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CN106549058A - Semiconductor device manufacturing method - Google Patents

Semiconductor device manufacturing method Download PDF

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Publication number
CN106549058A
CN106549058A CN201510609662.3A CN201510609662A CN106549058A CN 106549058 A CN106549058 A CN 106549058A CN 201510609662 A CN201510609662 A CN 201510609662A CN 106549058 A CN106549058 A CN 106549058A
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CN
China
Prior art keywords
silicon
layer
germanium
germanium silicon
lamination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510609662.3A
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Chinese (zh)
Inventor
秦长亮
殷华湘
赵超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute of Microelectronics of CAS
Original Assignee
Institute of Microelectronics of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Microelectronics of CAS filed Critical Institute of Microelectronics of CAS
Priority to CN201510609662.3A priority Critical patent/CN106549058A/en
Publication of CN106549058A publication Critical patent/CN106549058A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66787Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
    • H01L29/66795Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/26Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, elements provided for in two or more of the groups H01L29/16, H01L29/18, H01L29/20, H01L29/22, H01L29/24, e.g. alloys
    • H01L29/267Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, elements provided for in two or more of the groups H01L29/16, H01L29/18, H01L29/20, H01L29/22, H01L29/24, e.g. alloys in different semiconductor regions, e.g. heterojunctions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/785Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thin Film Transistor (AREA)

Abstract

The invention provides a FinFET manufacturing method, which forms a silicon/germanium-silicon lamination and removes one material to form a nanowire, wherein the silicon/germanium-silicon lamination is contained in a fin, the nanowire does not need to be supported by an extra pad, so that the difficulty of the process is reduced, and the wet etching process with high selection ratio can be used to remove one material without using a dry etching process due to the property difference of the silicon and the germanium-silicon, so that the process is further simplified; and the method is compatible with the conventional FinFET process, and the FinFET nanowire device can be simply, conveniently and effectively obtained.

Description

Method, semi-conductor device manufacturing method
Technical field
The present invention relates to method, semi-conductor device manufacturing method field, in particular to one kind The manufacture method of FinFET semiconductor device.
Background technology
Over nearly 30 years, semiconductor device is always according to Moore's Law scaled down, quasiconductor collection Characteristic size into circuit constantly reduces, and integrated level is improved constantly.As technology node enters deep Within submicrometer field, such as 100nm, or even within 45nm, conventional field effect transistor (FET), namely plane FET, start to meet with the restriction of various basic physical laws so as to The prospect of scaled down is challenged.The FET of numerous new structures is developed, to answer Demand to reality, wherein, FinFET is exactly a kind of new construction for having very much a scaled down potentiality Device.
FinFET, FinFET is a kind of many gate semiconductor devices.Due to structure On exclusive feature, FinFET becomes the device of deep submicron integrated circuit field very with prospects Part.As its name suggests, FinFET includes that the Fin of a substrate perpendicular to body silicon, Fin are claimed For fin or fin-shaped semiconductor column, different FinFET is separated by sti structure.It is different In conventional plane FET, the channel region of FinFET is within Fin.Gate insulator and grid Pole surrounds Fin in side and top surface, so as to form the grid at least two sides, i.e., positioned at the two of Fin Grid on individual side;Meanwhile, by the thickness for controlling Fin so that FinFET has splendid Characteristic:More preferable short-channel effect rejection ability, more preferable sub-threshold slope, relatively low pass State electric current, eliminates floater effect, and lower running voltage is more beneficial for scaled.
Although FinFET has above-mentioned various advantages, yet suffer from that electric current is little, grid-control is weak Situation.In order to solve the above problems, nano wire is considered as a kind of reasonable solution. But the lithographic method that the method for routine forms nano wire is more complicated, with conventional FinFET works Skill is simultaneously not bery compatible;Nano wire needs pad to be supported simultaneously.This causes technics comparing complicated, Improve cost of manufacture
Accordingly, it is desirable to provide a kind of new FinFET manufacture methods, with easier and effective Method forms nano wire.
The content of the invention
The present invention proposes a kind of FinFET manufacture methods, employs silicon/germanium silicon lamination and height Select than etching technics, the FinFET with nano thread structure is manufactured with simple and effective.
The invention provides a kind of method, semi-conductor device manufacturing method, for manufacturing FinFET, Comprise the steps:
For manufacturing FinFET, it is characterised in that comprise the steps:
Substrate is provided, and impurity layer is formed on the surface of the substrate;
Alternately laminated silicon/germanium silicon the lamination of silicon layer and germanium silicon layer is formed on the impurity layer;
By patterned process, fin is formed;
STI is formed in the fin both sides;
Form dummy gate oxide layer, dummy gate electrode storehouse, grid curb wall;
Form source drain extension area and source-drain area;
Comprehensive metallization medium layer, covers the dummy gate electrode storehouse;
Planarization process exposes the dummy gate electrode storehouse upper surface, and removes the illusory grid Pole storehouse and the dummy gate oxide layer;
Remove the silicon or germanium silicon material in the silicon/germanium silicon lamination;
Form gate insulator and grid.
According to an aspect of the present invention, the impurity layer is injection over the substrate or outer Prolong the layer that doping in situ is formed, which has and semiconductor device source-drain area to be made doping class The contrary impurity of type;Between the impurity layer and the substrate, formation prevents impurity diffusion Barrier layer;The barrier layer is element of the atomic number less than silicon, preferably carbon.
According to an aspect of the present invention, the top of the STI is higher than the silicon/germanium silicon lamination Bottom.
According to an aspect of the present invention, the silicon or germanium in the silicon/germanium silicon lamination is removed During silicon materials, silicon or germanium silicon material are removed using the technique of high etching selection ratio;Remove described During silicon in silicon/germanium silicon lamination, using dry etching or wet etching;Using wet etching When, select the organic solvent with hydroxyl, preferably TMAH.
It is an advantage of the current invention that:By forming silicon/germanium silicon lamination and removing one of which material To form nano wire, among being contained in fin due to silicon/germanium silicon lamination, nano wire simultaneously need not It is supported using extra pad, reduces the difficulty of technique, also, due to silicon and germanium silicon Material property differences, can adopt high selectivity wet-etching technology remove one of which material Material, and dry etch process need not be adopted, further simplify technique;And and invent side Method and routine FinFET process compatibles, can obtain FinFET nano wire devices with simple and effective Part.
Description of the drawings
The schematic flow sheet of the semiconductor making method that Fig. 1-10 present invention is provided.
Specific embodiment
Hereinafter, by the specific embodiment that illustrates in accompanying drawing describing the present invention.But should manage Solution, these descriptions are simply exemplary, and are not intended to limit the scope of the present invention.Additionally, In below illustrating, the description to known features and technology is eliminated, to avoid unnecessarily obscuring Idea of the invention.
The present invention provides a kind of method, semi-conductor device manufacturing method, in particular to one kind FinFET manufacture method.Below, referring to Figure of description, will be described in the present invention The method, semi-conductor device manufacturing method of offer.
First, referring to accompanying drawing 1, there is provided substrate 1, impurity layer 2 is formed on the surface of substrate 1. Substrate 1 can be needed and reasonable selection, including but not limited to body silicon substrate, SOI according to device application Substrate, germanium substrate, germanium silicon (SiGe) substrate, such as compound semiconductor materials, gallium nitride (GaN), GaAs (GaAs), indium phosphide (InP) etc..For with conventional semiconductors work The consideration of skill compatibility and cost, the substrate 1 in the present embodiment are served as a contrast preferably by body silicon Bottom.
The layer that impurity layer 2 is formed for injection on substrate 1 or extension doping in situ, which has The impurity contrary with semiconductor device source-drain area doping type to be made.Further optionally, Between impurity layer 2 and substrate 1, formation prevents the barrier layer (not shown) that impurity spreads. Barrier layer can prevent the impurity element diffusion in impurity layer 2 and the doping for preventing in substrate 1 Elements Diffusion, can adopt and inject or be epitaxially formed on substrate 1.Barrier layer includes atom Element of the ordinal number less than silicon, it is preferred to use carbon produces barrier effect.
Then, referring to Fig. 2, on impurity layer 2, form silicon layer and germanium silicon layer is alternately laminated Silicon/germanium silicon lamination 3.Silicon/germanium silicon lamination 3 is preferably formed using epitaxy technique, and its bottom is Silicon or germanium, in the embodiment of present invention diagram, employ germanium silicon layer for the bottom;It is optional Embodiment in, silicon layer can be adopted for the bottom.Silicon/germanium silicon lamination 3 is for subsequent The thickness that nano wire, every layer of silicon layer and germanium silicon layer are formed in technique is 2-50nm, preferably 5-15nm, the number of stacking are generally more than 3 layers, preferably 5 layers, i.e., bottom-up Germanium silicon/silicon/germanium silicon/silicon/germanium silicon.
Referring to Fig. 3, which is side view, by patterned process, forms fin.Preferably, Fin includes the protuberance 4 of silicon/germanium silicon lamination 3, impurity layer 2 and substrate 1.
Then, referring to Fig. 4, which is side view, forms sti structure 5 in fin both sides.Its In, sti structure 5 is formed on substrate 1, using SiO2, the material such as SiON, specifically Technique include but is not limited to PECVD, HDP-CVD, RTO (rapid thermal oxidation) Deng.Preferably, bottom of the top of sti structure 5 higher than silicon/germanium silicon lamination 3, to realize receiving Isolation between nanowire device.
After sti structure 5 is formed, referring to Fig. 5, dummy gate oxide layer 6 is formed, it is illusory Stack 7, grid curb wall 8.Dummy gate oxide layer 6, dummy gate electrode storehouse 7, gate electrode side 8 lines of wall are typically intersected vertically with fin lines across on fin.Dummy gate oxide layer 6 is, for example, SiO2, the material of dummy gate electrode storehouse 7 is polysilicon or non-crystalline silicon etc., at this In one embodiment of invention, non-crystalline silicon is employed.The concrete forming method bag of grid curb wall 8 Include:Deposited overall grid curb wall material, and be etched back, wherein, grid curb wall material bag Include but be not limited to Si3N4
Then, referring to Fig. 6, source drain extension area and source-drain area 9 are formed.Concrete technology includes Except part silicon/3 material of germanium silicon lamination, source-drain electrode groove is formed, source drain extension area is then carried out With the filling of source-drain area 9, for example with techniques such as extensions.Source drain extension area and source-drain area 9 are also Silicide, or stress material can be adopted.
Referring to Fig. 7, comprehensive metallization medium layer 10 covers dummy gate electrode storehouse 7, gate electrode side Wall 8 etc..10 material of dielectric layer is SiO2Deng.
Then, referring to Fig. 8, flatening process is adopted to process to expose dummy gate electrode storehouse 7 Upper surface, then, remove dummy gate electrode storehouse 7 and dummy gate oxide layer 6, to form grid Pole groove 11.Gate recess 11 also expose the fin including silicon/germanium silicon lamination 3 top surface and Side.
Referring to Fig. 9, via the gate recess 11 for exposing, remove in silicon/germanium silicon lamination 3 One of silicon or germanium silicon material.Preferably, using high selectivity etching technics, for example dry method or Person's wet etching, removes silicon or germanium silicon.Wet etching is more electedly adopted, and does not adopt dry method to carve Etching technique, can further Simplified flowsheet.Silicon materials are eliminated in the preferred embodiment of the invention, When using wet etching, organic solvent of the selection with hydroxyl, preferably TMAH, this In the case of, retain germanium silicon as nano wire, namely the channel region of device, germanium-silicon groove area can have There is more preferable device performance;In an alternate embodiment of the invention, silicon can be retained with selective removal germanium silicon Material.To eliminate the schematic diagram after silicon materials in Fig. 9, wherein diagonal line hatches are represented and are eliminated The space formed after silicon materials.
Then, referring to Figure 10, gate insulator and grid 12 are formed.Gate insulator and grid Pole 12 is HKMG, wherein, gate insulator adopts high-K gate insulating layer material, choosing From one or a combination set of following material constitute one or more layers:Al2O3, HfO2, including HfSiOx、HfSiON、HfAlOx、HfTaOx、HfLaOx、HfAlSiOxAnd HfLaSiOx At least one in interior hafnio high K dielectric material, including ZrO2、La2O3、LaAlO3、 TiO2, or Y2O3At least one in interior rare earth base high K dielectric material.And the material of grid For metal, alloy or metallic compound, such as TiN, TaN, W etc..Gate insulator and Grid 12 surrounds remaining germanium silicon or silicon nanowires in silicon/germanium silicon lamination 3, so as to shaper Part.To surround the schematic diagram of germanium silicon nanowires in Figure 10, its medium square shadow representation grid is exhausted Edge layer and grid 12.
More than, the method, semi-conductor device manufacturing method of the present invention is illustrated.In the side of the present invention In method, by forming silicon/germanium silicon lamination and removing one of which material to form nano wire, by Among silicon/germanium silicon lamination is contained in fin, nano wire simultaneously need not be entered using extra pad Row is supported, and reduces the difficulty of technique, also, due to silicon and the Material property differences of germanium silicon, The wet-etching technology of high selectivity can be adopted to remove one of which material, and need not be using dry Method etching technics, further simplify technique;And and the method and the routine FinFET that invent Process compatible, can obtain FinFET nano-wire devices with simple and effective.
Although with reference to one or more exemplary embodiments explanation present invention, people in the art Member could be aware that without departing from the scope of the invention and device architecture and/or technological process made respectively Plant suitable change and equivalents.Additionally, can be made by disclosed teaching many may fitting In particular condition or material modification without deviating from the scope of the invention.Therefore, the purpose of the present invention Do not lie in be limited to as realize the present invention preferred forms and disclosed specific reality Example is applied, and disclosed device architecture and its manufacture method will include what is fallen within the scope of the present invention All embodiments.

Claims (7)

1. a kind of method, semi-conductor device manufacturing method, for manufacturing FinFET, its feature exists In comprising the steps:
Substrate is provided, and impurity layer is formed on the surface of the substrate;
Alternately laminated silicon/germanium silicon the lamination of silicon layer and germanium silicon layer is formed on the impurity layer;
By patterned process, fin is formed;
STI is formed in the fin both sides;
Form dummy gate oxide layer, dummy gate electrode storehouse, grid curb wall;
Form source drain extension area and source-drain area;
Comprehensive metallization medium layer, covers the dummy gate electrode storehouse;
Planarization process exposes the dummy gate electrode storehouse upper surface, and removes the illusory grid Pole storehouse and the dummy gate oxide layer;
Remove the silicon or germanium silicon material in the silicon/germanium silicon lamination;
Form gate insulator and grid.
2. method according to claim 1, it is characterised in that the impurity layer is in institute The layer that injection or extension doping in situ are formed on substrate is stated, which has partly is led with to make The contrary impurity of body device source-drain area doping type.
3. method according to claim 2, it is characterised in that in the impurity layer and institute State between substrate, formation prevents the barrier layer that impurity spreads.
4. method according to claim 3, it is characterised in that the barrier layer is atom Element of the ordinal number less than silicon, preferably carbon.
5. method according to claim 1, it is characterised in that the top of the STI is high In the bottom of the silicon/germanium silicon lamination.
6. method according to claim 1, it is characterised in that removing the silicon/germanium silicon During silicon or germanium silicon material in lamination, silicon or germanium silicon are removed using the technique of high etching selection ratio Material.
7. method according to claim 6, it is characterised in that remove the silicon/germanium silicon and fold Layer in silicon when, using dry etching or wet etching;During using wet etching, tool is selected There are the organic solvent of hydroxyl, preferably TMAH.
CN201510609662.3A 2015-09-22 2015-09-22 Semiconductor device manufacturing method Pending CN106549058A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510609662.3A CN106549058A (en) 2015-09-22 2015-09-22 Semiconductor device manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510609662.3A CN106549058A (en) 2015-09-22 2015-09-22 Semiconductor device manufacturing method

Publications (1)

Publication Number Publication Date
CN106549058A true CN106549058A (en) 2017-03-29

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Country Status (1)

Country Link
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050224889A1 (en) * 2004-04-09 2005-10-13 Chang-Woo Oh Surrounded-channel transistors with directionally etched gate or insulator formation regions and methods of fabrication therefor
CN103238208A (en) * 2010-12-01 2013-08-07 英特尔公司 Silicon and silicon germanium nanowire structures
US20140264253A1 (en) * 2013-03-14 2014-09-18 Seiyon Kim Leakage reduction structures for nanowire transistors
CN104126228A (en) * 2011-12-23 2014-10-29 英特尔公司 Non-planar gate fully-enclosed device and method of making same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050224889A1 (en) * 2004-04-09 2005-10-13 Chang-Woo Oh Surrounded-channel transistors with directionally etched gate or insulator formation regions and methods of fabrication therefor
CN103238208A (en) * 2010-12-01 2013-08-07 英特尔公司 Silicon and silicon germanium nanowire structures
CN104126228A (en) * 2011-12-23 2014-10-29 英特尔公司 Non-planar gate fully-enclosed device and method of making same
US20140264253A1 (en) * 2013-03-14 2014-09-18 Seiyon Kim Leakage reduction structures for nanowire transistors

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Application publication date: 20170329

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