CN106283865B - A kind of surface sizing agent for paper making and preparation method thereof - Google Patents
A kind of surface sizing agent for paper making and preparation method thereof Download PDFInfo
- Publication number
- CN106283865B CN106283865B CN201510235148.8A CN201510235148A CN106283865B CN 106283865 B CN106283865 B CN 106283865B CN 201510235148 A CN201510235148 A CN 201510235148A CN 106283865 B CN106283865 B CN 106283865B
- Authority
- CN
- China
- Prior art keywords
- parts
- high speed
- water
- speed shearing
- sizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paper (AREA)
Abstract
The invention discloses a kind of surface sizing agent for paper making and preparation method thereof, surface sizing agent for paper making includes according to the raw material of parts by weight：Deionized water, AKD originals powder, styrene maleic anhydride copolymer, iso-octyl APEO, epoxysilicone, non-iron aluminium sulfate, maltodextrin, water-soluble cationic resins, chitin, stabilizer, hardening agent, the stabilizer is zirconium oxychloride or methenamine, and the hardening agent is polymer alumina.Preparation method of the present invention is simple, cost is low, sizing efficiency is good, there are preferable affinity and retention with fiber, improve the surface strength and water-resistance of page, paper is avoided to occur getting damp and move back the phenomenon of glue after applying glue, with excellent mechanical stability, iso-octyl APEO has good defoaming effect simultaneously, it is not necessary to it is possible to additionally incorporate defoamer, improves the surface smoothness of paper.
Description
Technical field
The present invention relates to papermaking chemical product technical field, specifically a kind of surface sizing agent for paper making and preparation method thereof.
Background technology
Top sizing can make up China's paper-making industry and largely be asked using the series caused by non-wood-fiber and secondary stock
Topic, assign paper excellent performance, adapt to the current papermaking in China and printing industry growth requirement, while also comply with Overseas Development
Main trend, it is reasonably combined excellent using cheap natural polymer product and performance in order to preferably play the effect of top sizing
Different synthetic polymer auxiliary agent, it is very necessary to accelerate existing product performance improvement and develop the inexpensive product of novel high-quality.
The deep and thorough time detected from the COBB values and PDC of body paper can see, the applying glue of body paper and moving for water-soluble component
It is closely related to move speed, with the raising of body paper degree of sizing, PDA transit times extend, and the migration rate of moisture is drastically accelerated.When
The water suction weight of body paper is 29g/m2When, water translocation is 3 percent seconds through the shortest time of pattern, when the water suction of body paper
Weight reduction is to 16g/m2When, water translocation extends to 3/10ths seconds through the shortest time of pattern, therefore, although COBB is surveyed
The only poor 13g/m of fixed degree of sizing2, and migration velocity reduces ten times.
The content of the invention
It is an object of the invention to provide surface sizing agent for paper making that a kind of dosage is few, cost is low and preparation method thereof,
To solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of surface sizing agent for paper making, include according to the raw material of parts by weight：Deionized water 35-45 parts, AKD original powder 10-
15 parts, styrene maleic anhydride copolymer 10-12 parts, iso-octyl APEO 8-12 parts, epoxysilicone 3-5 parts, iron-free
Aluminum sulfate 4-8 parts, maltodextrin 2-4 parts, water-soluble cationic resins 2-4 parts, chitin 2-4 parts, stabilizer 0.2-0.4 parts,
Hardening agent 0.2-0.5 parts, the stabilizer are zirconium oxychloride or methenamine, and the hardening agent is polymer alumina.
As the further scheme of the present invention：The surface sizing agent for paper making, include according to the raw material of parts by weight：Go from
Sub- 40 parts of water, 12 parts of AKD originals powder, 11 parts of styrene maleic anhydride copolymer, 10 parts of iso-octyl APEO, epoxysilicone
4 parts, 6 parts of non-iron aluminium sulfate, 3 parts of maltodextrin, 3 parts of water-soluble cationic resins, 3 parts of chitin, 0.3 part of stabilizer, strengthen
0.3 part of agent.
The preparation method of the surface sizing agent for paper making, is comprised the following steps that：
（1）Each raw material is weighed according to parts by weight；
（2）AKD original powder is put into and melts in kettle that to be heated to 70-80 DEG C of thawing standby；
（3）Styrene maleic anhydride copolymer, iso-octyl APEO, epoxysilicone and chitin are put into double oars
In Agravicmixer, stirring 2-3h obtains mixture A at 80-100 DEG C；
（4）Deionized water, starch and water-soluble cationic resins are added to the system equipped with high speed shearing emulsification dispersion machine
In standby kettle, start the high speed shearing emulsification dispersion machine and carry out the scattered 20-30min of high speed shearing emulsification；
（5）Prepare kettle and be heated to 50-60 DEG C, the AKD after the thawing is put into and prepared in kettle, carry out high speed shearing emulsification
After scattered 10-15min, add mixture A and continue high speed shearing emulsification and disperse 5-8min；
（6）Non-iron aluminium sulfate, stabilizer and hardening agent are added, after carrying out the scattered 5-8min of high speed shearing emulsification, in 60-70
1-2h is incubated at DEG C, finished product kettle is back to and is cooled to 25-35 DEG C and obtain finished product sizing agent.
Compared with prior art, the beneficial effects of the invention are as follows：
Preparation method of the present invention is simple, cost is low, sizing efficiency is good, has preferable affinity and retention with fiber, changes
The surface strength and water-resistance of kind page, paper is avoided after applying glue occur getting damp and move back the phenomenon of glue, have excellent machinery steady
It is qualitative, while iso-octyl APEO has good defoaming effect, it is not necessary to defoamer is it is possible to additionally incorporate, improves the table of paper
Face smoothness.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
In the embodiment of the present invention, a kind of surface sizing agent for paper making, include according to the raw material of parts by weight：Deionized water 35
Part, 10 parts of AKD originals powder, 10 parts of styrene maleic anhydride copolymer, 8 parts of iso-octyl APEO, 3 parts of epoxysilicone, nothing
4 parts of iron aluminum sulfate, 2 parts of maltodextrin, 2 parts of water-soluble cationic resins, 2 parts of chitin, 0.2 part of zirconium oxychloride, polymerization oxidation
0.2 part of aluminium.
The preparation method of the surface sizing agent for paper making, is comprised the following steps that：
（1）Each raw material is weighed according to parts by weight；
（2）AKD original powder is put into and melts in kettle that to be heated to 70 DEG C of thawings standby；
（3）Styrene maleic anhydride copolymer, iso-octyl APEO, epoxysilicone and chitin are put into double oars
In Agravicmixer, stirring 2h obtains mixture A at 80 DEG C；
（4）Deionized water, starch and water-soluble cationic resins are added to the system equipped with high speed shearing emulsification dispersion machine
In standby kettle, start the high speed shearing emulsification dispersion machine and carry out the scattered 20min of high speed shearing emulsification；
（5）Prepare kettle and be heated to 50 DEG C, the AKD after the thawing is put into and prepared in kettle, carry out high speed shearing emulsification point
After dissipating 10min, add mixture A and continue high speed shearing emulsification and disperse 5min；
（6）Non-iron aluminium sulfate, zirconium oxychloride and polymer alumina are added, after carrying out the scattered 5min of high speed shearing emulsification,
1h is incubated at 60 DEG C, finished product kettle is back to and is cooled to 25 DEG C and obtain finished product sizing agent.
Embodiment 2
In the embodiment of the present invention, a kind of surface sizing agent for paper making, include according to the raw material of parts by weight：Deionized water 40
Part, 12 parts of AKD originals powder, 11 parts of styrene maleic anhydride copolymer, 10 parts of iso-octyl APEO, 4 parts of epoxysilicone, nothing
6 parts of iron aluminum sulfate, 3 parts of maltodextrin, 3 parts of water-soluble cationic resins, 3 parts of chitin, 0.3 part of methenamine, polymerization oxidation
0.3 part of aluminium.
The preparation method of the surface sizing agent for paper making, is comprised the following steps that：
（1）Each raw material is weighed according to parts by weight；
（2）AKD original powder is put into and melts in kettle that to be heated to 75 DEG C of thawings standby；
（3）Styrene maleic anhydride copolymer, iso-octyl APEO, epoxysilicone and chitin are put into double oars
In Agravicmixer, stirring 2.5h obtains mixture A at 90 DEG C；
（4）Deionized water, starch and water-soluble cationic resins are added to the system equipped with high speed shearing emulsification dispersion machine
In standby kettle, start the high speed shearing emulsification dispersion machine and carry out the scattered 25min of high speed shearing emulsification；
（5）Prepare kettle and be heated to 55 DEG C, the AKD after the thawing is put into and prepared in kettle, carry out high speed shearing emulsification point
After dissipating 12min, add mixture A and continue high speed shearing emulsification and disperse 6min；
（6）Non-iron aluminium sulfate, methenamine and polymer alumina are added, after carrying out the scattered 6min of high speed shearing emulsification,
1.5h is incubated at 65 DEG C, finished product kettle is back to and is cooled to 30 DEG C and obtain finished product sizing agent.
Embodiment 3
In the embodiment of the present invention, a kind of surface sizing agent for paper making, include according to the raw material of parts by weight：Deionized water 45
Part, 15 parts of AKD originals powder, 12 parts of styrene maleic anhydride copolymer, 12 parts of iso-octyl APEO, 5 parts of epoxysilicone, nothing
8 parts of iron aluminum sulfate, 4 parts of maltodextrin, 4 parts of water-soluble cationic resins, 4 parts of chitin, 0.4 part of zirconium oxychloride, polymerization oxidation
0.5 part of aluminium.
The preparation method of the surface sizing agent for paper making, is comprised the following steps that：
（1）Each raw material is weighed according to parts by weight；
（2）AKD original powder is put into and melts in kettle that to be heated to 80 DEG C of thawings standby；
（3）Styrene maleic anhydride copolymer, iso-octyl APEO, epoxysilicone and chitin are put into double oars
In Agravicmixer, stirring 3h obtains mixture A at 100 DEG C；
（4）Deionized water, starch and water-soluble cationic resins are added to the system equipped with high speed shearing emulsification dispersion machine
In standby kettle, start the high speed shearing emulsification dispersion machine and carry out the scattered 30min of high speed shearing emulsification；
（5）Prepare kettle and be heated to 60 DEG C, the AKD after the thawing is put into and prepared in kettle, carry out high speed shearing emulsification point
After dissipating 15min, add mixture A and continue high speed shearing emulsification and disperse 8min；
（6）Non-iron aluminium sulfate, zirconium oxychloride and polymer alumina are added, after carrying out the scattered 8min of high speed shearing emulsification,
2h is incubated at 70 DEG C, finished product kettle is back to and is cooled to 35 DEG C and obtain finished product sizing agent.
Preparation method of the present invention is simple, cost is low, sizing efficiency is good, has preferable affinity and retention with fiber, changes
The surface strength and water-resistance of kind page, paper is avoided after applying glue occur getting damp and move back the phenomenon of glue, have excellent machinery steady
It is qualitative, while iso-octyl APEO has good defoaming effect, it is not necessary to defoamer is it is possible to additionally incorporate, improves the table of paper
Face smoothness.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, can also be on the premise of this patent objective not be departed from one skilled in the relevant art's possessed knowledge
Various changes can be made.
Claims (3)
1. a kind of surface sizing agent for paper making, it is characterised in that include according to the raw material of parts by weight：Deionized water 35-45 parts,
AKD original powder 10-15 parts, styrene maleic anhydride copolymer 10-12 parts, iso-octyl APEO 8-12 parts, epoxysilicone
3-5 parts, non-iron aluminium sulfate 4-8 parts, maltodextrin 2-4 parts, water-soluble cationic resins 2-4 parts, chitin 2-4 parts, stabilizer
0.2-0.4 parts, hardening agent 0.2-0.5 parts, the stabilizer are zirconium oxychloride or methenamine, and the hardening agent is polymerization oxidation
Aluminium.
2. surface sizing agent for paper making according to claim 1, it is characterised in that include according to the raw material of parts by weight：Go
40 parts of ionized water, 12 parts of AKD originals powder, 11 parts of styrene maleic anhydride copolymer, 10 parts of iso-octyl APEO, epoxy silica
It is 4 parts of alkane, 6 parts of non-iron aluminium sulfate, 3 parts of maltodextrin, 3 parts of water-soluble cationic resins, 3 parts of chitin, 0.3 part of stabilizer, strong
0.3 part of agent.
A kind of 3. preparation method of surface sizing agent for paper making as described in claim 1-2 is any, it is characterised in that specific step
It is rapid as follows：
（1）Each raw material is weighed according to parts by weight；
（2）AKD original powder is put into and melts in kettle that to be heated to 70-80 DEG C of thawing standby；
（3）Styrene maleic anhydride copolymer, iso-octyl APEO, epoxysilicone and chitin are put into double oars without weight
In power mixer, stirring 2-3h obtains mixture A at 80-100 DEG C；
（4）Deionized water, starch and water-soluble cationic resins are added to equipped with high speed shearing emulsification dispersion machine and prepare kettle
In, start the high speed shearing emulsification dispersion machine and carry out the scattered 20-30min of high speed shearing emulsification；
（5）Prepare kettle and be heated to 50-60 DEG C, the AKD after the thawing is put into and prepared in kettle, carry out high speed shearing emulsification and disperse
After 10-15min, add mixture A and continue high speed shearing emulsification and disperse 5-8min；
（6）Non-iron aluminium sulfate, stabilizer and hardening agent are added, after carrying out the scattered 5-8min of high speed shearing emulsification, at 60-70 DEG C
1-2h is incubated, finished product kettle is back to and is cooled to 25-35 DEG C and obtain finished product sizing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510235148.8A CN106283865B (en) | 2015-05-11 | 2015-05-11 | A kind of surface sizing agent for paper making and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510235148.8A CN106283865B (en) | 2015-05-11 | 2015-05-11 | A kind of surface sizing agent for paper making and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106283865A CN106283865A (en) | 2017-01-04 |
| CN106283865B true CN106283865B (en) | 2017-11-17 |
Family
ID=57630569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510235148.8A Expired - Fee Related CN106283865B (en) | 2015-05-11 | 2015-05-11 | A kind of surface sizing agent for paper making and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106283865B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106758517A (en) * | 2017-01-19 | 2017-05-31 | 中山联合鸿兴造纸有限公司 | A kind of page surface glue-applying technique method |
| CN108018740A (en) * | 2017-11-10 | 2018-05-11 | 苏州恒康新材料有限公司 | A kind of glue used in paper-making and preparation method thereof |
| CN111410697B (en) * | 2020-05-29 | 2021-12-17 | 上海晨光文具股份有限公司 | Oil-in-water emulsion ink and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1194018A (en) * | 1995-08-25 | 1998-09-23 | Cytec技术有限公司 | Methods and agents for improving paper printability and strength |
| CN1802469A (en) * | 2003-05-06 | 2006-07-12 | 国际纸业公司 | A process for preparing sized paper and paperboard |
| CN1977081A (en) * | 2004-06-29 | 2007-06-06 | 西巴特殊化学品控股有限公司 | Product for use in papermaking and preparation thereof |
| CN104499363A (en) * | 2015-01-09 | 2015-04-08 | 广州天赐高新材料股份有限公司 | AKD emulsion and preparation method thereof |
-
2015
- 2015-05-11 CN CN201510235148.8A patent/CN106283865B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1194018A (en) * | 1995-08-25 | 1998-09-23 | Cytec技术有限公司 | Methods and agents for improving paper printability and strength |
| CN1802469A (en) * | 2003-05-06 | 2006-07-12 | 国际纸业公司 | A process for preparing sized paper and paperboard |
| CN1977081A (en) * | 2004-06-29 | 2007-06-06 | 西巴特殊化学品控股有限公司 | Product for use in papermaking and preparation thereof |
| CN104499363A (en) * | 2015-01-09 | 2015-04-08 | 广州天赐高新材料股份有限公司 | AKD emulsion and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106283865A (en) | 2017-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106283865B (en) | A kind of surface sizing agent for paper making and preparation method thereof | |
| CN110878490B (en) | Preparation method of high-melting-point AKD type surface sizing agent | |
| CN101949108B (en) | Polyethyleneimine-modified AKD sizing agent and preparation method thereof | |
| CN101806019B (en) | Surface sizing agent for papermaking and production process thereof | |
| CN103665173B (en) | The method of preparation high-substitution-decation cation starch emulsifier | |
| CN101429742B (en) | Surface sizing additive for papermaking | |
| CN111560790B (en) | Water-resistant and moisture-proof method for corrugated base paper | |
| CN106381759B (en) | A kind of corrugated paper surface solid gluing reinforcing agent composition and its manufacturing method | |
| CN104988796A (en) | Enhanced multifunctional surface sizing assistant for papermaking and preparation method thereof | |
| CN102535249B (en) | Novel wet strengthening agent for papermaking and preparation method and application thereof | |
| CN107118709A (en) | A kind of preparation method of high-strength, quick-drying type adhesive for paper box | |
| CN111576082A (en) | Cation dispersed rosin size and preparation method thereof | |
| CN104805732A (en) | Styrene-acrylate emulsion type efficient surface sizing agent and preparing method thereof | |
| CN103388282B (en) | A kind of decorating base paper surface conditioning agent and preparation method thereof | |
| CN105648846B (en) | A kind of environment-friendly type dipping paper and preparation method thereof | |
| CN102517999A (en) | Double-sizing preparation process for liquid packaging white cardboard | |
| CN103806335A (en) | Preparation method for corrugated paper ring crush reinforcing agent | |
| CN101200864A (en) | AKD neutral glue and method for preparing same | |
| CN108867196A (en) | A kind of environment-friendly type waterproof paper and preparation method thereof | |
| CN102587202B (en) | Preparation technology for craft paper and paint for coating craft paper | |
| CN102517992A (en) | Compound surface reinforcing agent for packaging paperboard and method for preparing same | |
| CN109183505A (en) | A kind of production technology of flexible package punch coating paper | |
| CN101240517B (en) | Method for complexing composite starch sizing agent | |
| CN109629313A (en) | A kind of preparation method of fluting medium | |
| CN102852033A (en) | Surface sizing agent for paper manufacture |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171117 Termination date: 20180511 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |