CN106431304A - 圆球形具有净化空气功能的木薯渣轻质通孔陶粒 - Google Patents
圆球形具有净化空气功能的木薯渣轻质通孔陶粒 Download PDFInfo
- Publication number
- CN106431304A CN106431304A CN201610847332.2A CN201610847332A CN106431304A CN 106431304 A CN106431304 A CN 106431304A CN 201610847332 A CN201610847332 A CN 201610847332A CN 106431304 A CN106431304 A CN 106431304A
- Authority
- CN
- China
- Prior art keywords
- spheroidal
- air purification
- purification function
- manioc waste
- lightweight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004887 air purification Methods 0.000 title claims abstract description 116
- 239000002699 waste material Substances 0.000 claims abstract description 130
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims abstract description 119
- 229960000892 attapulgite Drugs 0.000 claims abstract description 62
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 62
- 239000000843 powder Substances 0.000 claims abstract description 48
- 239000004927 clay Substances 0.000 claims abstract description 44
- 239000007921 spray Substances 0.000 claims abstract description 37
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 238000001035 drying Methods 0.000 claims abstract description 29
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000009413 insulation Methods 0.000 claims abstract description 7
- 229910001388 sodium aluminate Inorganic materials 0.000 claims abstract description 7
- 240000003183 Manihot esculenta Species 0.000 claims description 118
- 239000000463 material Substances 0.000 claims description 35
- 230000001699 photocatalysis Effects 0.000 claims description 33
- 239000011265 semifinished product Substances 0.000 claims description 29
- 239000002245 particle Substances 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 15
- 239000008187 granular material Substances 0.000 claims description 15
- 239000002893 slag Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 238000000855 fermentation Methods 0.000 claims description 10
- 230000004151 fermentation Effects 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 9
- 235000013339 cereals Nutrition 0.000 claims description 9
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 9
- 239000010451 perlite Substances 0.000 claims description 8
- 235000019362 perlite Nutrition 0.000 claims description 8
- 238000000746 purification Methods 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- 244000061456 Solanum tuberosum Species 0.000 claims description 5
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 239000002023 wood Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 238000000643 oven drying Methods 0.000 claims description 3
- -1 polydimethylsiloxane Polymers 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 230000004064 dysfunction Effects 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- RZYKUPXRYIOEME-UHFFFAOYSA-N CCCCCCCCCCCC[S] Chemical compound CCCCCCCCCCCC[S] RZYKUPXRYIOEME-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 230000003111 delayed effect Effects 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 21
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 14
- 238000010521 absorption reaction Methods 0.000 abstract description 12
- 229910021529 ammonia Inorganic materials 0.000 abstract description 7
- 239000003344 environmental pollutant Substances 0.000 abstract description 7
- 231100000719 pollutant Toxicity 0.000 abstract description 7
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract description 6
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 4
- 239000011941 photocatalyst Substances 0.000 abstract description 3
- 238000007873 sieving Methods 0.000 abstract description 3
- 238000002791 soaking Methods 0.000 abstract description 3
- 238000001354 calcination Methods 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 241000658379 Manihot esculenta subsp. esculenta Species 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 238000005469 granulation Methods 0.000 abstract 1
- 230000003179 granulation Effects 0.000 abstract 1
- 230000010354 integration Effects 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000011282 treatment Methods 0.000 abstract 1
- 239000012855 volatile organic compound Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 13
- 230000008569 process Effects 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 6
- 239000011324 bead Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 229910052613 tourmaline Inorganic materials 0.000 description 4
- 239000011032 tourmaline Substances 0.000 description 4
- 229940070527 tourmaline Drugs 0.000 description 4
- 239000010457 zeolite Substances 0.000 description 4
- 239000004141 Sodium laurylsulphate Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 3
- 238000013475 authorization Methods 0.000 description 3
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000004531 microgranule Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 230000009965 odorless effect Effects 0.000 description 3
- 235000019355 sepiolite Nutrition 0.000 description 3
- 229910052624 sepiolite Inorganic materials 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 230000009967 tasteless effect Effects 0.000 description 3
- 241001116389 Aloe Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000331528 Chlorophytum capense Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004113 Sepiolite Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 241001464837 Viridiplantae Species 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 235000011399 aloe vera Nutrition 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 239000011812 mixed powder Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241000876833 Emberizinae Species 0.000 description 1
- 244000252337 Epipremnum pinnatum Species 0.000 description 1
- 241000221079 Euphorbia <genus> Species 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- LUTSRLYCMSCGCS-BWOMAWGNSA-N [(3s,8r,9s,10r,13s)-10,13-dimethyl-17-oxo-1,2,3,4,7,8,9,11,12,16-decahydrocyclopenta[a]phenanthren-3-yl] acetate Chemical compound C([C@@H]12)C[C@]3(C)C(=O)CC=C3[C@@H]1CC=C1[C@]2(C)CC[C@H](OC(=O)C)C1 LUTSRLYCMSCGCS-BWOMAWGNSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007850 degeneration Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004033 diameter control Methods 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 210000004247 hand Anatomy 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/009—Porous or hollow ceramic granular materials, e.g. microballoons
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/5116—Ag or Au
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
- C04B2235/3222—Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/448—Sulphates or sulphites
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/94—Products characterised by their shape
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Catalysts (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
本发明公开了一种圆球形具有净化空气功能的木薯渣轻质通孔陶粒，其技术方案的要点是，配料由具有净化空气功能的凹凸棒陶土粉、木薯渣、活性白土废渣、白炭黑、活性氧化铝、铝酸钠、十二烷基硫酸钠、可擦洗凹凸棒光触媒喷涂液等组成；将配料进行搅拌、挤压造粒、烘干、焙烧、保温、筛分、浸泡、烘干、筛分、密封包装为圆球形具有净化空气功能的木薯渣轻质通孔陶粒；圆球形具有净化空气功能的木薯渣轻质通孔陶粒具有比表面积大、堆积密度低、吸湿率高、吸附性能优越、轻质强度好、微孔和大孔为一体的特点，适用于放置在室内、家具橱柜、车辆、飞机、船舶或其它建筑物内，进行吸附和降解甲醛、氨、苯、TVOC等污染物，以达到净化空气的目的。
Description
技术领域
本发明涉及陶粒，具体涉及一种圆球形具有净化空气功能的木薯渣轻质通孔陶粒。
背景技术
目前市场上供应的空气净化剂有以下几种类型：吸附型空气净化剂、遮盖型除味产品和分解型除味产品。吸附型空气净化剂是利用活性炭、竹炭、分子筛、矿物质等材料的物理吸附、化学吸附、催化氧化和还原等性能去除污染物的净化产品；遮盖型除味产品是利用芳香烃的香味遮盖空气中的各种异味，很多空气清新剂事实上并没有将异味清除，只是用一种香型将异味掩盖而已；分解型空气净化产品在市面上比较少见。
中国专利授权公告号：CN 103861421 B，授权公告日：2015年11月18日，名称为“一种空气净化剂”，公开了“一种空气净化剂，其制备原料按质量分数含有：硅藻土粉、沸石粉、麦饭石粉、电气石粉、活性炭粉，海泡石粉、二氧化钛粉，并采用如下方法制备：1)将硅藻土粉、沸石粉、麦饭石粉、电气石粉、活性炭粉，海泡石粉、二氧化钛粉混合；2)将步骤1)所得混合物造粒；3)烘干步骤2)造粒后所得混合物。本发明制得的空气净化剂比表面大而且均匀，对空气中有害物质的吸附分解效果好，是用于室内，车内等封闭空间的环境净化和各种空气净化器的理想选择材料”。
上述专利的不足之处是：⑴硅藻土粉、沸石粉、麦饭石粉、电气石粉、活性炭粉和海泡石粉没有经过必要的改性处理，很难真正发挥其有效净化空气的作用。⑵所得混合粉体添加20-30％的清水搅拌后采用圆盘造粒机造粒，是一种直径为1.2-1.6mm的圆形颗粒。该发明的混合粉体自身正常含水率大于10％，加水造粒后的圆形颗粒含水率将大于30％，而烘干温度在低于100℃情况下，很难在3个小时内将圆形颗粒烘干。⑶硅藻土、沸石、麦饭石、电气石和海泡石在250～450℃进行热处理加工后，其吸附性能比较好，这是本领域的技术人员共知；该发明的圆形颗粒在低于100℃情况下进行烘干，并不能有效提高净化空气的作用，而且圆形颗粒的抗压强度也很小，用手轻轻一捏，就会将圆形颗粒捏碎为粉未状。
市场上供应的圆球形空气净化剂、分子筛、干燥剂或其它的圆球形颗粒，在造粒过程中是先将粉状配料加工成一种直径小于0.5毫米的小球，然后将配制好的雾状水溶液，喷洒在运转中的造粒机内的小球里，再将粉状配料洒落在湿润的小球的表面，经过多次重复的喷洒雾状水溶液和将粉状配料洒落在湿润的小球的表面，经过一层又一层的包裹，小球的体积不断增大，最终完成造粒的全过程，制备成一种圆球形颗粒，由于圆球形颗粒内部结构非常密实，大大减少了圆球形颗粒有效的比表面积，圆球形颗粒的比重和堆积密度都比较大，直接影响到圆球形颗粒的吸附净化效果。
发明内容
本发明的目的是克服现有技术中不足之处，提供一种圆球形具有净化空气功能的木薯渣轻质通孔陶粒。
圆球形具有净化空气功能的木薯渣轻质通孔陶粒的配料由具有净化空气功能的凹凸棒陶土粉、木薯渣、活性白土废渣、白炭黑、轻质碳酸钙、轻质氧化镁、活性氧化铝、铝酸钠、空心微珠、熟石膏粉、膨胀珍珠岩、十二烷基硫酸钠和可擦洗凹凸棒光触媒喷涂液组成。
圆球形具有净化空气功能的木薯渣轻质通孔陶粒的生产方法：将圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品的配料进行搅拌、挤压造粒、烘干、焙烧、保温、筛分、浸泡、烘干、筛分、密封包装为圆球形具有净化空气功能的木薯渣轻质通孔陶粒。
具有净化空气功能的凹凸棒陶土粉由高粘凹凸棒石粘土、凹凸棒恒湿调理剂、天然矿物吸附过滤剂、侧柏叶、硅酸铝纤维和聚丙烯酰胺组成，具有较好的粘结性、可塑性、触变性、耐火性和热稳定性，能有效的吸附空气中甲醛、氨和苯等有害物质，保护环境和增进人们的身体健康，本发明选用具有净化空气功能的凹凸棒陶土粉的颗粒细度≤0.074毫米。
木薯又称南洋薯、木番薯、树薯，是大戟科植物的块根，有肉质长圆柱形块根，块根肉质富含淀粉,供食用或作糊料，可磨木薯粉、做面包、提供木薯淀粉和浆洗用淀粉乃至酒精饮料，木薯渣是一种生产酒精后的废渣，本发明选用木薯渣的颗粒细度≤0.074毫米。
活性白土是一种无臭、无味、无毒的白色或米色粉末或颗粒，经脱色以后的活性白土失去了活性即成为活性白土废渣，一些油厂都将这些活性白土废渣丢弃，如果得不到及时处理，活性白土废渣内的脂类有机质发酵后产生霉变和恶臭，不仅资源浪费，污染环境及地下水质，而且易引起火灾，将对社会和企业造成一定的损失；本发明选用活性白土废渣的颗粒细度≤0.149毫米。
白炭黑是一种超微细无机多孔性物质，由于其粒径很小，具有比表面积大、表面吸附力强、化学纯度高、分散性能好、优越的稳定性、补强性、增稠性、附着力和触变性等特异的性能。
轻质碳酸钙颗粒微细、表面较粗糙，比表面积大，轻质碳酸钙还具有不沉降，易分散，光泽好等特性，本发明选用轻质碳酸钙的颗粒细度≤0.074毫米。
轻质氧化镁为白色轻质疏松无定型粉末，无臭无味，无毒，轻质氧化镁所占体积约为重质氧化镁的三倍左右，有高度耐火绝热性能，增强剂、胶粘剂，本发明选用轻质氧化镁的颗粒细度≤0.074毫米。
活性氧化铝是一种多孔性、高分散度的固体材料，有很大的表面积，其微孔表面具备催化作用所要求的特性，如吸附性能、表面活性、优良的热稳定性等，所以被广泛地用作化学反应的催化剂和催化剂载体，本发明选用活性氧化铝的颗粒细度≤0.074毫米。
铝酸钠又名偏铝酸钠，是一种常见化学物品，白色、无臭、无味，呈强碱性的固体，在空气中易吸收水份和二氧化碳，本发明选用铝酸钠的颗粒细度≤0.074毫米。
天然二水石膏又称为生石膏，经过煅烧、磨细可得熟石膏粉，熟石膏有较多的微孔结构，使之具优良的隔音、隔热和防火性能，本发明选用熟石膏粉的颗粒细度≤0.074毫米。
空心微珠外观为灰白色，是一种松散、流动性好的粉体材料，空心微珠比重小、表面光滑、强度大、易分散，本发明选用空心微珠的颗粒细度≤≤0.149毫米。
珍珠岩经膨胀而成为一种轻质、多功能新型材料，具有表观密度轻、导热系数低、化学稳定性好等特点，本发明选用膨胀珍珠岩的颗粒细度≤0.074毫米。
十二烷基硫酸钠为白色或淡黄色粉状，溶于水，对碱和硬水不敏感，具有去污、乳化和优异的发泡力，是一种无毒的阴离子表面活性剂。
可擦洗凹凸棒光触媒喷涂液喷涂在建筑物或装饰材料表面，在光的照射下，可以持续不断的吸附和降解甲醛、氨、苯、甲苯、二甲苯、TVOC等污染物，并具有极强的杀菌、除臭、防霉、防污自洁和净化空气的功能。
本发明通过下述技术方案予以实现：
1、圆球形具有净化空气功能的木薯渣轻质通孔陶粒的配料按重量百分比由下列组分组成：圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品55～95％和可擦洗凹凸棒光触媒喷涂液5～45％。
2、圆球形具有净化空气功能的木薯渣轻质通孔陶粒的生产方法：⑴先将可擦洗凹凸棒光触媒喷涂液放入浸泡池里，再将圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品缓慢加入浸泡池内的可擦洗凹凸棒光触媒喷涂液中，圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品内外的微孔，不断的吸入可擦洗凹凸棒光触媒喷涂液，直至呈饱和状态；⑵从浸泡池里取出吸满可擦洗凹凸棒光触媒喷涂液的圆球形具有净化空气功能的木薯渣轻质通孔陶粒，输送到低温回转式烘干炉中进行烘干，烘干温度控制在150～180℃，烘干时间控制在1～3小时；⑶将低温烘干后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒输送到平板振动筛中进行筛分，筛去破碎的颗粒和粉状物，密封包装为圆球形具有净化空气功能的木薯渣轻质通孔陶粒的成品。
3、圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品的配料按重量百分比由下列组分组成：具有净化空气功能的凹凸棒陶土粉10～45％、木薯渣5～25％、活性白土废渣2～10％、白炭黑1～8％、轻质碳酸钙1～5％、轻质氧化镁1～5％、活性氧化铝1～5％、铝酸钠0.5～5％、空心微珠0.5～5％、熟石膏粉0.5～5％、膨胀珍珠岩0.5～5％、十二烷基硫酸钠0.5～5％和水10～40％。
4、圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品的生产方法：⑴将圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品的配料输入已经运转的搅拌混合机中，搅拌混合为圆球形具有净化空气功能的木薯渣轻质通孔陶粒的混合物；⑵将圆球形具有净化空气功能的木薯渣轻质通孔陶粒的混合物输送到挤压造粒机中，挤压造粒为圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料，圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料中心的大孔为通孔；⑶将圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输送到回转式烘干炉中进行烘干，烘干温度控制在200～250℃，烘干时间控制在1～4小时；⑷将烘干后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输送到回转式焙烧炉中焙烧，燃烧室的温度控制在900～950℃，焙烧时间控制在1～3小时；⑸将焙烧后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料，输入不锈钢圆筒库中保温，保温时间控制在24～72小时；⑹将保温冷却后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输送到滚筒振动筛中进行筛分，筛去破碎的颗粒和粉状物为圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品。
5、具有净化空气功能的凹凸棒陶土粉的生产方法是：⑴将具有净化空气功能的凹凸棒陶土粉的配料混合后输入粉碎机中进行粉碎，粉碎后的混合物颗粒细度小于0.5毫米；⑵将粉状混合物加入浸泡陈腐池中用水进行浸泡陈腐处理为半成品，浸泡陈腐时间控制在7～30天；⑶将半成品输入真空挤出机中挤压成圆柱形条状物，圆柱形条状物的直径控制在2～10毫米；⑷将圆柱形条状物输入到水泥晒场进行晾晒，晾晒后的圆柱形条状物含水量小于15％；⑸将晾晒后的圆柱形条状物输入磨机中进行磨粉为粉状物，粉状物的颗粒细度小于0.074毫米。
具有净化空气功能的凹凸棒陶土粉的配料按重量百分比由下列组分组成：高粘凹凸棒石粘土35～60％、凹凸棒恒湿调理剂10～35％、天然矿物吸附过滤剂5～20％、侧柏叶2～15％、硅酸铝纤维1～5％和聚丙烯酰胺0.1～3％。
具有净化空气功能的凹凸棒陶土粉是采用由本发明人于2011年2月25日申请的“具有净化空气功能的凹凸棒陶土粉”，中国专利授权公告号为：CN 102173743 B，授权公告日：2012年7月25日。
高粘凹凸棒石粘土是采用提高凹凸棒石粘土粘度的加工工艺生产的凹凸棒石粘土，从矿区开采的凹凸棒石粘土，需要经过30～120天的自然风化；改性处理方法是：以重量百分比计算，取自然风化后的凹凸棒石粘土94～98％，均匀加入2～6％碳酸钠，共同输入浸泡池中，加入清水进行浸泡陈化，浸泡时间为72～120小时；取浸泡后的凹凸棒石粘土，输入搅拌机中进行搅拌，并将搅拌后的凹凸棒石粘土，经挤压机挤成薄片，其厚度控制在0.5～2毫米，将凹凸棒石粘土薄片，进行晾晒，晾晒后的凹凸棒石粘土薄片，其含水量≤15％；配料以重量百分比计算：晾晒后的凹凸棒石粘土94～98％、高吸水树脂0.5～5％和纤维素0.5～3％，将上述配料进行搅拌，搅拌均匀后输入磨机中进行磨粉，颗粒细度≤0.074毫米；
上述生产工艺是采用由本发明人于2005年6月20日申请的“提高凹凸棒石粘土粘度的加工工艺”，中国专利授权公告号为：CN 1317067C，授权公告日：2007年5月23日。
高粘凹凸棒石粘土的检测方法：取28.0g凹凸棒石粘土粉试样，加入高速搅拌机的悬浮液杯中，再加入372g水，将悬浮液杯置于高速搅拌机上，在11000转/分钟的转速下搅拌20分钟，再将经过高速搅拌试样悬浮液倒入250mL的烧杯中，使用NDJ-1型旋转粘度计测试悬浮液的粘度，测试粘度值≥2200 mPa•s为高粘凹凸棒石粘土。
6、可擦洗凹凸棒光触媒喷涂液的配料按重量百分比由下列组分组成：酸化后的凹凸棒石粘土4～15％、高粘凹凸棒石粘土3～10％、纳米二氧化钛1～5％、白炭黑1～5％、纳米载银抗菌粉0.5～5％、纳米氧化镁0.5～5％、纳米二氧化锆0～5％、纳米氧化铝0～5％、纳米氧化锌0～5％、聚乙烯醇0.5～5％、聚乙二醇0.1～3％、聚二甲基硅氧烷0.1～2％和去离子水50～82％；
可擦洗凹凸棒光触媒喷涂液的生产方法：⑴将可擦洗凹凸棒光触媒喷涂液的配料输入已经运转的高速分散机中进行强力搅拌、分散和乳化，然后输入三辊研磨机中研磨为可擦洗凹凸棒光触媒喷涂液的半成品；⑵将可擦洗凹凸棒光触媒喷涂液的半成品输入胶体磨中，再次进行分散、乳化、粉碎、均质、消泡和研磨；⑶研磨后的可擦洗凹凸棒光触媒喷涂液中固体颗粒的粒度≤0.01毫米，罐装为可擦洗凹凸棒光触媒喷涂液。
可擦洗凹凸棒光触媒喷涂液是采用由本申请人于2016年07月29日申请的“可擦洗凹凸棒光触媒喷涂液”，中国专利申请号为：201610612590.2。
本发明中所述含水量百分比为重量百分比。
本发明中的具有净化空气功能的凹凸棒陶土粉内有大量的微孔和活性炭，具有较好的粘结性、可塑性、触变性、耐火性和热稳定性，能有效的吸附空气中甲醛、氨和苯等有害物质。
采用具有净化空气功能的凹凸棒陶土粉为主要原料，生产圆球形具有净化空气功能的木薯渣轻质通孔陶粒，充分发挥了具有净化空气功能的凹凸棒陶土粉的有效功能。
木薯渣内的有机质、纤维素、半纤维素和木质素在焙烧过程中，能提高了燃烧气流的热量，不但能节省能源，还有利于将圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料的内部能完全烧透；提高了圆球形具有净化空气功能的木薯渣轻质通孔陶粒的吸附性能，降低堆积密度和增加圆球形具有净化空气功能的木薯渣轻质通孔陶粒内部的孔隙率。
活性白土废渣在焙烧过程中，活性白土废渣内的脂类和有机质共同参加圆球形具有净化空气功能的木薯渣轻质通孔陶粒的焙烧，提高了燃烧气流的热量，不但能节省能源，还有利于圆球形具有净化空气功能的木薯渣轻质通孔陶粒的内部能完全烧透，增加圆球形具有净化空气功能的木薯渣轻质通孔陶粒内部的孔隙率。
白炭黑、轻质氧化镁、活性氧化铝和铝酸钠能提高圆球形具有净化空气功能的木薯渣轻质通孔陶粒的吸附能力和增加圆球形具有净化空气功能的木薯渣轻质通孔陶粒的颗粒强度。
圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品的配料中采用十二烷基硫酸钠，有利于在搅拌混合过程中能产生大量的泡沫，以增加圆球形具有净化空气功能的木薯渣轻质通孔陶粒内部的微孔。
轻质碳酸钙、熟石膏粉、空心微珠和膨胀珍珠岩能降低圆球形具有净化空气功能的木薯渣轻质通孔陶粒的堆积密度，增加圆球形具有净化空气功能的木薯渣轻质通孔陶粒内部的孔隙率。
吸入可擦洗凹凸棒光触媒喷涂液的圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品，经过烘干后为圆球形具有净化空气功能的木薯渣轻质通孔陶粒，在光的照射下，圆球形具有净化空气功能的木薯渣轻质通孔陶粒可以持续不断的吸附和降解甲醛、氨、苯和TVOC等污染物，并具有极强的杀菌、除臭、防霉、防污自洁和净化空气的功能。
挤压造粒后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料含水率大于30％，直接输送到回转式焙烧炉中高温焙烧，在高温焙烧过程中，陶粒毛坯料的表面先开始烧结固化，而内部的水蒸汽很难快速蒸发出来，陶粒毛坯料将会产生爆裂，而且也不能将陶粒毛坯料内部烧透。
本发明先将圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输送到回转式烘干炉中缓慢进行预烘干，烘干温度控制在150～250℃，再将烘干后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输送到回转式焙烧炉中焙烧，燃烧室的温度控制在900～950℃，可以确保在焙烧过程中将圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料烧透，不会产生爆裂。
焙烧后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料内在温度仍然高达700℃以上，将焙烧后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输入不锈钢圆筒库中保温，可以利用自身的余热，继续对圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料均匀加热，不但能确保将圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料内部完全烧透，还能起到均匀散布热量的作用，以提高圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料的内在质量。
圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料表面和内部有大量的微孔，是一种开口孔，开口孔不仅彼此贯通还与外界相通，圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料中心的大孔是一种通孔，有利于在焙烧过程中，能够将陶粒内部完全烧透，并能增加陶粒的有效比表面积、强度和降低堆积密度。
圆球形具有净化空气功能的木薯渣轻质通孔陶粒具有比表面积大、堆积密度低、吸湿率高、吸附性能优越、外观造型美观无异味、轻质强度好、微孔和大孔为一体的特点，圆球形具有净化空气功能的木薯渣轻质通孔陶粒在干燥状态下没有粉尘，可以吸附空气中大量的甲醛、氨、苯和TVOC等污染物，长年浸泡在水中也不会产生崩解。
吸入可擦洗凹凸棒光触媒喷涂液的圆球形具有净化空气功能的木薯渣轻质通孔陶粒，是在吸附的基础上进行降解，全面提高了圆球形具有净化空气功能的木薯渣轻质通孔陶粒吸附和净化空气的能力。
圆球形具有净化空气功能的木薯渣轻质通孔陶粒经过长时间的使用，吸附一定量的污染物后，木薯渣光触媒降解能力开始下降，会呈现出饱和状态，采用90～100℃的热水，将已经处于饱和状态的圆球形具有净化空气功能的木薯渣轻质通孔陶粒进行反冲洗，清洗粘附在圆球形具有净化空气功能的木薯渣轻质通孔陶粒内外的木薯渣光触媒薄膜或微粒，清洗干净后，将新配制的可擦洗凹凸棒光触媒喷涂液，喷涂或浸泡到圆球形具有净化空气功能的木薯渣轻质通孔陶粒内外，并进行烘干或晒干，可以继续发挥圆球形具有净化空气功能的木薯渣轻质通孔陶粒净化空气的作用。
清洗下来的微粒废渣可以用于种植吊兰、芦荟、虎尾兰、袖珍椰子、常春藤和绿萝等绿色植物，微粒废渣内没有分解的殘留物将会被吊兰、芦荟、虎尾兰等绿色植物缓慢吸附分解，不会产生新的污染。
圆球形具有净化空气功能的木薯渣轻质通孔陶粒适用于放置在室内、家具橱柜、车辆、飞机、船舶、地铁、隧道、高速公路隔音板、军事设施、装饰材料、公共场所或其它建筑物内，进行吸附和降解甲醛、氨、苯、TVOC等污染物，以达到长时间净化空气的目的。
附图说明
图1是圆球形具有净化空气功能的木薯渣轻质通孔陶粒示意图，图2是圆球形具有净化空气功能的木薯渣轻质通孔陶粒A-A剖面图。
如图所示：1是圆球形具有净化空气功能的木薯渣轻质通孔陶粒，2是圆球形具有净化空气功能的木薯渣轻质通孔陶粒的通孔。
具体实施方式
下面结合实施例对本发明作进一步的描述：
1、圆球形具有净化空气功能的木薯渣轻质通孔陶粒1的配料按重量百分比由下列组分组成：圆球形具有净化空气功能的木薯渣轻质通孔陶粒1半成品88％和可擦洗凹凸棒光触媒喷涂液12％。
2、圆球形具有净化空气功能的木薯渣轻质通孔陶粒1的生产方法：⑴先将可擦洗凹凸棒光触媒喷涂液放入浸泡池里，再圆球形具有净化空气功能的木薯渣轻质通孔陶粒1半成品缓慢加入浸泡池内的可擦洗凹凸棒光触媒喷涂液中，圆球形具有净化空气功能的木薯渣轻质通孔陶粒1半成品内外的微孔，不断的吸入可擦洗凹凸棒光触媒喷涂液，直至呈饱和状态；⑵从浸泡池里取出吸满可擦洗凹凸棒光触媒喷涂液的圆球形具有净化空气功能的木薯渣轻质通孔陶粒1，输送到低温回转式烘干炉中进行烘干，烘干温度控制在160～180℃，烘干时间控制在2小时；⑶将低温烘干后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒1输送到平板振动筛中进行筛分，筛去破碎的颗粒和粉状物，密封包装为圆球形具有净化空气功能的木薯渣轻质通孔陶粒1的成品。
3、圆球形具有净化空气功能的木薯渣轻质通孔陶粒1半成品的配料按重量百分比由下列组分组成：具有净化空气功能的凹凸棒陶土粉38％、木薯渣12％、活性白土废渣4％、白炭黑3％、轻质碳酸钙2％、轻质氧化镁2％、活性氧化铝2％、铝酸钠2％、空心微珠1％、熟石膏粉1％、膨胀珍珠岩1％、十二烷基硫酸钠2％和水30％。
4、圆球形具有净化空气功能的木薯渣轻质通孔陶粒1半成品的生产方法：⑴将圆球形具有净化空气功能的木薯渣轻质通孔陶粒1半成品的配料输入已经运转的搅拌混合机中，搅拌混合为圆球形具有净化空气功能的木薯渣轻质通孔陶粒1的混合物；⑵将圆球形具有净化空气功能的木薯渣轻质通孔陶粒1的混合物输送到挤压造粒机中，挤压造粒为圆球形具有净化空气功能的木薯渣轻质通孔陶粒1毛坯料，圆球形具有净化空气功能的木薯渣轻质通孔陶粒1毛坯料中心的大孔为通孔2；⑶将圆球形具有净化空气功能的木薯渣轻质通孔陶粒1毛坯料输送到回转式烘干炉中进行烘干，烘干温度控制在220～240℃，烘干时间控制在2小时；⑷将烘干后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒1毛坯料输送到回转式焙烧炉中焙烧，燃烧室的温度控制在900～920℃，焙烧时间控制在1小时；⑸将焙烧后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒1毛坯料，输入不锈钢圆筒库中保温，保温时间控制在48小时；⑹将保温冷却后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒1毛坯料输送到滚筒振动筛中进行筛分，筛去破碎的颗粒和粉状物为圆球形具有净化空气功能的木薯渣轻质通孔陶粒1半成品。
Claims (3)
1.一种圆球形具有净化空气功能的木薯渣轻质通孔陶粒，其特征在于，圆球形具有净化空气功能的木薯渣轻质通孔陶粒的配料按重量百分比由下列组分组成：圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品55～95％和可擦洗凹凸棒光触媒喷涂液5～45％；
所述圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品的配料按重量百分比由下列组分组成：具有净化空气功能的凹凸棒陶土粉10～45％、木薯渣5～25％、活性白土废渣2～10％、白炭黑1～8％、轻质碳酸钙1～5％、轻质氧化镁1～5％、活性氧化铝1～5％、铝酸钠0.5～5％、空心微珠0.5～5％、熟石膏粉0.5～5％、膨胀珍珠岩0.5～5％、十二烷基硫酸钠0.5～5％和水10～40％；
圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品的生产方法：⑴将圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品的配料输入已经运转的搅拌混合机中，搅拌混合为圆球形具有净化空气功能的木薯渣轻质通孔陶粒的混合物；⑵将圆球形具有净化空气功能的木薯渣轻质通孔陶粒的混合物输送到挤压造粒机中，挤压造粒为圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料，圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料中心的大孔为通孔；⑶将圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输送到回转式烘干炉中进行烘干，烘干温度控制在200～250℃，烘干时间控制在1～4小时；⑷将烘干后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输送到回转式焙烧炉中焙烧，燃烧室的温度控制在900～950℃，焙烧时间控制在1～3小时；⑸将焙烧后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料，输入不锈钢圆筒库中保温，保温时间控制在24～72小时；⑹将保温冷却后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒毛坯料输送到滚筒振动筛中进行筛分，筛去破碎的颗粒和粉状物为圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品；
所述可擦洗凹凸棒光触媒喷涂液的配料按重量百分比由下列组分组成：酸化后的凹凸棒石粘土4～15％、高粘凹凸棒石粘土3～10％、纳米二氧化钛1～5％、白炭黑1～5％、纳米载银抗菌粉0.5～5％、纳米氧化镁0.5～5％、纳米二氧化锆0～5％、纳米氧化铝0～5％、纳米氧化锌0～5％、聚乙烯醇0.5～5％、聚乙二醇0.1～3％、聚二甲基硅氧烷0.1～2％和去离子水50～82％；
可擦洗凹凸棒光触媒喷涂液的生产方法：⑴将可擦洗凹凸棒光触媒喷涂液的配料输入已经运转的高速分散机中进行强力搅拌、分散和乳化，然后输入三辊研磨机中研磨为可擦洗凹凸棒光触媒喷涂液的半成品；⑵将可擦洗凹凸棒光触媒喷涂液的半成品输入胶体磨中，再次进行分散、乳化、粉碎、均质、消泡和研磨；⑶研磨后的可擦洗凹凸棒光触媒喷涂液中固体颗粒的粒度≤0.01毫米，罐装为可擦洗凹凸棒光触媒喷涂液。
2.根据权利要求1所述的圆球形具有净化空气功能的木薯渣轻质通孔陶粒，其特征在于，具有净化空气功能的凹凸棒陶土粉的颗粒细度≤0.074毫米，木薯渣的颗粒细度≤0.074毫米,活性白土废渣的颗粒细度≤0.149毫米，轻质碳酸钙的颗粒细度≤0.074毫米，轻质氧化镁的颗粒细度≤0.074毫米，活性氧化铝的颗粒细度≤0.074毫米，铝酸钠的颗粒细度≤0.074毫米，空心微珠的颗粒细度≤0.149毫米，熟石膏粉的颗粒细度≤0.074毫米，膨胀珍珠岩的颗粒细度≤0.074毫米。
3.根据权利要求1所述的圆球形具有净化空气功能的木薯渣轻质通孔陶粒，其特征在于，圆球形具有净化空气功能的木薯渣轻质通孔陶粒的生产方法：⑴先将可擦洗凹凸棒光触媒喷涂液放入浸泡池里，再将圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品缓慢加入浸泡池内的可擦洗凹凸棒光触媒喷涂液中，圆球形具有净化空气功能的木薯渣轻质通孔陶粒半成品内外的微孔，不断的吸入可擦洗凹凸棒光触媒喷涂液，直至呈饱和状态；⑵从浸泡池里取出吸满可擦洗凹凸棒光触媒喷涂液的圆球形具有净化空气功能的木薯渣轻质通孔陶粒，输送到低温回转式烘干炉中进行烘干，烘干温度控制在150～180℃，烘干时间控制在1～3小时；⑶将低温烘干后的圆球形具有净化空气功能的木薯渣轻质通孔陶粒输送到平板振动筛中进行筛分，筛去破碎的颗粒和粉状物，密封包装为圆球形具有净化空气功能的木薯渣轻质通孔陶粒的成品。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610847332.2A CN106431304A (zh) | 2016-09-24 | 2016-09-24 | 圆球形具有净化空气功能的木薯渣轻质通孔陶粒 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610847332.2A CN106431304A (zh) | 2016-09-24 | 2016-09-24 | 圆球形具有净化空气功能的木薯渣轻质通孔陶粒 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106431304A true CN106431304A (zh) | 2017-02-22 |
Family
ID=58167293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610847332.2A Pending CN106431304A (zh) | 2016-09-24 | 2016-09-24 | 圆球形具有净化空气功能的木薯渣轻质通孔陶粒 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106431304A (zh) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102350298A (zh) * | 2011-09-06 | 2012-02-15 | 厦门建霖工业有限公司 | 一种净水用的多功能复合吸附材料及其制备方法 |
| CN104072189A (zh) * | 2014-07-08 | 2014-10-01 | 尹小林 | 用赤泥和植物残渣制造轻质多孔烧结材料的方法 |
| CN105906321A (zh) * | 2016-06-28 | 2016-08-31 | 平凉华晨非金属应用科技有限公司 | 煤矸石轻质通孔陶粒 |
-
2016
- 2016-09-24 CN CN201610847332.2A patent/CN106431304A/zh active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102350298A (zh) * | 2011-09-06 | 2012-02-15 | 厦门建霖工业有限公司 | 一种净水用的多功能复合吸附材料及其制备方法 |
| CN104072189A (zh) * | 2014-07-08 | 2014-10-01 | 尹小林 | 用赤泥和植物残渣制造轻质多孔烧结材料的方法 |
| CN105906321A (zh) * | 2016-06-28 | 2016-08-31 | 平凉华晨非金属应用科技有限公司 | 煤矸石轻质通孔陶粒 |
Non-Patent Citations (1)
| Title |
|---|
| 北京纺织工程学会编: "《2004高性能纤维研发与应用技术研讨会论文集》", 31 May 2004 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106431263A (zh) | 圆球形具有净化空气功能的硅藻土轻质通孔陶粒 | |
| CN106431463A (zh) | 圆柱形具有净化空气功能的凹凸棒轻质通孔陶粒 | |
| CN106431291A (zh) | 圆柱形具有净化空气功能的高岭土轻质通孔陶粒 | |
| CN106431281A (zh) | 圆球形具有净化空气功能的高岭土轻质通孔陶粒 | |
| CN106431215A (zh) | 圆柱形具有净化空气功能的膨润土轻质通孔陶粒 | |
| CN106431474A (zh) | 梅花形具有净化空气功能的硅藻土轻质通孔陶粒 | |
| CN106431211A (zh) | 圆球形具有净化空气功能的绿泥石轻质通孔陶粒 | |
| CN106431459A (zh) | 圆柱形具有净化空气功能的海泡石轻质通孔陶粒 | |
| CN106431304A (zh) | 圆球形具有净化空气功能的木薯渣轻质通孔陶粒 | |
| CN106431264A (zh) | 圆柱形具有净化空气功能的木薯渣轻质通孔陶粒 | |
| CN106431308A (zh) | 梅花形具有净化空气功能的木薯渣轻质通孔陶粒 | |
| CN106431272A (zh) | 圆球形具有净化空气功能的膨润土轻质通孔陶粒 | |
| CN106431260A (zh) | 圆柱形具有净化空气功能的甘蔗灰轻质通孔陶粒 | |
| CN106431261A (zh) | 圆柱形具有净化空气功能的硅藻土轻质通孔陶粒 | |
| CN106431231A (zh) | 圆球形具有净化空气功能的醋渣轻质通孔陶粒 | |
| CN106431218A (zh) | 圆柱形具有净化空气功能的醋渣轻质通孔陶粒 | |
| CN106431262A (zh) | 圆球形具有净化空气功能的料姜石轻质通孔陶粒 | |
| CN106431268A (zh) | 圆柱形具有净化空气功能的麦饭石轻质通孔陶粒 | |
| CN106467409A (zh) | 圆球形具有净化空气功能的甘蔗灰轻质通孔陶粒 | |
| CN106431480A (zh) | 圆柱形具有净化空气功能的料姜石轻质通孔陶粒 | |
| CN106431269A (zh) | 圆柱形具有净化空气功能的菱镁矿轻质通孔陶粒 | |
| CN106431460A (zh) | 圆柱形具有净化空气功能的桉树皮轻质通孔陶粒 | |
| CN106431232A (zh) | 圆柱形具有净化空气功能的伊利石轻质通孔陶粒 | |
| CN106467405A (zh) | 圆球形具有净化空气功能的凹凸棒轻质通孔陶粒 | |
| CN106431311A (zh) | 圆球形具有净化空气功能的铝矾土轻质通孔陶粒 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170222 |
|
| WD01 | Invention patent application deemed withdrawn after publication |