CN106489942A - Herbicidal combinations and its application - Google Patents
Herbicidal combinations and its application Download PDFInfo
- Publication number
- CN106489942A CN106489942A CN201610786514.3A CN201610786514A CN106489942A CN 106489942 A CN106489942 A CN 106489942A CN 201610786514 A CN201610786514 A CN 201610786514A CN 106489942 A CN106489942 A CN 106489942A
- Authority
- CN
- China
- Prior art keywords
- trichlopyr
- quinmerac
- herbicidal combinations
- florasulam
- quinoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Herbicidal combinations and its application, it is characterised in that with quinmerac, trichlopyr as principle active component, quinmerac, the weight ratio of trichlopyr are 150 to described Herbicidal combinations:1‑1:16, composition can also further include florasulam, and the ratio of quinmerac, trichlopyr and florasulam is 1 150:1‑80:0.1 40, for wheat paddock after seedling cauline leaf process, broad leaved weed is prevented and kill off, synergistic effect is notable.
Description
Technical field：
The invention belongs to agriculture herbicide field, it is related to that a kind of wheat paddock containing quinmerac, trichlopyr is compound to be removed
Careless agent, prevents and kill off broad leaved weed for wheat paddock after seedling cauline leaf process.
Technical background：
Quinmerac (Quinmerac), is called quinmerac, and chemistry is entitled, and (the chloro- 8-Quinoline Carboxylic Acids of 3- methyl -7-, are seedlings
The hormone like herbicide that front or after seedling is used, can be absorbed by the root of plant and leaf, then top and the base portion transfer to plant.Quinoline
Oxalic acid is the quinoline carboxylic acid herbicide that is developed by BASF AG, it is adaptable to cereal crop, wheat and beet, prevents and kill off pig calamity
Calamity, Veronica and other weeds, wherein umbellate form section crop are very sensitive to which.
Trichlopyr (Triclopyr), No. CAS is:55335-06-3, structural formula are as follows,
Trichlopyr belongs to inner sucting conduction type selective herbicide, by blade face and the Root Absorption of plant, and in plant
It is transmitted to complete stool in vivo, causes its root, stem, leaf deformity, reserve substance to exhaust, by embolism or rupture, plant is gradually dead for vascular bundle
Die.Can be used for the gramineous crop such as field such as wheat, corn, oat, Chinese sorghum and prevent and kill off the broad leaved weeds such as nettle, garden sorrel, morning glory.
Florasulam (Diclosulam), CAS registration numbers：145701-21-9, structural formula are as follows：
Florasulam is the triazolopyrimidine sulfonamides herbicide that is developed by Dow Agrosciences LLC, can be used to
Preventing and treating broad leaved weed such as clearvers, chickweed, Polygonum weeds, compositae weeds etc..
After the herbicide of single-activity component is used for controlling weeds for a long time, strengthens can the resistance of weeds, make the quick of weeds
Perception declines, and can increase formulation rate, so as to cause the pollution of environment.And the development difficulty of new herbicide is increasing, expend
Time and financial resources also increasing, therefore rational mixture herbicide a kind of is selected with improving herbicidal effect and becoming current.
Herbicide rational mixture not only can expand herbicidal spectrum, delay the generation of Weed Resistance, good compounding improve weeding effect
Really, synergistic effect is played, it will be apparent that improve the effect of herbicide.
Content of the invention：
It is an object of the invention to provide the low herbicidal composition of drug cost, the broad leaved weed of wheat paddock is had compared with
Good prevention effect, can be used for wheat paddock after seedling cauline leaf process, prevents and kill off broad leaved weed.The technical solution adopted in the present invention
For：
A kind of compound herbicide containing quinmerac, trichlopyr, it is characterised in that described herbicide is with quinoline grass
Acid, trichlopyr are principle active component, and quinmerac, the weight ratio of trichlopyr are 150:1-1:16, preferably
Ratio is 100:1-1:16, more preferably 50:1-16.In further technical scheme, active ingredient can also include
Florasulam, the ratio of quinmerac, trichlopyr and florasulam is 1-150:1-80:0.1-40, further preferably
Technical scheme be 1-100:1-80:0.1-40, is still more preferably 5-150:1-20:0.1-5.In compound herbicide,
The content of active ingredient is 1-85%, preferably 30-75%.
The herbicide of the present invention is used for wheat paddock after seedling cauline leaf process, prevents and kill off broad leaved weed.
The preparation formulation that herbicide of the present invention can be prepared according to the method well known to those skilled in the art of the present technique, including
Water dispersible granules, wettable powder, wet seed dressing, missible oil, suspending agent, oil suspending agent, suspension emulsion, suspension seed-coating agent, aqueous emulsion, micro-
Emulsion etc.；
Known auxiliary agent has emulsifying agent, wetting dispersing agent, suspending agent, disintegrant, binding agent, antifreezing agent, thickener, stable
Agent, defoamer etc.；
The emulsifying agent that can be applicable in the insecticides adjuvant of the present invention includes but is not limited to phenethyl phenol polyoxyethylene polyoxy
Propylene ether, styrylphenol formaldehyde resin PULLRONIC F68 block type polyethers, aliphatic acid polyethenoxy ether, polyoxy
Ethene fatty alcohol ether, trilaurin APEO, two Bian xenyl APEOs, glyceryl monolaurate polyoxy
Vinethene, styrylphenol polyoxyethylene ether, castor oil polyoxyethylene ether, ethoxy castor oil APEO, alkyl phenol
Polyoxyethylene polyoxypropylene ether, styryl phenyl APEO, secondary octyl phenol polyethenoxy ether, Nonyl pheno
Ether, alkylaryl polyoxyethylene poly-oxygen propylene aether, APES, sorbitan fatty acid ester polyoxyethylene groups
Ether, aliphatic alcohol polyoxyethylene sulfonate, polyoxyethylene alkylphenol formaldehyde condensation products, dodecyl sodium sulfonate calcium, decyl alcohol polyoxy second
Alkene ether sulfosuccinic acid sodium, APES formaldehyde condensation product sodium sulphate, APES succinate monoester
Sulfonate, alkylphenol-polyethenoxy phosphate, APES sulfosuccinates, polyoxyethylene fatty acid fat, poly-
Methyl acrylate, Polyoxyethylene fatty ammonia, ethoxy castor oil, alkyl-diethylene glycol ether-sodium sulfonate, fatty acid polyglycol ethylene glycol
One or more in ester, fast penetration enhancer T, oleic acid PEG400 ester and AEO；
Dispersant in the aforementioned insecticides adjuvant that can be applicable to the present invention includes but is not limited to sodium lignin sulfonate, methylene
Base sodium dinaphthalenesulfonate, calcium lignosulfonate, Sodium Polyacrylate, sodium methylene bis-naphthalene sulfonate, dispersing agent MF, poly-
The contracting of vinylpyrrolidone, alkyl amide taurate, the sodium salt of alkyl naphthalene sulfonic acid condensation polymer and sodium methylene bis-naphthalene sulfonate formaldehyde
One or more in compound；
Wetting agent is selected from Negel, lauryl sodium sulfate, Teepol, neopelex,
Fatty alcohol polyglycol ether sulfate, AEO, NPE, sorbitan fatty acid ester gather
The mixture of oxygen vinethene, alkyl naphthalene formaldehyde condensation product, alkylnaphthalene sulfonate and anion wetting agent；
The solvent includes water, 1-METHYLPYRROLIDONE, DMF, tributyl phosphate, tetrahydrofurfuryl alcohol, first
Benzene, dimethylbenzene, dimethyl sulfoxide (DMSO), tetrahydrofuran, Isosorbide-5-Nitrae dioxane, cyclohexanol, cyclohexanone, epoxidized soybean oil, plant soybean
Oil, liquid wax, lubricating oil or solvent naphtha 100, No. 150, No. 180, No. 200 etc., can also be other solvents commonly used in the art；
Described filler is selected from white carbon, kaolin, precipitated calcium carbonate, diatomite, cornstarch, quartz sand, talcum powder, sulphur
One or more of sour ammonium, sodium sulphate, sodium chloride, potassium chloride, fine particle calcium carbonate etc.；
Antifreezing agent is selected from one or more of ethylene glycol, propane diols, urea, diethylene glycol (DEG), glycerine etc.；
Thickener selected from xanthans, polyvinyl alcohol, organobentonite, hydroxymethyl cellulose, aluminium-magnesium silicate etc. one kind or
Several.
The advantage of compound herbicide of the present invention is：
Rationally, synergistic effect significantly, can be used for wheat paddock after seedling cauline leaf process and prevent and kill off broad leaved weed component.
Specific embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight ratio, but this
Bright it is not limited thereto.
1st, toxicity is determined
For further appreciating that the synergy of the mixture to weeds of the application, the present inventor is to quinmerac and trichlorine pyrrole oxygen second
The mixture of acid has carried out cauline leaf process synergy toxicity measure.
Test material：Clearvers, chickweed.
Test method：
A certain amount of weeding active ingredient active compound is weighed, after fully dissolving, single dose mother liquor is configured to respectively, according to mixture mesh
Setting series proportioning, each proportioning arranges 5～7 concentration gradients.Representative sensitivity is selected according to single dose herbicidal spectrum
Weed seed, cultivates standby to 3 leaf, 1 heart.After the weeds cauline leaf process that will select to number, incubated at room temperature in illumination box is placed on
20 days, prevention effect (fresh weight preventive effect or strain preventive effect) is calculated, then ED is calculated with least square method50(95% confidence limit), then use
The abundant methods of Sun Yun calculate co-toxicity coefficient (CTC).Co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80
Show as antagonism；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.Test result is shown in Table 1-4.
Synergy measurement result of the 1 different ratio quinmerac trichlopyr of table to clearvers
| Medicament | Proportioning | ED50(ga.i/ mus) | Co-toxicity coefficient |
| Quinmerac (abbreviation quinoline) | —— | 10.52 | —— |
| Trichlopyr (referred to as three) | —— | 42.63 | —— |
| Quinoline three | 150:1 | 8.67 | 121.95 |
| Quinoline three | 100:2 | 8.72 | 122.45 |
| Quinoline three | 30:4 | 7.99 | 144.47 |
| Quinoline three | 1:1 | 8.05 | 209.63 |
| Quinoline three | 10:8 | 9.82 | 161.04 |
| Quinoline three | 1:16 | 28.23 | 128.02 |
Synergy measurement result of the 2 different ratio quinmerac trichlopyr florasulam of table to clearvers
The synergy measurement result of table 3, different ratio quinmerac trichlopyr to chickweed
| Medicament | Proportioning | ED50(ga.i/ mus) | Co-toxicity coefficient |
| Quinmerac (abbreviation quinoline) | —— | 12.07 | —— |
| Trichlopyr (referred to as three) | —— | 44.36 | —— |
| Quinoline three | 150:1 | 10.01 | 121.16 |
| Quinoline three | 100:2 | 9.92 | 123.44 |
| Quinoline three | 30:4 | 10.71 | 123.25 |
| Quinoline three | 1:1 | 9.99 | 189.96 |
| Quinoline three | 10:8 | 10.28 | 173.56 |
| Quinoline three | 1:16 | 30.32 | 126.41 |
Synergy measurement result of the 4 different ratio quinmerac trichlopyr florasulam of table to chickweed
| Medicament | Proportioning | ED50(ga.i/ mus) | Co-toxicity coefficient |
| Quinmerac (abbreviation quinoline) | —— | 12.07 | —— |
| Trichlopyr (referred to as three) | —— | 44.36 | —— |
| Florasulam (referred to as double) | —— | 14.37 | —— |
| Quinoline three pairs | 5:10:1 | 18.78 | 120.12 |
| Quinoline three pairs | 15:1:10 | 10.56 | 125.54 |
| Quinoline three pairs | 30:60:20 | 16.16 | 130.16 |
| Quinoline three pairs | 40:40:40 | 11.67 | 146.91 |
| Quinoline three pairs | 100:40:20 | 11.53 | 131.18 |
| Quinoline three pairs | 150:1:10 | 9.68 | 126.52 |
The measurement result of table 1-4 shows, quinmerac and trichlopyr, quinmerac, trichlopyr and double fluorine sulphurs
Careless amine is respectively 150:1-1:16 and 1-150:1-80:In the proportion of 0.1-40, obvious synergistic effect is respectively provided with.
2nd, example of formulations
Embodiment 1,15.1% quinmerac trichlopyr suspending agent
Quinmerac 15%, trichlopyr 0.1%, APES 15%, neopelex
7%, xanthans 1%, glycerine 1%, water to 100%, being configured to weight/mass percentage composition according to conventional formulation method is
15.1% quinmerac trichlopyr suspending agent.
Embodiment 2,51% quinmerac trichlopyr wettable powder
Quinmerac 50%, trichlopyr 1%, sodium methylene bis-naphthalene sulfonate 17%, sodium lignin sulfonate 11%, alkyl
Phenol polyethenoxy ether 4%, white carbon 5%, kaolin supplies 100%, is configured to quality percentage according to conventional formulation method and contains
Measure the quinmerac trichlopyr wettable powder for 51%.
Embodiment 3,34% quinmerac trichlopyr water dispersible granules
Weigh quinmerac 30%, trichlopyr 4%, polycarboxylate 8%, alkylnaphthalene sulfonate formaldehyde condensation products 3%,
Tea seed cake 2%, calcium dodecyl benzene sulfonate 6%, White Carbon black 2%, diatomite add to 100% weight portion.The frequent regulation of above-mentioned raw materials
The method of water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 34% quinmerac trichlorine pyrrole oxygen
Acetic acid water dispersible granules.
Embodiment 4,60% quinmerac trichlopyr aqueous emulsion
Quinmerac 30%, trichlopyr 30%, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 8%, APES 6%,
Tea Saponin 9%, glycerine 5%, xanthans 2%, water supplies 100%, is configured to quality percentage according to conventional formulation method and contains
Measure the quinmerac trichlopyr aqueous emulsion for 60%.
Embodiment 5,36% quinmerac trichlopyr missible oil
By quinmerac 20%, trichlopyr 16%, calcium dodecyl benzene sulfonate 11%, AEO
5%th, single oleamide polyoxyethylene groups disodium sulfosuccinate 9%, oleic acid 11%, 1-METHYLPYRROLIDONE supplies 100%, mixing
Uniformly, 36% quinmerac trichlopyr cream preparation had both been obtained.
Embodiment 6,34% quinmerac trichlopyr oil-suspending agent
Quinmerac 2%, trichlopyr 32%, sodium alkyl benzene sulfonate 5%, styrene phenol APEO 5%, silicon
Sour sodium 5%, epoxidized soybean oil 6%, glycerine 2%, mineral oil add to 100% weight portion.Blended through raw material, high speed shear point
Scattered 30min, with prepared 34% quinmerac trichlopyr oil-suspending agent after sand mill sand milling.
Embodiment 7,16% quinmerac trichlopyr florasulam suspending agent
Quinmerac 5%, trichlopyr 10%, florasulam 1%, APES 12%, dodecane
Base benzene sulfonic acid sodium salt 4%, polycarboxylate 3%, xanthans 5%, glycerine 1%, water to 100% are matched somebody with somebody according to conventional formulation method
Make the quinmerac trichlopyr florasulam suspending agent that weight/mass percentage composition is 16%.
Embodiment 8,26% quinmerac trichlopyr florasulam wettable powder
Quinmerac 15%, trichlopyr 1%, florasulam 10%, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 13%, lignin
Sodium sulfonate 11%, polyoxyethylene alkylphenol formaldehyde condensation products 3%, APES 4%, white carbon 5%, kaolin are mended
Foot 100%, is configured to the quinmerac trichlopyr that weight/mass percentage composition is 26% according to conventional formulation method double
Penoxsulam wettable powder.
Embodiment 9,22% quinmerac trichlopyr florasulam water dispersible granules
Quinmerac 6%, trichlopyr 12%, florasulam 4%, polycarboxylate 11%, alkylnaphthalene sulfonate first
Aldehyde condensate 4%, tea seed cake 2%, calcium dodecyl benzene sulfonate 7%, White Carbon black 2%, diatomite add to 100% weight portion.Above-mentioned
The method of raw material frequent regulation water intaking dispersible granule mixes, ultra micro air-flow crushing, mixing, granulation step produce 22% quinoline careless
Sour trichlopyr florasulam water dispersible granules.
Embodiment 10,30% quinmerac trichlopyr florasulam aqueous emulsion
Quinmerac 10%, trichlopyr 10%, 10% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 18% of florasulam, alkyl phenol
APEO 7%, Tea Saponin 3%, glycerine 1%, xanthans 2%, water supplies 100%, matches somebody with somebody according to conventional formulation method
Make the quinmerac trichlopyr florasulam aqueous emulsion that weight/mass percentage composition is 30%.
Embodiment 11,32% quinmerac trichlopyr florasulam missible oil
By quinmerac 20%, trichlopyr 8%, florasulam 4%, calcium dodecyl benzene sulfonate 15%, fat
Alcohol APEO 15%, single oleamide polyoxyethylene groups disodium sulfosuccinate 9%, oleic acid 11%, 1-METHYLPYRROLIDONE
100% is supplied, is well mixed, both obtained 32% quinmerac trichlopyr florasulam cream preparation.
Embodiment 12,25.1% quinmerac trichlopyr florasulam oil-suspending agent
Quinmerac 15%, trichlopyr 0.1%, florasulam 10%, sodium alkyl benzene sulfonate 15%, styrene benzene
Phenol polyethenoxy ether 5%, sodium metasilicate 5%, epoxidized soybean oil 6%, glycerine 2%, soybean oil add to 100% weight portion.Through original
Material is blended, and high speed shear disperses 30min, with the double fluorine of prepared 25.1% quinmerac trichlopyr after sand mill sand milling
Sulphur grass amine oil-suspending agent.
3rd, field control effectiveness test
Reagent agent：Complex weedicide in embodiment 1-12.
Comparison medicament：48% trichlopyr missible oil (comparison medicament 1), 20% florasulam suspending agent (comparison medicine
Agent 2), 50% quinmerac wettable powder (comparison medicament 3).
Preventing and treating crop：Wheat.
Prevent and kill off object：Clearvers, chickweed, tongue of sparrow grass, Veronica.
Test method：Testing is carried out in wheat paddock, and each group processes 3 repetitions, and processing area is about 20m2,
According to the area of experimental plot, the good various medicaments of precise, after seedling cauline leaf process.30d weeds after statistics administration
Death condition, the activity of weeding of the various medicaments of comparison.The results are shown in Table 5.
30d herbicidal effects after composition medicine of the table 5 containing quinmerac
Field experiment result shows that quinmerac trichlopyr, the double fluorine sulphurs of quinmerac trichlopyr are careless
The compounding of amine is preferable to the preventive effect of the broad leaved weeds such as the clearvers of wheat paddock, chickweed, tongue of sparrow grass, Veronica, compared with single dose,
Activity of weeding is enhanced, and synergistic effect is obvious.Estimated according to field, in the range of test dose, plant growth is just
Often, have no that plant produces poisoning and anomaly, to wheat safety.Illustrate, quinmerac trichlopyr, quinmerac three
After chlorine pyrrole fluoroacetic acid florasulam compounding, can have complementary advantages, expand weed control spectrum, reduce each plant demand, reduce use
Cost.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, the present invention range of the technology design in, multiple simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
Claims (8)
1. a kind of Herbicidal combinations, it is characterised in that described Herbicidal combinations are with quinmerac, trichlopyr as mainly having
Effect composition, quinmerac and trichlopyr weight ratio are 150:1-1:16.
2. Herbicidal combinations according to claim 1, it is characterised in that the weight ratio of quinmerac and trichlopyr is 100:
1-1:16, more preferably 50:1-16.
3. according to the arbitrary described Herbicidal combinations of claim 1-2, it is characterised in that florasulam, quinoline grass can also be included
The ratio of acid, trichlopyr and florasulam is 1-150:1-80:0.1-40.
4. Herbicidal combinations according to claim 3, it is characterised in that the ratio of quinmerac, trichlopyr and florasulam
For 1-100:1-80:0.1-40, preferably 5-150:1-20:0.1-5.
5. according to the arbitrary described Herbicidal combinations of claim 1-4, it is characterised in that the content of active ingredient is 1-85%, excellent
Select 30-75%.
6. according to the arbitrary described Herbicidal combinations of claim 1-5, it is characterised in that Herbicidal combinations and insecticides adjuvant are prepared
Any one formulation allowed on agricultural chemicals.
7. according to the arbitrary described Herbicidal combinations of claim 1-6, it is characterised in that the formulation of the Herbicidal combinations is water
Dispersible granule, wettable powder, missible oil, aqueous suspension agent, oil suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
8. the arbitrary described Herbicidal combinations of claim 1-7 prevent and kill off broad leaved weed for wheat paddock after seedling cauline leaf process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610786514.3A CN106489942A (en) | 2016-08-31 | 2016-08-31 | Herbicidal combinations and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610786514.3A CN106489942A (en) | 2016-08-31 | 2016-08-31 | Herbicidal combinations and its application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106489942A true CN106489942A (en) | 2017-03-15 |
Family
ID=58291324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610786514.3A Pending CN106489942A (en) | 2016-08-31 | 2016-08-31 | Herbicidal combinations and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106489942A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4715889A (en) * | 1982-09-07 | 1987-12-29 | Basf Aktiengesellschaft | Quinoline derivatives and their use for controlling undesirable plant growth |
| CN102318618A (en) * | 2011-07-07 | 2012-01-18 | 陕西美邦农药有限公司 | Weeding composition containing florasulam and fluroxypyr |
| CN105592705A (en) * | 2013-10-11 | 2016-05-18 | 美国陶氏益农公司 | Aqueous herbicidal concentrates |
| CN106879596A (en) * | 2015-12-15 | 2017-06-23 | 四川利尔作物科学有限公司 | Herbicidal combinations and its application |
-
2016
- 2016-08-31 CN CN201610786514.3A patent/CN106489942A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4715889A (en) * | 1982-09-07 | 1987-12-29 | Basf Aktiengesellschaft | Quinoline derivatives and their use for controlling undesirable plant growth |
| CN102318618A (en) * | 2011-07-07 | 2012-01-18 | 陕西美邦农药有限公司 | Weeding composition containing florasulam and fluroxypyr |
| CN105592705A (en) * | 2013-10-11 | 2016-05-18 | 美国陶氏益农公司 | Aqueous herbicidal concentrates |
| CN106879596A (en) * | 2015-12-15 | 2017-06-23 | 四川利尔作物科学有限公司 | Herbicidal combinations and its application |
Non-Patent Citations (1)
| Title |
|---|
| BADOWSKI, MAREK,ET,AL.: "Efficacy of triclopyr with florasulam and fluroxypyr mixtures", 《PROGRESS IN PLANT PROTECTION》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104430451A (en) | Herbicidal composition containing triafamone and halosulfuron-methyl | |
| CN104920441A (en) | Pesticide composition for preventing and treating striped flea beetles | |
| CN104068024A (en) | Herbicide composition and application thereof | |
| CN103098803B (en) | Penoxsuam is with clomazone composition pesticide | |
| CN104430450A (en) | Herbicidal composition of triafamone and pyrazosulfuron | |
| CN106472529A (en) | Herbicidal combinations and its application | |
| CN107686777A (en) | A kind of 2-methyl-4-chloropheeffervescent water-soluble granule and preparation method thereof | |
| CN105284856A (en) | Weeding combination containing halauxifen-methyl and thiencarbazone-methyl | |
| CN109497079A (en) | A kind of Herbicidal combinations and its application method and purposes | |
| CN106489942A (en) | Herbicidal combinations and its application | |
| CN104839171B (en) | Herbicidal combinations containing three azole amides and Oxyfluorfen | |
| CN106386813B (en) | Herbicidal combinations and its application | |
| CN104206400A (en) | Formamido-pyrazosulfuron-methyl and iodosulfuron-methyl sodium composite herbicide | |
| CN101584324A (en) | 2-cyano-3-amino-3-phenylancryic acetate and epoxiconazole-containing antiseptic composition | |
| CN106259400B (en) | A kind of Herbicidal combinations containing Sulfonylurea and propyl-ester nitorfen | |
| CN108739834B (en) | Weeding composition containing penoxsulam | |
| CN107751214A (en) | Herbicidal combinations and its application | |
| CN109463389A (en) | A kind of Herbicidal combinations containing oxaziclomefone Yu chlorine fluorine pyridine ester | |
| CN102771481A (en) | Corn field weedicide composition | |
| CN102771492B (en) | Herbicide composition containing sulfosulfuron and clodinafop-propargyl | |
| CN103190411A (en) | Herbicide composite, preparation and application of preparation | |
| CN110731346B (en) | Ternary weeding composition containing benzobicyclon | |
| CN108849941A (en) | A kind of Herbicidal combinations containing Huan Wu Evil humulone, penoxsuam and pretilachlor | |
| CN107751226B (en) | Herbicide composition containing pyridate and flufenacet | |
| CN106489943A (en) | Herbicidal combinations and its application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170315 |