CN106397808B - A kind of manufacture craft for the mouse that bears dirty - Google Patents
A kind of manufacture craft for the mouse that bears dirty Download PDFInfo
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- CN106397808B CN106397808B CN201610766931.1A CN201610766931A CN106397808B CN 106397808 B CN106397808 B CN 106397808B CN 201610766931 A CN201610766931 A CN 201610766931A CN 106397808 B CN106397808 B CN 106397808B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
- C08J7/0423—Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
- C08J2483/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Plant Pathology (AREA)
- Detergent Compositions (AREA)
- Paints Or Removers (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
This patent belongs to computer accessories field, specifically discloses a kind of manufacture craft of mouse that bears dirty, which is characterized in that the mouse case of ABS material is impregnated in nitric acid solution, after taking-up cleans up in deionized water, and drying for standby；A formula: butyl titanate is added to absolute ethanol, and continues to stir；B formula: deionized water, acetic acid, absolute ethyl alcohol and stirring are uniformly mixed；A is formulated and is added in B formula, and is stirred to obtain colloidal sol；By the colloidal sol by after drying later, then rinsing mouse case surface using ethyl alcohol on spray gun even application to mouse case；Then mouse case is successively immersed in stearic ethanol solution and the toluene solution of PFTDS；It rinses, and is dried at room temperature for by dehydrated alcohol after mouse case is dry, the mouse case to bear dirty can be obtained.By being surface-treated to mouse case, ultra-hydrophobicity is made it have, improves its stain resistance ability, this method is easy to operate, easy to use.
Description
Technical field
The present invention relates to computer accessories fields, and in particular to a kind of manufacture craft for the mouse that bears dirty.
Background technique
After 21 century enters the information age, computer industry flourishes, and computer application is in worldwide
It is interior more and more common.With the raising of living standards of the people and the development of science and technology, the quantity of computer personal user is continuous
Soaring, application level is continuously improved, and especially the fields such as internet, communication, multimedia achieve marvelous achievement in application.
Mouse is that people use one of indispensable component of computer.When people use mouse, need whole hand being all held in mouse
On.And mouse is used for a long time, sweat stain etc. on hand can be polluteed to mouse surface, mouse surface is made to generate spot, be easy to grow
Endophytic bacteria.If once there is pathogenic bacteria to breed in mouse surface, it will generate strong influence to the health of human body.
The super-hydrophobic phenomenon of leaves of plants especially lotus leaf surface attracts attention.This super-hydrophobic phenomenon has
Significant hydrophobic, desorption, anti-sticking, self-cleaning function.Hydrophobicity is one of important feature of material surface, when drop and material table
Face is in contact, it be still able to maintain droplet profile or surface spreading formed liquid film, this property usually with water contact angle come
It measures.Usual surface of the contact angle greater than 150 ° becomes super hydrophobic surface.If material has superhydrophobic property, will significantly mention
The ability of its high stain resistance.
If can be surface-treated to mouse case, ultra-hydrophobicity is made it have, prevents from sweat stain etc. on hand
Dirt is adhered to mouse surface, greatly improves the stain resistance ability of mouse.
Summary of the invention
The purpose of the present invention is to provide a kind of manufacture crafts of mouse that bears dirty.Purpose is by carrying out to mouse case
Surface treatment, makes it have ultra-hydrophobicity, improves its stain resistance ability, this method is easy to operate, easy to use.
In order to achieve the above objectives, base case of the invention are as follows: (following alleged " number " is " mass fraction ")
Step 1, the mouse case of ABS material is impregnated 30~60 minutes in 10% nitric acid solution, take out go from
After being cleaned up in sub- water, drying for standby；
A formula: 8.5 parts of butyl titanates are added in 20 parts of dehydrated alcohols, and continue to stir；
B formula: 1.5 parts of deionized waters, 5 parts of acetic acid, 20 parts of absolute ethyl alcohol and stirrings are uniformly mixed；
A is formulated with the ratio of volume ratio 1:1 and is added in B formula, and is stirred 1 day, transparent light is finally obtained
Faint yellow colloidal sol, number described above are mass fraction；
Step 2, by the faint yellow colloidal sol by after the shell dries, then spraying on spray gun even application to mouse case
Once；Then 30~60 minutes dry under the conditions of 60 DEG C, then mouse case surface is rinsed using ethyl alcohol；
Step 3, mouse case is immersed in the stearic ethanol solution of 0.5~1wt% 30~60 minutes；Later 60
It is 3~6 hours dry under the conditions of DEG C；
Step 4, the mouse case after drying impregnates 60~90 minutes in the toluene solution of 0.5~2%PFTDS again, it
After be dried at room temperature for；
Step 5, mouse case finally is rinsed using dehydrated alcohol, is dried at room temperature for, can be obtained outside the mouse to bear dirty
Shell.
The working principle and advantage of this programme are: it is surface-treated by the shell to ABS material mouse, it is then sharp
The mouse case with nano coating is obtained, then again by titanium dioxide deposition on mouse case sample with sol-gal process
Stearic acid and PFTDS immersion treatment are passed through to the titanium dioxide nano coating of mouse case, coating surface energy is reduced, makes it have
Ultra-hydrophobicity.Just because of the presence of this super-hydrophobic coat, the anti-pollution for greatly improving mouse case can and have
There is certain self-cleaning ability.In the long-time use process of mouse, the dirts such as the sweat stain of watch face can be effectively prevent viscous
It is attached on mouse case.And titanium dioxide is mutually adsorbed by sol-gal process by the housing base of chemical bond and mouse, is adsorbed
Power is strong, and wear-resisting property is good, improves the service life of coating.And titanium dioxide nano coating also has bactericidal property.
Preferred embodiment one: as the preferred embodiment of basic scheme, nitric acid of the mouse case of the ABS material 10%
It is impregnated 40 minutes in solution, inventor's discovery is best using the sample effect that bears dirty of the gain of parameter.
Preferred embodiment two: preferably one preferred embodiment: the butyl titanate in the A formula passes through 30 points
Clock is uniformly added into dehydrated alcohol, and continues to stir, and inventor's discovery was uniformly added into butyl titanate by 30 minutes can be more
Add sufficient mixed solution, the uniformity of solution is good.
Preferred embodiment three: preferably two preferred embodiment: described A formula was uniformly added into B in 1 hour to match
Fang Zhong, and continue to stir, inventor's discovery uses which, and the uniformity of obtained faint yellow colloidal sol is best.
Preferred embodiment four: preferably three preferred embodiment: the faint yellow colloidal sol must not exceed using the time
24 hours, and continue to stir, inventor's effect that finds to bear dirty using the product that the parameter obtains through a large number of experiments was good.
Preferred embodiment five: preferably four preferred embodiment: the sample by spraying is under the conditions of 60 DEG C
Dry 40 minutes, inventor find that the product for using the parameter the to obtain effect that bears dirty is good through a large number of experiments.
Preferred embodiment six: preferably five preferred embodiment: described is coated with outside the mouse of coating of titanium dioxide
Shell impregnates 45 minutes in the stearic ethanol solution of 0.7wt%, and inventor has found to obtain using the parameter through a large number of experiments
To the product effect that bears dirty it is good.
Preferred embodiment seven: preferably six preferred embodiment: described to have passed through stearic acid treated outside mouse
Shell impregnates 70 minutes in the toluene solution of 1% PFTDS, and inventor through a large number of experiments has found to obtain using the parameter
The product effect that bears dirty is good.
Detailed description of the invention
Fig. 1 is the water drop contact surface chart of the embodiment of the present invention 3；
Fig. 2 is the water drop contact surface chart of the embodiment of the present invention 4.
Specific embodiment
Below by specific embodiment, the present invention is described in further detail:
Term used in this specification " PFTDS " refers to: " 1H, 1H, 2H, 2H- perfluoro decyl trichlorosilane ".
" number " used in this book specification refers to " mass fraction ".
Embodiment 1:
Step 1, the mouse case of ABS material is impregnated 30 minutes in 10% nitric acid solution, is taken out in deionized water
In clean up after, drying for standby.
A formula: 8.5 parts of butyl titanates were uniformly added into 20 parts of dehydrated alcohols by 30 minutes, and continued to stir；
B formula: 1.5 parts of deionized waters, 5 parts of acetic acid, 20 parts of absolute ethyl alcohol and stirrings are uniformly mixed.
A is formulated with the ratio of volume ratio 1:1 and is uniformly added into 1 hour in B formula, and is stirred 1 day, final
To the faint yellow colloidal sol of transparent light.
Step 2, by the faint yellow colloidal sol by after the shell dries, then spraying on spray gun even application to mouse case
Once.Obtained sample is 30 minutes dry under the conditions of 60 DEG C, then rinses mouse case surface using ethyl alcohol.
Step 3, then mouse case is immersed in the stearic ethanol solution of 0.5wt% 30 minutes.Later at 60 DEG C
Under the conditions of dry 3 hours.
Step 4, the mouse case after drying impregnates 60 minutes in the toluene solution of 0.5%PFTDS again, later in room temperature
Lower drying.
Step 5, after dry mouse case is dried at room temperature for after dehydrated alcohol rinses, and be can be obtained and is born dirty
Mouse case.
The same day, still not used TiO 2 sol poured into waste liquid pool, and second day not reusable.
Embodiment 2:
Step 1, the mouse case of ABS material is impregnated 60 minutes in 10% nitric acid solution, is taken out in deionized water
In clean up after, drying for standby.
A formula: 8.5 parts of butyl titanates were uniformly added into 20 parts of dehydrated alcohols by 30 minutes, and continued to stir；
B formula: 1.5 parts of deionized waters, 5 parts of acetic acid, 20 parts of absolute ethyl alcohol and stirrings are uniformly mixed.
A is formulated by being uniformly added within 1 hour in B formula with the ratio of volume ratio 1:1, and is stirred 1 day, finally
Obtain the faint yellow colloidal sol of transparent light.
Step 2, by the faint yellow colloidal sol by after the shell dries, then spraying on spray gun even application to mouse case
Once.Obtained sample is 60 minutes dry under the conditions of 60 DEG C, then rinses mouse case surface using ethyl alcohol.
Step 3, mouse case is immersed in the stearic ethanol solution of 1wt% 60 minutes.Later under the conditions of 60 DEG C
It is 6 hours dry.
Step 4, the mouse case after drying impregnates 90 minutes in the toluene solution of 2%PFTDS again, later in room temperature
Lower drying.
Step 5, mouse case finally is rinsed using dehydrated alcohol, is dried at room temperature for, can be obtained outside the mouse to bear dirty
Shell.
The same day, still not used TiO 2 sol poured into waste liquid pool, and second day not reusable.
Embodiment 3:
Step 1, the mouse case of ABS material is impregnated 40 minutes in 10% nitric acid solution, is taken out in deionized water
In clean up after, drying for standby.
A formula: 8.5 parts of butyl titanates were uniformly added into 20 parts of dehydrated alcohols by 30 minutes, and continued to stir；
B formula: 1.5 parts of deionized waters, 5 parts of acetic acid, 20 parts of absolute ethyl alcohol and stirrings are uniformly mixed.
A formula is uniformly added into after an hour in B formula with the ratio of volume ratio 1:1, and is stirred 1 day, finally
Obtain the faint yellow colloidal sol of transparent light.
Step 2, by the faint yellow colloidal sol by after the shell dries, then spraying on spray gun even application to mouse case
Once.Obtained sample is 40 minutes dry under the conditions of 60 DEG C, then rinses mouse case surface using ethyl alcohol.
Step 3, then mouse case is immersed in the stearic ethanol solution of 0.7wt% 45 minutes.Later at 60 DEG C
Under the conditions of dry 5 hours.
Step 4, the mouse case after dry impregnates 70 minutes in the toluene solution of 1%PFTDS again, later at room temperature
It is dry.
Step 5, the mouse case after drying is dried at room temperature for after dehydrated alcohol rinses, can be obtained and bear dirty
Mouse case.
The same day, still not used TiO 2 sol poured into waste liquid pool, and second day not reusable.
Embodiment 4:
By the mouse case of ABS material without any processing, directly progress water droplet contact angle experiment.
From Fig. 1 and Fig. 2 can obviously from treated that mouse water droplet wellability is obviously deteriorated by super-hydrophobic, bear dirty
Property significantly improves.
What has been described above is only an embodiment of the present invention, and the common sense such as well known specific structure and characteristic are not made herein in scheme
Excessive description.It, without departing from the structure of the invention, can be with it should be pointed out that for those skilled in the art
Several modifications and improvements are made, these also should be considered as protection scope of the present invention, these all will not influence what the present invention was implemented
Effect and patent practicability.The scope of protection required by this application should be based on the content of the claims, in specification
The records such as specific embodiment can be used for explaining the content of claim.
Claims (8)
1. a kind of manufacture craft for the mouse that bears dirty, which is characterized in that
Step 1, the mouse case of ABS material is impregnated 30~60 minutes in 10% nitric acid solution, is taken out in deionized water
In clean up after, drying for standby；
A formula: 8.5 parts of butyl titanates are added in 20 parts of dehydrated alcohols, and continue to stir；
B formula: 1.5 parts of deionized waters, 5 parts of acetic acid, 20 parts of absolute ethyl alcohol and stirrings are uniformly mixed；
A is formulated with the ratio of volume ratio 1:1 and is added in B formula, and is stirred 1 day, the yellowish of transparent light is finally obtained
Color colloidal sol, number described above are mass fraction；
Step 2, by the faint yellow colloidal sol by after the shell dries, then spraying primary on spray gun even application to mouse case；
Then 30~60 minutes dry under the conditions of 60 DEG C, then mouse case surface is rinsed using ethyl alcohol；
Step 3, mouse case is immersed in the stearic ethanol solution of 0.5~1wt% 30~60 minutes；Later in 60 DEG C of items
It is 3~6 hours dry under part；
Step 4, the mouse case after drying impregnates 60~90 minutes in the toluene solution of 0.5~2%PFTDS again, Zhi Hou
It dries at room temperature；
Step 5, mouse case finally is rinsed using dehydrated alcohol, is dried at room temperature for, the mouse case to bear dirty can be obtained.
2. a kind of manufacture craft of mouse that bears dirty according to claim 1, which is characterized in that the mouse of the ABS material
Mark shell impregnates 40 minutes in 10% nitric acid solution.
3. a kind of manufacture craft of mouse that bears dirty according to claim 2, which is characterized in that the titanium in the A formula
Sour four butyl esters were uniformly added into dehydrated alcohol by 30 minutes, and continued to stir.
4. a kind of manufacture craft of mouse that bears dirty according to claim 3, which is characterized in that described that A formula is small 1
When in be uniformly added into B formula, and continue to stir.
5. a kind of manufacture craft of mouse that bears dirty according to claim 4, which is characterized in that the faint yellow colloidal sol makes
It must not exceed 24 hours with the time, and continue to stir.
6. a kind of manufacture craft of mouse that bears dirty according to claim 5, which is characterized in that the sample by spraying
Product are 40 minutes dry under the conditions of 60 DEG C.
7. a kind of manufacture craft of mouse that bears dirty according to claim 6, which is characterized in that described is coated with titanium dioxide
The mouse case of titanium coating impregnates 45 minutes in the stearic ethanol solution of 0.7wt%.
8. a kind of manufacture craft of mouse that bears dirty according to claim 7, which is characterized in that described have passed through stearic acid
Treated, and mouse case impregnates 70 minutes in the toluene solution of 1% PFTDS.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610766931.1A CN106397808B (en) | 2016-08-31 | 2016-08-31 | A kind of manufacture craft for the mouse that bears dirty |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610766931.1A CN106397808B (en) | 2016-08-31 | 2016-08-31 | A kind of manufacture craft for the mouse that bears dirty |
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| CN106397808A CN106397808A (en) | 2017-02-15 |
| CN106397808B true CN106397808B (en) | 2019-01-22 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109487317A (en) * | 2018-11-08 | 2019-03-19 | 石狮市青灿兴五金工艺品有限公司 | A kind of antibacterial belt fastener and its manufacturing method |
| CN109666960A (en) * | 2018-11-08 | 2019-04-23 | 石狮市青灿兴五金工艺品有限公司 | A kind of anti-pattern exuviae buckle and its manufacturing method |
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|---|---|---|---|---|
| DE19938551A1 (en) * | 1999-08-18 | 2001-02-22 | Penth Bernd | Production of waterproof coatings, e.g. on metals, glass, ceramics or wood, involves coating with thin, nanoscale metal oxide layer from sol and then applying alkyl-trialkoxy-silane by condensation reaction |
| CN102937841A (en) * | 2012-11-20 | 2013-02-20 | 福建农林大学 | Sweat-absorbent antifouling film-sprayed mouse and preparation method thereof |
| CN103436138A (en) * | 2013-08-08 | 2013-12-11 | 中科院广州化学有限公司 | Stable and transparent super-hydrophobic or super-amphiphobic coating as well as preparation method and application thereof |
| CN104710684A (en) * | 2013-12-13 | 2015-06-17 | 黑龙江鑫达企业集团有限公司 | Modified antibiotic sweat-resistant plastic for keyboards and mice, and preparation method thereof |
| CN104927638A (en) * | 2015-06-10 | 2015-09-23 | 上海大学 | Antifouling coating material based on amphiphilic sol and preparation method for antifouling coating material |
-
2016
- 2016-08-31 CN CN201610766931.1A patent/CN106397808B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19938551A1 (en) * | 1999-08-18 | 2001-02-22 | Penth Bernd | Production of waterproof coatings, e.g. on metals, glass, ceramics or wood, involves coating with thin, nanoscale metal oxide layer from sol and then applying alkyl-trialkoxy-silane by condensation reaction |
| CN102937841A (en) * | 2012-11-20 | 2013-02-20 | 福建农林大学 | Sweat-absorbent antifouling film-sprayed mouse and preparation method thereof |
| CN103436138A (en) * | 2013-08-08 | 2013-12-11 | 中科院广州化学有限公司 | Stable and transparent super-hydrophobic or super-amphiphobic coating as well as preparation method and application thereof |
| CN104710684A (en) * | 2013-12-13 | 2015-06-17 | 黑龙江鑫达企业集团有限公司 | Modified antibiotic sweat-resistant plastic for keyboards and mice, and preparation method thereof |
| CN104927638A (en) * | 2015-06-10 | 2015-09-23 | 上海大学 | Antifouling coating material based on amphiphilic sol and preparation method for antifouling coating material |
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