan, dodine, ethoxyquinoline, Grandox fumigant,
Fenamidone, Fenarimol, RH-7592, fenfuram, zarilamid, butadiene morpholine, pyrazoles urethane, fervam, ferimzone, fluorine
Chlorine sclex, Flusilazole, flusulfamide, Flutriafol, phosethyl-Al, smart furalaxyl, hexaconazole, hymexazos, imazalil, imines
Azoles, iminoctadine, kind bacterium azoles, IBP, naphthalene pyrrole bacterium amine, Mancozeb, mandipropamid, mebenil, metconazole, benzene oxygen bacterium
Amine, midolthromycin, nitrothalisopropyl, octhilinone, oxycarboxin, pefurazoate, Pencycuron, Rabcide, pipron, Prochloraz, oxime
Bacterium ester or Tebuconazole.Preferably, bactericide b be flumorph, fluorine ether bacterium acid amides, fluopyram, Silthiopham, fluoxastrobin or
Benzyl nalidixic bacterium ester.
Preferably, content of the active ingredient in bactericidal composition is 0.001 ~ 99.999%.
Preferably, the mass ratio of compound a and bactericide b is 1 ~ 20：1~20.
It is further preferred that content of the active ingredient in bactericidal composition is 50%.
It is further preferred that the mass ratio of compound a and bactericide b is 1：1.
Preferably, formulation is the formulation of permission in agricultural production.
It is further preferred that formulation is suspending agent, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, suspension emulsion, missible oil, water
Agent, pulvis, water dispersible granules, granule, dry suspending agent, seed coat agent, suspension seed-coating agent, Seed Treatment emulsion, tablet, effervescent agent
Or fumigant.
It is further preferred that a kind of bactericidal composition of novel pesticide, formulation is wettable powder, in parts by weight, including
Following components：Compound a 40.0%, dimethomorph 10.0%, dodecyl phenol polyglycol ether 3.5%, sodium lignin sulfonate
4.0%, lagoriolite 5.5%, montmorillonite 2 5% and water 12%.
The present invention has advantages below compared to existing technology：
Compound a in composition of the invention contains pyridyl pyrazoles acid amides female ring structure, and the structure bactericidal effect is good, can use
In agricultural, forestry or the preventing and treating of sanitary insect pest, the especially compound can with it is existing it is bactericide compounded use, resist the property of medicine
Germ has good prevention effect；Compound a of the invention and existing conventional bactericide no interactions resistance, and with low
Toxicity, it is environment-friendly, using safety, wide sterilization spectrum, the advantage that drug effect is rapid and the duration is long, oranges and tangerines Penicillium notatum, pears can be killed
The major part germ such as black star bacterium, Puccinia recondita；The bactericidal composition of novel pesticide of the invention belongs to low-toxin farm chemicals, to crop
Consumption is few can to play good bactericidal effect, and the injury to crop is small, and noresidue, environmental safety is high；Two kinds of compounds
Compounding use also has synergistic function, is reduced when two kinds of consumptions of bactericide are than single use, so as to improve sterilization
Effect, increased security, reduce labour cost, reduce environmental pollution.
Specific embodiment
It is an object of the invention to provide a kind of bactericidal composition of novel pesticide, it is achieved through the following technical solutions：
A kind of bactericidal composition of novel pesticide, its active ingredient includes that structural formula is the compound a of I and at least one bactericide b；
The structural formula of described compound a is as follows：
Structural formula I；
Described bactericide b is azoles mepanipyrim, amisulbrom, smart M 9834, benzene metsulfovax, chloronaphthalene pyrrole bacterium amine, benzene thiophene Evil bacterium
Piperazine, biphenyl pyrrole bacterium amine, ring propionyl bacterium amine, cyflufenamid, double chlorine zarilamid, fenhexamid, zarilamid, pyrazoles urethane, fluorine bacterium mite
Ester, flumorph, fluopicolide, fluopyram, fluorine thiazole bacterium nitrile, fluxapyroxad, iprovalicarb, thiophene acyl bacterium ketone, naphthalene pyrrole
Bacterium amine, isotianil, the mite that disappears are more, orysastrobin, Evil thiophene piperazine bacterium Ling, Evil imidazoles, penflufen-containing, pyrrole metsulfovax, the third oxygen quinoline azoles
It is quinoline, azoles amine bacterium ester, benzyl nalidixic bacterium ester, pyriminostrobin, benzene pyridine bacterium ketone, SYP-Z048, ring benzene pyrrole bacterium amine, Silthiopham, volution bacterium amine, different
Fourth ethoxyquin, trifluoro methoxy prestige, figured silk fabrics ammonia bacterium ester, fluorine ether bacterium acid amides, Boscalid, prothioconazoles, fluoxastrobin, the phonetic bacterium of fluorine
Amine, metrafenone, Metalaxyl-M, pyraclostrobin, figured silk fabrics bacterium amine, penta ring azoles, benomyl, bicarbonate, MBAMT, biphenyl triazole
Alcohol, bromuconazole, sulphur carboxylic fourth pyrimidine, difoltan, carboxin, ring propionyl bacterium amine, chloroneb, SYP-3375, cyazofamid, white urea
Cyanogen, cyproconazole, debacarb, Euparen, botran, olefin conversion, diphenylamines, Delan, dodine, ethoxyquinoline, Grandox fumigant,
Fenamidone, Fenarimol, RH-7592, fenfuram, zarilamid, butadiene morpholine, pyrazoles urethane, fervam, ferimzone, fluorine
Chlorine sclex, Flusilazole, flusulfamide, Flutriafol, phosethyl-Al, smart furalaxyl, hexaconazole, hymexazos, imazalil, imines
Azoles, iminoctadine, kind bacterium azoles, IBP, naphthalene pyrrole bacterium amine, Mancozeb, mandipropamid, mebenil, metconazole, benzene oxygen bacterium
Amine, midolthromycin, nitrothalisopropyl, octhilinone, oxycarboxin, pefurazoate, Pencycuron, Rabcide, pipron, Prochloraz, oxime
Bacterium ester or Tebuconazole.Preferably, bactericide b be flumorph, fluorine ether bacterium acid amides, fluopyram, Silthiopham, fluoxastrobin or
Benzyl nalidixic bacterium ester.
Preferably, content of the active ingredient in bactericidal composition is 0.001 ~ 99.999%.
Preferably, the mass ratio of compound a and bactericide b is 1 ~ 20：1~20.
It is further preferred that content of the active ingredient in bactericidal composition is 50%.
It is further preferred that the mass ratio of compound a and bactericide b is 1：1.
Preferably, formulation is the formulation of permission in agricultural production.
It is further preferred that formulation is suspending agent, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, suspension emulsion, missible oil, water
Agent, pulvis, water dispersible granules, granule, dry suspending agent, seed coat agent, suspension seed-coating agent, Seed Treatment emulsion, tablet, effervescent agent
Or fumigant.
It is further preferred that a kind of bactericidal composition of novel pesticide, formulation is wettable powder, in parts by weight, including
Following components：Compound a 40.0%, dimethomorph 10.0%, dodecyl phenol polyglycol ether 3.5%, sodium lignin sulfonate
4.0%, lagoriolite 5.5%, montmorillonite 2 5% and water 12%.
Compound a is the compound shown in structural formula I in the embodiment of the present invention：
；
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of bactericidal composition of novel pesticide, formulation is suspending agent, in parts by weight, including following components：Compound a 10%,
Evil thiophene piperazine bacterium spirit 15%, butyl polyoxyethylene block copolymer 3.5%, ethylene glycol copolymer 1.0%, styrene acrylic is birdsed of the same feather flock together
Compound 1.5%, xanthans 0.2%, propane diols 5.0%, silica 0.1%, BIT 0.2% and water are mended
Sufficient surplus.
Embodiment 2
A kind of bactericidal composition of novel pesticide, formulation is suspending agent, in parts by weight, including following components：Compound a 10%,
Azoles mepanipyrim 20%, Flusilazole 3.5%, butyl polyoxyethylene copolymer 4.0%, styrene acrylic polmer 1.5%, xanthans
0.2%, propane diols 5.0%, silica 0.1%, BIT 0.2%, aromatic petroleum base hydrocarbon 20.0% and water
Supply surplus.
Embodiment 3
A kind of bactericidal composition of novel pesticide, formulation is microemulsion, in parts by weight, including following components：Compound a 1%, Yin
Azoles flusulfamide 4.0%, PVP-VA copolymer 35.0%, alkyl polyglycoside 30.0%, monoolein
18.0% and water supply surplus.
Embodiment 4
A kind of bactericidal composition of novel pesticide, formulation is wettable powder, in parts by weight, including following components：Compound a
40.0%, dimethomorph 10.0%, dodecyl phenol polyglycol ether 3.5%, sodium lignin sulfonate 4.0%, lagoriolite 5.5%,
Montmorillonite 2 5% and water 12%.
The synergy shown by two mixture of active principles can make these active components one or two
While amount of application declines, it is ensured that good prevention effect.There is certain lasting effect more than expected effect after application, so that
Be conducive to quickly killing harmful bacteria, improve the death rate.The reduction of active component amount of application, reduces the cost of agricultural producer,
And chemically reactive substance residual in the environment is reduced, environmental pressure is alleviated, foodsafety is improve.
The presence of cooperative effect between two kinds of active components is can determine that by means of Colby formula：
P=A+B-AB/100；
Using Colby methods, by being primarily based on be administered alone two kinds of activity of component, the prediction activity P of mixture is calculated,
The presence of cooperative interaction between to determine two kinds of active components.
In above-mentioned formula, A is that a kind of component being administered alone with amount of application x is lived with the biology that degree of preventing and treating percentage is represented
Property；B is the bioactivity that the second component applied with amount of application y is represented with degree of preventing and treating percentage.If their effect is strict
On see it is adduction, and in the absence of interaction, then the formula is applied with amount of application x the A's and B that is applied with amount of application y
The expected bioactivity of mixture calculates P.If the effect of the mixture set up in experiment exists more than expected activity, P
Synergistic function.
It is below biology test example, the content displaying tested composition of the invention is to specific harmful bacteria
Prevention effect.Prevention effect represents the suppression to harmful bacteria development, including harmful bacteria death.Those skilled in the art should
Solution, the harmful bacteria preventing and treating protection provided by the compound is not limited to these species.
Biology tests A
To evaluate the prevention effect to Powdery Mildew, using culture dish culture Powdery Mildew, pathogenic bacteria are applied active component or
Its composition, sets blank control test, observes prevention effect.
Test-compound and composition are prepared using the solution comprising nonionic surfactant.The compound of preparation and
Composition, in each test unit applied on top 1ml liquid, will test the growth feelings for observing mycelia in triplicate by sprayer
Condition evaluates drug effect.
The results are shown in Table 1 to calculate result average value in triplicate and general, and wherein compound a is applied with 0.1ppm dosage
With.
Prevention effect table of the table 1 to Powdery Mildew
* desired value is based on being calculated using Colby formula.
The preventing and treating effect that compound a and bactericide b are applied in combination can be seen that by the prevention effect to Powdery Mildew of table 1
Fruit is more than desired value, may infer that composition has synergistic function.
Biological test B
To evaluate the prevention effect to late disease bacteria, using culture dish culture late disease bacteria, pathogenic bacteria are applied active ingredient or
Its composition, sets blank control test, observes prevention effect.
Test-compound and composition are prepared using the solution comprising nonionic surfactant.The compound of preparation and
Composition, in each test unit applied on top 1ml liquid, experiment is repeated 3 times by sprayer, observes mycelial growth situation
Evaluate drug effect.
The results are shown in Table 1 to calculate result average value in triplicate and general, and wherein compound a is applied with 0.1ppm dosage
With.
Prevention effect table of the table 2 to late disease bacteria
* desired value is based on being calculated using Colby formula.
The preventing and treating effect that compound a and bactericide b are applied in combination can be seen that by the prevention effect to late disease bacteria of table 2
Fruit is more than desired value, may infer that composition has synergistic function.
Field conditions are increasingly complex than laboratory environment, of the invention group of the content displaying of following field tests test
Prevention effect of the compound to specific harmful bacteria.Prevention effect represent to harmful bacteria development suppression, including harmful bacteria death,
Also, harmful bacteria preventing and treating protection provided by the present invention is not limited to these species.
To evaluate the prevention effect of compound a and fluorine ether bacterium acid amides to cucumber downy mildew, in cucumber downy mildew early period of origination,
Compound a and fluorine ether bacterium acid amides are configured to suspending agent, converting into liquid point cell according to different dosages is uniformly sprayed at Huang
Drug effect is observed on melon blade on time to be counted, test of pesticide effectiveness result is as shown in table 3.
The prevention effect table of the compound a of table 3 and fluorine ether bacterium acid amides to cucumber downy mildew
Compound a and fluorine ether bacterium acyl are can be seen that to the prevention effect of cucumber downy mildew by the compound a of table 3 and fluorine ether bacterium acid amides
Significantly better than the effect that compound a and fluorine ether bacterium acid amides are used alone, both can produce bright the prevention effect that amine is applied in combination
Aobvious synergistic function.
To evaluate the prevention effect of compound a and dimethomorph to downy mildew of garpe, in downy mildew of garpe early period of origination, will
Compound a and dimethomorph are configured to suspending agent, and converting into liquid point cell according to different dosages is uniformly sprayed at grape leaf
Drug effect is observed on piece on time to be counted, test of pesticide effectiveness result is as shown in table 4.
The prevention effect table of the compound a of table 4 and dimethomorph to downy mildew of garpe
Compound a and dimethomorph group are can be seen that to the prevention effect of downy mildew of garpe by the compound a of table 4 and dimethomorph
Significantly better than the effect that compound a and dimethomorph are used alone, both can produce obvious association to the prevention effect that conjunction is used
Same synergistic effect.
Claims (9)
1. a kind of bactericidal composition of novel pesticide, it is characterised in that：Its active ingredient includes that structural formula is the compound a and extremely of I
A kind of few bactericide b；
The structural formula of described compound a is as follows：
Described bactericide b is azoles mepanipyrim, amisulbrom, smart M 9834, benzene metsulfovax, chloronaphthalene pyrrole bacterium amine, benzene thiophene Evil bacterium
Piperazine, biphenyl pyrrole bacterium amine, ring propionyl bacterium amine, cyflufenamid, double chlorine zarilamid, fenhexamid, zarilamid, pyrazoles urethane, fluorine bacterium mite
Ester, flumorph, fluopicolide, fluopyram, fluorine thiazole bacterium nitrile, fluxapyroxad, iprovalicarb, thiophene acyl bacterium ketone, naphthalene pyrrole
Bacterium amine, isotianil, the mite that disappears are more, orysastrobin, Evil thiophene piperazine bacterium Ling, Evil imidazoles, penflufen-containing, pyrrole metsulfovax, the third oxygen quinoline azoles
It is quinoline, azoles amine bacterium ester, benzyl nalidixic bacterium ester, pyriminostrobin, benzene pyridine bacterium ketone, SYP-Z048, ring benzene pyrrole bacterium amine, Silthiopham, volution bacterium amine, different
Fourth ethoxyquin, trifluoro methoxy prestige, figured silk fabrics ammonia bacterium ester, fluorine ether bacterium acid amides, Boscalid, prothioconazoles, fluoxastrobin, the phonetic bacterium of fluorine
Amine, metrafenone, Metalaxyl-M, pyraclostrobin, figured silk fabrics bacterium amine, penta ring azoles, benomyl, bicarbonate, MBAMT, biphenyl triazole
Alcohol, bromuconazole, sulphur carboxylic fourth pyrimidine, difoltan, carboxin, ring propionyl bacterium amine, chloroneb, SYP-3375, cyazofamid, white urea
Cyanogen, cyproconazole, debacarb, Euparen, botran, olefin conversion, diphenylamines, Delan, dodine, ethoxyquinoline, Grandox fumigant,
Fenamidone, Fenarimol, RH-7592, fenfuram, zarilamid, butadiene morpholine, pyrazoles urethane, fervam, ferimzone, fluorine
Chlorine sclex, Flusilazole, flusulfamide, Flutriafol, phosethyl-Al, smart furalaxyl, hexaconazole, hymexazos, imazalil, imines
Azoles, iminoctadine, kind bacterium azoles, IBP, naphthalene pyrrole bacterium amine, Mancozeb, mandipropamid, mebenil, metconazole, benzene oxygen bacterium
Amine, midolthromycin, nitrothalisopropyl, octhilinone, oxycarboxin, pefurazoate, Pencycuron, Rabcide, pipron, Prochloraz, oxime
Bacterium ester or Tebuconazole.
2. the bactericidal composition of novel pesticide according to claim 1, it is characterised in that：Described bactericide b be flumorph,
Fluorine ether bacterium acid amides, fluopyram, Silthiopham, fluoxastrobin or benzyl nalidixic bacterium ester.
3. the bactericidal composition of novel pesticide according to claim 1, it is characterised in that：Described active ingredient is at sterilized group
Content in compound is 0.001 ~ 99.999%.
4. the bactericidal composition of novel pesticide according to claim 1, it is characterised in that：The quality of compound a and bactericide b
Than being 1 ~ 20：1~20.
5. the bactericidal composition of novel pesticide according to claim 3, it is characterised in that：Described active ingredient is at sterilized group
Content in compound is 50%.
6. the bactericidal composition of novel pesticide according to claim 4, it is characterised in that：The quality of compound a and bactericide b
Than being 1：1.
7. the bactericidal composition of novel pesticide according to claim 1, it is characterised in that：Its formulation is permission in agricultural production
Formulation.
8. the bactericidal composition of novel pesticide according to claim 7, it is characterised in that：Described formulation is suspending agent, micro-
Capsule suspending agent, microcapsule suspension-suspendinagent agent, suspension emulsion, missible oil, aqua, pulvis, water dispersible granules, granule, dry suspending agent, kind
Clothing agent, suspension seed-coating agent, Seed Treatment emulsion, tablet, effervescent agent or fumigant.
9. the bactericidal composition of novel pesticide according to claim 1, it is characterised in that：A kind of Bactericidal composite of novel pesticide
Thing, formulation is wettable powder, in parts by weight, including following components：Compound a 40.0%, dimethomorph 10.0%, 12
Alkyl phenol polyethylene glycol ethers 3.5%, sodium lignin sulfonate 4.0%, lagoriolite 5.5%, montmorillonite 2 5% and water 12%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710029079.4A CN106804599A (en) | 2017-01-16 | 2017-01-16 | A kind of bactericidal composition of novel pesticide |
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| CN201710029079.4A CN106804599A (en) | 2017-01-16 | 2017-01-16 | A kind of bactericidal composition of novel pesticide |
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| CN106804599A true CN106804599A (en) | 2017-06-09 |
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| CN201710029079.4A Pending CN106804599A (en) | 2017-01-16 | 2017-01-16 | A kind of bactericidal composition of novel pesticide |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100391338C (en) * | 2001-08-13 | 2008-06-04 | 纳幕尔杜邦公司 | Arthropodicidal anthranilamides |
| CN104003976A (en) * | 2014-05-07 | 2014-08-27 | 肇庆市真格生物科技有限公司 | Polysubstituted pyridyl pyrazole amide and its preparation method and use |
| CN104031027A (en) * | 2014-05-14 | 2014-09-10 | 山东省联合农药工业有限公司 | Pyrazole-ring-containing pesticide for plants |
-
2017
- 2017-01-16 CN CN201710029079.4A patent/CN106804599A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100391338C (en) * | 2001-08-13 | 2008-06-04 | 纳幕尔杜邦公司 | Arthropodicidal anthranilamides |
| CN104003976A (en) * | 2014-05-07 | 2014-08-27 | 肇庆市真格生物科技有限公司 | Polysubstituted pyridyl pyrazole amide and its preparation method and use |
| CN104031027A (en) * | 2014-05-14 | 2014-09-10 | 山东省联合农药工业有限公司 | Pyrazole-ring-containing pesticide for plants |
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