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CN106566680A - 高效洗衣液及其制备方法 - Google Patents

高效洗衣液及其制备方法 Download PDF

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CN106566680A
CN106566680A CN201610890368.9A CN201610890368A CN106566680A CN 106566680 A CN106566680 A CN 106566680A CN 201610890368 A CN201610890368 A CN 201610890368A CN 106566680 A CN106566680 A CN 106566680A
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parts
sodium
laundry detergent
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agent
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向洋
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Chongqing Wuyi Clean New Material Co Ltd
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Chongqing Wuyi Clean New Material Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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    • C11D3/2075—Carboxylic acids-salts thereof
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38618—Protease or amylase in liquid compositions only
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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Abstract

本发明属于日用品技术领域，具体涉及一种高效洗衣液。该洗衣液由以下质量份组分组成：脂肪酸甲酯乙氧基氧化物6.32‑8.54份、聚乙二醇辛基苯基醚1.38‑1.45份、烷基酚聚氧乙烯醚1.26‑1.33份、碳酸氢钠0.41‑0.54份、硫酸钠1.2‑1.7份、复合酶0.18‑0.25份、酶稳定剂0.15‑0.18份、聚乙二醇2.4‑2.8份、硼砂1.3‑1.6份、pH调节剂0.56‑0.63份、抗再沉积剂0.36‑0.48份、荧光增白剂0.35‑0.41份、柠檬油0.14‑0.17份和水59‑66份。本发明的洗衣液味道清香，去污能力强，抗污渍再沉积能力好，其制备方法简单，易于工业化生产。

Description

高效洗衣液及其制备方法
技术领域
本发明属于日用品技术领域，具体涉及一种高效洗衣液及其制备方法。
背景技术
洗衣液是一种使用方便、易溶、香味好的织物洗涤用品。洗衣液在洗衣过程中不伤手、不伤衣，而且衣物洗后会更加蓬松、柔软、光滑亮泽，能够维护衣服的色泽，不容易洗旧，不容易受水质的影响，没有残留，所以洗衣液越来越受到人们的青睐。
但是现有的洗衣液去污能力不好。
发明内容
有鉴于此，本发明的目的在于提供一种高效洗衣液。该洗衣液去污效果好。
为实现以上目的，本发明的技术方案如下：
一种高效洗衣液，由以下质量份组分组成：脂肪酸甲酯乙氧基氧化物6.32-8.54份、聚乙二醇辛基苯基醚1.38-1.45份、烷基酚聚氧乙烯醚1.26-1.33份、碳酸氢钠0.41-0.54份、硫酸钠1.2-1.7份、复合酶0.18-0.25份、酶稳定剂0.15-0.18份、聚乙二醇2.4-2.8份、硼砂1.3-1.6份、pH调节剂0.56-0.63份、抗再沉积剂0.36-0.48份、荧光增白剂0.35-0.41份、柠檬油0.14-0.17份和水59-66份。
所述脂肪酸甲酯乙氧基化物(FMEE)是一种典型的非离子表面活性剂，是以脂肪酸甲酯经相应催化剂作用下，直接与环氧乙烷(EO)发生加成制得，与传统的脂肪醇乙氧基化物(AEO)相比，具有低泡沫、高浊点，冷水溶速度快，除油除蜡效果好，在冬季仍具有很好的流动性。
所述聚乙二醇辛基苯基醚是一种非离子型表面活性剂(或称去污剂)，分子量为646.86，能溶解脂质，以增加抗体对细胞膜的通透性。
所述复合酶是一种生物制剂，富含蛋白酶、淀粉酶、果胶酶等。
所述硼砂是非常重要的含硼矿物及硼化合物。通常为含有无色晶体的白色粉末，易溶于水。硼砂有广泛的用途，可用作清洁剂、化妆品、杀虫剂，也可用于配置缓冲溶液和制取其他硼化合物等。
所述柠檬油是由柠檬的新鲜果皮经压榨而得的黄色液体，有浓郁的柠檬香气。
进一步，所述烷基酚聚氧乙烯醚为壬基酚聚氧乙烯醚、辛基酚聚氧乙烯醚或二者的组合物。所述烷基酚聚氧乙烯醚(APEO)是一种重要的聚氧乙烯型非离子表面活性剂，它具有性质稳定、耐酸碱和成本低等特征，主要用以生产高性能洗涤剂，是印染助剂中最常用的主要原料之一。
进一步，所述烷基酚聚氧乙烯醚由壬基酚聚氧乙烯醚和辛基酚聚氧乙烯醚按照2：3的质量比配比而成。
进一步，所述酶稳定剂由甲酸钠和甲酸钙按照1:2的质量比配比而成。
进一步，所述聚乙二醇的分子量为7500-8000。所述聚乙二醇无毒、无刺激性，味微苦，具有良好的水溶性，并与许多有机物组份有良好的相溶性。它们具有优良的润滑性、保湿性、分散性、粘接剂、抗静电剂及柔软剂。
进一步，所述pH调节剂由无水硅酸钠和碳酸钠按照4:3的质量比配比而成。所述PH调节剂又称为PH值调节剂、酸度调节剂或PH值控制剂。
进一步，所述抗再沉积剂为丙烯酸聚合物、丙烯酸-马来酸酐共聚物或二者的组合物。抗再沉积是从织物纤维或其他物体洗脱下来的不涪解固体污垢，使其分散并悬浮于洗涤溶液，而不再返回沉积到织物或其他物体上的一种洗涤作用。具有这种抗再沉积作用的物质称为抗再沉积剂，如羧甲基纤维素钠、内烯酸均聚物等。
进一步，所述抗再沉积剂由丙烯酸聚合物和丙烯酸-马来酸酐共聚物按照2:1的质量比配比而成。
进一步，所述荧光增白剂为苯并噁唑类荧光增白剂或1,3-二苯基-吡唑啉类荧光增白剂。所述荧光增白剂是一种荧光染料，或称为白色染料，也是一种复杂的有机化合物。它的特性是能激发入射光线产生荧光，使所染物质获得类似萤石的闪闪发光的效应，使肉眼看到的物质很白。
本发明的目的还在于保护所述高效洗衣液的制备方法，具体包括以下步骤：
S1:将碳酸氢钠、硫酸钠溶于水中，搅拌均匀；
S2:将步骤S1所得溶液加热至63-65℃，加入聚乙二醇，搅拌均匀，冷却至50-55℃，加入聚乙二醇辛基苯基醚、烷基酚聚氧乙烯醚、脂肪酸甲酯乙氧基氧化物，并搅拌均匀，冷却至室温；
S3:向步骤S2所得混合物中依次加入硼砂、复合酶、酶稳定剂、荧光增白剂、抗再沉积剂、pH调节剂和柠檬油；搅拌均匀。
本发明的有益效果在于：
本发明的洗衣液味道清香，去污能力强，抗污渍再沉积能力好，其制备方法简单，易于工业化生产。
具体实施方式
下面将结合实施例对本发明的实施方案进行详细描述，但是本领域技术人员将会理解，下列实施例仅用于说明本发明，而不应视为限定本发明的范围。优选实施例中未注明具体条件的实验方法，通常按照常规条件。
实施例1
一种高效洗衣液，其组成为：脂肪酸甲酯乙氧基氧化物8.54kg、聚乙二醇辛基苯基醚1.45kg、壬基酚聚氧乙烯醚1.26kg、碳酸氢钠0.54kg、硫酸钠1.7kg、复合酶0.25kg、甲酸钠0.05kg、甲酸钙0.1kg、分子量为7500-8000的聚乙二醇2.4kg、硼砂1.6kg、无水硅酸钠0.32kg、碳酸钠0.24kg、丙烯酸聚合物0.36kg、苯并噁唑类荧光增白剂0.41kg、柠檬油0.14kg和水59kg。
所述高效洗衣液的制备方法为：
S1:将碳酸氢钠、硫酸钠溶于水中，搅拌均匀；
S2:将步骤S1所得溶液加热至65℃，加入聚乙二醇，搅拌均匀，冷却至55℃，加入聚乙二醇辛基苯基醚、壬基酚聚氧乙烯醚、脂肪酸甲酯乙氧基氧化物，并搅拌均匀，冷却至室温；
S3:向步骤S2所得混合物中依次加入硼砂、复合酶、甲酸钠、甲酸钙、苯并噁唑类荧光增白剂、丙烯酸聚合物、无水硅酸钠、碳酸钠和柠檬油；搅拌均匀。
实施例2
一种高效洗衣液，其组成为：脂肪酸甲酯乙氧基氧化物6.32kg、聚乙二醇辛基苯基醚1.38kg、辛基酚聚氧乙烯醚1.33kg、碳酸氢钠0.41kg、硫酸钠1.2kg、复合酶0.18kg、甲酸钠0.06kg、甲酸钙0.12kg、分子量为7500-8000的聚乙二醇2.8kg、硼砂1.3kg、无水硅酸钠0.36kg、碳酸钠0.27kg、丙烯酸-马来酸酐共聚物0.48kg、1,3-二苯基-吡唑啉类荧光增白剂0.41kg、柠檬油0.17kg和水66kg。
所述高效洗衣液的制备方法为：
S1:将碳酸氢钠、硫酸钠溶于水中，搅拌均匀；
S2:将步骤S1所得溶液加热至63℃，加入聚乙二醇，搅拌均匀，冷却至50℃，加入聚乙二醇辛基苯基醚、辛基酚聚氧乙烯醚、脂肪酸甲酯乙氧基氧化物，并搅拌均匀，冷却至室温；
S3:向步骤S2所得混合物中依次加入硼砂、复合酶、甲酸钠、甲酸钙、1,3-二苯基-吡唑啉类荧光增白剂、丙烯酸-马来酸酐共聚物、无水硅酸钠和碳酸钠和柠檬油；搅拌均匀。
实施例3
一种高效洗衣液，其组成为：脂肪酸甲酯乙氧基氧化物7.55kg、聚乙二醇辛基苯基醚1.42kg、壬基酚聚氧乙烯醚、辛基酚聚氧乙烯醚或二者按照2：3的质量比1.3kg、碳酸氢钠0.48kg、硫酸钠1.6kg、复合酶0.21kg、甲酸钠0.052kg、甲酸钙0.104kg、分子量为7500-8000的聚乙二醇2.6kg、硼砂1.4kg、无水硅酸0.324kg、碳酸钠0.243kg、丙烯酸聚合物0.3kg、丙烯酸-马来酸酐共聚物0.15kg、苯并噁唑类荧光增白剂0.38kg、柠檬油0.16kg和水63kg。
所述高效洗衣液的制备方法为：
S1:将碳酸氢钠、硫酸钠溶于水中，搅拌均匀；
S2:将步骤S1所得溶液加热至64℃，加入聚乙二醇，搅拌均匀，冷却至52℃，加入聚乙二醇辛基苯基醚、壬基酚聚氧乙烯醚、辛基酚聚氧乙烯醚、脂肪酸甲酯乙氧基氧化物，并搅拌均匀，冷却至室温；
S3:向步骤S2所得混合物中依次加入硼砂、复合酶、甲酸钠、甲酸钙、苯并噁唑类荧光增白剂、丙烯酸聚合物、丙烯酸-马来酸酐共聚物、无水硅酸钠和碳酸钠和柠檬油；搅拌均匀。
对比例1
一种高效洗衣液，其组成为：脂肪酸甲酯乙氧基氧化物6.64kg、聚乙二醇辛基苯基醚1.39kg、辛基酚聚氧乙烯醚1.28kg、碳酸氢钠0.49kg、硫酸钠1.3kg、复合酶0.19kg、甲酸钠0.05kg、甲酸钙0.1kg、分子量为7500-8000的聚乙二醇2.5kg、硼砂1.36kg、无水硅酸钠0.32kg、碳酸钠0.24kg、1,3-二苯基-吡唑啉类荧光增白剂0.36kg、柠檬油0.15kg和水60kg。
所述高效洗衣液的制备方法为：
S1:将碳酸氢钠、硫酸钠溶于水中，搅拌均匀；
S2:将步骤S1所得溶液加热至64℃，加入聚乙二醇，搅拌均匀，冷却至54℃，加入聚乙二醇辛基苯基醚、辛基酚聚氧乙烯醚、脂肪酸甲酯乙氧基氧化物，并搅拌均匀，冷却至室温；
S3:向步骤S2所得混合物中依次加入硼砂、复合酶、甲酸钠、甲酸钙、1,3-二苯基-吡唑啉类荧光增白剂、丙烯酸聚合物、无水硅酸钠和碳酸钠和柠檬油；搅拌均匀。
对比例2
一种高效洗衣液，其组成为：脂肪酸甲酯乙氧基氧化物7.56kg、聚乙二醇辛基苯基醚1.42kg、辛基酚聚氧乙烯醚1.29kg、碳酸氢钠0.45kg、硫酸钠1.27kg、复合酶0.19kg、甲酸钠0.06kg、甲酸钙0.12kg、分子量为7500-8000的聚乙二醇2.7kg、硼砂1.4kg、无水硅酸钠0.324kg、碳酸钠0.243kg、丙烯酸-马来酸酐共聚物比0.55kg、1,3-二苯基-吡唑啉类荧光增白剂0.37kg、柠檬油0.16kg和水65kg。
所述高效洗衣液的制备方法为：
S1:将碳酸氢钠、硫酸钠溶于水中，搅拌均匀；
S2:将步骤S1所得溶液加热至63℃，加入聚乙二醇，搅拌均匀，冷却至53℃，加入聚乙二醇辛基苯基醚、辛基酚聚氧乙烯醚、脂肪酸甲酯乙氧基氧化物，并搅拌均匀，冷却至室温；
S3:向步骤S2所得混合物中依次加入硼砂、复合酶、甲酸钠、甲酸钙、1,3-二苯基-吡唑啉类荧光增白剂、丙烯酸-马来酸酐共聚物或二者、无水硅酸钠和碳酸钠和柠檬油；搅拌均匀。
对比例3
一种高效洗衣液，其组成为：脂肪酸甲酯乙氧基氧化物8.14kg、聚乙二醇辛基苯基醚1.42kg、壬基酚聚氧乙烯醚1.33kg、碳酸氢钠0.53kg、硫酸钠1.38kg、复合酶0.24kg、甲酸钠0.052kg、甲酸钙0.104kg、分子量为7500-8000的聚乙二醇2.5kg、硼砂1.36kg、无水硅酸钠0.328kg、碳酸钠0.246kg、丙烯酸聚合物0.37kg、苯并噁唑类荧光增白剂0.36kg、柠檬油0.16kg和水65kg。
所述高效洗衣液的制备方法为：
S1:将碳酸氢钠、硫酸钠溶于水中，搅拌均匀；
S2:将步骤S1所得溶液加热至65℃，加入聚乙二醇，搅拌均匀，冷却至51℃，加入聚乙二醇辛基苯基醚、壬基酚聚氧乙烯醚、脂肪酸甲酯乙氧基氧化物、丙烯酸聚合物，并搅拌均匀，冷却至室温；
S3:向步骤S2所得混合物中依次加入硼砂、复合酶、甲酸钠、甲酸钙、苯并噁唑类荧光增白剂、无水硅酸钠和碳酸钠和柠檬油；搅拌均匀。
对比例4
以公开号为CN103773622A发明专利申请实施例4所述配方进行洗衣液配制。配方为：脂肪醇聚氧乙烯醚10kg、脂肪醇聚氧乙烯醚硫酸钠8kg、α-烯基磺酸钠1kg、仲烷基硫酸钠5kg、椰子油脂肪酸二乙醇胺5kg、碱性蛋白酶1kg、乙二酸1kg、檬酸钠和三乙醇胺复配混合物1kg、二苯乙烯基联苯类荧光增白剂0.05kg、香精0.5kg、防腐剂0.05kg、去离子水67.4kg。
洗衣液外观及性能测试
对实施例1-3及对比例1-4得到的洗衣液进行外观、气味、稳定性方面的感官评价，结果如下表所示：
备注：外观测试方法为：取适量样品置于干燥洁净试管内，在非直射光线条件下进行观察。耐寒稳定性测试方法为：将100mL样品倒入洁净的250mL无色具塞广口玻璃瓶中，置于-5±2℃冰箱中，24h后取出，置于室内恢复至室温后，检查外观。耐热稳定性测试方法为：将100mL样品倒入洁净的250mL无色具塞广口玻璃瓶中，置于40±2℃冰箱中，24h后取出，置于室内恢复至室温后，检查外观。
按照《GB/T13174-2008衣料用洗涤剂去污力及循环洗涤性能的测定》，对实施例1-3及对比例1-4得到的洗衣液，进行去污值、白度保持比值、沉积灰分比值方面的测试，结果如下表所示：
最后说明的是，以上实施例仅用以说明本发明的技术方案而非限制，尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的宗旨和范围，其均应涵盖在本发明的权利要求范围当中。

Claims (10)

1.一种高效洗衣液，其特征在于，由以下质量份组分组成：脂肪酸甲酯乙氧基氧化物6.32-8.54份、聚乙二醇辛基苯基醚1.38-1.45份、烷基酚聚氧乙烯醚1.26-1.33份、碳酸氢钠0.41-0.54份、硫酸钠1.2-1.7份、复合酶0.18-0.25份、酶稳定剂0.15-0.18份、聚乙二醇2.4-2.8份、硼砂1.3-1.6份、pH调节剂0.56-0.63份、抗再沉积剂0.36-0.48份、荧光增白剂0.35-0.41份、柠檬油0.14-0.17份和水59-66份。
2.根据权利要求1所述的一种高效洗衣液，其特征在于，所述烷基酚聚氧乙烯醚为壬基酚聚氧乙烯醚、辛基酚聚氧乙烯醚或二者的组合物。
3.根据权利要求2所述的一种高效洗衣液，其特征在于，所述烷基酚聚氧乙烯醚由壬基酚聚氧乙烯醚和辛基酚聚氧乙烯醚按照2：3的质量比配比而成。
4.根据权利要求1所述的一种高效洗衣液，其特征在于，所述酶稳定剂由甲酸钠和甲酸钙按照1:2的质量比配比而成。
5.根据权利要求1所述的一种高效洗衣液，其特征在于，所述聚乙二醇的分子量为7500-8000。
6.根据权利要求1所述的一种高效洗衣液，其特征在于，所述pH调节剂由无水硅酸钠和碳酸钠按照4:3的质量比配比而成。
7.根据权利要求1所述的一种高效洗衣液，其特征在于，所述抗再沉积剂为丙烯酸聚合物、丙烯酸-马来酸酐共聚物或二者的组合物。
8.根据权利要求7所述的一种高效洗衣液，其特征在于，所述抗再沉积剂由丙烯酸聚合物和丙烯酸-马来酸酐共聚物按照2:1的质量比配比而成。
9.根据权利要求1所述的一种高效洗衣液，其特征在于，所述荧光增白剂为苯并噁唑类荧光增白剂或1,3-二苯基-吡唑啉类荧光增白剂。
10.权利要求1所述的高效洗衣液的制备方法，其特征在于，包括以下步骤：
S1:将碳酸氢钠、硫酸钠溶于水中，搅拌均匀；
S2:将步骤S1所得溶液加热至63-65℃，加入聚乙二醇，搅拌均匀，冷却至50-55℃，加入聚乙二醇辛基苯基醚、烷基酚聚氧乙烯醚、脂肪酸甲酯乙氧基氧化物，并搅拌均匀；冷却至室温；
S3:向步骤S2所得混合物中依次加入硼砂、复合酶、酶稳定剂、荧光增白剂、抗再沉积剂、pH调节剂和柠檬油；搅拌均匀。
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CN102876483A (zh) * 2012-10-11 2013-01-16 广州立白企业集团有限公司 一种低泡易漂型洗衣液组合物及其制备方法
CN104232364A (zh) * 2014-09-30 2014-12-24 郑通彪 一种花香洗衣液
CN105567454A (zh) * 2015-12-30 2016-05-11 广州市南大实业有限公司 一种抗菌洗衣液及其制备方法与应用
CN105907503A (zh) * 2016-05-24 2016-08-31 攀柔莎（江苏）生物科技股份有限公司 一种高效浓缩洗衣液

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102876483A (zh) * 2012-10-11 2013-01-16 广州立白企业集团有限公司 一种低泡易漂型洗衣液组合物及其制备方法
CN104232364A (zh) * 2014-09-30 2014-12-24 郑通彪 一种花香洗衣液
CN105567454A (zh) * 2015-12-30 2016-05-11 广州市南大实业有限公司 一种抗菌洗衣液及其制备方法与应用
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