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CN106758570A - Carbon nanotube modified heightening damping vibration attenuation mute steel rail - Google Patents

Carbon nanotube modified heightening damping vibration attenuation mute steel rail Download PDF

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Publication number
CN106758570A
CN106758570A CN201710033145.5A CN201710033145A CN106758570A CN 106758570 A CN106758570 A CN 106758570A CN 201710033145 A CN201710033145 A CN 201710033145A CN 106758570 A CN106758570 A CN 106758570A
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damping
layer
thickness
steel rail
padded
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CN106758570B (en
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黄微波
李华阳
黄舰
冯超
杨林
李栋
梁龙强
李向东
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Qingdao Metro Group Co ltd
Qingdao University of Technology
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Qingdao University of Technology
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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01BPERMANENT WAY; PERMANENT-WAY TOOLS; MACHINES FOR MAKING RAILWAYS OF ALL KINDS
    • E01B19/00Protection of permanent way against development of dust or against the effect of wind, sun, frost, or corrosion; Means to reduce development of noise
    • E01B19/003Means for reducing the development or propagation of noise
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/02Ingredients treated with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/14Applications used for foams

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Vibration Prevention Devices (AREA)
  • Laminated Bodies (AREA)

Abstract

垫高阻尼减振静音钢轨,包括钢轨基层、阻尼单元和阻尼层I,所述阻尼单元包括阻尼层A和垫高层,所述垫高层位于靠近阻尼层I的一侧,所述阻尼层A位于靠近钢轨基层的一侧。所述垫高层与阻尼层A的厚度比为4‑16;所述垫高层与阻尼层I的厚度比为4‑16。所述垫高层为碳纳米管改性聚氨酯泡沫。所述碳纳米管改性聚氨酯泡沫中均匀分布有若干空心槽。本发明采用碳纳米管改性空心槽泡沫作为垫高层,不但使垫高层与原有阻尼结构共同组成垫高阻尼结构,而且可以增加垫高层的抗剪强度(从减振角度考虑要求垫高层抗剪强度尽可能地大)、提高垫高层的防火性能、增加垫高层自身的阻尼效果、并且弥补由于较多的空心槽所造成的垫高层强度过低的问题。

The raised damping and vibration-reducing silent rail includes a rail base, a damping unit, and a damping layer I. The damping unit includes a damping layer A and a cushion layer. The cushion layer is located on the side close to the damping layer I. The damping layer A is located at The side close to the base of the rail. The thickness ratio of the cushion layer to the damping layer A is 4-16; the thickness ratio of the cushion layer to the damping layer I is 4-16. The cushion layer is carbon nanotube modified polyurethane foam. Several hollow grooves are uniformly distributed in the carbon nanotube modified polyurethane foam. The present invention adopts the carbon nanotube modified hollow groove foam as the cushion layer, which not only makes the cushion layer and the original damping structure jointly form a cushion damping structure, but also can increase the shear strength of the cushion layer (considering from the perspective of vibration reduction that the cushion layer is required to The shear strength should be as large as possible), improve the fire performance of the bedding layer, increase the damping effect of the bedding layer itself, and make up for the low strength of the bedding layer caused by more hollow grooves.

Description

碳纳米管改性垫高阻尼减振静音钢轨Carbon nanotube modified pad height damping vibration reduction silent rail

技术领域technical field

本发明属于建筑领域,涉及一种减振静音钢轨,具体地说,涉及一种碳纳米管改性垫高阻尼减振静音钢轨。The invention belongs to the field of construction, and relates to a vibration-damping and silent steel rail, in particular to a carbon nanotube-modified pad height damping and vibration-damping silent steel rail.

背景技术Background technique

当今社会中,各种各样的振动和噪声层出不穷,避无可避。然而,这种环境的长期作用不仅影响人们的身心健康,还导致结构设备因长期振动而疲劳破坏、精密仪器灵敏度下降。因此,控制振动、降低噪声已经成为迫切需要解决的课题。In today's society, all kinds of vibrations and noises emerge in endlessly and cannot be avoided. However, the long-term effect of this environment not only affects people's physical and mental health, but also leads to fatigue damage of structural equipment due to long-term vibration, and a decrease in the sensitivity of precision instruments. Therefore, controlling vibration and reducing noise has become an urgent problem to be solved.

近几年,随着阻尼材料在工程减振领域的广泛使用,阻尼钢轨也开始得到广泛的关注。现有的阻尼钢轨主要形式包括以下三种:(1)在钢轨侧面粘贴一层阻尼层,组成自由阻尼结构;(2)在阻尼层外再包裹一层约束层,形成约束阻尼结构;(3)在阻尼层内加入异型迷宫结构,组成迷宫式约束阻尼;(4)在约束阻尼结构中添加一层磁性材料层/磁性吸附层,并且使用一层或者多层阻尼层。其中,自由阻尼结构主要依靠阻尼层的拉压变形来耗散能量。而约束阻尼结构主要依靠阻尼层的剪切变形来耗散能量,同时阻尼层也会产生拉压变形,从而耗散更多的能量。迷宫式约束阻尼,耗能原理与约束阻尼结构大致相同;加入迷宫结构的目的是为了增大剪切变形。对于在约束阻尼结构中添加磁性材料层的阻尼结构,其耗能机理与约束阻尼结构完全相同;增加的磁性材料层是为了通过磁性材料本身进行吸振并且增加结构整体性。然而,以上四种结构都存在内半层阻尼对耗能贡献不大的情况,降低了阻尼层减振耗能的效率,造成阻尼材料的浪费,提高成本。此外,迷宫约束阻尼结构制作工艺过于复杂,不利于产品推广。而加入了磁性材料层的约束阻尼结构,本质上与原有约束阻尼结构相同,新加入的磁性材料层不但很难提供比阻尼材料更好的减振耗能效果,也不能增加吸音效果,并且会增加结构质量。对于使用喷涂工艺的阻尼层,由于其本身不存在层间结合力问题,也就不需要磁性材料来增加整体性。In recent years, with the widespread use of damping materials in the field of engineering vibration reduction, damping rails have also begun to receive widespread attention. The main forms of existing damping rails include the following three types: (1) a layer of damping layer is pasted on the side of the rail to form a free damping structure; (2) a constrained layer is wrapped outside the damping layer to form a constrained damping structure; (3) ) adding a special-shaped labyrinth structure in the damping layer to form a labyrinth constrained damping; (4) adding a magnetic material layer/magnetic adsorption layer to the constrained damping structure, and using one or more damping layers. Among them, the free damping structure mainly relies on the tension and compression deformation of the damping layer to dissipate energy. The constrained damping structure mainly relies on the shear deformation of the damping layer to dissipate energy, and the damping layer also produces tension and compression deformation, thereby dissipating more energy. The energy dissipation principle of the labyrinth constrained damping is roughly the same as that of the constrained damping structure; the purpose of adding the labyrinth structure is to increase the shear deformation. For the damping structure in which a magnetic material layer is added to the constrained damping structure, the energy dissipation mechanism is exactly the same as that of the constrained damping structure; the added magnetic material layer is to absorb vibration through the magnetic material itself and increase the structural integrity. However, the above four structures all have the situation that the inner half-layer damping does not contribute much to energy consumption, which reduces the efficiency of the damping layer in reducing vibration and energy consumption, resulting in waste of damping materials and increasing costs. In addition, the manufacturing process of the labyrinth constrained damping structure is too complicated, which is not conducive to product promotion. The constrained damping structure with the addition of a magnetic material layer is essentially the same as the original constrained damping structure. The newly added magnetic material layer is not only difficult to provide a better vibration reduction and energy dissipation effect than the damping material, but also cannot increase the sound absorption effect, and Will increase the structural quality. For the damping layer using the spraying process, since there is no problem of interlayer bonding force, there is no need for magnetic materials to increase the integrity.

常冠军等人(《粘弹性阻尼材料》,国防工业出版社,2012年,230页)的研究表明,在阻尼层与基板之间牢固地粘合一层抗剪刚度极大而抗弯刚度极小的材料作为中间层(Spacer),可使结构损耗因子提高,且可降低系统的质量。他们认为,在给定厚度的阻尼结构中,2/3的阻尼作用发生在外部的半层材料中,因此内半层可以用“无重量”的材料取代。这个内半层“无重量”的材料称为扩变层或垫高层,它可以加大从粘接的中线平面算起的阻尼处理距离(相当于增加阻尼层的厚度),从而也就加大了粘弹层的拉压变形,结构阻尼也就随之增大。同时,扩变层的加入还有加宽有效阻尼温度宽度的作用。并且因为扩变层材料密度很小,所以可以显著降低阻尼材料系统的表观质量。目前采用的垫高层是蜂窝状或者蓬松的硬泡沫,其附带作用是吸声和隔热。然而,由于现有的垫高阻尼结构往往采用已经固化的阻尼材料通过粘接剂粘接,容易产生层间结合不牢固、扩变层强度过低的问题;当垫高阻尼结构应用于较大振动构件的减振时,这种问题尤为明显。此外,采用普通的硬泡沫不耐火,也存在钢轨不防火、安全性不能保证等问题。Chang Guan et al. ("Viscoelastic Damping Materials", National Defense Industry Press, 2012, p. 230) showed that a layer firmly bonded between the damping layer and the substrate has a very high shear stiffness and a very high bending stiffness. A small material as an intermediate layer (Spacer) can increase the structural loss factor and reduce the quality of the system. They argue that in a damping structure of a given thickness, two-thirds of the damping occurs in the outer half-layer material, so that the inner half-layer can be replaced with a "weightless" material. The "weightless" material of the inner half layer is called the expansion layer or the pad layer, which can increase the damping treatment distance from the bonded midline plane (equivalent to increasing the thickness of the damping layer), thus increasing the thickness of the damping layer. The tension and compression deformation of the viscoelastic layer is reduced, and the structural damping increases accordingly. At the same time, the addition of the expansion layer also has the effect of widening the effective damping temperature width. And because the material density of the expansion layer is very small, the apparent quality of the damping material system can be significantly reduced. The cushion layer currently used is honeycomb or fluffy hard foam, and its incidental functions are sound absorption and heat insulation. However, since the existing padding damping structure is often bonded with cured damping materials through adhesives, it is easy to cause problems such as weak interlayer bonding and low strength of the expansion layer; when the padding damping structure is applied to larger This problem is especially obvious when the vibration of the vibrating member is damped. In addition, the use of ordinary hard foam is not fire-resistant, and there are also problems such as the rails are not fire-proof, and the safety cannot be guaranteed.

目前,基于碳纳米管的研究热度,许多人已经针对在泡沫中添加碳纳米管进行了研究。其中,大多采用物理添加的方法。而Kuan H C和Jung Y C等人采用了化学键键合的方法向聚氨酯泡沫中添加碳纳米管。然而,其添加碳纳米管的目的是提高材料的强度和韧性,以及提高材料的导电性、电磁屏蔽性和光电子发射性。基于上述目的,目前添加了碳纳米管的聚氨酯泡沫的应用仅限于以下几个方面:电子材料领域、智能材料领域、节能材料领域和生物医学材料领域。At present, based on the research enthusiasm of carbon nanotubes, many people have conducted research on adding carbon nanotubes to foam. Among them, the method of physical addition is mostly used. Kuan HC and Jung Y C et al. used chemical bonding to add carbon nanotubes to polyurethane foam. However, the purpose of adding carbon nanotubes is to increase the strength and toughness of the material, as well as to improve the conductivity, electromagnetic shielding and photoelectron emission of the material. Based on the above purpose, the current application of polyurethane foam with added carbon nanotubes is limited to the following areas: electronic materials, smart materials, energy-saving materials and biomedical materials.

发明内容Contents of the invention

针对现有垫高阻尼减振静音钢轨所存在的问题,本发明所述的碳纳米管改性垫高阻尼减振静音钢轨采用了碳纳米管改性空心槽泡沫,不但增加了垫高层的抗剪强度和阻尼效果,而且提高垫高层的防火性能,改善了空心槽所导致的垫高层强度过低的问题。Aiming at the problems existing in the existing high-damping damping and vibration-reducing mute rails, the carbon nanotube modified cushioning high-damping and vibration-damping silent rails of the present invention use carbon nanotube-modified hollow groove foam, which not only increases the resistance of the cushion layer It not only improves the shear strength and damping effect, but also improves the fire performance of the cushion layer, and improves the problem of low strength of the cushion layer caused by the hollow groove.

本发明的技术方案:垫高阻尼减振静音钢轨,包括钢轨基层、阻尼单元和阻尼层I,所述阻尼单元包括阻尼层A和垫高层,所述垫高层位于靠近阻尼层I的一侧,所述阻尼层A位于靠近钢轨基层的一侧。所述垫高层与阻尼层A的厚度比为4-16;所述垫高层与阻尼层I的厚度比为4-16。所述垫高层为碳纳米管改性聚氨酯泡沫。The technical solution of the present invention: padding the damping and damping silent rail, including the rail base layer, the damping unit and the damping layer I, the damping unit including the damping layer A and the cushioning layer, the cushioning layer is located on the side close to the damping layer I, The damping layer A is located on the side close to the base layer of the rail. The thickness ratio of the cushion layer to the damping layer A is 4-16; the thickness ratio of the cushion layer to the damping layer I is 4-16. The cushion layer is carbon nanotube modified polyurethane foam.

所述碳纳米管改性聚氨酯泡沫的制备包括以下步骤:(1)对碳纳米管进行改性,得到羟基化的碳纳米管;(2)步骤(1)得到的羟基化的碳纳米管加入到用于制备垫高层泡沫的B组分,即羟基化合物中;(3)将混合了羟基化碳纳米管的B组分与A组分异氰酸酯在60-80℃的温度条件和15-18MPa的压力条件下反应,即可得到碳纳米管改性聚氨酯泡沫。其中,所述碳纳米管改性聚氨酯泡沫中均匀分布有若干空心槽,所述相邻空心槽之间的间隔不小于4-6mm;所述空心槽的孔径为4-6mm。碳纳米管改性空心槽垫高层与现有的硬泡沫材料垫高层相比抗剪强度更大,更利于阻尼层的耗能,故可以提高减振性能。The preparation of the carbon nanotube-modified polyurethane foam comprises the following steps: (1) modifying the carbon nanotubes to obtain hydroxylated carbon nanotubes; (2) adding the hydroxylated carbon nanotubes obtained in step (1) to into the B component used to prepare the cushion layer foam, that is, the hydroxyl compound; (3) mix the B component mixed with hydroxylated carbon nanotubes and the A component isocyanate at a temperature of 60-80°C and a temperature of 15-18MPa Reacting under pressure conditions, the carbon nanotube modified polyurethane foam can be obtained. Wherein, several hollow grooves are evenly distributed in the carbon nanotube modified polyurethane foam, and the interval between the adjacent hollow grooves is not less than 4-6mm; the hole diameter of the hollow grooves is 4-6mm. Compared with the existing hard foam material cushion layer, the carbon nanotube modified hollow groove cushion layer has higher shear strength, which is more conducive to the energy dissipation of the damping layer, so the vibration damping performance can be improved.

其中,所述阻尼层I远离阻尼单元的一侧还设有约束层,所述约束层为钢板;所述阻尼单元的数量是1-3。Wherein, the side of the damping layer I away from the damping unit is further provided with a constrained layer, and the constrained layer is a steel plate; the number of the damping units is 1-3.

其中,所述每个阻尼单元的垫高层与阻尼层A之间设有镶嵌在二者表面的金刚砂层,所述金刚砂的数量为0.5-1.5kg/m2,所述金刚砂的粒径为1.6-2.0mm。Wherein, a corundum layer inlaid on the surface of each damping unit is provided between the pad layer and the damping layer A, the quantity of the corundum is 0.5-1.5kg/m 2 , and the particle size of the corundum is 1.6 -2.0mm.

羟基化碳纳米管的制备主要分为两步:The preparation of hydroxylated carbon nanotubes is mainly divided into two steps:

1.采用混酸法对碳纳米管进行改性,将单壁碳纳米管(SWCNT)用40ml浓硫酸和硝酸的3:1混合溶液进行处理,然后将混合物在40℃的条件下用超声波处理3小时。即可在碳纳米管表面引入羧基。1. The carbon nanotubes were modified by the mixed acid method, and the single-walled carbon nanotubes (SWCNTs) were treated with a 3:1 mixed solution of 40ml concentrated sulfuric acid and nitric acid, and then the mixture was ultrasonically treated at 40°C for 3 Hour. Carboxyl groups can be introduced on the surface of carbon nanotubes.

2.将20毫克有第一步得到的羧基化单壁碳纳米管分散到无水四氢呋喃中并进行超声波处理30分钟。之后加入2毫克氢化铝锂并进行超声波处理1小时。将得到的反应混合物缓慢加入到200毫升甲醇中并用聚碳酸酯滤纸进行过滤。然后将所得产物在真空烘箱中以80℃干燥3小时。即可得到羟基化的碳纳米管。2. Disperse 20 mg of the carboxylated single-walled carbon nanotubes obtained in the first step in anhydrous tetrahydrofuran and perform ultrasonic treatment for 30 minutes. Then 2 mg of lithium aluminum hydride were added and sonicated for 1 hour. The resulting reaction mixture was slowly added to 200 ml of methanol and filtered with polycarbonate filter paper. The resulting product was then dried in a vacuum oven at 80°C for 3 hours. Hydroxylated carbon nanotubes can be obtained.

自由垫高阻尼减振静音钢轨的制备方法,包括以下步骤:(1)在钢轨基层的侧面喷涂阻尼材料得到阻尼层A,然后进行喷砂处理;(2)处理后在阻尼层A上浇筑作为垫高层的碳纳米管改性聚氨酯泡沫;(3)在碳纳米管改性聚氨酯泡沫上继续喷涂阻尼材料得到阻尼层I;即可得到垫高阻尼减振静音钢轨中的自由垫高阻尼减振静音钢轨。所述阻尼层A的厚度为3-5mm,所述垫高层的厚度为18-22mm,所述阻尼层I的厚度均为3-5mm。阻尼层采用直接喷涂的施工方法,产品一体性好、工艺简单、成本低廉、工程应用方便。The preparation method of the free height damping and vibration reduction mute rail comprises the following steps: (1) spraying the damping material on the side of the rail base to obtain the damping layer A, and then performing sandblasting; (2) pouring on the damping layer A after the treatment as The carbon nanotube modified polyurethane foam of the cushion layer; (3) continue to spray the damping material on the carbon nanotube modified polyurethane foam to obtain the damping layer I; the free cushion height damping and vibration reduction in the cushion height damping and vibration reduction mute rail can be obtained Silent rails. The thickness of the damping layer A is 3-5mm, the thickness of the cushion layer is 18-22mm, and the thickness of the damping layer I is 3-5mm. The damping layer adopts the construction method of direct spraying, which has good product integrity, simple process, low cost and convenient engineering application.

约束垫高阻尼减振静音钢轨的制备方法,包括以下步骤:(1)在钢轨基层的侧面喷涂阻尼材料得到阻尼层A,然后进行喷砂处理;(2)处理后在阻尼层A上浇筑作为垫高层的碳纳米管改性聚氨酯泡沫;(3)在碳纳米管改性聚氨酯泡沫上继续喷涂阻尼材料得到阻尼层I;(4)在阻尼层I外包裹厚度为1-3mm的钢板作为约束层,即可得到垫高阻尼减振静音钢轨中的约束垫高阻尼减振静音钢轨。即可得到垫高阻尼减振静音钢轨中的自由垫高阻尼减振静音钢轨。所述阻尼层A的厚度为1-3mm,所述垫高层的厚度为14-16mm,所述阻尼层I的厚度均为1-3mm。The preparation method of the restrained height damping and vibration-reducing mute rail comprises the following steps: (1) spraying damping material on the side of the rail base to obtain a damping layer A, and then performing sandblasting treatment; (2) pouring on the damping layer A after treatment as The carbon nanotube modified polyurethane foam of the upper layer; (3) continue to spray the damping material on the carbon nanotube modified polyurethane foam to obtain the damping layer I; (4) wrap the steel plate with a thickness of 1-3mm on the damping layer I as a constraint layer, the restrained heightened damping vibration damping silent rail in the padding damping vibration reducing silent rail can be obtained. The free height damping vibration damping silent steel rail in the cushioning height damping vibration damping silent steel rail can be obtained. The thickness of the damping layer A is 1-3mm, the thickness of the cushion layer is 14-16mm, and the thickness of the damping layer I is 1-3mm.

多层约束垫高阻尼减振静音钢轨的制备方法,包括以下步骤:(1)在钢轨基层的侧面喷涂阻尼材料得到阻尼层A,然后进行喷砂处理;(2)处理后在阻尼层A上浇筑作为垫高层的碳纳米管改性聚氨酯泡沫;(2a)在最外层的阻尼单元的碳纳米管改性聚氨酯泡沫上继续喷涂阻尼材料,喷砂处理;浇筑作为垫高层的碳纳米管改性聚氨酯泡沫;重复进行步骤(2a),直至阻尼单元的数量达到要求;(3)在碳纳米管改性聚氨酯泡沫上继续喷涂阻尼材料得到阻尼层I;(4)在阻尼层I外包裹厚度为1-3mm的钢板作为约束层,即可得到垫高阻尼减振静音钢轨中的多层约束垫高阻尼减振静音钢轨。所述阻尼层A的厚度为1-3mm,所述垫高层的厚度为14-16mm,所述阻尼层I的厚度均为1-3mm。The preparation method of the multi-layer constrained pad height damping and vibration-reducing silent rail comprises the following steps: (1) spraying damping material on the side of the rail base layer to obtain a damping layer A, and then performing sandblasting treatment; Pouring the carbon nanotube modified polyurethane foam as the cushion layer; (2a) continue spraying damping material on the carbon nanotube modified polyurethane foam of the outermost damping unit, and sandblasting; pouring the carbon nanotube modified polyurethane foam as the cushion layer permanent polyurethane foam; repeat step (2a), until the number of damping units reaches the requirements; (3) continue to spray damping material on the carbon nanotube modified polyurethane foam to obtain damping layer I; (4) wrap thickness in damping layer I A steel plate with a diameter of 1-3mm is used as the constraining layer to obtain a multi-layer constrained cushioning, damping, vibration-reducing and silent rail in the raised-damping, vibration-reducing, and silent rail. The thickness of the damping layer A is 1-3mm, the thickness of the cushion layer is 14-16mm, and the thickness of the damping layer I is 1-3mm.

所述喷砂处理的具体步骤为:喷涂时机为喷涂阻尼材料后8-10秒;喷砂气压为0.6-0.8兆帕,喷砂距离为1米,温度为15-25摄氏度。采用以上参数进行喷砂处理时,砂砾在相邻两层各嵌入一半,减振降噪的效果最好。The specific steps of the sandblasting treatment are as follows: the spraying timing is 8-10 seconds after the damping material is sprayed; the sandblasting air pressure is 0.6-0.8 MPa, the sandblasting distance is 1 meter, and the temperature is 15-25 degrees Celsius. When the above parameters are used for sandblasting, the gravel is embedded in half of the adjacent two layers, and the effect of vibration and noise reduction is the best.

为验证本发明所述的垫高阻尼减振静音钢轨具有优异的减振性能,本发明采用下述方法对本发明所述的垫高阻尼减振静音钢轨与空白钢板进行振动测试。取500mm×43mm×3.5mm钢板作为基材(相当于钢轨)制作垫高阻尼减振静音地板,所述垫高阻尼减振静音地板的结构参数详见实施例1-9。其中,采用密度为200kg/m3的聚氨酯泡沫层作为垫高层;青岛理工大学功能材料研究所提供的聚氨酯类粘弹阻尼材料作为阻尼层。将500mm×43mm×3.5mm钢板作为空白式样,进行对比。In order to verify that the raised damping and vibration-reducing silent steel rail of the present invention has excellent vibration-reducing performance, the present invention adopts the following method to carry out a vibration test on the raised damping and vibration-reducing silent steel rail of the present invention and a blank steel plate. A 500mm×43mm×3.5mm steel plate is used as a base material (equivalent to a steel rail) to make a raised damping, vibration-reduction and quiet floor. The structural parameters of the raised damping, vibration-reduction and quiet floor are detailed in Examples 1-9. Among them, the polyurethane foam layer with a density of 200kg/ m3 is used as the cushion layer; the polyurethane viscoelastic damping material provided by the Institute of Functional Materials of Qingdao Technological University is used as the damping layer. A 500mm×43mm×3.5mm steel plate was used as a blank sample for comparison.

采用北京东方振动和噪声技术研究所的DASP智能数据采集和信号分析系统V10进行数据采集和分析。试验方法采用锤击激振法,模拟式样受到激振后振动自由衰减的过程。为降低外部支撑对振动自由衰减的影响,用细鱼线将式样水平吊起,吊点在钢板左右两侧50mm处;拾振点和激振点分别在钢板面的左右两侧25mm处,如图4所示;采样频率为2048Hz,激振头为钢头,激振力为45N。The DASP intelligent data acquisition and signal analysis system V10 of Beijing Oriental Institute of Vibration and Noise Technology is used for data acquisition and analysis. The test method adopts the hammer excitation method to simulate the process of free attenuation of vibration after the sample is excited. In order to reduce the influence of external support on the free attenuation of vibration, the pattern is hoisted horizontally with a thin fishing line. The lifting point is 50mm from the left and right sides of the steel plate; the vibration pickup point and the excitation point are respectively 25mm from the left and right sides of the steel plate. As shown in Figure 4; the sampling frequency is 2048Hz, the excitation head is a steel head, and the excitation force is 45N.

本发明的有益效果:Beneficial effects of the present invention:

1、与现有技术相比,本发明采用碳纳米管改性空心槽泡沫作为垫高层,不但使垫高层与原有阻尼结构共同组成垫高阻尼结构,而且可以增加垫高层的抗剪强度(从减振角度考虑要求垫高层抗剪强度尽可能地大)、提高垫高层的防火性能、增加垫高层自身的阻尼效果、并且弥补由于较多的空心槽所造成的垫高层强度过低的问题。1. Compared with the prior art, the present invention adopts the carbon nanotube modified hollow groove foam as the pad layer, which not only makes the pad layer and the original damping structure jointly form a pad height damping structure, but also can increase the shear strength of the pad layer ( From the perspective of vibration reduction, it is required that the shear strength of the cushion layer be as large as possible), improve the fire performance of the cushion layer, increase the damping effect of the cushion layer itself, and make up for the low strength of the cushion layer caused by more hollow grooves .

2.本发明在阻尼层与垫高层之间进行喷砂处理,可以使层间结合更加牢固,同时还可以增加阻尼材料与垫高层之间的接触面积从而提高阻尼减振效果。2. In the present invention, the sandblasting treatment is performed between the damping layer and the cushion layer, which can make the interlayer bond more firm, and can also increase the contact area between the damping material and the cushion layer so as to improve the damping and vibration reduction effect.

3、相比硬泡沫材料的垫高层,碳纳米管改性空心槽垫高层具有非常好的阻燃性能,作为在地铁隧道中使用的静音钢轨的组成部分,可以有效防火、提供更好的安全保障。3. Compared with the cushion layer of hard foam material, the carbon nanotube modified hollow groove cushion layer has very good flame retardancy. As a component of the silent steel rail used in the subway tunnel, it can effectively prevent fire and provide better safety Assure.

4、本发明在钢轨基层和阻尼单元之间设置了阻尼层A,一方面增加垫高层的牢固程度;另一方面确保钢轨无论振动从里向外传播和从外向里传播都是垫高阻尼结构。4. The present invention sets a damping layer A between the rail base layer and the damping unit, on the one hand, it increases the firmness of the padding layer; on the other hand, it ensures that the rail is a padding damping structure no matter whether the vibration propagates from the inside to the outside or from the outside to the inside .

附图说明Description of drawings

图1为本发明所述的垫高层的结构示意图;Fig. 1 is the structural representation of cushion layer described in the present invention;

图2本发明所述的自由垫高阻尼减振静音钢轨;Fig. 2 free height damping and vibration reduction silent steel rail of the present invention;

图3本发明所述的约束垫高阻尼减振静音钢轨;Fig. 3 Constraint pad height damping damping silent steel rail of the present invention;

图4本发明所述的多层约束垫高阻尼减振静音钢轨;Fig. 4 multi-layer constraining pad height damping damping silent steel rail of the present invention;

图5为本发明所述的锤击激振法测试装置的结构示意图;Fig. 5 is the structural representation of the hammer vibration excitation test device of the present invention;

其中,1为泡沫,2为空心槽,3为钢轨,4为阻尼层I,5为阻尼层A,6为约束层。Among them, 1 is foam, 2 is hollow groove, 3 is rail, 4 is damping layer I, 5 is damping layer A, and 6 is constraining layer.

具体实施方式detailed description

下面结合实施例对本发明做进一步的说明。Below in conjunction with embodiment the present invention will be further described.

实施例1:自由垫高阻尼减振静音钢轨Embodiment 1: free height damping and vibration reduction silent steel rail

自由垫高阻尼减振静音钢轨,包括钢轨基层、阻尼单元和阻尼层I,所述阻尼单元包括阻尼层A和垫高层,所述垫高层位于靠近阻尼层I的一侧,所述阻尼层A位于靠近钢轨基层的一侧。所述垫高层为碳纳米管改性聚氨酯泡沫。所述阻尼层A的厚度为5mm,所述垫高层的厚度为20mm,所述阻尼层I的厚度均为5mm。其中,所述垫高层与阻尼层A之间设有镶嵌在二者表面的金刚砂层,所述金刚砂的数量为4.0kg/m2,所述金刚砂的粒径为1.6mm。The free cushioning damping and vibration-reducing mute rail includes a rail base, a damping unit and a damping layer I, and the damping unit includes a damping layer A and a cushion layer, the cushion layer is located on the side close to the damping layer I, and the damping layer A Located on the side close to the base of the rail. The cushion layer is carbon nanotube modified polyurethane foam. The thickness of the damping layer A is 5mm, the thickness of the cushion layer is 20mm, and the thickness of the damping layer I is 5mm. Wherein, a corundum layer inlaid on the surfaces of the cushion layer and the damping layer A is provided, the quantity of the corundum is 4.0kg/m 2 , and the particle size of the corundum is 1.6mm.

所述碳纳米管改性聚氨酯泡沫的制备包括以下步骤:The preparation of the carbon nanotube modified polyurethane foam comprises the following steps:

(1)对碳纳米管进行改性,得到羟基化的碳纳米管;详细步骤为:(1a)采用混酸法对碳纳米管进行改性,将单壁碳纳米管(SWCNT)用40ml浓硫酸和硝酸的3:1混合溶液进行处理,然后将混合物在40℃的条件下用超声波处理3小时。即可在碳纳米管表面引入羧基。(1b)将20毫克有第一步得到的羧基化单壁碳纳米管分散到无水四氢呋喃中并进行超声波处理30分钟。之后加入2毫克氢化铝锂并进行超声波处理1小时。将得到的反应混合物缓慢加入到200毫升甲醇中并用聚碳酸酯滤纸进行过滤。然后将所得产物在真空烘箱中以80℃干燥3小时。即可得到羟基化的碳纳米管。(1) modify the carbon nanotubes to obtain hydroxylated carbon nanotubes; the detailed steps are: (1a) adopt the mixed acid method to modify the carbon nanotubes, and use 40ml concentrated sulfuric acid to single-wall carbon nanotubes (SWCNTs) and nitric acid in a 3:1 mixture, and then the mixture was sonicated at 40°C for 3 hours. Carboxyl groups can be introduced on the surface of carbon nanotubes. (1b) Disperse 20 mg of the carboxylated single-walled carbon nanotubes obtained in the first step in anhydrous tetrahydrofuran and perform ultrasonic treatment for 30 minutes. Then 2 mg of lithium aluminum hydride were added and sonicated for 1 hour. The resulting reaction mixture was slowly added to 200 ml of methanol and filtered with polycarbonate filter paper. The resulting product was then dried in a vacuum oven at 80°C for 3 hours. Hydroxylated carbon nanotubes can be obtained.

(2)步骤(1)得到的羟基化的碳纳米管加入到用于制备垫高层泡沫的B组分,即羟基化合物中;(2) The hydroxylated carbon nanotubes obtained in step (1) are added to the B component for preparing the cushion layer foam, that is, the hydroxyl compound;

(3)将混合了羟基化碳纳米管的B组分与A组分异氰酸酯在70℃的温度条件和18MPa的压力条件下反应,即可得到碳纳米管改性聚氨酯泡沫。其中,所述碳纳米管改性聚氨酯泡沫中均匀分布有若干空心槽,所述相邻空心槽之间的间隔不小于4mm;所述空心槽的孔径为4mm。碳纳米管改性空心槽垫高层与现有的硬泡沫材料垫高层相比抗剪强度更大,更利于阻尼层的耗能,故可以提高减振性能。(3) React component B mixed with hydroxylated carbon nanotubes and component A isocyanate at a temperature of 70° C. and a pressure of 18 MPa to obtain carbon nanotube-modified polyurethane foam. Wherein, several hollow grooves are uniformly distributed in the carbon nanotube modified polyurethane foam, and the interval between the adjacent hollow grooves is not less than 4mm; the hole diameter of the hollow grooves is 4mm. Compared with the existing hard foam material cushion layer, the carbon nanotube modified hollow groove cushion layer has higher shear strength, which is more conducive to the energy dissipation of the damping layer, so the vibration damping performance can be improved.

自由垫高阻尼减振静音钢轨的制备方法,包括以下步骤:(1)在钢轨基层的侧面喷涂阻尼材料得到阻尼层A,然后进行喷砂处理;(2)处理后在阻尼层A上浇筑作为垫高层的碳纳米管改性聚氨酯泡沫;(3)在碳纳米管改性聚氨酯泡沫上继续喷涂阻尼材料得到阻尼层I,即可得到垫高阻尼减振静音钢轨中的自由垫高阻尼减振静音钢轨。阻尼层采用直接喷涂的施工方法,产品一体性好、工艺简单、成本低廉、工程应用方便。所述喷砂处理的具体步骤为:喷涂时机为喷涂阻尼材料后10秒;喷砂气压为0.6Mpa,喷砂距离为1m,温度为20℃。采用以上参数进行喷砂处理时,砂砾在相邻两层各嵌入一半,减振降噪的效果最好。The preparation method of the free height damping and vibration reduction mute rail comprises the following steps: (1) spraying the damping material on the side of the rail base to obtain the damping layer A, and then performing sandblasting; (2) pouring on the damping layer A after the treatment as The carbon nanotube modified polyurethane foam of the cushion layer; (3) continue to spray the damping material on the carbon nanotube modified polyurethane foam to obtain the damping layer I, which can obtain the free cushion height damping and vibration reduction in the cushion height damping and vibration reduction mute rail Silent rails. The damping layer adopts the construction method of direct spraying, which has good product integrity, simple process, low cost and convenient engineering application. The specific steps of the sandblasting treatment are as follows: the spraying timing is 10 seconds after the damping material is sprayed; the sandblasting air pressure is 0.6Mpa, the sandblasting distance is 1m, and the temperature is 20°C. When the above parameters are used for sandblasting, the gravel is embedded in half of the adjacent two layers, and the effect of vibration and noise reduction is the best.

为验证本发明所述的垫高阻尼减振静音钢轨具有优异的减振性能,采用下述方法对上述方法制备的垫高阻尼减振静音地板与空白钢板进行振动测试。In order to verify the excellent damping performance of the raised damping, vibration-absorbing and silent steel rail of the present invention, the following method was used to carry out a vibration test on the raised damping, vibration-reducing and quiet floor and the blank steel plate prepared by the above method.

测试方法:采用500mm×43mm×3.5mm钢板作为地板基材制备垫高阻尼减振静音地板式样,同时将该钢板作为空白钢板。采用北京东方振动和噪声技术研究所的DASP智能数据采集和信号分析系统V10进行数据采集和分析。试验方法采用锤击激振法,模拟式样受到激振后振动自由衰减的过程。为降低外部支撑对振动自由衰减的影响,用细鱼线将式样水平吊起,吊点在钢板左右两侧50mm处;拾振点和激振点分别在钢板面的左右两侧25mm处,如图4所示;采样频率为2048Hz,激振头为钢头,激振力为45N。Test method: A 500mm×43mm×3.5mm steel plate is used as the floor substrate to prepare a raised damping and vibration-reducing mute floor pattern, and the steel plate is used as a blank steel plate. The DASP intelligent data acquisition and signal analysis system V10 of Beijing Oriental Institute of Vibration and Noise Technology is used for data acquisition and analysis. The test method adopts the hammer excitation method to simulate the process of free attenuation of vibration after the sample is excited. In order to reduce the influence of external support on the free attenuation of vibration, the pattern is hoisted horizontally with a thin fishing line. The lifting point is 50mm from the left and right sides of the steel plate; the vibration pickup point and the excitation point are respectively 25mm from the left and right sides of the steel plate. As shown in Figure 4; the sampling frequency is 2048Hz, the excitation head is a steel head, and the excitation force is 45N.

实施例2:自由垫高阻尼减振静音钢轨Embodiment 2: free height damping and vibration reduction silent steel rail

与实施例1不同的是,自由垫高阻尼减振静音钢轨,所述阻尼层A的厚度为3mm,所述垫高层的厚度为18mm,所述阻尼层I的厚度均为3mm。其中,所述垫高层与阻尼层A之间均设有镶嵌在二者表面的金刚砂层,所述金刚砂的数量为0.5kg/m2,所述金刚砂的粒径为1.8mm。The difference from Example 1 is that the damping and vibration-absorbing silent steel rails are freely raised, the thickness of the damping layer A is 3mm, the thickness of the cushioning layer is 18mm, and the thickness of the damping layer I is 3mm. Wherein, a corundum layer inlaid on the surfaces of the cushion layer and the damping layer A is provided, the quantity of the corundum is 0.5kg/m 2 , and the particle size of the corundum is 1.8mm.

所述碳纳米管改性聚氨酯泡沫的制备,所述步骤(3)中,将混合了羟基化碳纳米管的B组分与A组分异氰酸酯在80℃的温度条件和15MPa的压力条件下反应,即可得到碳纳米管改性聚氨酯泡沫。所述相邻空心槽之间的间隔不小于5mm;所述空心槽的孔径为5mm。The preparation of the carbon nanotube modified polyurethane foam, in the step (3), react the B component mixed with the hydroxylated carbon nanotube and the A component isocyanate at a temperature of 80°C and a pressure of 15MPa , the carbon nanotube modified polyurethane foam can be obtained. The interval between the adjacent hollow grooves is not less than 5mm; the hole diameter of the hollow grooves is 5mm.

自由垫高阻尼减振静音钢轨的制备方法,所述喷砂处理的具体步骤为:喷涂时机为喷涂阻尼材料后8秒;喷砂气压为0.7MPa,喷砂距离为1米,温度为25℃。The preparation method of the free pad height damping and vibration reduction mute rail, the specific steps of the sandblasting treatment are: the spraying timing is 8 seconds after spraying the damping material; the sandblasting air pressure is 0.7MPa, the sandblasting distance is 1 meter, and the temperature is 25°C .

实施例3:自由垫高阻尼减振静音钢轨Embodiment 3: free height damping and vibration reduction silent steel rail

与实施例1不同的是,自由垫高阻尼减振静音钢轨,所述阻尼层A的厚度为4mm,所述垫高层的厚度为22mm,所述阻尼层I的厚度均为4mm。The difference from Example 1 is that the damping and vibration-damping silent steel rails are freely raised, the thickness of the damping layer A is 4mm, the thickness of the cushioning layer is 22mm, and the thickness of the damping layer I is 4mm.

实施例4:约束垫高阻尼减振静音钢轨Embodiment 4: Constraint Pad High Damping Vibration Damping Silent Steel Rail

与实施例1不同的是,约束垫高阻尼减振静音钢轨,所述阻尼层I远离阻尼单元的一侧还设有约束层,所述约束层为钢板。所述阻尼层A的厚度为2mm,所述垫高层的厚度为15mm,所述阻尼层I的厚度均为2mm。所述金刚砂的数量为1.5kg/m2,所述金刚砂的粒径为2.0mm。The difference from Example 1 is that the restraint pad height damps the vibration-absorbing silent steel rail, and the side of the damping layer I away from the damping unit is further provided with a constraining layer, and the constraining layer is a steel plate. The thickness of the damping layer A is 2mm, the thickness of the cushion layer is 15mm, and the thickness of the damping layer I is 2mm. The quantity of the corundum is 1.5kg/m2, and the particle diameter of the corundum is 2.0mm.

所述碳纳米管改性聚氨酯泡沫的制备,步骤(3)将混合了羟基化碳纳米管的B组分与A组分异氰酸酯在60℃的温度条件和16MPa的压力条件下反应,即可得到碳纳米管改性聚氨酯泡沫。所述相邻空心槽之间的间隔不小于6mm;所述空心槽的孔径为6mm。In the preparation of the carbon nanotube-modified polyurethane foam, step (3) reacts the B component mixed with the hydroxylated carbon nanotubes and the A component isocyanate at a temperature of 60°C and a pressure of 16MPa to obtain Carbon nanotube modified polyurethane foam. The interval between the adjacent hollow grooves is not less than 6mm; the hole diameter of the hollow grooves is 6mm.

约束垫高阻尼减振静音钢轨的制备方法,步骤(3)在碳纳米管改性聚氨酯泡沫上继续喷涂阻尼材料,得到阻尼层I;(4)在阻尼层I外包裹厚度为2mm的钢板作为约束层,即可得到垫高阻尼减振静音钢轨中的约束垫高阻尼减振静音钢轨。所述喷砂处理的具体步骤为:喷涂时机为喷涂阻尼材料后9秒;喷砂气压为0.8MPa,喷砂距离为1米,温度为22℃。The preparation method of the restrained pad height damping and vibration-reducing silent steel rail, step (3) continues to spray damping material on carbon nanotube modified polyurethane foam, obtains damping layer I; Constraint layer, can obtain the restrained heightened damping vibration damping silent steel rail in the padding damping vibration reducing silent steel rail. The specific steps of the sandblasting treatment are as follows: the spraying timing is 9 seconds after the damping material is sprayed; the sandblasting air pressure is 0.8 MPa, the sandblasting distance is 1 meter, and the temperature is 22°C.

实施例5:约束垫高阻尼减振静音钢轨Embodiment 5: Constraint Pad High Damping Vibration Damping Silent Steel Rail

与实施例4不同的是,约束垫高阻尼减振静音钢轨,所述阻尼层A的厚度为3mm,所述垫高层的厚度为16mm,所述阻尼层I的厚度均为3mm。所述金刚砂的数量为0.8kg/m2,所述金刚砂的粒径为1.9mm。The difference from Example 4 is that the damping and vibration-damping silent rails are constrained, the thickness of the damping layer A is 3mm, the thickness of the cushioning layer is 16mm, and the thickness of the damping layer I is 3mm. The quantity of the corundum is 0.8kg/m 2 , and the particle size of the corundum is 1.9mm.

所述碳纳米管改性聚氨酯泡沫的制备,步骤(3)将混合了羟基化碳纳米管的B组分与A组分异氰酸酯在65℃的温度条件和17.5MPa的压力条件下反应,即可得到碳纳米管改性聚氨酯泡沫。所述相邻空心槽之间的间隔不小于4.5mm;所述空心槽的孔径为5.5mm。In the preparation of the carbon nanotube-modified polyurethane foam, the step (3) reacts the B component mixed with the hydroxylated carbon nanotubes and the A component isocyanate at a temperature of 65°C and a pressure of 17.5MPa. Obtain carbon nanotube modified polyurethane foam. The interval between the adjacent hollow grooves is not less than 4.5mm; the hole diameter of the hollow grooves is 5.5mm.

约束垫高阻尼减振静音钢轨的制备方法,步骤(4)在阻尼层I外包裹厚度为1mm的钢板作为约束层,即可得到垫高阻尼减振静音钢轨中的约束垫高阻尼减振静音钢轨。所述喷砂处理的具体步骤为:喷涂时机为喷涂阻尼材料后9秒;喷砂气压为0.7MPa,喷砂距离为1米,温度为24℃。The preparation method of restrained height damping and vibration reduction mute steel rail, step (4) wraps the steel plate that thickness is 1mm in damping layer I as constraining layer, can obtain the restraint height damping vibration reduction mute in the height damping damping and silence rail rails. The specific steps of the sandblasting treatment are as follows: the spraying timing is 9 seconds after the damping material is sprayed; the sandblasting air pressure is 0.7 MPa, the sandblasting distance is 1 meter, and the temperature is 24°C.

实施例6:约束垫高阻尼减振静音钢轨Embodiment 6: Constraint Pad High Damping Vibration Damping Silent Steel Rail

与实施例4不同的是,约束垫高阻尼减振静音钢轨,所述阻尼层A的厚度为1mm,所述垫高层的厚度为14mm,所述阻尼层I的厚度均为1mm。The difference from Example 4 is that the damping and vibration-damping silent rails are restrained, the thickness of the damping layer A is 1mm, the thickness of the cushioning layer is 14mm, and the thickness of the damping layer I is 1mm.

实施例7:多层约束垫高阻尼减振静音钢轨Embodiment 7: Multi-layer constrained pad height damping vibration reduction silent steel rail

与实施例1不同的是,多层约束垫高阻尼减振静音钢轨,所述阻尼层I远离阻尼单元的一侧还设有约束层所述约束层为钢板;所述阻尼单元的数量是2。所述阻尼层A的厚度为1mm,所述垫高层的厚度为10mm,所述阻尼层I的厚度均为1mm。所述金刚砂的数量为1.2kg/m2,所述金刚砂的粒径为1.7mm。The difference from Example 1 is that the multi-layer restraint pad height damping damping mute steel rail, the side of the damping layer 1 far away from the damping unit is also provided with a constraining layer and the constraining layer is a steel plate; the number of the damping unit is 2 . The thickness of the damping layer A is 1 mm, the thickness of the cushion layer is 10 mm, and the thickness of the damping layer I is 1 mm. The quantity of the corundum is 1.2kg/m 2 , and the particle size of the corundum is 1.7mm.

所述碳纳米管改性聚氨酯泡沫的制备,步骤(3)将混合了羟基化碳纳米管的B组分与A组分异氰酸酯在75℃的温度条件和16.5MPa的压力条件下反应,即可得到碳纳米管改性聚氨酯泡沫。所述相邻空心槽之间的间隔不小于5.5mm;所述空心槽的孔径为4.5mm。The preparation of the carbon nanotube-modified polyurethane foam, step (3) reacts the B component mixed with the hydroxylated carbon nanotubes and the A component isocyanate at a temperature of 75°C and a pressure of 16.5MPa, then Obtain carbon nanotube modified polyurethane foam. The interval between the adjacent hollow grooves is not less than 5.5mm; the hole diameter of the hollow grooves is 4.5mm.

多层约束垫高阻尼减振静音钢轨的制备方法,还包括位于步骤(2)和步骤(3)之间的步骤(2a):在最外层的阻尼单元的碳纳米管改性聚氨酯泡沫上继续喷涂阻尼材料,喷砂处理;浇筑作为垫高层的碳纳米管改性聚氨酯泡沫;重复进行步骤(2a),直至阻尼单元的数量达到要求;(4)在阻尼层I外包裹厚度为3mm的钢板作为约束层,即可得到垫高阻尼减振静音钢轨中的多层约束垫高阻尼减振静音钢轨。The preparation method of the multi-layer constrained pad height damping vibration-absorbing silent steel rail also includes the step (2a) between the step (2) and the step (3): on the carbon nanotube modified polyurethane foam of the damping unit of the outermost layer Continue to spray the damping material, sandblasting; pouring the carbon nanotube modified polyurethane foam as the cushion layer; repeat step (2a), until the number of damping units reaches the requirements; (4) wrapping the damping layer I with a thickness of 3mm The steel plate is used as the constraining layer, and the multi-layer constrained heightening, damping, vibration-reducing and silent steel rail in the raised-damping, vibration-reducing and quiet steel rail can be obtained.

实施例8:多层约束垫高阻尼减振静音钢轨Embodiment 8: Multi-layer constrained pad height damping vibration reduction silent steel rail

与实施例7不同的是,多层约束垫高阻尼减振静音钢轨,所述阻尼单元的数量是3。所述阻尼层A的厚度为1.5mm,所述垫高层的厚度为12mm,所述阻尼层I的厚度均为1.5mm。所述金刚砂的数量为1.0kg/m2,所述金刚砂的粒径为1.8mm。The difference from Embodiment 7 is that the number of the damping units is three for the multi-layer constrained pad height damping vibration damping silent steel rail. The thickness of the damping layer A is 1.5mm, the thickness of the cushion layer is 12mm, and the thickness of the damping layer I is 1.5mm. The quantity of the corundum is 1.0 kg/m 2 , and the particle size of the corundum is 1.8 mm.

所述碳纳米管改性聚氨酯泡沫的制备,步骤(3)将混合了羟基化碳纳米管的B组分与A组分异氰酸酯在70℃的温度条件和17MPa的压力条件下反应,即可得到碳纳米管改性聚氨酯泡沫。所述相邻空心槽之间的间隔不小于5mm;所述空心槽的孔径为5mm。In the preparation of the carbon nanotube-modified polyurethane foam, step (3) reacts component B mixed with hydroxylated carbon nanotubes and component A isocyanate at a temperature of 70°C and a pressure of 17MPa to obtain Carbon nanotube modified polyurethane foam. The interval between the adjacent hollow grooves is not less than 5mm; the hole diameter of the hollow grooves is 5mm.

多层约束垫高阻尼减振静音钢轨的制备方法,包括以下步骤:重复进行步骤(2a)2次;(4)在阻尼层I外包裹厚度为2mm的钢板作为约束层,即可得到垫高阻尼减振静音钢轨中的多层约束垫高阻尼减振静音钢轨。The preparation method of the multi-layer constrained pad height damping and vibration-reducing mute rail comprises the following steps: repeating step (2a) twice; (4) wrapping a steel plate with a thickness of 2 mm on the damping layer I as the constrained layer to obtain the pad height The multi-layer constraint pad in the damping and vibration-damping silent steel rail heightens the damping and vibration-damping silent steel rail.

实施例9:多层约束垫高阻尼减振静音钢轨Embodiment 9: Multi-layer constrained pad height damping vibration reduction silent steel rail

与实施例7不同的是,多层约束垫高阻尼减振静音钢轨,所述阻尼单元的数量是3。所述阻尼层A的厚度为0.5mm,所述垫高层的厚度为8mm,所述阻尼层I的厚度均为0.5mm。The difference from Embodiment 7 is that the number of the damping units is three for the multi-layer constrained pad height damping vibration damping silent steel rail. The thickness of the damping layer A is 0.5mm, the thickness of the cushion layer is 8mm, and the thickness of the damping layer I is 0.5mm.

多层约束垫高阻尼减振静音钢轨的制备方法,包括以下步骤:重复进行步骤(2a)2次;(4)在阻尼层I外包裹厚度为2mm的钢板作为约束层,即可得到垫高阻尼减振静音钢轨中的多层约束垫高阻尼减振静音钢轨。The preparation method of the multi-layer constrained pad height damping and vibration-reducing mute rail comprises the following steps: repeating step (2a) twice; (4) wrapping a steel plate with a thickness of 2 mm on the damping layer I as the constrained layer to obtain the pad height The multi-layer constraint pad in the damping and vibration-damping silent steel rail heightens the damping and vibration-damping silent steel rail.

表1实施例1-9检测结果列表Table 1 Example 1-9 test result list

一阶损耗因子first order loss factor 二阶损耗因子second order loss factor 振动加速度总级值Total value of vibration acceleration 空白钢板blank steel plate 0.0140.014 0.0160.016 158.0158.0 实施例1Example 1 0.1340.134 0.1670.167 144.5144.5 实施例2Example 2 0.1250.125 0.1560.156 145.1145.1 实施例3Example 3 0.1290.129 0.1610.161 144.8144.8 实施例4Example 4 0.1610.161 0.1960.196 140.6140.6 实施例5Example 5 0.1690.169 0.2010.201 140.1140.1 实施例6Example 6 0.1550.155 0.1890.189 141.9141.9 实施例7Example 7 0.1930.193 0.2340.234 139.2139.2 实施例8Example 8 0.2240.224 0.2570.257 138.0138.0 实施例9Example 9 0.2120.212 0.2430.243 138.5138.5

损耗因子代表结构的耗能能力,越大越好;振动加速度总级值表明结构的振动情况,越小越好。由表1可知,与空白钢板相比,实施例1-9制备的减振降噪静音钢轨,损耗因子增加一个数量级,振动加速度总级值则减小13-20dB。其中,以实例8效果最好,与空白板相比振动加速度总级值能降低20dB;其余实例相比空白板振动加速度总级值都有明显降低,损耗因子相比空白板均有明显增大。说明多层约束垫高阻尼减振静音钢轨的减振降噪效果最好。The loss factor represents the energy dissipation capacity of the structure, the larger the better; the total vibration acceleration value indicates the vibration of the structure, the smaller the better. It can be seen from Table 1 that compared with the blank steel plate, the loss factor of the vibration-damping, noise-reducing and silent rail prepared in Examples 1-9 increases by an order of magnitude, and the total level of vibration acceleration decreases by 13-20dB. Among them, Example 8 has the best effect. Compared with the blank board, the total value of vibration acceleration can be reduced by 20dB; compared with the blank board, the total value of vibration acceleration in other cases is significantly lower, and the loss factor is significantly increased compared with the blank board. . It shows that the damping and noise reduction effect of the multi-layer constrained pad height damping and silent rail is the best.

Claims (10)

1. padded damping vibration attenuation silencing steel rail, it is characterised in that:Including rail basic unit, damping unit and damping layer I, the damping Unit includes damping layer A and pad level, and the pad level is located near the side of damping layer I, and the damping layer A is located near steel The side of base of the rail layer;The pad level is 4-16 with the thickness ratio of damping layer A;The pad level is with the thickness ratio of damping layer I 4-16;The pad level is carbon nano-tube modification polyurethane foam;The preparation of the carbon nano-tube modification polyurethane foam includes Following steps:(1) CNT is modified, obtains hydroxylated CNT;(2) what step (1) was obtained is hydroxylated CNT is added in the B component for preparing pad level foam, i.e. hydroxy compounds;(3) hydroxylating carbon will be mixed with to receive The B component of mitron is reacted with component A isocyanates, you can obtain carbon nano-tube modification polyurethane foam.
2. padded damping vibration attenuation silencing steel rail according to claim 1, it is characterised in that:The poly- ammonia of carbon nano-tube modification Some grooves are evenly distributed with ester foam, the aperture of the groove is 4-6mm, the interval between the adjacent hollow groove Not less than 4-6mm.
3. padded damping vibration attenuation silencing steel rail according to claim 1 and 2, it is characterised in that:It is anti-in the step (3) Answer 60-80 DEG C of temperature, reaction pressure 15-18MPa.
4. padded damping vibration attenuation silencing steel rail according to claim 3, it is characterised in that:The damping layer I is away from damping The side of unit is additionally provided with restraint layer, and the restraint layer is steel plate;The quantity of the damping unit is 1-3.
5. padded damping vibration attenuation silencing steel rail according to claim 3, it is characterised in that:It is padded in the damping unit The silicon carbide layer for being embedded in the two surface is equipped between layer and damping layer A, the quantity of the diamond dust is 0.5-1.5kg/m2, The particle diameter of the diamond dust is 1.6-2.0mm.
6. the preparation method of padded damping vibration attenuation silencing steel rail, it is characterised in that:Comprise the following steps:(1) in rail basic unit Side spraying damping material obtains damping layer A, then carries out blasting treatment;(2) poured as padded on damping layer A after processing The carbon nano-tube modification polyurethane foam of layer, completes a damping unit;(3) continue on carbon nano-tube modification polyurethane foam Spraying damping material obtains damping layer I;The padded damping vibration attenuation of freedom that can obtain in padded damping vibration attenuation silencing steel rail is Jing Yin Rail.
7. the preparation method of padded damping vibration attenuation silencing steel rail according to claim 6, it is characterised in that:The damping layer The thickness of A is 3-5mm, and the thickness of the pad level is 18-22mm, and the thickness of the damping layer I is 3-5mm.
8. the preparation method of padded damping vibration attenuation silencing steel rail according to claim 6, it is characterised in that:Also include step (4):It is the steel plate of 1-3mm as restraint layer in damping layer I outer wrappings thickness, you can in obtaining padded damping vibration attenuation silencing steel rail The padded damping vibration attenuation silencing steel rail of constraint;The thickness of the damping layer A is 1-3mm, and the thickness of the pad level is 14- 16mm, the thickness of the damping layer I is 1-3mm.
9. the preparation method of padded damping vibration attenuation silencing steel rail according to claim 6, it is characterised in that:Also include being located at The step of between step (2) and step (3) (2a):On the carbon nano-tube modification polyurethane foam of outermost damping unit after Continuous spraying damping material, blasting treatment;Then pour as the carbon nano-tube modification polyurethane foam of pad level;Repeat step Suddenly (2a), until the quantity of damping unit reaches requirement;Step (4):In damping layer I outer wrappings thickness for the steel plate of 1-3mm is made It is restraint layer, you can the multilayer obtained in padded damping vibration attenuation silencing steel rail constrains padded damping vibration attenuation silencing steel rail;The resistance The thickness of Buddhist nun's layer A is 0.5-1.5mm, and the thickness of the pad level is 8-12mm, and the thickness of the damping layer I is 0.5- 1.5mm。
10. the preparation method of padded damping vibration attenuation silencing steel rail according to claim 9, it is characterised in that:The sandblasting What is processed concretely comprises the following steps:Spraying opportunity is 8-10s after spraying damping material;Sandblasting air pressure is 0.6-0.8MPa, sandblasting distance It is 1m, temperature is 15-25 DEG C.
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CN205763804U (en) * 2016-06-28 2016-12-07 四川睿铁科技有限责任公司 A kind of silencing steel rail production line cast operation auxiliary mould

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CN107351465A (en) * 2017-07-19 2017-11-17 北京海月星科技有限公司 A kind of preparation method of heat-insulated vibration suppression material and application
CN110864836A (en) * 2019-11-15 2020-03-06 华东交通大学 Longitudinal force detection method based on steel rail
CN110864836B (en) * 2019-11-15 2021-09-10 华东交通大学 Longitudinal force detection method based on steel rail
CN112250820A (en) * 2020-10-21 2021-01-22 盐城市恒丰海绵有限公司 Sinking-bottom expanded polyurethane with high tearing property and preparation method thereof

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