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CN106479439A - A kind of ice melting agent for transformer station and preparation method thereof - Google Patents

A kind of ice melting agent for transformer station and preparation method thereof Download PDF

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Publication number
CN106479439A
CN106479439A CN201610896683.2A CN201610896683A CN106479439A CN 106479439 A CN106479439 A CN 106479439A CN 201610896683 A CN201610896683 A CN 201610896683A CN 106479439 A CN106479439 A CN 106479439A
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CN
China
Prior art keywords
ice melting
stirring
melting agent
transformer station
weight percentage
Prior art date
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Granted
Application number
CN201610896683.2A
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Chinese (zh)
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CN106479439B (en
Inventor
覃绍先
何剑峰
吴军
杨旭
马文杰
魏莉芳
林磊
郑卫军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUBEI CHAONENG ELECTRIC POWER CO Ltd
State Grid Corp of China SGCC
Maintenance Branch of State Grid Hubei Electric Power Co Ltd
Original Assignee
Hubei Super Power & Ultrahigh Pressure Electric Power Technology Development Co Ltd
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Priority to CN201610896683.2A priority Critical patent/CN106479439B/en
Publication of CN106479439A publication Critical patent/CN106479439A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C09K3/185Thawing materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)

Abstract

The invention discloses a kind of preparation method of the ice melting agent for transformer station, comprise the steps of:1), by weight percentage, in the state of stirring, successively by propylene glycol:26%~34%, diethylene glycol:46%~52% adds in container, continues stirring, fully dissolves;2), by weight percentage, in the state of stirring, continue to sequentially add triethanolamine:1%~3%, natrium carbonicum calcinatum:2%~4%, stirring is simultaneously fully dissolved;3), by weight percentage, in the state of stirring, by deionized water:13%~18% addition step 2) in the solution that has been completely dissolved, the pH value making solution is 6.5~7.2;4), after stirring 30 minutes, 4 hours are stood;5) last, filter subpackage with 1 micron of filter;The ice melting agent of transformer station of the present invention adopts nanotechnology, its pH value close to 7, the equal non-corrosiveness to power equipment, no any toxic action to environment.

Description

A kind of ice melting agent for transformer station and preparation method thereof
Technical field
The invention belongs to transformer station's ice-melt, anti-icing technical field and in particular to a kind of ice melting agent for transformer station and its Preparation method.
Background technology
China had made significant headway to the development of ice melting agent in recent years, but it is mainly in road, bridge, building Deng the removing of surface ice and snow, a ice melting agent is not therefore also had to research and develop for transformer station, and ice-melt in the market Agent there is also many defects in actual use, and such as to concrete-bridge and road, periphery green plants have serious Corrosivity and murder by poisoning, the service life of serious curtailment building, causes its upkeep cost high;Ice melting agent is short for action time, long-pending Need repeatedly sprinkling etc. when snowfall is many, be not particularly suited for transformer station's icing and remove.So transformer station of current China is commonly used De-icing method has directly using the two methods of next powered knockout ice slush of insulated operating rod and ground connection bar.Although confirming in practice The effectiveness of utensil, but using above still suffering from some problems, such as ice-melt efficiency is slow, must have substantial amounts of manpower, to transformer station's instrument Equipment have infringement, electrical equipment need in defects such as ice-melts under power down mode, therefore China be directed to transformer station's icing clear with ice melting agent Except also in blank stage.
Content of the invention
In view of this, in order to overcome the deficiencies in the prior art, the present invention provide a kind of ice melting agent for transformer station and its Preparation method, can effectively remove transformer station's icing, the secondary icing after also preventing transformer station's icing from removing, and reduce and make because of ice and snow The converting station electric power accident becoming.
For achieving the above object, technical scheme is as follows:
A kind of preparation method of the ice melting agent for transformer station, comprises the steps of:
1), by weight percentage, in the state of stirring, successively by propylene glycol:26%~34%, diethylene glycol: 46%~52% adds in container, continues stirring, fully dissolves;
2), by weight percentage, in the state of stirring, continue to sequentially add triethanolamine:1%~3%, anhydrous carbon Sour sodium:2%~4%, stirring is simultaneously fully dissolved;
3), by weight percentage, in the state of stirring, by deionized water:13%~18% addition step 2) complete In the solution of CL, the pH value making solution is 6.5~7.2;
4), after stirring 30 minutes, 4 hours are stood;
5) last, filter subpackage with 1 micron of filter.
Further, comprise following component by weight percentage:Propylene glycol:32%, diethylene glycol:46%, three ethanol Amine:1%, natrium carbonicum calcinatum:2%, deionized water:17%, balance of impurity.
Further, comprise following component by weight percentage:Propylene glycol:31%, diethylene glycol:50%, three ethanol Amine:1%, natrium carbonicum calcinatum:2%, deionized water:14%, balance of impurity.
Further, comprise following component by weight percentage:Propylene glycol:28%, diethylene glycol:48%, three ethanol Amine:2%, natrium carbonicum calcinatum:3%, deionized water:16%, balance of impurity.
Further, the pH value of solution is 6.8.
Further, the pH value of solution is 7.
Further, the pH value of solution is 7.2.
The present invention also provides a kind of ice melting agent for transformer station, and described ice melting agent to be prepared using aforesaid method.
Beneficial effects of the present invention are:The ice melting agent for transformer station of the present invention adopts nanotechnology, according to certain Proportioning merges various raw materials, and its pH value, close to 7, belongs to neutral, therefore to electric force pole tower, insulator chain, metal wire Cable and the equal non-corrosiveness of power equipment, to plant, microorganism, soil, periphery water system and the no any toxic action of environment.
1) deionized water in ice melting agent etc. can reduce the electrical conductivity of ice melting agent well, so that in icing reset procedure Power failure process need not be carried out to substation equipment, greatly improve electric power netting safe running natural law;
2) reagent such as propylene glycol has good cryoprotective effects, make ice melting agent under -15 DEG C to -33 DEG C of low temperature condition still Outstanding ice melting capability can be kept, meet the ice melting agent technical specification of Administration of Quality and Technology Supervision of Beijing formulation, be a kind of Gao An The ice melting agent of full property.In addition the triethanolamine in ice melting agent, natrium carbonicum calcinatum etc. can make ice melting agent remain to after using 30 minutes Keep superpower ice melting capability, secondary icing can be stoped, usually can keep 24 hours not freezing.
Specific embodiment
Below in conjunction with embodiments of the invention, the technical scheme in the embodiment of the present invention is clearly and completely retouched State it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on the present invention In embodiment, the every other enforcement that those of ordinary skill in the art are obtained under the premise of not making creative work Example, broadly falls into the scope of protection of the invention.
Embodiment one
A kind of preparation method of the ice melting agent for transformer station, comprises the steps of:
1), by weight percentage, in the state of stirring, successively by propylene glycol:32%th, diethylene glycol:46% addition In container, continue stirring, fully dissolve;
2), by weight percentage, in the state of stirring, continue to sequentially add triethanolamine:1%th, natrium carbonicum calcinatum: 2%, stirring is simultaneously fully dissolved;
3), by weight percentage, in the state of stirring, by deionized water:17% addition step 2) it is completely dissolved Solution in, make solution pH value be 6.8;
4), after stirring 30 minutes, 4 hours are stood;
5) last, filter subpackage with 1 micron of filter.
Wherein, the freezing point (v that next time freezes:v,1:1 diluent):≤-33℃.
Embodiment two
A kind of preparation method of the ice melting agent for transformer station, comprises the steps of:
1), by weight percentage, in the state of stirring, successively by propylene glycol:31%th, diethylene glycol:50% addition In container, continue stirring, fully dissolve;
2), by weight percentage, in the state of stirring, continue to sequentially add triethanolamine:1%th, natrium carbonicum calcinatum: 2%, stirring is simultaneously fully dissolved;
3), by weight percentage, in the state of stirring, by deionized water:14% addition step 2) it is completely dissolved Solution in, make solution pH value be 7;
4), after stirring 30 minutes, 4 hours are stood;
5) last, filter subpackage with 1 micron of filter.
Wherein, the freezing point (v that next time freezes:v,1:1 diluent):≤-33℃.
Embodiment three
A kind of preparation method of the ice melting agent for transformer station, comprises the steps of:
1), by weight percentage, in the state of stirring, successively by propylene glycol:28%th, diethylene glycol:48% addition In container, continue stirring, fully dissolve;
2), by weight percentage, in the state of stirring, continue to sequentially add triethanolamine:2%th, natrium carbonicum calcinatum: 3%, stirring is simultaneously fully dissolved;
3), by weight percentage, in the state of stirring, by deionized water:16% addition step 2) it is completely dissolved Solution in, make solution pH value be 7.2;
4), after stirring 30 minutes, 4 hours are stood;
5) last, filter subpackage with 1 micron of filter.
Wherein, the freezing point (v that next time freezes:v,1:1 diluent):≤-33℃.
Implementation result
First, a kind of ice melting agent ice-melt velocity measuring test for transformer station of the present invention
The method of mensure ice-melt speed more general at present has two kinds:One kind is the set time, measures in this time Ice storage, another kind is that the ice melting agent measuring certain mass has melted the time needed for the ice of certain mass completely.In view of simplicity Property and operability, this experiment adopts the former, that is,:Take the porcelain evaporating dishes of 8 lOOmL, built-in equivalent 50mL water, after freezing reality, incite somebody to action The ice melting agent of equivalent spills on ice, measures 15min with tipping, the ice storage after 30min, 45min, 60min.When comparing different Between Internal melt accumulation both may compare its ice-melt speed.Water yield is more, illustrates that ice-melt speed is faster.
(1) experimentation
A, in porcelain evaporating dishes inject 50mL distilled water, be placed in refrigerator-freezer, freeze under the conditions of 10 DEG C and be frozen into for 12 hours Ice.
B, refrigerator doors are opened, temperature is respectively adjusted to 10 DEG C, 15 DEG C, 20 DEG C, 25 DEG C, 30 DEG C, -35 DEG C each porcelain is steamed Send out ware to arrange in certain sequence neatly.
C, in 1 minute, lOg ice melting agent is uniformly scattered onto on ice pan face.Respectively in 15min, 30min, 45min, Collect the ice melting after 60min, survey its volume.
(2) experimental result and discussion
When ice melting agent be sprinkling upon in ice face produce ice-melt effect when, can hear, ice crack sound, in the week of ice melting agent Enclose and form a lot " pittings ", ultimately form the ice face in gully in length and breadth at the position having ice melting agent.
Table 1:Ice-melt rating results
Table 2:Ice-melt rating results under different temperatures
Can draw from Tables 1 and 2:The ice-melt speed of calcium chloride and transformer station's environment-friendly type ice melting agent is the fastest, is sodium chloride 2 About times;Very fast in the ice-melt speed of starting stage calcium chloride and transformer station's environment-friendly type ice melting agent, it is 4~5 times of sodium chloride, reason It is calcium chloride and propylene glycol, diethylene glycol class material are respectively provided with stronger wettability power;Calcium chloride and transformer station's ring when -20 DEG C Guarantor's type ice melting agent ice melting capability somewhat gap, sodium chloride now almost " lost efficacy ";At -30 DEG C, transformer station's environment-friendly type ice-melt Agent also has preferable ice melting capability;In ice-melt effect from ice-melt speed and low temperature, transformer station's environment-friendly type ice melting agent series It is superior to sodium chloride and calcium chloride.
2nd, a kind of ice melting agent for transformer station of the present invention is to corrosion of carbon steel rate determination
At present, conventional ice melting agent is calcium chloride, for elder generation is taking the ice melting agent that calcium chloride and the present invention are used for transformer station as a example Bright, the mass percentage concentration of each ice melting agent is still 3%, and each style does two parallel laboratory tests.
Experimental result
After interval is soaked 7 days, calcium chloride solution and aqueous solution all become bronzing, and bottom has black precipitate to generate;This Invent the ice-melt agent solution clear for transformer station, generation is no precipitated in bottom.It is immersed in calcium chloride solution and aqueous solution Carbon steel coupon surface all cover one layer of dark brown color substance, after doing processing of rust removing, there is pitting corrosion phenomenon on steel disc surface, and is immersed in chlorination Steel disc pitting corrosion phenomenon most serious in sodium solution;The steel disc being immersed in water also there occurs corrosion;It is immersed in this product solution Steel disc surface-brightening as before.
Table 3:For transformer station ice melting agent with respect to calcium chloride and water corrosion inhibition rate
As can be seen from Table 3:The corrosive nature calcium chloride of ice melting agent>Water>Ice melting agent for transformer station;Single chlorination Calcium is the most serious to the corrosion of carbon steel, its corrosion rate is 3 times of water, and corrosion depth is 4 times of water;Single water pair Also more heavy corrosion speed and corrosion depth is 2 times about of transformer station's ice melting agent to steel corrosion;Ice-melt for transformer station Agent is less to corrosion of carbon steel, also lower than the corrosivity of pure water.
Embodiment described above only have expressed embodiments of the present invention, and its description is more concrete and detailed, but can not Therefore it is interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, Without departing from the inventive concept of the premise, some deformation can also be made and improve, these broadly fall into the protection model of the present invention Enclose.Therefore, the protection domain of patent of the present invention should be defined by claims.

Claims (8)

1. a kind of preparation method of the ice melting agent for transformer station is it is characterised in that comprise the steps of:
1), by weight percentage, in the state of stirring, successively by propylene glycol:26%~34%, diethylene glycol:46%~ 52% adds in container, continues stirring, fully dissolves;
2), by weight percentage, in the state of stirring, continue to sequentially add triethanolamine:1%~3%, Carbon Dioxide Sodium:2%~4%, stirring is simultaneously fully dissolved;
3), by weight percentage, in the state of stirring, by deionized water:13%~18% addition step 2) completely molten In the solution of solution, the pH value making solution is 6.5~7.2;
4), after stirring 30 minutes, 4 hours are stood;
5) last, filter subpackage with 1 micron of filter.
2. a kind of ice melting agent for transformer station according to claim 1 preparation method it is characterised in that:Comprise as follows Component by weight percentage:Propylene glycol:32%, diethylene glycol:46%, triethanolamine:1%, natrium carbonicum calcinatum:2%, go Ionized water:17%, balance of impurity.
3. a kind of ice melting agent for transformer station according to claim 1 preparation method it is characterised in that:Comprise as follows Component by weight percentage:Propylene glycol:31%, diethylene glycol:50%, triethanolamine:1%, natrium carbonicum calcinatum:2%, go Ionized water:14%, balance of impurity.
4. a kind of ice melting agent for transformer station according to claim 1 preparation method it is characterised in that:Comprise as follows Component by weight percentage:Propylene glycol:28%, diethylene glycol:48%, triethanolamine:2%, natrium carbonicum calcinatum:3%, go Ionized water:16%, balance of impurity.
5. a kind of ice melting agent for transformer station according to claim 2 preparation method it is characterised in that:The pH of solution It is worth for 6.8.
6. a kind of ice melting agent for transformer station according to claim 3 preparation method it is characterised in that:The pH of solution It is worth for 7.
7. a kind of ice melting agent for transformer station according to claim 4 preparation method it is characterised in that:The pH of solution It is worth for 7.2.
8. a kind of ice melting agent for transformer station it is characterised in that:Described ice melting agent adopts any one of claim 1-7 Method preparing.
CN201610896683.2A 2016-10-13 2016-10-13 A kind of ice melting agent and preparation method thereof for substation Active CN106479439B (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108963871A (en) * 2018-09-07 2018-12-07 国家电网有限公司 A kind of comprehensive apparatus for examination and repair of power circuit
CN109021922A (en) * 2018-08-21 2018-12-18 国网河南省电力公司西峡县供电公司 A kind of removing ice of power transmission line ice melting agent and preparation method thereof
CN109103810A (en) * 2018-10-31 2018-12-28 国家电网有限公司 A kind of online replacement insulator arrangement
CN109149491A (en) * 2018-08-21 2019-01-04 国网河南省电力公司开封供电公司 A kind of ice-melting device for transmission line
CN109167319A (en) * 2018-09-07 2019-01-08 国家电网有限公司 A kind of distribution network line deicer
CN109193538A (en) * 2018-09-30 2019-01-11 国网河南省电力公司社旗县供电公司 A kind of overhead transmission line periodic cleaning equipment
CN109217173A (en) * 2018-09-30 2019-01-15 国网河南省电力公司西峡县供电公司 A kind of vibration damper on power transmission line hotline maintenance robot
CN109286151A (en) * 2018-09-07 2019-01-29 国家电网有限公司 A kind of long distance transmission line periodic cleaning device
CN109301751A (en) * 2018-10-27 2019-02-01 国网河南省电力公司西峡县供电公司 A kind of damper hotline maintenance robot
CN109327005A (en) * 2018-09-30 2019-02-12 国网河南省电力公司西峡县供电公司 A kind of field removing ice of power transmission line and waterproofing agent flusher
CN109449819A (en) * 2018-10-31 2019-03-08 国家电网有限公司 A kind of insulator surface on-Line Monitor Device

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CN87106033A (en) * 1986-08-28 1988-03-23 联合碳化加拿大公司 Aircraft de-icing and anti-icing compositions
CN1168406A (en) * 1997-06-25 1997-12-24 徐宏彪 Ice and snow melting agent and its use method
CN102732217A (en) * 2012-07-06 2012-10-17 陕西科灵威航空化工有限责任公司 Deicing and anti-icing liquid for airplane
CN103820081A (en) * 2014-02-28 2014-05-28 呼和浩特铁路局科研所 Snow-melting agent

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CN87106033A (en) * 1986-08-28 1988-03-23 联合碳化加拿大公司 Aircraft de-icing and anti-icing compositions
CN1168406A (en) * 1997-06-25 1997-12-24 徐宏彪 Ice and snow melting agent and its use method
CN102732217A (en) * 2012-07-06 2012-10-17 陕西科灵威航空化工有限责任公司 Deicing and anti-icing liquid for airplane
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021922A (en) * 2018-08-21 2018-12-18 国网河南省电力公司西峡县供电公司 A kind of removing ice of power transmission line ice melting agent and preparation method thereof
CN109149491A (en) * 2018-08-21 2019-01-04 国网河南省电力公司开封供电公司 A kind of ice-melting device for transmission line
CN109167319A (en) * 2018-09-07 2019-01-08 国家电网有限公司 A kind of distribution network line deicer
CN109286151A (en) * 2018-09-07 2019-01-29 国家电网有限公司 A kind of long distance transmission line periodic cleaning device
CN108963871A (en) * 2018-09-07 2018-12-07 国家电网有限公司 A kind of comprehensive apparatus for examination and repair of power circuit
CN109217173B (en) * 2018-09-30 2020-08-28 国网河南省电力公司西峡县供电公司 Electrified maintenance robot for shockproof hammer of power transmission line
CN109327005B (en) * 2018-09-30 2020-09-01 国网河南省电力公司西峡县供电公司 Deicing and waterproofing agent spraying device for field power transmission line
CN109193538A (en) * 2018-09-30 2019-01-11 国网河南省电力公司社旗县供电公司 A kind of overhead transmission line periodic cleaning equipment
CN109217173A (en) * 2018-09-30 2019-01-15 国网河南省电力公司西峡县供电公司 A kind of vibration damper on power transmission line hotline maintenance robot
CN109327005A (en) * 2018-09-30 2019-02-12 国网河南省电力公司西峡县供电公司 A kind of field removing ice of power transmission line and waterproofing agent flusher
CN109301751A (en) * 2018-10-27 2019-02-01 国网河南省电力公司西峡县供电公司 A kind of damper hotline maintenance robot
CN109301751B (en) * 2018-10-27 2020-09-01 国网河南省电力公司西峡县供电公司 Electrified maintenance robot for damper
CN109103810B (en) * 2018-10-31 2020-06-09 国家电网有限公司 Online insulator replacing device
CN109449819B (en) * 2018-10-31 2020-07-03 国家电网有限公司 Insulator surface on-line monitoring device
CN109449819A (en) * 2018-10-31 2019-03-08 国家电网有限公司 A kind of insulator surface on-Line Monitor Device
CN109103810A (en) * 2018-10-31 2018-12-28 国家电网有限公司 A kind of online replacement insulator arrangement

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