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CN106367127B - Alcohol-based fuel and preparation method thereof - Google Patents

Alcohol-based fuel and preparation method thereof Download PDF

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Publication number
CN106367127B
CN106367127B CN201610779376.6A CN201610779376A CN106367127B CN 106367127 B CN106367127 B CN 106367127B CN 201610779376 A CN201610779376 A CN 201610779376A CN 106367127 B CN106367127 B CN 106367127B
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CN
China
Prior art keywords
alcohol
based fuel
emulsifying agent
coal tar
methanol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201610779376.6A
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Chinese (zh)
Other versions
CN106367127A (en
Inventor
匡利刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan Jiuxin Yesheng Energy Technology Co Ltd
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Wuhan Jiuxin Yesheng Energy Technology Co Ltd
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Priority to CN201610779376.6A priority Critical patent/CN106367127B/en
Publication of CN106367127A publication Critical patent/CN106367127A/en
Application granted granted Critical
Publication of CN106367127B publication Critical patent/CN106367127B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/26—Organic compounds containing phosphorus
    • C10L1/2666—Organic compounds containing phosphorus macromolecular compounds
    • C10L1/2683—Organic compounds containing phosphorus macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon to carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2250/00—Structural features of fuel components or fuel compositions, either in solid, liquid or gaseous state
    • C10L2250/08—Emulsion details

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The present invention provides alcohol-based fuel and preparation method thereof.By mass percentage, alcohol-based fuel includes 65%~80% methanol, 10%~25% coal tar, 0.5%~1.5% ferrocene, 3%~6% emulsifying agent and 3%~5% smoke elimination stabilizer.Emulsifying agent preferably uses compound emulsifying agent.The alcohol-based fuel of the present invention is homogeneous liquid, and good fluidity, proportion is between 0.9 1.03, and calorific value is high, more than 7000 kilocalories/Kg；Efficiency of combustion greatly improves, and improves more than 40%.In the present invention, the coal tar after emulsification and methanol are added to the water, compatibility is good, obtains the alcohol-based fuel of homogeneous liquid, and the addition of coal tar and ferrocene can greatly improve the calorific value and efficiency of combustion of alcohol-based fuel.It is cost-effective in diesel oil, liquefied gas, natural gas.

Description

Alcohol-based fuel and preparation method thereof
Technical field
The present invention relates to fuel technology field, more particularly to alcohol-based fuel and preparation method thereof.
Background technology
Alcohol-based fuel is exactly the fuel configured using alcohols (such as methanol, ethanol, butanol) material as main body.It is with liquid Or existing for solid form.It is also a kind of biomass energy, is various countries as nuclear energy, solar energy, wind power energy, hydraulic energy The environment protection clean energy that government widelys popularize at present；In face of the exhaustion of fossil energy, alcohol-based fuel is most potential new replaces For the energy.But in existing alcohol-based fuel, in order to keep the stability of alcohol-based fuel and high calorific value, addition is many auxiliary mostly Additive is helped, causes the complicated component of existing alcohol-based fuel, production cost height.Although existing alcohol-based fuel is sacrificing life On the premise of producing cost, high calorific value is obtained, but because its efficiency of combustion is limited, cause Actual combustion calorific value also not high.
The content of the invention
For the drawbacks described above and problem of prior art, the purpose of the embodiment of the present invention is to provide a kind of alcohol-based fuel, solution Certainly existing alcohol-based fuel complicated component, and actual calorific value improves limited technical problem.
In order to achieve the above object, the present invention provides following technical scheme：
Alcohol-based fuel, by mass percentage, including 65%~80% methanol, 10%~25% coal tar, 0.5%~ 1.5% ferrocene, 3%~6% emulsifying agent and 3%~5% smoke elimination stabilizer.
Further, by mass percentage, the alcohol-based fuel includes 70% methanol, 20% coal tar, the two of 1% Luxuriant iron, 5% emulsifying agent and 4% smoke elimination stabilizer.
Further, by mass percentage, the alcohol-based fuel include 75% methanol, 15% coal tar, 1.5% Ferrocene, 4.5% emulsifying agent and 4% smoke elimination stabilizer.
Further, the emulsifying agent uses AEO, polyethenoxy ether and octylphenolpolyoxyethylene A kind of in ether or wherein at least two kinds of composition.When using composition, with any than mixing.
Preferably, the AEO, polyethenoxy ether and Octylphenol polyoxyethylene ether are according to mass ratio The composition mixed for 3-5 ﹕ 1-3 ﹕ 1.
Preferably, the AEO, polyethenoxy ether and Octylphenol polyoxyethylene ether are according to mass ratio For the composition of the ﹕ 1 of 4 ﹕ 2 mixing.
Further, the smoke elimination stabilizer uses potassium citrate.
The preparation method of the alcohol-based fuel of the present invention, through the following steps that complete：
Step 1: according to the component and dosage of above-mentioned alcohol-based fuel, prepare each raw material；
Step 2: coal tar and ferrocene are well mixed, obtain mixing oil phase；Then emulsifying agent is added into mixing oil phase In, stirring and emulsifying, obtain coal tar emulsifying liquid；
Step 3: then mixing methanol, coal tar emulsifying liquid and smoke elimination stabilizer, alcohol-based fuel is produced.
The alcohol-based fuel of the present invention is homogeneous liquid, and in brown, good fluidity, proportion is between 0.9-1.03, and calorific value Height, more than 5000 kilocalories/Kg；Efficiency of combustion greatly improves, and reaches more than 95%.In the present invention, by the coal tar after emulsification and Methanol is added to the water, and compatibility is good, obtains the alcohol-based fuel of homogeneous liquid.Meanwhile coal tar is cheap as fuel price, calorific value Height, containing abundant carbon atom, but combustion efficiency is bad, it is difficult to burn fully.And methanol includes abundant oxygen atom, the two combination The combustion efficiency of coal tar can significantly be improved, improve mobility, reduce exhaust emission, improve the calorific value of alcoholized oil.Therefore, coal The addition of tar and ferrocene, also methanol Synergistic, the calorific value and efficiency of combustion of alcohol-based fuel can be greatly improved.It is cost-effective In diesel oil, liquefied gas, natural gas.
Embodiment
Below in conjunction with embodiments of the invention, technical scheme is clearly and completely described, it is clear that Described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based on the implementation in the present invention Example, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, is belonged to The scope of protection of the invention.
Embodiment 1
The alcohol-based fuel of embodiment 1, by mass percentage, including 65% methanol, 25% coal tar, the two of 1% cyclopentadienyls Iron, 5% emulsifying agent and 4% smoke elimination stabilizer.
Wherein, the emulsifying agent uses AEO.
The smoke elimination stabilizer uses potassium citrate.
The preparation method of the alcohol-based fuel of embodiment 1, through the following steps that complete：
Step 1: according to the component and dosage of above-mentioned alcohol-based fuel, prepare each raw material；
Step 2: coal tar and ferrocene are well mixed, obtain mixing oil phase；Then emulsifying agent is added into mixing oil phase In, stirring and emulsifying, obtain coal tar emulsifying liquid；
Step 3: then mixing methanol, coal tar emulsifying liquid and smoke elimination stabilizer, alcohol-based fuel is produced.
Embodiment 2
The alcohol-based fuel of embodiment 2, by mass percentage, including 80% methanol, 10% coal tar, the two of 1% cyclopentadienyls Iron, 5% emulsifying agent and 4% smoke elimination stabilizer.
Wherein, the emulsifying agent is the AEO, polyethenoxy ether and Octylphenol polyoxyethylene ether According to the composition that mass ratio is the ﹕ 1 of 4 ﹕ 2 mixing.
The smoke elimination stabilizer uses potassium citrate.
The preparation method of the alcohol-based fuel of embodiment 2 is identical with embodiment 1.
Embodiment 3
The alcohol-based fuel of embodiment 3, by mass percentage, including 70% methanol, 20% coal tar, the two of 1% cyclopentadienyls Iron, 5% emulsifying agent and 4% smoke elimination stabilizer.
Wherein, the emulsifying agent is that the AEO and polyethenoxy ether according to mass ratio are that 4 ﹕ 2 are mixed Composition.
The smoke elimination stabilizer uses potassium citrate.
The preparation method of the alcohol-based fuel of embodiment 3 is identical with embodiment 1.
Embodiment 4
The alcohol-based fuel of embodiment 4, by mass percentage, including 75% methanol, 15% coal tar, the two of 1.5% Luxuriant iron, 4.5% emulsifying agent and 4% smoke elimination stabilizer.
Wherein, the emulsifying agent is the AEO, polyethenoxy ether and Octylphenol polyoxyethylene ether According to the composition that mass ratio is the ﹕ 1 of 4 ﹕ 2 mixing.
The smoke elimination stabilizer uses potassium citrate.
The preparation method of the alcohol-based fuel of embodiment 4 is identical with embodiment 1.
The present invention has carried out calorific value to the alcohol-based fuel of above-described embodiment 1 to embodiment 4 respectively and efficiency of combustion carries out Test, test result are as described in Table 1.
Table 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Calorific value (kilocalorie/Kg) 5355 5000 5300 5145
Efficiency of combustion 96% 97% 96% 97%
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any Those familiar with the art the invention discloses technical scope in, change or replacement can be readily occurred in, should all be contained Cover within protection scope of the present invention.Therefore, protection scope of the present invention described should be defined by scope of the claims.

Claims (6)

1. alcohol-based fuel, it is characterised in that by mass percentage, composed of the following components：65%~80% methanol, 10%~ 25% coal tar, 0.5%~1.5% ferrocene, 3%~6% emulsifying agent and 3%~5% smoke elimination stabilizer；
The smoke elimination stabilizer uses potassium citrate；
The emulsifying agent use AEO, polyethenoxy ether and Octylphenol polyoxyethylene ether in one kind or Wherein at least two kinds of composition.
2. alcohol-based fuel according to claim 1, it is characterised in that by mass percentage, the alcohol-based fuel includes 70% methanol, 20% coal tar, 1% ferrocene, 5% emulsifying agent and 4% smoke elimination stabilizer.
3. alcohol-based fuel according to claim 1, it is characterised in that by mass percentage, the alcohol-based fuel includes 75% methanol, 15% coal tar, 1% ferrocene, 5% emulsifying agent and 4% smoke elimination stabilizer.
4. alcohol-based fuel according to claim 1, it is characterised in that the emulsifying agent is the aliphatic alcohol polyethenoxy Ether, polyethenoxy ether and Octylphenol polyoxyethylene ether are according to the composition that mass ratio is that 3-5 ﹕ 1-3 ﹕ 1 are mixed.
5. alcohol-based fuel according to claim 4, it is characterised in that the emulsifying agent is the aliphatic alcohol polyethenoxy Ether, polyethenoxy ether and Octylphenol polyoxyethylene ether are according to the composition that mass ratio is the ﹕ 1 of 4 ﹕ 2 mixing.
6. the preparation method of alcohol-based fuel, it is characterised in that through the following steps that complete：
Step 1: the component and dosage of the alcohol-based fuel as any one of the claims 1 to 5, prepare each raw material；
Step 2: coal tar and ferrocene are well mixed, obtain mixing oil phase；Then emulsifying agent is added in mixing oil phase, Stirring and emulsifying, obtain coal tar emulsifying liquid；
Step 3: then mixing methanol, coal tar emulsifying liquid and smoke elimination stabilizer, alcohol-based fuel is produced.
CN201610779376.6A 2016-08-30 2016-08-30 Alcohol-based fuel and preparation method thereof Expired - Fee Related CN106367127B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610779376.6A CN106367127B (en) 2016-08-30 2016-08-30 Alcohol-based fuel and preparation method thereof

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Application Number Priority Date Filing Date Title
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CN106367127A CN106367127A (en) 2017-02-01
CN106367127B true CN106367127B (en) 2018-01-09

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115011383A (en) * 2021-03-04 2022-09-06 吴勇 Emulsified methanol fuel and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1105382A (en) * 1993-11-19 1995-07-19 钟凯 Synthesized liquid fuel
CN101270306A (en) * 2008-05-14 2008-09-24 上海安投新能源科技有限公司 General fuel for vehicle
US20160083665A1 (en) * 2014-09-23 2016-03-24 Attostat, Inc. Fuel additive composition and related methods
CN105647596A (en) * 2015-12-31 2016-06-08 山西华顿实业有限公司 Mixed fuel based on methanol and coal for increasing calorific value of methanol fuel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1105382A (en) * 1993-11-19 1995-07-19 钟凯 Synthesized liquid fuel
CN101270306A (en) * 2008-05-14 2008-09-24 上海安投新能源科技有限公司 General fuel for vehicle
US20160083665A1 (en) * 2014-09-23 2016-03-24 Attostat, Inc. Fuel additive composition and related methods
CN105647596A (en) * 2015-12-31 2016-06-08 山西华顿实业有限公司 Mixed fuel based on methanol and coal for increasing calorific value of methanol fuel

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Granted publication date: 20180109

Termination date: 20190830