CN106517240B - The method for synthesizing flakes ZSM-12 zeolite molecular sieves with single small molecule organic formwork agent - Google Patents
The method for synthesizing flakes ZSM-12 zeolite molecular sieves with single small molecule organic formwork agent Download PDFInfo
- Publication number
- CN106517240B CN106517240B CN201610932017.XA CN201610932017A CN106517240B CN 106517240 B CN106517240 B CN 106517240B CN 201610932017 A CN201610932017 A CN 201610932017A CN 106517240 B CN106517240 B CN 106517240B
- Authority
- CN
- China
- Prior art keywords
- zsm
- flakes
- zeolite molecular
- organic formwork
- molecular sieves
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010457 zeolite Substances 0.000 title claims abstract description 31
- 238000009415 formwork Methods 0.000 title claims abstract description 24
- 239000002808 molecular sieve Substances 0.000 title claims abstract description 17
- 150000003384 small molecules Chemical class 0.000 title claims abstract description 17
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910021536 Zeolite Inorganic materials 0.000 title claims abstract description 16
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 10
- 230000002194 synthesizing effect Effects 0.000 title claims description 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 13
- 238000002425 crystallisation Methods 0.000 claims abstract description 11
- 230000008025 crystallization Effects 0.000 claims abstract description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 10
- 239000010703 silicon Substances 0.000 claims abstract description 10
- 239000003513 alkali Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical group [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 8
- 238000003786 synthesis reaction Methods 0.000 abstract description 8
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 17
- 238000001035 drying Methods 0.000 description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- -1 polytetrafluoroethylene Polymers 0.000 description 3
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/42—Type ZSM-12
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The present invention relates to Molecular Sieve Morphologies to regulate and control preparation method, it is desirable to provide a method of with 12 zeolite molecular sieves of single small molecule organic formwork agent synthesis flakes ZSM.Including step：Water, silicon source, alkali source and template are mixed, or continue to mix to uniform after adding silicon source again；It is subsequently placed in reaction kettle, crystallization products therefrom is filtered, dried to get to the original powder of 12 zeolite molecular sieves of ZSM.The present invention not only extends the type of the organic formwork agent of synthesis 12 zeolites of ZSM, but also synthesized product has the flakes pattern for being different from other products.Product not only maintains good crystallinity and purity, but also the novel in shape of obtained product, from having not been reported.The present invention has inspiration meaning for controlling the pattern of zeolite molecular sieve.
Description
Technical field
The invention belongs to Molecular Sieve Morphologies to regulate and control preparation method, more particularly to one kind is with single small molecule organic formwork structure
The method for synthesizing flakes ZSM-12 zeolite molecular sieves.
Background technology
ZSM-12 zeolites are a kind of silica-rich zeolites with one-dimensional twelve-ring pore passage structure.It by Rosinski and
Rubin et al. is synthesized for the first time 1974, and pore size isIt has during isomerization, hydrocarbon cracking and conversion etc.
There is excellent catalytic performance.In recent decades, researcher has done research work in large quantities in the synthesis of ZSM-12 zeolites.Its
It is middle to find that the template of synthesis ZSM-12 zeolites is various, such as tetraethyl ammonium, benzyltrimethylammon.um, bi-quaternary ammonium salt etc..These
Use of the organic formwork agent in the synthesis of ZSM-12 zeolites can obtain the product of different-shape, can obtain rodlike, spherical, bulk
Pattern.Catalytic performance can be caused prodigious influence by being typically different the product of pattern.
Therefore, have great importance come the pattern for regulating and controlling ZSM-12 zeolites by design template agent.
Invention content
The technical problem to be solved by the present invention is to overcome deficiency in the prior art, it is organic to design a kind of single small molecule
The method that formwork structure synthesizes flakes ZSM-12 zeolite molecular sieves, and the design of template is by controlling its intramolecular group
Angle to be unfolded.
To solve technical problem, solution of the invention is：
There is provided it is a kind of with single small molecule organic formwork agent synthesize flakes ZSM-12 zeolite molecular sieves method, including with
Lower step：
Water, silicon source, alkali source and template are mixed, or continue to mix to uniform after adding silicon source again；It is subsequently placed in anti-
It answers in kettle, in 140~200 DEG C of crystallization 1d~6d, product filters, dries to get to the original powder of ZSM-12 zeolite molecular sieves；
The molecular structural formula of the template is shown below：
Controlling the additive amount of each reaction raw materials makes its molar ratio range be：15~40H2O∶SiO2: 0~0.01Al2O3∶
0.06~0.14 (Na2O or K2O): 0.1~0.3 template.
In the present invention, source of aluminium is aluminum sulfate or sodium metaaluminate；Silicon source is the Ludox that dioxide-containing silica is 30%；
Alkali source is potassium hydroxide or sodium hydroxide.
The present invention also provides a kind of method for the template for preparing and being synthesized for flakes ZSM-12 zeolite molecular sieves, packets
Include step：To 100g to 200ml ethyl alcohol is added in benzyl dichloride, 117g crassitudes are added, are stirred back in 80 DEG C of oil baths
Stream reaction 2d；After reaction, ether is added into reaction product, the white solid of generation is precipitated through filtering, drying, as mould
Plate agent.
In terms of existing technologies, the beneficial effects of the present invention are：
1, ZSM-12 zeolite molecular sieves are synthesized by using novel single small molecule organic formwork structure, not only extends conjunction
At the type of the organic formwork agent of ZSM-12 zeolites, and synthesized product has the flakes shape for being different from other products
Looks.
2, compared with prior art, this product not only maintains good crystallinity and purity, but also obtained product
Novel in shape, from having not been reported.The present invention has inspiration meaning for controlling the pattern of zeolite molecular sieve.
Description of the drawings
Fig. 1：The XRD spectra of the ZSM-12 zeolites of novel single small molecule organic formwork synthesis.
Fig. 2：The ZSM-12 zeolites stereoscan photograph (low power) of novel single small molecule organic formwork synthesis.
Fig. 3：The ZSM-12 zeolites stereoscan photograph (high power) of novel single small molecule organic formwork synthesis.
Specific implementation mode
Single small molecule organic formwork agent (hereafter being referred to symbol T) used in the present invention, preparation method：By 100g
Benzyl dichloride is placed in 500ml round-bottomed flasks, 200ml ethyl alcohol is added, 117g crassitudes are then added, in 80 DEG C of oil baths
In be stirred at reflux reaction 2d, after reaction, into reaction product be added ether producible white solid precipitate, process
Filter, drying can be obtained required template.
The molecular structural formula of template is as follows：
Embodiment 1：Novel single small molecule organic formwork synthesizes flakes ZSM-12 zeolites
By 8.12g H2O, 0.046g Al2(SO4)3·18H2(T, structure is such as O, 0.15g NaOH, 1.0g organic formwork agent
Fig. 1) and the Ludox of 3.32g dioxide-containing silicas 30% is placed in beaker and stirs evenly, and is then added to this gel poly-
In tetrafluoroethene stainless steel cauldron, 160 DEG C of crystallization 3d, that is, complete crystallizations, product filters, and product is obtained after drying.Reaction raw materials
Proportioning it is as follows：
35H2O:SiO2:0.0042Al2O3:0.11Na2O:0.2T
Through X-ray diffraction analysis, its structure is to belong to the ZSM-12 zeolite molecular sieves (Fig. 2) of MTW, and pass through scanning electricity
Mirror photo can be seen that the pattern (low power) of flakes is presented in synthesized product, and the flakes pattern of product is by stick
It intersects to be formed (high power).Attached drawing 2-3 is that novel single small molecule organic formwork synthesizes flakes ZSM-12 zeolites
Stereoscan photograph (SEM).
Embodiment 2：Novel single small molecule organic formwork synthesizes total silicon flakes ZSM-12 zeolites
By 2.2g H2O, 0.18g NaOH, 0.55g organic formwork agent (T, structure such as Fig. 1) and 3.32g silica contain
The Ludox of amount 30%, which is placed in beaker, to stir evenly, and then this gel is added in polytetrafluoroethylene (PTFE) stainless steel cauldron,
140 DEG C of crystallization 6d, that is, complete crystallizations, product filter, and product is obtained after drying.The proportioning of reaction raw materials is as follows：
15H2O:SiO2:0.14Na2O:0.1T
Embodiment 3：Novel single small molecule organic formwork high―temperature nuclei flakes ZSM-12 zeolites
By 9.67g H2O, 0.039g NaAlO2, 0.07g NaOH, 1.6g organic formwork agent (T, structure such as Fig. 1) and
The Ludox of 3.32g dioxide-containing silicas 30%, which is placed in beaker, to stir evenly, this gel is then added to polytetrafluoroethylene (PTFE)
In stainless steel cauldron, 200 DEG C of crystallization 1d, that is, complete crystallizations, product filters, and product is obtained after drying.Reaction raw materials are matched such as
Under：
40H2O:SiO2:0.01Al2O3:0.06Na2O:0.3T
Embodiment 4：Novel single small molecule organic formwork high―temperature nuclei total silicon flakes ZSM-5 zeolite
By 8.12g H2O, 0.16g KOH, 1.1g organic formwork agent (T, structure such as Fig. 1) and 3.32g silica contain
The Ludox of amount 30%, which is placed in beaker, to stir evenly, and then this gel is added in polytetrafluoroethylene (PTFE) stainless steel cauldron,
200 DEG C of crystallization 1d, that is, complete crystallizations, product filter, and product is obtained after drying.The proportioning of reaction raw materials is as follows：
35H2O:SiO2:0.07K2O:0.2T
The above is only several case study on implementation of the present invention, not does limitation in any form to the present invention,
Although the present invention is disclosed as above with preferable case study on implementation, however, it is not intended to limit the invention, any skill for being familiar with this profession
Art personnel, without departing from the scope of the present invention, when structure and technology contents using the disclosure above make it is a little
Change or be modified to the equivalence enforcement cases of equivalent variations.But every content without departing from technical solution of the present invention, foundation
The technical spirit of the present invention still belongs to the present invention to any simple modification, equivalent change and modification made by the above case study on implementation
In technical proposal scope.
Claims (2)
1. a kind of method synthesizing flakes ZSM-12 zeolite molecular sieves with single small molecule organic formwork agent, which is characterized in that
Include the following steps：
Water, silicon source, alkali source and template are mixed, or continue to mix to uniform after adding silicon source again；It is subsequently placed in reaction kettle
In, in 140~200 DEG C of crystallization 1d~6d, product filters, dries to get to the original powder of ZSM-12 zeolite molecular sieves；
The molecular structural formula of the template is shown below：
Controlling the additive amount of each reaction raw materials makes its molar ratio range be：15~40H2O∶SiO2: 0~0.01Al2O3: 0.06~
0.14Na2O or K2O: 0.1~0.3 template.
2. according to the method described in claim 1, it is characterized in that, source of aluminium is aluminum sulfate or sodium metaaluminate；Silicon source is two
The Ludox that silica content is 30%；Alkali source is potassium hydroxide or sodium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610932017.XA CN106517240B (en) | 2016-10-25 | 2016-10-25 | The method for synthesizing flakes ZSM-12 zeolite molecular sieves with single small molecule organic formwork agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610932017.XA CN106517240B (en) | 2016-10-25 | 2016-10-25 | The method for synthesizing flakes ZSM-12 zeolite molecular sieves with single small molecule organic formwork agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106517240A CN106517240A (en) | 2017-03-22 |
| CN106517240B true CN106517240B (en) | 2018-07-24 |
Family
ID=58292723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610932017.XA Active CN106517240B (en) | 2016-10-25 | 2016-10-25 | The method for synthesizing flakes ZSM-12 zeolite molecular sieves with single small molecule organic formwork agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106517240B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2737525C1 (en) * | 2019-06-27 | 2020-12-01 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Method of producing zeolite with mtw structure (zsm-12 type) |
| RU2745824C1 (en) * | 2020-06-28 | 2021-04-01 | Федеральное государственное бюджетное образовательное учреждение высшего образования «Московский государственный университет имени М.В.Ломоносова» (МГУ) | Method for producing zeolites of the zsm-12 type with the mtw structure |
| RU2773945C1 (en) * | 2021-10-05 | 2022-06-14 | Федеральное государственное бюджетное образовательное учреждение высшего образования «Московский государственный университет имени М.В.Ломоносова» (МГУ) | Method for obtaining a composite material with a hierarchical structure |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107032368B (en) * | 2017-04-13 | 2019-08-06 | 上海交通大学 | A kind of MTW Zeolitic NanoRods and preparation method thereof with symbiotic structure |
| CN109437231A (en) * | 2018-11-28 | 2019-03-08 | 东莞理工学院 | A kind of preparation method of flakes ZSM-5 molecular sieve |
| RU2711757C1 (en) * | 2019-07-31 | 2020-01-21 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Method of producing zsm-12 flake zeolite with mtw structure |
| RU2731469C1 (en) * | 2019-07-31 | 2020-09-03 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Method of producing zsm-12 flake zeolite with mtw structure |
| CN116022805A (en) * | 2021-10-26 | 2023-04-28 | 中国石油化工股份有限公司 | Small-grain ZSM-12 molecular sieve and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4391785A (en) * | 1981-12-21 | 1983-07-05 | Mobil Oil Corporation | Preparation of ZSM-12 type zeolites |
| US4482531A (en) * | 1983-04-29 | 1984-11-13 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
| US4559213A (en) * | 1983-04-29 | 1985-12-17 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
| CN104437606A (en) * | 2013-09-24 | 2015-03-25 | 中国石油化工股份有限公司 | ZSM-12 molecular sieve of multilayer structure and preparation method thereof |
-
2016
- 2016-10-25 CN CN201610932017.XA patent/CN106517240B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4391785A (en) * | 1981-12-21 | 1983-07-05 | Mobil Oil Corporation | Preparation of ZSM-12 type zeolites |
| US4482531A (en) * | 1983-04-29 | 1984-11-13 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
| US4559213A (en) * | 1983-04-29 | 1985-12-17 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
| CN104437606A (en) * | 2013-09-24 | 2015-03-25 | 中国石油化工股份有限公司 | ZSM-12 molecular sieve of multilayer structure and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2737525C1 (en) * | 2019-06-27 | 2020-12-01 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) | Method of producing zeolite with mtw structure (zsm-12 type) |
| RU2745824C1 (en) * | 2020-06-28 | 2021-04-01 | Федеральное государственное бюджетное образовательное учреждение высшего образования «Московский государственный университет имени М.В.Ломоносова» (МГУ) | Method for producing zeolites of the zsm-12 type with the mtw structure |
| RU2773945C1 (en) * | 2021-10-05 | 2022-06-14 | Федеральное государственное бюджетное образовательное учреждение высшего образования «Московский государственный университет имени М.В.Ломоносова» (МГУ) | Method for obtaining a composite material with a hierarchical structure |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106517240A (en) | 2017-03-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106517240B (en) | The method for synthesizing flakes ZSM-12 zeolite molecular sieves with single small molecule organic formwork agent | |
| CN107758691B (en) | The preparation method of high silicon CHA types SSZ-13 molecular sieves | |
| CN106542539B (en) | The method for synthesizing macropore EMM-23 zeolite molecular sieves with polyquaternium template | |
| TWI745283B (en) | A method for the synthesis of a type of fer/mor composite molecular sieve | |
| CN102745708B (en) | Synthetic method of mesoporous-microporous molecular sieve with improved hydrothermal stability | |
| CN101172243B (en) | Mesoporous material/micropore molecular sieve composite material and preparation method thereof | |
| CN106698456B (en) | The method of the line style polyquaternary amine alkali organic formwork agent one-step synthesis method molecular sieves of ITQ-13 containing aluminium | |
| CN109311687A (en) | The method of continuous synthetic zeolite material | |
| CN108217682A (en) | The method of method synthesis Silicon-rich ZSM-48 zeolite molecular sieves is oriented to using crystal seed | |
| CN107555446A (en) | A kind of preparation method of multi-stage porous Y type molecular sieve | |
| TW201114685A (en) | Method of preparing ZSM-5 zeolite using nanocrystalline ZSM-5 seeds | |
| CN102311124B (en) | Method for preparing Silicalite-1/ZSM-5 composite molecular sieve | |
| CN103626203B (en) | A kind of preparation of nanometer of molecular sieve of ZSM 5 | |
| CN109701619A (en) | SSZ-13/SSZ-39 composite molecular sieves and its synthetic method | |
| CN103172081A (en) | High-molecular organic polymer template synthesized compound pore structure molecular sieve and preparation method thereof | |
| CN108190913A (en) | The method of method synthesis Silicon-rich ZSM-5 zeolite molecular sieve is oriented to using crystal seed | |
| CN105858682A (en) | Method for utilizing ZSM-11 molecular sieve synthesizing mother liquor | |
| CN104828837B (en) | A kind of method of synthesizing submicron NaA molecular sieve | |
| Sumari et al. | Effect of temperature synthesis on structural behaviours of NaY zeolite using local sand as a silica source | |
| CN106587102A (en) | Synthetic method of ZSM-12 type zeolite molecular sieve | |
| CN108217683A (en) | The method of method synthesis Silicon-rich ZSM-23 zeolite molecular sieves is oriented to using crystal seed | |
| CN107010641A (en) | A kind of zeolite molecular sieves of three-level hole shell core ZSM 5 and preparation method thereof | |
| CN108014841A (en) | Cu-SSZ-13/ZSM-5 composite molecular sieves and its synthetic method | |
| CN106946268B (en) | A kind of MOR/ZSM-35 composite molecular screen and its synthetic method | |
| CN109279621A (en) | A method of using general ion thermal method synthesis of silica-base zeolite molecular sieve |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |