CN106538582A - A kind of bactericidal composition of the ketone of bacterium containing phenol and Prochloraz - Google Patents
A kind of bactericidal composition of the ketone of bacterium containing phenol and Prochloraz Download PDFInfo
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- CN106538582A CN106538582A CN201610959992.XA CN201610959992A CN106538582A CN 106538582 A CN106538582 A CN 106538582A CN 201610959992 A CN201610959992 A CN 201610959992A CN 106538582 A CN106538582 A CN 106538582A
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- prochloraz
- phenol
- ketone
- bacterium
- surfactant
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aldehyde or keto groups, or thio analogues thereof, directly attached to an aromatic ring system, e.g. acetophenone; Derivatives thereof, e.g. acetals
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses the bactericidal composition of a kind of ketone of bacterium containing phenol and Prochloraz, including the Prochloraz and phenol bacterium ketone of 4% 72% weight ratios, Prochloraz is 1 with the weight ratio of phenol bacterium ketone：0.5‑20；The solvent or carrier or auxiliary agent of 22% 96% weight ratios；The surfactant of 1% 10% weight ratios.After the present invention is by Prochloraz and phenol bacterium ketone compounding, obtains the notable synergistic to various fungal diseases and act on, i.e., significantly, lasting effect extends the quick-acting of antibacterial；The dosage of pesticide is reduced simultaneously, is expanded action spectrum, is saved drug cost by reducing unit administration amount, spraying times；The pollution to environment is significantly reduced, and has delayed the drug-fast generation of plant, extend the service life of phenol bacterium ketone and Prochloraz.
Description
Technical field
The invention belongs to technical field of pesticide, is more particularly to the bactericidal composition of a kind of ketone of bacterium containing phenol and Prochloraz.
Background technology
The botanical fungicide of the useful independent intellectual property right of Fen Juntongshi China, its chemical name is：1- o-hydroxy-phenyls
Butanone.
Semen Ginkgo is China's Special plant, is referred to as plant living fossil, and strong stress resistance is not endangered by disease pest, numerous studies card
Bright, Semen Ginkgo contains agricultural bactericidal material, and thus, China's researcher has formulated new disinfectant use in agriculture phenol bacterium ketone.Phenol bacterium ketone
The most of diseases caused to pathomycetes such as Ascomycetes, Basidiomycetess, deuteromycetes and oomycetes subclass have protection, treatment
With the activity rooted out, can be used to place the various fungal diseases on the crops such as Semen Tritici aestivi, Fructus Mali pumilae, Fructus Vitis viniferae, vegetable, Citrus, Oryza sativa L..It is right
Crop, people, storage and beneficial organism safety, it is substantially pollution-free to environment.But phenol bacterium ketone has concentration in application process
, the deficiency such as the longevity of residure shorter, use cost higher big compared with high, unit area dosage, and have certain drug resistance risk, it is unfavorable for
The sustainable development of environment.
Prochloraz is a kind of wide-spectrum bactericide, and Prochloraz is the important kind in imidazoles series bactericidal agent, be efficiently, wide spectrum,
Low-toxicity antibacterial, with multiple actions such as prevention ＆ protection treatments.The disease caused by ascomycetess and Fungi Imperfecti by various crop
With obvious preventive effect, it is also possible to mixed with most of antibacterial, Insecticides (tech) ＆ Herbicides (tech), preferable prevention effect is respectively provided with.It is right
Multiple diseases on field crop, fruit and vegetable, turf and ornamental plant have treatment and eradicant action.
Phenol bacterium ketone and Prochloraz have the disease-resistant effectiveness of significant antibacterial to all kinds of industrial crops, but in application process, deposit
It is big compared with high, unit area dosage in concentration, the deficiency such as residual period is shorter, use cost is higher, and have certain anti-
Medicine risk.
The content of the invention
It is an object of the invention to provide one kind can, side effect longer with Synergistic phenolic ketone alcohol and Prochloraz, service life
The bactericidal composition of the less ketone of bacterium containing phenol and Prochloraz.
According to an aspect of the invention, there is provided the bactericidal composition of a kind of ketone of bacterium containing phenol and Prochloraz, its feature exists
In, comprising
The Prochloraz and phenol bacterium ketone of 4%-72% weight ratio, the Prochloraz are 1 with the weight ratio of the phenol bacterium ketone：0.5-
20；
The solvent or carrier or auxiliary agent of 22%-96% weight ratio；
The surfactant of 1%-10% weight ratio.
In some embodiments, the Prochloraz and the weight ratio of the phenol bacterium ketone are 1:1.5-10.
In some embodiments, the phenol bacterium ketone be 1- o-hydroxyphenyl butanones, the chemical structural formula of the phenol bacterium ketone
For：
In some embodiments, the compositionss that prepared by the Prochloraz, phenol bacterium ketone, solvent and surfactant are breast
Oil, the solvent are selected from benzene,toluene,xylene, methanol, ethanol, isopropanol, butanol, a line oil, cyclohexanone, dimethyl formyl
One or more mixing of amine, dimethyl sulfoxide, N-Methyl pyrrolidone, ethyl acetate, acetone, butanone, glycol ether apoplexy due to endogenous wind
Thing, the surfactant gather selected from alkylbenzenesulfonate, aliphatic alcohol sulfate, alkylphenol polyoxyethylene, alkyl phenyl phenol
One or more in oxygen vinyl Ether, alkylphenol-polyethenoxy polyethenoxy ether, alkyl phenyl phenol polyethenoxy polyethenoxy ether
Mixture.
In some embodiments, what prepared by the Prochloraz, phenol bacterium ketone, carrier and surfactant state compositionss for can
WP or granule, the carrier are Kaolin, bentonite, active hargil, meerschaum, white carbon, kieselguhr, lightweight carbon
One or more mixture in sour calcium, Pulvis Talci, Gypsum Fibrosum preparata, chalky soil, potter's clay, montmorillonite and clay, the surface activity
Agent is sodium methylene bis-naphthalene sulfonate, lignosulfonates, carboxymethyl cellulose salt class, alkylsulfonate, aliphatic alcohol sulfate, alkane
One or more mixture in base phenol polyethenoxy ether.
In some embodiments, also including deionized water, the Prochloraz, phenol bacterium ketone, deionized water, auxiliary agent and surface
Compositionss prepared by activating agent are emulsion agent, and the solvent is water, and the surfactant is alkylbenzenesulfonate, fatty alcohol sulfur
Hydrochlorate, alkylphenol polyoxyethylene, alkyl phenyl phenol polyethenoxy ether, alkylphenol-polyethenoxy polyethenoxy ether, base phenyl phenol
One or more mixture in polyoxyethylene poly-oxygen propylene aether, the auxiliary agent are selected from polyvinyl alcohol, polyvinylpyrrolidone, carboxylic
In methyl (ethyl) cellulose, xanthan gum, arabic gum, gelatin, starch, alginic acid, carbamide, ethylene glycol, Propylene Glycol, glycerol
One or more mixture.
Its advantage is：After the present invention is by Prochloraz and phenol bacterium ketone compounding, obtain to the bright of various fungal diseases
Significantly, lasting effect extends the quick-acting of aobvious potentiation, i.e. antibacterial.The dosage of pesticide is reduced simultaneously, expands effect
Spectrum, saves drug cost by reducing unit administration amount, spraying times, significantly reduces the pollution to environment, and delay
Plant drug-fast generation, extends the service life of phenol bacterium ketone and Prochloraz.
Specific embodiment
Embodiment 1
20 grams of Prochloraz (hundred contents of folding), 10 grams of phenol bacterium ketone, 4 grams of calcium dodecyl benzene sulfonate, fatty alcohol-polyoxyethylene ether
(n=20) 6 grams, with 20 grams of diformamide, xylene soluble obtains 100 grams of missible oil products.
Embodiment 2
30 grams of Prochloraz (hundred contents of folding), 20 grams of phenol bacterium ketone, 2 grams of calcium dodecyl benzene sulfonate, NPE
(n=20) 3 grams, 5 grams of line oil, 0.3 gram of carboxymethyl cellulose salt, 3 grams of Propylene Glycol, 0.2 gram of defoamer, deionized water is added to
100 grams, using high shear agitation mulser dispersed with stirring, mixing speed is 2000 revs/min, and mixing time is 30 minutes, is obtained
Homogeneous flowable white " milky " liquid product.
Embodiment 3
10 grams of Prochloraz (hundred contents of folding), 20 grams of phenol bacterium ketone, NNO4 gram, BX2 gram, 10 grams of white carbon, active hargil is added
To 100 grams, Jing comminution by gas stream to mean diameter is 20um wettable powders.
Embodiment 4
5 grams of Prochloraz (hundred contents of folding), 30 grams of phenol bacterium ketone, 4 grams of sodium lignin sulfonate, 2 grams of dodecyl sodium sulfate, Linesless charcoal
Black 20 grams, bentonite is added to 100 grams, and Jing comminution by gas stream to mean diameter is 20um wettable powders, in above-mentioned wettable powder
10 gram of 6% polyvinyl alcohol water solution of middle addition simultaneously stirs, and is dried by extruder grain, obtains 100 grams of 2mm*5mm and dispersible
Property granule product.
Embodiment 5
20 grams of Prochloraz (hundred contents of folding), 20 grams of phenol bacterium ketone, 0.5 gram of calcium dodecyl benzene sulfonate, dodecylphenyl phenol
3 grams of polyoxyethylene poly-oxygen propylene aether, 3 grams of cyclohexanone, 0.4 gram of xanthan gum, 0.1 gram of defoamer, deionized water adds to 100 grams, adopts
With high shear agitation mulser dispersed with stirring, mixing speed is 4000 revs/min, and mixing time is 15 minutes, obtains and can uniformly flow
Dynamic white " milky " liquid product.
Field test 1
Phenol bacterium ketone Prochloraz EC rice blasts
First, test objective
For prevention effects of the clear and definite phenol bacterium ketone Prochloraz EW to rice sheath blight disease, inquire into which and use technology, be big face
Product application provides foundation.
Test method
1st, reagent agent：
40% Fen Juntong EW Jiangsu Tenglong Biological Pharmaceutical Co., Ltd. provides
30% Prochloraz SC Jiangsu Tenglong Biological Pharmaceutical Co., Ltd. provides
40% phenol bacterium ketone Prochloraz EC examples detailed above, 5 gained preparation
EXPERIMENTAL DESIGN and method
Basic condition：This test is located in four groups of the Bei Jiang villages in Yandu District Bei Jiang towns paddy field, for trying rice varieties is
Huaidao 9, direct sowing culture, preferably, growth is balanced for Oryza sativa L. growing way.22.6 DEG C of temperature on average (minimum per day 19.7 during test
DEG C, 25.2 DEG C of highest), non-rainfall in 6 days after first time medicine, after second medicine in 15 days, at 8 days on rain day, rainfall 117.3mm.
EXPERIMENTAL DESIGN
1. 40% phenol bacterium ketone EW100ml/ mus
2. 40% phenol bacterium ketone Prochloraz 20ml/ mus
3. 30% Prochloraz SC 20ml/ mus
4. clear water control
20 square metres of plot area, in triplicate, random district's groups arrangement.
Spraying time and method
In (full heading time) dispenser twice on the 12nd of (the cut phase) on the 5th of September in 2009 and September, every mu of dosage is to 40 kilograms of water
It is conventional to spray.
Efficacy survey
(the rice blast state of an illness is basicly stable) investigation drug effect 14 days after second dispenser, 5 points of samplings, per 2 chis 2, per cell
10 chis 2 are investigated, investigation rice blast morbidity series calculates prevention effect, and test data carries out variance Jing after arcsine conversion
Analysis, DuncanShi duncan's new multiple range method multiple comparisons.
Safety observations
Phenol bacterium ketone treatment region paddy growth situation is observed after dispenser irregularly.
2nd, result of the test (being shown in Table one)
Table one, result of the test：40% phenol bacterium ketone Prochloraz EC prevents and treats rice blast
3rd, brief summary and discussion
1st, result of the test shows that 40% phenol bacterium ketone EW has good control effect to rice blast, its prevention effect
It is suitable with 30% Tebuconazole SC preventive effects.
2nd, phenol bacterium ketone is mixed with Prochloraz acts on notable synergistic.
3rd, 40% phenol bacterium ketone Prochloraz consumption 20ml is advisable, in Oryza sativa L. cut phase and full heading time dispenser twice, can be effective
Control Oryza sativa L. rice blast is caused harm.
Field test 2
30% phenol bacterium ketone Prochloraz EC prevents and treats apple anthracnose
First, test objective
For prevention effects of the clear and definite phenol bacterium ketone Prochloraz EC to apple anthracnose, inquire into which and use technology, be big face
Product application provides foundation.
Test method
1st, reagent agent：
40% Fen Juntong EW Jiangsu Tenglong Biological Pharmaceutical Co., Ltd. provides
30% Prochloraz SC Jiangsu Tenglong Biological Pharmaceutical Co., Ltd. provides
30% phenol bacterium ketone Prochloraz EC examples detailed above, 1 gained preparation
EXPERIMENTAL DESIGN and method
Basic condition：This test is located in four groups of Yandu District Bei Jiang towns Bei Jiang villages, one piece of farmland, and experimental cultivar is Fructus Mali pumilae, long
Preferably, growth is balanced for gesture.During test, 22.6 DEG C of temperature on average (minimum per day 19.7 DEG C, 25.2 DEG C of highest), are used for the first time
Non- rainfall in 6 days after medicine, after second medicine in 15 days, at 8 days on rain day, rainfall 117.3mm.
EXPERIMENTAL DESIGN
1. 40% phenol bacterium EW1000 times of liquid of ketone
2. 30% phenol bacterium ketone Prochloraz 2000ml/ mus
3. 30% Prochloraz SC 2000ml/ mus
4. clear water control
20 square metres of plot area, in triplicate, random district's groups arrangement.
Spraying time and method and efficacy survey
The state of an illness of apple anthracnose is investigated before medicine, in the first time dispenser of state of an illness initial stage, per dispenser in 7 days once, dispenser 3 altogether
It is secondary.7 days after third time dispenser, Semen arachidis hypogaeae disease index is investigated respectively and preventive effect is calculated within 14 days, 30 days.
Safety observations
Phenol bacterium ketone treatment region apple development situation is observed after dispenser irregularly.
2nd, result of the test (being shown in Table two)
Table two, result of the test：40% phenol bacterium ketone Prochloraz EC prevents and treats apple anthracnose
3rd, brief summary and discussion
1st, result of the test shows that 40% phenol bacterium ketone EW has good control effect to apple anthracnose, its prevention effect
It is suitable with 30% Tebuconazole SC preventive effects.
2nd, phenol bacterium ketone is mixed with Prochloraz acts on notable synergistic.
3rd, 40% phenol bacterium ketone Prochloraz 2000 times of liquid of consumption are advisable, and early stage dispenser occurs twice in apple anthracnose, can
Effective control apple anthracnose is caused harm.
Crossing indoor and field test proves, in the present invention after the reasonable compounding of two kinds of antibacterial, with obvious potentiation
Effect, is significantly improved to the prevention effect of corps diseases, and can expand fungicidal spectrum, delay the drug-fast product of pathogen
It is raw.Specific experiment result is：Prochloraz is 1 with the mass percent of phenol bacterium ketone：(1.5-10) relatively to Oryza sativa L. compared with single dose when
The co-toxicity coefficient (CTC) of rice blast between 152.5-264.3, to the co-toxicity coefficient of apple anthracnose be 149.7-265.4 it
Between.Prochloraz is compounded with both phenol bacterium ketone and can delay to a certain extent the drug-fast generation of pathogen, improves drug effect, is dropped
Low cost.
Above-described is only some embodiments of the present invention.For those of ordinary skill in the art, do not taking off
On the premise of conceiving from the invention, some deformations and improvement can also be made, these belong to protection scope of the present invention.
Claims (6)
1. the bactericidal composition of a kind of ketone of bacterium containing phenol and Prochloraz, it is characterised in that include
The Prochloraz and phenol bacterium ketone of 4%-72% weight ratio, the Prochloraz are 1 with the weight ratio of the phenol bacterium ketone：0.5-20；
The solvent or carrier or auxiliary agent of 22%-96% weight ratio；
The surfactant of 1%-10% weight ratio.
2. the bactericidal composition of the ketone of bacterium containing phenol according to claim 1 and Prochloraz, it is characterised in that the Prochloraz with
The weight ratio of the phenol bacterium ketone is 1:1.5-10.
3. the bactericidal composition of the ketone of bacterium containing phenol according to claim 1 and Prochloraz, it is characterised in that the phenol bacterium ketone is
1- o-hydroxyphenyl butanones, the chemical structural formula of the phenol bacterium ketone is：
。
4. the bactericidal composition of the ketone of bacterium containing phenol according to any one of claim 1-3 and Prochloraz, it is characterised in that described
Compositionss prepared by Prochloraz, phenol bacterium ketone, solvent and surfactant are cream, the solvent selected from benzene,toluene,xylene,
Methanol, ethanol, isopropanol, butanol, a line oil, cyclohexanone, dimethylformamide, dimethyl sulfoxide, N-Methyl pyrrolidone, second
Acetoacetic ester, acetone, butanone, one or more mixture of glycol ether apoplexy due to endogenous wind, the surfactant are selected from alkyl benzene sulphonate
Salt, aliphatic alcohol sulfate, alkylphenol polyoxyethylene, alkyl phenyl phenol polyethenoxy ether, alkylphenol-polyethenoxy polyoxypropylene
One or more mixture in ether, alkyl phenyl phenol polyethenoxy polyethenoxy ether.
5. the bactericidal composition of the ketone of bacterium containing phenol according to any one of claim 1-3 and Prochloraz, it is characterised in that described
It is wettable powder or granule that prepared by Prochloraz, phenol bacterium ketone, carrier and surfactant states compositionss, and the carrier is high
Ridge soil, bentonite, active hargil, meerschaum, white carbon, kieselguhr, precipitated calcium carbonate, Pulvis Talci, Gypsum Fibrosum preparata, chalky soil, pottery
One or more mixture in soil, montmorillonite and clay, the surfactant are sodium methylene bis-naphthalene sulfonate, sulfomethylated lignin
One or more in hydrochlorate, carboxymethyl cellulose salt class, alkylsulfonate, aliphatic alcohol sulfate, alkylphenol polyoxyethylene
Mixture.
6. the bactericidal composition of the ketone of bacterium containing phenol according to any one of claim 1-3 and Prochloraz, it is characterised in that also wrap
Include deionized water, compositionss prepared by the Prochloraz, phenol bacterium ketone, deionized water, auxiliary agent and surfactant are emulsion agent, institute
It is water to state solvent, and the surfactant is alkylbenzenesulfonate, aliphatic alcohol sulfate, alkylphenol polyoxyethylene, alkylbenzene
One kind in base phenol polyethenoxy ether, alkylphenol-polyethenoxy polyethenoxy ether, base phenyl phenol polyoxyethylene poly-oxygen propylene aether or
Several mixture, the auxiliary agent selected from polyvinyl alcohol, polyvinylpyrrolidone, carboxymethyl (ethyl) cellulose, xanthan gum, I
One or more mixture in primary glue, gelatin, starch, alginic acid, carbamide, ethylene glycol, Propylene Glycol, glycerol.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1294113A (en) * | 1999-11-01 | 2001-05-09 | 莱阳农学院 | Artificial compound 1-o-hydroxyphenyl butanone and its synthesizing process and usage |
| CN101427676A (en) * | 2008-09-03 | 2009-05-13 | 江苏腾龙生物药业有限公司 | Phenolactone aqueous emulsion and preparation method thereof |
| CN102037972A (en) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | Sterilization composition containing mycophenolic ketone and hexaconazole |
| CN102037961A (en) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | Sterilization composition containing mycophenolic ketone and fenoxanil |
| WO2014120355A1 (en) * | 2012-12-19 | 2014-08-07 | Dow Agrosciences Llc | Pesticidal compositions and processes related thereto |
| CN106614618A (en) * | 2016-10-28 | 2017-05-10 | 江苏腾龙生物药业有限公司 | A sterilization composition comprising 1-(2-hydroxyphenyl)-1-butanone and tebuconazole |
-
2016
- 2016-10-28 CN CN201610959992.XA patent/CN106538582A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1294113A (en) * | 1999-11-01 | 2001-05-09 | 莱阳农学院 | Artificial compound 1-o-hydroxyphenyl butanone and its synthesizing process and usage |
| CN101427676A (en) * | 2008-09-03 | 2009-05-13 | 江苏腾龙生物药业有限公司 | Phenolactone aqueous emulsion and preparation method thereof |
| CN102037972A (en) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | Sterilization composition containing mycophenolic ketone and hexaconazole |
| CN102037961A (en) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | Sterilization composition containing mycophenolic ketone and fenoxanil |
| WO2014120355A1 (en) * | 2012-12-19 | 2014-08-07 | Dow Agrosciences Llc | Pesticidal compositions and processes related thereto |
| CN106614618A (en) * | 2016-10-28 | 2017-05-10 | 江苏腾龙生物药业有限公司 | A sterilization composition comprising 1-(2-hydroxyphenyl)-1-butanone and tebuconazole |
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Application publication date: 20170329 |