CN106753881A - One kind removal stain laundry composition - Google Patents
One kind removal stain laundry composition Download PDFInfo
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- CN106753881A CN106753881A CN201610953099.6A CN201610953099A CN106753881A CN 106753881 A CN106753881 A CN 106753881A CN 201610953099 A CN201610953099 A CN 201610953099A CN 106753881 A CN106753881 A CN 106753881A
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- parts
- glossy privet
- ethanol
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- vinasse
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- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 241000830535 Ligustrum lucidum Species 0.000 claims abstract description 98
- 240000006108 Allium ampeloprasum Species 0.000 claims abstract description 46
- 235000005254 Allium ampeloprasum Nutrition 0.000 claims abstract description 46
- 239000006286 aqueous extract Substances 0.000 claims abstract description 37
- 235000006886 Zingiber officinale Nutrition 0.000 claims abstract description 17
- 235000008397 ginger Nutrition 0.000 claims abstract description 17
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 17
- 239000000341 volatile oil Substances 0.000 claims abstract description 17
- 230000001954 sterilising effect Effects 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 132
- 239000000047 product Substances 0.000 claims description 83
- 239000004365 Protease Substances 0.000 claims description 67
- 239000011347 resin Substances 0.000 claims description 61
- 229920005989 resin Polymers 0.000 claims description 61
- 238000000605 extraction Methods 0.000 claims description 49
- 102000004190 Enzymes Human genes 0.000 claims description 47
- 108090000790 Enzymes Proteins 0.000 claims description 47
- 108091005804 Peptidases Proteins 0.000 claims description 47
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 47
- 229940088598 enzyme Drugs 0.000 claims description 47
- 235000019419 proteases Nutrition 0.000 claims description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- 238000002360 preparation method Methods 0.000 claims description 31
- 239000000287 crude extract Substances 0.000 claims description 30
- 239000012153 distilled water Substances 0.000 claims description 30
- 239000000796 flavoring agent Substances 0.000 claims description 30
- 235000019634 flavors Nutrition 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 28
- 239000004382 Amylase Substances 0.000 claims description 27
- 102000013142 Amylases Human genes 0.000 claims description 27
- 108010065511 Amylases Proteins 0.000 claims description 27
- 235000019418 amylase Nutrition 0.000 claims description 27
- 239000000284 extract Substances 0.000 claims description 25
- 239000004094 surface-active agent Substances 0.000 claims description 25
- 239000000843 powder Substances 0.000 claims description 21
- 108090000526 Papain Proteins 0.000 claims description 20
- 239000000706 filtrate Substances 0.000 claims description 20
- 235000019834 papain Nutrition 0.000 claims description 20
- 229940055729 papain Drugs 0.000 claims description 20
- 241000234314 Zingiber Species 0.000 claims description 16
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 13
- 238000005119 centrifugation Methods 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 11
- 230000007071 enzymatic hydrolysis Effects 0.000 claims description 10
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 claims description 10
- 230000007062 hydrolysis Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 10
- 238000001471 micro-filtration Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 230000010355 oscillation Effects 0.000 claims description 10
- 238000002390 rotary evaporation Methods 0.000 claims description 10
- 238000007873 sieving Methods 0.000 claims description 10
- 238000001179 sorption measurement Methods 0.000 claims description 10
- 238000000967 suction filtration Methods 0.000 claims description 10
- 239000006228 supernatant Substances 0.000 claims description 10
- 239000012528 membrane Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 238000002386 leaching Methods 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 abstract description 6
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 230000000975 bioactive effect Effects 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 230000003115 biocidal effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000004615 ingredient Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 231100000419 toxicity Toxicity 0.000 abstract description 4
- 230000001988 toxicity Effects 0.000 abstract description 4
- 239000003205 fragrance Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 244000273928 Zingiber officinale Species 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 16
- 239000000463 material Substances 0.000 description 11
- 238000005374 membrane filtration Methods 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 8
- 241000894006 Bacteria Species 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 210000004027 cell Anatomy 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 230000002503 metabolic effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 244000000383 Allium odorum Species 0.000 description 1
- 235000018645 Allium odorum Nutrition 0.000 description 1
- 206010053759 Growth retardation Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 231100000001 growth retardation Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- -1 hydroxylmethyl Chemical group 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000013642 negative control Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 210000003463 organelle Anatomy 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- XUIMIQQOPSSXEZ-RNFDNDRNSA-N silicon-32 atom Chemical group [32Si] XUIMIQQOPSSXEZ-RNFDNDRNSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
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- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
Abstract
It is an object of the invention to provide one kind removal stain laundry composition, with nano silicon, nano zine oxide and natural plant composition as primary raw material, contain abundant bioactive ingredients in extracting product, leek enzymolysis product, vinasse aqueous extract by ginger essential oil, glossy privet, reach the degerming effect of Synergistic antibacterial, with natural plant fragrance, with the most of laundry composition sterilizing ability for solving the problems, such as existing production it is poor, durable antibiotic is poor, have certain toxicity.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, and in particular to one kind removal stain laundry composition.
Background technology
With the development and the increasingly raising of human living standard of science and technology, people increasingly pay attention to health, and in the market is existing
Some liquid detergents are all one-side sterilized or antibacterial actions, and sterilizing ability is poor, there is certain toxicity, stimulates skin, pollutes environment,
Consumer cannot be met to liquid detergent strong disinfecting, durable antibiotic, the demand of gentle environmental protection.
Nano material is that particle diameter is accomplished into nano level simple substance, and nanometer materials are to staphylococcus aureus, Escherichia coli
There is strong suppression and killing action etc. tens of kinds of pathogenic microorganisms, have good bactericidal effect under low concentration, and
It is harmless, and it is widely used in medicine equipment, textile, household electrical appliances, infant's product etc..
The content of the invention
It is an object of the invention to provide one kind removal stain laundry composition, with nano silicon, nano oxygen
It is primary raw material to change zinc and natural plant composition, and product, leek enzymolysis product, vinasse water extraction are extracted by ginger essential oil, glossy privet
Take in liquid containing abundant bioactive ingredients, reach the degerming effect of Synergistic antibacterial, with natural plant fragrance, to solve
Most of laundry composition sterilizing ability of certainly existing production is poor, durable antibiotic is poor, have the problem of certain toxicity.
The present invention is that, by the following technical programs to realize above-mentioned purpose, one kind removes stain laundry composition, by
The component composition of following parts by weight meter：11-17 parts of shitosan amphoteric polymeric surfactant, nano silicon 26-
37 parts, sodium cellulose glycolate 7-11 parts, enzyme 0.2-0.7 parts, nano zine oxide 1-3 parts, ginger essential oil 1-5 parts, glossy privet
Extract 4-9 parts of product, 12-18 parts of leek enzymolysis product, 27-43 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the removal stain laundry composition is made up of the component of following percentage by weight meter：Shell gathers
Sugared amphoteric polymeric surfactant 13-16 parts, nano silicon 29-34 parts, sodium cellulose glycolate 8-9 parts, enzyme
0.3-0.5 parts, nano zine oxide 1-2 parts, ginger essential oil 2-3 parts, glossy privet extract 5-8 parts of product, leek enzymolysis product 13-
15 parts, 32-38 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Particularly, the particle diameter of the nano silicon is 50-80nm, and the particle diameter of nano zine oxide is 90-110nm.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=10-22.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
The preparation method of present invention removal stain laundry composition, comprises the following steps：Shell is added toward softened water
Glycan amphoteric polymeric surfactant and nano silicon, stir, and add nano zine oxide, hydroxylmethyl cellulose
Plain sodium, enzyme, ginger essential oil, stir, and are eventually adding glossy privet and extract product, vinasse aqueous extract, the stirring of leek enzymolysis product
It is uniform.
Present invention removal stain laundry composition is with shitosan amphoteric polymeric surfactant and nanometer titanium dioxide
Silicon is aided with nano zine oxide as primary surfactant, then coordinates the composition of amylase and protease, can quickly with fabric on
Spot work and by its effective removal, while each component is cooperateed with, stable system can extend the shelf-life of product.
In the present invention, vinasse aqueous extract, glossy privet extract product, in leek enzymolysis product rich in natural bioactive into
Point, by these bioactive ingredients by synergistic function, while can be by each component especially nano silicon
Synergistic, act on the cell membrane and cell film system of pathogenic bacteria, destroy depend on membrane structure integrality directly and rapidly
Energetic supersession and the selective permeability to material depended on for existence of cell and organelle, make nutriment and metabolite without
Method makes microorganism lose nutrition and causes its growth retardation normally through cell membrane, reaches the purpose of restraining and sterilizing bacteria；Or pass through
Suppress the respiration of pathogenic bacteria, metabolic activity is obstructed, it is impossible to maintain normal dynamic membrane structure, cause the self-dissolving of cell.
By groups such as the abundant hydroxyls that contains in the active component in invention, hydrogen bond easily is formed with active site in alcohol, and then
Cause metabolic system disorderly, and then reach the effect of antibiotic and sterilizing.
The present invention with nano silicon, nano zine oxide and natural plant composition as primary raw material, by ginger essential oil,
Glossy privet contains abundant bioactive ingredients in extracting product, leek enzymolysis product, vinasse aqueous extract, reaches Synergistic and resists
The degerming effect of bacterium, it is poor, persistently anti-with the most of laundry composition sterilizing ability for solving existing production with natural plant fragrance
Bacterium property is poor, have the problem of certain toxicity.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Embodiment 1
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Shitosan Amphiphatic high polymer
15 parts of surfactant, 32 parts of nano silicon, 8 parts of sodium cellulose glycolate, 0.4 part of enzyme, 2 parts of nano zine oxide,
2 parts of ginger essential oil, glossy privet extract 7 parts of product, 14 parts of leek enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=18.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
Embodiment 2
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Shitosan Amphiphatic high polymer
15 parts of surfactant, 32 parts of nano silicon, 8 parts of sodium cellulose glycolate, 0.3 part of enzyme, 1 part of nano zine oxide,
2 parts of ginger essential oil, glossy privet extract 5 parts of product, 13 parts of leek enzymolysis product, 32 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=10.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
Embodiment 3
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Shitosan Amphiphatic high polymer
15 parts of surfactant, 32 parts of nano silicon, 9 parts of sodium cellulose glycolate, 0.5 part of enzyme, 2 parts of nano zine oxide,
3 parts of ginger essential oil, glossy privet extract 8 parts of product, 15 parts of leek enzymolysis product, 38 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
Embodiment 4
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Shitosan Amphiphatic high polymer
13 parts of surfactant, 29 parts of nano silicon, 8 parts of sodium cellulose glycolate, 0.4 part of enzyme, 2 parts of nano zine oxide,
2 parts of ginger essential oil, glossy privet extract 7 parts of product, 14 parts of leek enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=20.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
Embodiment 5
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Shitosan Amphiphatic high polymer
16 parts of surfactant, 34 parts of nano silicon, 8 parts of sodium cellulose glycolate, 0.4 part of enzyme, 2 parts of nano zine oxide,
2 parts of ginger essential oil, glossy privet extract 7 parts of product, 14 parts of leek enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=12.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
Comparative example 1
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Nano silicon 32
Part, 8 parts of sodium cellulose glycolate, 0.4 part of enzyme, 2 parts of nano zine oxide, 2 parts of ginger essential oil, glossy privet extract 7 parts of product, fragrant-flowered garlic
14 parts of dish enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
Comparative example 2
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Shitosan Amphiphatic high polymer
15 parts of surfactant, 8 parts of sodium cellulose glycolate, 0.4 part of enzyme, 2 parts of nano zine oxide, 2 parts of ginger essential oil, glossy privet carry
Take 7 parts of product, 14 parts of leek enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=16.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
Comparative example 3
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Shitosan Amphiphatic high polymer
15 parts of surfactant, 32 parts of nano silicon, 8 parts of sodium cellulose glycolate, 0.4 part of enzyme, 2 parts of nano zine oxide,
2 parts of ginger essential oil, 14 parts of leek enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the leek enzymolysis product is：Leek after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of flavor protease and papain mixed enzymolysis, enzymatic hydrolysis condition
For：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, flavor protease and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains leek enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=14.
Comparative example 4
One kind removal stain laundry composition, is made up of the component of following percentage by weight meter：Shitosan Amphiphatic high polymer
15 parts of surfactant, 32 parts of nano silicon, 8 parts of sodium cellulose glycolate, 0.4 part of enzyme, 2 parts of nano zine oxide,
2 parts of ginger essential oil, glossy privet extract 7 parts of product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=18.
Further, the preparation method of the glossy privet extraction product is：By glossy privet clean dry, then glossy privet is pulverized
50 mesh sieves are simultaneously crossed in end, and the glossy privet powder after sieving adds 70% ethanol, the quality (g) of glossy privet powder and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains glossy privet crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Female
Loyal crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Glossy privet is obtained after concentration and extracts product.
Comparative example 5
This comparative example chooses prestige Lay（Guangzhou）The batch of commodity Co., Ltd production is that 20150821 Wei Lushi imitates laundry entirely
Liquid.
Comparative example 6
This comparative example is the laundry composition prepared according to CMC GBs.
Measure of merit
1. detergency experiment
According to the laundry composition prepared in GB ∕ T 13174-2008, testing example 1-5 and comparative example 1-6 to three kinds of dirts
Cloth（JB01-carbon black soiled cotton, JB02-albumen soiled cotton and JB03-sebum soiled cotton）Detergency.Tested in 457nm with whiteness instrument
Soiled cotton wash before whiteness value.Four pieces of every kind of soiled cotton（6cm×6cm）, washed at 30 DEG C.Detergency test machine rotating speed is 120rpm, is stirred
Mix 20min.Then, the whiteness value after measurement washing, rinsing and drying.Of same method, made as with reference to sample using standard flour
Identical test.Detergency is expressed from the next：Detergency=（RAW-RBW）/（RAW R-RBW R）；
Wherein, RAWAnd RBWWhiteness value respectively before and after laundry composition washing, RAW RAnd RBW RRespectively before and after standard flour washing
Average whiteness value.
| Test group | JB01 | JB02 | JB03 |
| Embodiment 1 | 1.47 | 1.59 | 1.55 |
| Embodiment 2 | 1.39 | 1.58 | 1.54 |
| Embodiment 3 | 1.45 | 1.61 | 1.58 |
| Embodiment 4 | 1.32 | 1.64 | 1.63 |
| Embodiment 5 | 1.27 | 1.38 | 1.49 |
| Comparative example 1 | 0.58 | 0.73 | 0.60 |
| Comparative example 2 | 0.76 | 0.52 | 0.39 |
| Comparative example 3 | 0.67 | 0.89 | 0.77 |
| Comparative example 4 | 0.77 | 0.81 | 0.71 |
| Comparative example 5 | 1.11 | 1.20 | 1.07 |
| Comparative example 6 | 1.04 | 1.09 | 0.98 |
2. bacteriostatic test
It is 5.0 × 10 to prepare bacteria concentration respectively5-5.0×106The staphylococcus aureus bacteria suspension of cfu/ml and Escherichia coli
Bacteria suspension, takes 0.1ml bacteria suspensions and is spread evenly across Bacteria Culture primary surface, after after its natural drying, places an Oxford cup and exists
Center, light pressure is fixed.Laundry composition in extraction embodiment 1-5 and comparative example 1-6（Concentration is 0.2%）0.2ml is to Oxford
In cup, 37 DEG C are cultivated 24 hours, calculate antibacterial circle diameter size.With the PBS liquid of pH 7.2 as negative control, be not added with it is any
The culture medium of nutrient solution is used as aseptic blank.Every kind of liquid detergent sample is parallel to make 3 flat boards, repeats 2 times.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask and limited rather than described above, it is intended that all changes that will fall in the implication and scope of the equivalency of claim
Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.The ins and outs not described in detail in the present invention, can be by any in this area
Prior art is realized.Particularly, all technical characterstics not described in detail can be realized by any prior art in the present invention.
Claims (6)
1. it is a kind of to remove stain laundry composition, it is characterised in that to be made up of the component of following parts by weight meter：Shitosan
Amphoteric polymeric surfactant 11-17 parts, nano silicon 26-37 parts, sodium cellulose glycolate 7-11 parts, enzyme
0.2-0.7 parts, nano zine oxide 1-3 parts, ginger essential oil 1-5 parts, glossy privet extract 4-9 parts of product, leek enzymolysis product 12-
18 parts, 27-43 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
2. it is according to claim 1 to remove stain laundry composition, it is characterised in that the removal stain is washed
Clothing composition is made up of the component of following percentage by weight meter：13-16 parts of shitosan amphoteric polymeric surfactant, nanometer
Silica 29-34 parts, sodium cellulose glycolate 8-9 parts, enzyme 0.3-0.5 parts, nano zine oxide 1-2 parts, ginger essential oil
2-3 parts, glossy privet extract 5-8 parts of product, 13-15 parts of leek enzymolysis product, 32-38 parts of vinasse aqueous extract；
Described enzyme is the composition of amylase and protease, and the weight ratio of the amylase and protease is 1:1.
3. it is according to claim 1 to remove stain laundry composition, it is characterised in that the vinasse aqueous extract
Preparation method is：Vinasse after taking after making wine, by 1:4 solid-liquid ratio（g:mL）Distilled water is added, at room temperature mechanical shaking extraction
Filtered to get filtrate after 3 h, by filtrate again by 0.22 μm of sterilised membrane filter filtration sterilization, obtain vinasse aqueous extract, 4 DEG C of bars
Saved backup under part.
4. it is according to claim 1 to remove stain laundry composition, it is characterised in that the leek enzymolysis product
Preparation method is：Leek after stripping and slicing, the pretreatment such as blending, with solid-liquid ratio 1: 3（m/V）Add water, soaked overnight, using local flavor
The mode of protease and papain mixed enzymolysis, enzymatic hydrolysis condition is：45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2,
The enzyme concentration of flavor protease and papain is respectively 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, by enzymolysis liquid
The 5000r/min centrifugations 10min at 4 DEG C, takes supernatant, then obtain leek enzymolysis product by micro-filtration.
5. it is according to claim 1 to remove stain laundry composition, it is characterised in that the shitosan both sexes high score
The molecular formula of sub- surfactant is, wherein n=10-22.
6. it is according to claim 1 to remove stain laundry composition, it is characterised in that the glossy privet extracts product
Preparation method is：By glossy privet clean dry, then glossy privet grind into powder and 50 mesh sieves are crossed, the glossy privet powder after sieving adds
Enter 70% ethanol, the quality (g) of glossy privet powder is with the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument
(40 DEG C, 450 W) min of assisted extraction 20；Glossy privet ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, leaching
Carry 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering,
Obtain glossy privet crude extract；HPD-300 macroreticular resins are soaked into 24 h with 95% ethanol, distilled water is cleaned to after without ethanol flavor to be put
Enter the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Glossy privet crude extract is with 400 BV/h (BV:Macroreticular resin
Volume) the rate of adsorption be adsorbed on HPD-300 macroreticular resins, upper column quantity be 600 BV；The resin for having adsorbed uses 800
The distilled water of BV with the impurity on the flow velocity eluted resin of 1000 BV/h, then with 60% ethanol of 1200 BV to glutinous
The crude extract being attached on resin is eluted, and obtaining glossy privet after wash-out liquid condensing concentration extracts product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109749891A (en) * | 2017-11-08 | 2019-05-14 | 郭亚莲 | A kind of Traditional Chinese medicine laundry detergent |
| CN111925874A (en) * | 2020-09-10 | 2020-11-13 | 巢湖市圣洁洗涤服务有限公司 | Cleaning solution for sterilizing and disinfecting hotel bed sheet and quilt cover and preparation method thereof |
-
2016
- 2016-11-03 CN CN201610953099.6A patent/CN106753881A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109749891A (en) * | 2017-11-08 | 2019-05-14 | 郭亚莲 | A kind of Traditional Chinese medicine laundry detergent |
| CN111925874A (en) * | 2020-09-10 | 2020-11-13 | 巢湖市圣洁洗涤服务有限公司 | Cleaning solution for sterilizing and disinfecting hotel bed sheet and quilt cover and preparation method thereof |
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Application publication date: 20170531 |