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CN106256524B - Flexible plastic plastic material and its application - Google Patents

Flexible plastic plastic material and its application Download PDF

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Publication number
CN106256524B
CN106256524B CN201610637494.3A CN201610637494A CN106256524B CN 106256524 B CN106256524 B CN 106256524B CN 201610637494 A CN201610637494 A CN 201610637494A CN 106256524 B CN106256524 B CN 106256524B
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CN
China
Prior art keywords
plastic
plastic material
flexible plastic
flexible
matrix
Prior art date
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Expired - Fee Related
Application number
CN201610637494.3A
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Chinese (zh)
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CN106256524A (en
Inventor
孙倩倩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sui Meiqing
Original Assignee
Shanghai Kedou Electronic Technology Co Ltd
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Priority to CN201610637494.3A priority Critical patent/CN106256524B/en
Publication of CN106256524A publication Critical patent/CN106256524A/en
Application granted granted Critical
Publication of CN106256524B publication Critical patent/CN106256524B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00—Layered products having a non-planar shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/02—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica the layer of fibres or particles being impregnated or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B19/00—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica
    • B32B19/04—Layered products comprising a layer of natural mineral fibres or particles, e.g. asbestos, mica next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/14—Layered products comprising a layer of synthetic resin next to a particulate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0827—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using UV radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/025—Particulate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/02—Synthetic macromolecular particles
    • B32B2264/0214—Particles made of materials belonging to B32B27/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/101—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/41—Opaque
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/416—Reflective
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/71—Resistive to light or to UV

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Electromagnetism (AREA)
  • Toxicology (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Laminated Bodies (AREA)

Abstract

Flexible plastic plastic material and its application are related to resin base joint product.Flexible plastic plastic material, including light-cured resin based composites, including a matrix, described matrix includes two film layers, an interlayer is constituted between two film layers, and at least two particles are equipped in the interlayer, are filled with uncured light-cured resin based composites between at least two particles；At least one film layer is translucent material in two film layers.It is irradiated by light, realizes the solidification of uncured light-cured resin based composites, so that position between particle and particle be enable to fix, and then base shape is enable to fix, and then realize the solidification of flexible plastic plastic material.

Description

Flexible plastic plastic material and its application
The applying date of the original application of the divisional application are as follows: on 04 13rd, 2012, application No. is: 2012101093273, name Referred to as: particles filled formula photo-curing material and its application.
Technical field
The present invention relates to curing materials fields, and in particular to a kind of photo-curing material.
Background technique
Polymer matrix composites product is widely used in production and life.Polymer matrix composites can be used for manufacturing Various products all bring convenience to produce and living.But since these productions are complex, use Person cannot arbitrarily design the article of oneself needs according to the wish of oneself.
In addition, have many articles because of volume is larger in our lives, not readily transportable and storage.Such as table, chair, basin, The daily necessities such as bucket, for another example device housings, strip part of appliance, large-scale sheet part of appliance etc..Due to shape design Problem, although although these article weight be not it is very heavy, occupied space is big, there is a problem of that transport and storage are inconvenient.
Summary of the invention
The purpose of the present invention is to provide a kind of flexible plastic plastic materials, to solve the above technical problems.
The object of the invention is also to provide a kind of flexible plastic plastic material applications, to solve the above technical problems.
The present invention can be realized using following technical scheme:
Flexible plastic plastic material, including light-cured resin based composites, which is characterized in that described including a matrix Matrix includes two film layers, and an interlayer is constituted between two film layers, is equipped at least two particles in the interlayer, and at least two Uncured light-cured resin based composites are filled between the particle；At least one film layer is light transmission in two film layers Material.Two film layers are flexibility.It is flexible in order to which total is presented, allow for bending to store.
Light-cured resin based composites are the polymer matrix composites containing light curing agent, uncured light-cured resin Uncured in based composites is to say that the polymer matrix composites containing light curing agent yet there are no light, still in non-solid.It is logical Light irradiation is crossed, realizes the solidification of uncured light-cured resin based composites, to keep position between particle and particle solid It is fixed, and then so that base shape is fixed, and then realize the solidification of flexible plastic plastic material.Because significant portion material is Grain, rather than light-cured resin based composites, so cost is relatively low.
Particle can be foam beads, bead, glass microballoon, metallic particles, building stones particle, plastic grain etc..It is preferred that Bead and glass microballoon.
It is also provided with micro-capsule between two film layers, is filled with uncured light-cured resin base composite wood in micro-capsule Material.To improve mechanical property.
The particle is flexibility, flexible in order to which total is presented, and bending is allowed for store.Preferred foams Grain, flexiplast particle etc..
Distance between two film layers is greater than 2 times of the particle average thickness.In order to be overlapped mutually between particle, increase Strong mechanical performance.
The micro-capsule wall is flexibility.It is flexible in order to which total is presented, allow for bending to store.The micro-capsule Thickness can be set to the half of the distance between less than two film layers.In order to be overlapped mutually.
One film layer of described matrix is located below, and is fixedly arranged above one layer of auxiliary film, is fixed in the auxiliary film State particle.By being arranged particle in auxiliary film, auxiliary film is made to play certain fixed function to particle.And then arrange particle Cloth will not excessively concentrate at one or excessively dispersing.
Two layers or two layers or more additional film layer can be set between two film layers.
The interior vesica filled with gas can be set between two film layers.To reduce weight.
It can not be full of by uncured light-cured resin based composites in the micro-capsule of part, filled solid in remaining space Particle or gas, with tuning performance.The solid particle of filling can be foam, bead, metallic particles, building stones particle, modeling Expect particle etc..
The micro-capsule wall is elastic material.In order to more arbitrarily be bent, the randomness for enhancing storage and using.
Two film layers of described matrix are respectively elastic material, recessed in order to more arbitrarily be bent, stretched, manufactured It falls into or raised, the randomness that enhancing is stored and used.
Have in two film layers of described matrix one to be opaque, to prevent when carrying out light irradiation light penetrate entire base Body.
An inside in two film layers of described matrix is reflective material, in order to reflect light, is promoted real as early as possible Now solidify, and saves light energy.
Flexible plastic plastic material includes two matrixes, and two matrixes are arranged in parallel, and branch is equipped between described matrix and matrix Support member, the supporting element are flexible pipe body, are filled with uncured light-cured resin based composites in flexible pipe body.Do not having Before being solidified, supporting element and two matrixes are flexibility, allow to bend, and matrix between matrix at a distance from cannot get It is fixed, so the thickness of flexible plastic plastic material before curing can be relatively thin.
Two matrix peripheral sealings of the flexible plastic plastic material, and it is equipped with an air inlet.In storage, by two Air extraction between matrix, is bent supporting element, and then close up two matrixes inwardly, thinning, convenient for storage.
Before curing, air is filled with into the space between two matrixes by air inlet, and then makes two matrix separation simultaneously Spreading opens supporting element stretching, then carries out photocuring.To make two matrixes and supporting element solidify respectively, to make institute Certain thickness can be had after hardening by stating flexible plastic plastic material, and because be hollow structure, lighter in weight.
Described supporting element one end is fixed on the matrix of side, is formed a vertex, is at least further fixed on separately in the apex One end of one supporting element, i.e. an apex are fixed at least two supporting elements；The supporting element on total vertex on the matrix of side, Vertex is no longer total on the matrix of the other side.Therefore two can constitute a triangular shape structure between supporting element and matrix, because of triangular shape knot Structure has the characteristics that stablize, and the stability of material can be enhanced.
One apex can draw two, three or four supporting elements, can also draw more roots.It is preferred that drawing three The structure of root, four supporting elements.
Each apex draws two, three or four supporting elements, so that stabilized structure.
At least one layer is rupture pressure disc in two film layers, enhances fastness.It may be set to be shellproof film.
In two film layers wherein one layer be antiultraviolet film.The leakage of photocuring middle-ultraviolet lamp is placed, and after hardening Also function to the effect of isolation ultraviolet light.
The flexible plastic plastic material is sheet.It may be implemented to be cut, fold, beat money etc. in operation when use The combination of one or more operation, so that the contoured article needed, is then solidified.For complicated structure, Each simple component can be solidified respectively, be assembled after solidification.It can also be combined, combine before curing After solidified, in order to be firmly combined.
The flexible plastic plastic material prop up after for component shape to be formed, or the combination for multiple components. In use, carrying out solidifying the component that needs can be obtained after taking-up material is propped up.Described props up operation, can be one Component is individually propped up, or props up operation for realizing after several component combinations, constitutes the article of needs.
The flexible plastic plastic material is ship shape after propping up.Become ship after solidification.Can be one individually it is described soft Property moldable plastic material prop up after formed, being also possible to multiple flexible plastic plastic materials is combined, realization prop up after formed.
The flexible plastic plastic material is house shape after propping up.Become house after solidification.It can be one individually The flexible plastic plastic material is formed after propping up, and is also possible to multiple flexible plastic plastic materials and is combined, realization is propped up After formed.
The flexible plastic plastic material is device housings shape after propping up.Become device housings after solidification.It can be one A individually flexible plastic plastic material is formed after propping up, and is also possible to multiple flexible plastic plastic materials and is combined, Realization is formed after propping up.
The flexible plastic plastic material is table shape after propping up.Become desk after solidification.It can be one individually The flexible plastic plastic material is formed after propping up, and is also possible to multiple flexible plastic plastic materials and is combined, realization is propped up After formed.
The flexible plastic plastic material is chair shape after propping up.Become chair after solidification.It can be one individually The flexible plastic plastic material is formed after propping up, and is also possible to multiple flexible plastic plastic materials and is combined, realization is propped up After formed.
The flexible plastic plastic material is bed body shape after propping up.Become bed after solidification.It can be an individual institute It states after flexible plastic plastic material is propped up and is formed, be also possible to multiple flexible plastic plastic materials and be combined, after realization is propped up It is formed.
The flexible plastic plastic material is cabinet shape after propping up.Become cabinet after solidification.It can be one individually The flexible plastic plastic material is formed after propping up, and is also possible to multiple flexible plastic plastic materials and is combined, realization is propped up After formed.
The flexible plastic plastic material is fish jar shape after propping up.Become fish jar after solidification.It can be one individually The flexible plastic plastic material is formed after propping up, and is also possible to multiple flexible plastic plastic materials and is combined, realization is propped up After formed.
The flexible plastic plastic material is vase shape after propping up.Become vase after solidification.It can be one individually The flexible plastic plastic material is formed after propping up, and is also possible to multiple flexible plastic plastic materials and is combined, realization is propped up After formed.
The flexible plastic plastic material is tea table shape after propping up.Become tea table after solidification.It can be one individually The flexible plastic plastic material is formed after propping up, and is also possible to multiple flexible plastic plastic materials and is combined, realization is propped up After formed.
The flexible plastic plastic material is gear shape after propping up.Become gear after solidification.
For including two bases with large components, required flexible plastic plastic materials such as ship, house, device housings Body, two matrixes are arranged in parallel, and supporting element is equipped between described matrix and matrix, and the supporting element is flexible pipe body, flexible pipe body It is interior to be filled with uncured light-cured resin based composites.In order to shrink storage and enhance the mechanical strength after solidifying.
The shape of component required for the flexible plastic plastic material after inflation is shaped in advance is needing to make Gas is filled with the shape that component can be presented by the used time, solidifies the component that needs can be obtained by light.
Fibre reinforced materials is embedded in resin-based materials in uncured light-cured resin based composites, fiber increases Strong material can use one of reinforcing fibers such as glass fibre, plant fiber, carbon fiber or several.
It is mixed with pigment in uncured light-cured resin based composites in the micro-capsule, is coloured.To adapt to face Color or patterning requirement.
It is mixed with pigment in the uncured light-cured resin based composites filled between two film layers of described matrix, is carried out Coloring, to adapt to color or patterning requirement.
Pigment is mixed in uncured light-cured resin based composites and is mixed with electroluminescent powder, and is embedded with conducting wire.With It is easy to implement electroluminescent, to realize illumination or beautification.
It further include a light-shielding container, the flexible plastic plastic material is stored in the light-shielding container after folding, so as to In long-term storage.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of the invention；
Fig. 2 is another structural schematic diagram of the invention；
Fig. 3 is another structural schematic diagram of the invention；
Fig. 4 is another structural schematic diagram of the invention.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below Conjunction is specifically illustrating, and the present invention is further explained.
Referring to Fig.1, Fig. 2, Fig. 3 and Fig. 4, flexible plastic plastic material, including a matrix, matrix include two, two films An interlayer is constituted between layer 11, and at least two particles 12 are equipped in interlayer, are consolidated between at least two particles 12 filled with uncured light Change polymer matrix composites；At least one film layer is translucent material in two film layers 11.It is irradiated by light, realizes uncured light The solidification of solidified resin based composites so that position between particle 12 and particle 12 be enable to fix, and then obtains base shape With fixation, and then realize the solidification of flexible plastic plastic material.Because significant portion material is particle 12, rather than light-cured resin Based composites, so cost is relatively low.
One light shield layer can be equipped with using film layer made of translucent material outside, it is slowly solid during storage to avoid it Change, influences performance.Light shield layer is equipped with the unlatching line 3 that at least one bonding strength is easy to other positions, as bonding strength is opposite The weaker unlatching line in other positions or bonding strength are relative to the stronger unlatching line in other positions.Due to opening line 3 and other portions The bonding strength divided is inconsistent, and light shield layer is torn to come readily along the place that bonding strength changes, thus by opening 3 side of line Just remove light shield layer.
Particle 12 can be foam beads, bead, glass microballoon, metallic particles, building stones particle, plastic grain etc..It is excellent Select bead and glass microballoon.Plastic grain can also be recycled plastic granules, and the raw material of recycled plastic granules, which can be, to be added Among the process of work virgin material, remaining small corner or the unqualified raw material of quality.Such as: the leftover pieces that do not land, under Corner material, regrinding-material, rubber head material etc..The raw material of recycled plastic granules can also be used virgin material or use multiple Discarded plastics.Be conducive to save the cost using recycled plastic granules.
Two film layers 11 are made of flexible or elastic material.It is soft convenient for total is presented using flexible material Property, it can be bent, be stretched, manufacturing recess or protrusion, allowed to bend and store.Flexible plastic plastic material can be prefabricated into Certain form, using elastic material allow to store and transportational process in carry out part deformation, to facilitate storage, convenient for multiple when use It originally was the form being prefabricated into.
The particle 12 is flexibility, flexible in order to which total is presented, and bending is allowed for store.Preferred foams Grain, flexiplast particle etc..
As a preferred embodiment, the distance between two film layers 11 is greater than 2 times of 12 average thickness of particle.With Convenient for being overlapped mutually between particle 12, enhance mechanical performance.
Have in two film layers 11 of described matrix one to be opaque, to prevent when carrying out light irradiation light penetrate entire base Body.An inside in two film layers 11 of described matrix can be reflective material, in order to reflect light, promote real as early as possible Now solidify, and saves light energy.
The structure of flexible plastic plastic material equipped with micro-capsule 13: micro-capsule 13, micro-capsule are also provided between two film layers 11 Uncured light-cured resin based composites are filled in 13.To improve mechanical property.Micro-capsule wall can use flexible material It is made.It is flexible in order to which total is presented, allow for bending to store.The thickness of micro-capsule 13 can be set to less than two The half of distance between film layer 11.In order to be overlapped mutually.It can not be by uncured light-cured resin base in part micro-capsule 13 Composite material is full of, filled solid particle or gas in remaining space, with tuning performance.The solid particle of filling can be bubble Foam, bead, metallic particles, building stones particle, plastic grain etc..
It can be mixed into pigment in uncured light-cured resin based composites in micro-capsule 13, coloured.To adapt to Color or patterning requirement.Micro-capsule wall preferred elastomeric material.In order to more arbitrarily be bent, what enhancing was stored and used It is random.
Referring to fig. 2, the structure of the filled type photo-curing material equipped with auxiliary film: a film layer of matrix is located below, on Side is fixed with one layer of auxiliary, and 14, particle 12 is fixed in auxiliary film 14.By being arranged particle 12 in auxiliary film 14, make auxiliary Film 14 is helped to play certain fixed function to particle 12.And then the arrangement of particle 12 is made excessively not concentrate at one or excessively dividing It dissipates.In the case where being equipped with auxiliary film 14, the thickness of particle 12 can be equal to or slightly less than the distance between two film layers 11, i.e., The single layer in auxiliary film of grain 12 is arranged.Two layers or two layers or more additional film layer can be set between two film layers 11.Film layer in Fig. 2 Two layers of auxiliary film is equipped between 11.
The structure of filled type photo-curing material equipped with vesica 15: the interior capsule filled with gas can be set between two film layers 11 Bubble 15.To reduce weight.
Referring to Fig. 3, the structure of the filled type photo-curing material equipped with supporting element 16: flexible plastic plastic material includes two Matrix, two matrixes are arranged in parallel, and supporting element 16 is equipped between matrix and matrix, and supporting element 16 is interior solid filled with uncured light Change the flexible pipe body of polymer matrix composites.Before not solidified, supporting element 16 and two matrixes are flexibility, are permitted Perhaps bend, and matrix between matrix at a distance from cannot fix, so the thickness of flexible plastic plastic material is before curing It can be relatively thin.
As a preferred embodiment, two matrix peripheral sealings, and it is equipped with an air inlet 2.Two matrixes of air inlet connection Between space.In storage, the air between two matrixes is extracted out, is bent supporting element, and then close up two matrixes inwardly, It is thinning, convenient for storage.
Before curing, air is filled with into the space between two matrixes by air inlet 2, and then makes two matrix separation simultaneously Spreading opens the stretching of supporting element 16, then carries out photocuring.To make two matrixes and supporting element 16 solidify respectively, thus Make flexible plastic plastic material that can have certain thickness after hardening, and because is hollow structure, lighter in weight.
Matrix number as needed can increase, and each matrix is arranged in parallel, and supporting element, each matrix week are equipped between matrix and matrix Side sealing, and by internal venthole connection, it is equipped with an air inlet, the space between air inlet connection matrix.It, will in storage Air extraction between matrix, is bent supporting element, and then close up matrix inwardly, thinning, convenient for storage.Before curing, pass through Air inlet is filled with air into the space between two matrixes, and then makes two matrix separation and spreading, opens supporting element stretching, so After carry out photocuring.To make two matrixes and supporting element solidify respectively, to make the 12 filled type photocuring material of particle Material can have certain thickness after hardening, and because be hollow structure, lighter in weight.This structure is especially suitable for soft Property moldable plastic material production brick the case where, and do in the 12 filled type photo-curing material of particle of brick can be set it is more The interior vesica filled with gas, to mitigate brick body quality.
Supporting element one end is fixed on the matrix of side, is formed a vertex, is at least further fixed on another supporting element in apex One end, i.e. an apex is fixed at least two supporting elements；The supporting element on total vertex on the matrix of side, in another side group Vertex is no longer total on body.Therefore two can constitute a triangular shape structure between supporting element and matrix, because triangular shape structure has surely Determine feature, the stability of material can be enhanced.Supporting element can also be made into using elastic material, such filled type photo-curing material The setting shape of filled type photo-curing material can be restored to automatically by the elasticity of supporting element after external pressure removes.
One apex can draw two, three or four supporting elements, can also draw more roots.It is preferred that drawing three The structure of root, four supporting elements.The structure of two, three or four supporting elements can be drawn using each apex, so that knot Structure is firm.
User can according to need and micro-capsule, auxiliary film, vesica or supporting element is separately provided, can also be by micro-capsule, auxiliary Film, vesica or supporting element are arranged after being combined, and have the characteristic of particle additionally, due to micro-capsule and vesica, therefore can regard as respectively Particle, it is different according to the filler in micro-capsule, the particle with different performance can be regarded as, what is be filled in vesica is gas, can To regard gas particles as.
In order to increase the fastness of the filled type photo-curing material after solidifying, at least one layer is explosion-proof in two film layers 11 Film or shellproof film.Photocuring middle-ultraviolet lamp leaks outside in order to prevent, and also functions to the effect of isolation ultraviolet light, two films after hardening Layer 11 in wherein one layer be antiultraviolet film.
The preferred laminated structure of flexible plastic plastic material.It may be implemented the behaviour such as to be cut, fold, bend when use The combination of one of work or more than one operations, so that the contoured article needed, is then solidified.For complexity Structure can respectively solidify each simple component, be assembled after solidification.It can also be combined before curing, Solidified after combining, in order to be firmly combined.
Referring to fig. 4, flexible plastic plastic material can also use tubular structure, i.e. matrix uses tubular structure.Positioned at pipe Film layer 11 on the outside of shape matrix is translucent material.May be implemented to be cut, bend, stretch etc. when use one of operation or The combination of more than one operations, so that the pipe shape needed, is then solidified.Such as: a straight tube is needed, can be incited somebody to action Flexible plastic plastic material cut and is directly obtained；When the caliber of needs is less than the outer diameter of matrix, matrix can be carried out It the operation such as holds, draw, flexible plastic plastic material is forced to attenuate, being then inserted into and carried out in the pipe of the caliber uniform internal diameter needed Solidifying and setting；When the caliber of needs is greater than the outer diameter of matrix, it can be inserted into an expansion object in matrix, flexible plastic is forced to be moulded Expect that material is expanding, then carries out solidifying and setting；When needing bend pipe, it can be bent, the shape needed, then again into Row solidification.When making water pipe again, the preferred aluminum particulate particle of metallic particles.Contain in uncured light-cured resin based composites The preferred polyethylene of resin-based materials, polybutene or polyacrylic resin material.
Flexible plastic plastic material can also use linear structure, and theca externa is tubular structure, and theca interna is reduced to be located at Using an enhancing muscle in the theca externa of tubular structure, theca externa is translucent material, and the theca interna can be increased using fiber Strong material is made, fibre reinforced materials can using one of reinforcing fibers such as glass fibre, plant fiber, carbon fiber or It is several.It can also be connected using another structure, two film layer avris, constitute a tubular body, two film layers are all made of light transmission material Material is made.
The flexible plastic plastic material prop up after for component shape to be formed, or the combination for multiple components. In use, carrying out solidifying the component that needs can be obtained after taking-up material is propped up.Described props up operation, can be one Component is individually propped up, or props up operation for realizing after several component combinations, constitutes the article of needs.
The flexible plastic plastic material is hollow tubular after propping up.Become pipe fitting or pipe fitting joint after solidification.It is described soft Property moldable plastic material prop up after for brick shape.Become brick after solidification.The flexible plastic plastic material is ship shape after propping up.Solidification Become ship afterwards.The flexible plastic plastic material is house shape after propping up.Become house after solidification.The flexible plastic plastics Material is device housings shape after propping up.Become device housings after solidification.The flexible plastic plastic material is desk after propping up Shape.Become desk after solidification.The flexible plastic plastic material is chair shape after propping up.Become chair after solidification.It is described Flexible plastic plastic material is bed body shape after propping up.Become bed after solidification.The flexible plastic plastic material is cabinet after propping up Sub- shape.Become cabinet after solidification.The flexible plastic plastic material is fish jar shape after propping up.Become fish jar after solidification.Institute It states after flexible plastic plastic material is propped up as vase shape.The flexible plastic plastic material is tea table shape after propping up.Solidification Become tea table afterwards.The flexible plastic plastic material is gear shape after propping up.Become gear after solidification.
For including two bases with large components, required flexible plastic plastic materials such as ship, house, device housings Body, two matrixes are arranged in parallel, and supporting element is equipped between described matrix and matrix, and the supporting element is flexible pipe body, flexible pipe body It is interior to be filled with uncured light-cured resin based composites.In order to shrink storage and enhance the mechanical strength after solidifying.
The shape of component required for the flexible plastic plastic material after inflation is shaped in advance is needing to make Gas is filled with the shape that component can be presented by the used time, solidifies the component that needs can be obtained by light.
Fibre reinforced materials is embedded in resin-based materials in uncured light-cured resin based composites, fiber increases Strong material can use one of reinforcing fibers such as glass fibre, plant fiber, carbon fiber or several.
It is mixed with pigment in the uncured light-cured resin based composites filled between two film layers 11 of described matrix, into Row coloring, to adapt to color or patterning requirement.
Pigment is mixed in uncured light-cured resin based composites and is mixed with electroluminescent powder, and is embedded with conducting wire.With It is easy to implement electroluminescent, to realize illumination or beautification.Such as with alternating electric field, electroluminescent powder energy It is enough to shine.
Optical fiber can also be filled in the flexible plastic plastic material, in the one or both ends of optical fiber, also Light source can be equipped with.If optical fiber is the luminous optical fiber of body, optical fiber can be illuminated by light source Illuminate entire flexible plastic plastic material.Light source can be LED light source.
As a preferred embodiment, flexible plastic plastic material can also use tubular structure, i.e. matrix uses tubulose knot Structure.Conducting wire or optical fiber are equipped in the film layer of inside, conducting wire or optical fiber can be inserted into tubulose by way of the insertion of outside In film layer on the inside of matrix, it can also directly be embedded in flexible plastic plastic material, it can using on the inside of tubular matrix External insulation layer of the film layer as conducting wire, can be used as using the film layer being located on the inside of tubular matrix for constraining fibre-optic bundle Position restraint layer, the optical fiber that optical fiber selects body luminous.In the structure built in the optical fiber that body shines, it is located at Film layer on the inside of tubular matrix can be translucent material, and the film layer on the outside of tubular matrix can be light screening material, utilize light The light for leading fiber sending is solidified.
It further include a light-shielding container 4 referring to Fig. 4, the flexible plastic plastic material is stored in the shading after folding holds In device 4, in order to store for a long time.Light-shielding container 4 is equipped with the opening 5 that can be opened.Flexible plastic plastic material is put using preceding It sets in the light-shielding container 4 with shade function, is kept in dark place.In use, flexible plastic plastic material is held in shading It is taken out in device 4.After being fabricated to the shape of needs, solidified, ultraviolet radiator help can be opened and accelerate curing rate.
In addition, at least one film layer of flexible plastic plastic material can also be that layers of elastomeric film is made in elastic material, elasticity The advantages of film layer, has very much: during 1. transports and storage, can compel it and carry out certain deformation, to build small size, save Space；2. carrying out certain recovery using the elasticity of its own in use, external force can be removed, it is therefore not necessary to as above that Sample is inflated, but can be accelerated it by way of inflation and be restored speed；3. for repair or need further deformation Place, can use its elastic force and suitably deformed in the case where not changing big profile.This structure is especially suitable for film When layer is made as an article with specific modality with certain shape, matrix in advance.
Such as: matrix is enclosed type, such as spherical shape, jar, chest, including two film layers, and internally positioned film layer is inner membrance Layer, the film layer positioned at outside are theca externa, and theca interna is made of elastic material.Spherical substrate be equipped with aeration aperture, transport and During storage, extruded by aeration aperture through internal gas, to reduce volume.In use, external force is removed, in aeration aperture into Enter gas, theca interna restores gradually, can also accelerate it by way of inflating and restore speed.If theca externa uses On the one hand flexible material, theca externa made of flexible material during transport and storage, can buffer external pressure and play protection Effect；When on the one hand making, skin patching and embossing etc. can be deformed using the changeability of flexible material.
Again for example: matrix is type semienclosed, such as bowl, spoon, cup, plate, ashtray include two film layers, are located at interior The film layer in portion is theca interna, the film layer positioned at outside is theca externa, and theca interna is made of elastic material, the mistake transported and stored Cheng Zhong, external force compel its deformation, to reduce volume.In use, external force is removed, theca interna restores gradually, can also be pinched by hand, The modes such as beating, stretching accelerate its and restore speed.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (16)

1. flexible plastic plastic material, including light-cured resin based composites, which is characterized in that including a matrix, the base Body includes two film layers, and an interlayer is constituted between two film layers, is equipped at least two particles, at least two institutes in the interlayer It states between particle filled with uncured light-cured resin based composites；At least one film layer is light transmission material in two film layers Material；
Particle is one of foam beads, bead, glass microballoon, metallic particles, building stones particle, plastic grain or several Kind；
It is equipped with micro-capsule between two film layers, is filled with uncured light-cured resin based composites in micro-capsule；
One film layer of described matrix is located below, and is fixedly arranged above one layer of auxiliary film, and described is fixed in the auxiliary film Grain；
Pigment is mixed in uncured light-cured resin based composites and is mixed with electroluminescent powder, and is embedded with conducting wire；
Two film layers are flexible or elastic material；
Fibre reinforced materials, fiber reinforcement material are embedded in resin-based materials in uncured light-cured resin based composites Material uses one of glass fibre, plant fiber, carbon fiber or several.
2. flexible plastic plastic material according to claim 1, it is characterised in that: the distance between two film layers is greater than 2 times of the particle average thickness.
3. flexible plastic plastic material according to claim 1, it is characterised in that: the micro-capsule wall is flexible or elastic material Material.
4. flexible plastic plastic material according to claim 1, it is characterised in that: the thickness of the micro-capsule is set smaller than The half of distance between two film layers.
5. flexible plastic plastic material according to claim 1, it is characterised in that: be arranged two layers between two film layers or Two layers of person or more additional film layer.
6. flexible plastic plastic material according to claim 1, it is characterised in that: between two film layers be arranged in filled with The vesica of gas.
7. flexible plastic plastic material according to claim 1, it is characterised in that: part micro-capsule is not consolidated by uncured light Change polymer matrix composites to be full of, filled solid particle or gas in remaining space；
The solid particle of filling is one of foam, bead, metallic particles, building stones particle, plastic grain or several.
8. flexible plastic plastic material according to claim 1, it is characterised in that: have one in two film layers of described matrix A is opaque.
9. flexible plastic plastic material according to claim 1, it is characterised in that: one in two film layers of described matrix A inside is reflective material.
10. flexible plastic plastic material according to claim 1, it is characterised in that: flexible plastic plastic material includes two A matrix, two matrixes are arranged in parallel, and supporting element are equipped between described matrix and matrix, the supporting element is flexible pipe body, flexible Uncured light-cured resin based composites are filled in tube body；
Described supporting element one end is fixed on the matrix of side, is formed a vertex, is at least further fixed on another in the apex One end of support member, i.e. an apex are fixed at least two supporting elements；The supporting element on total vertex on the matrix of side, another Vertex is no longer total on side group body.
11. flexible plastic plastic material according to claim 10, it is characterised in that: apex draw two, three or Four supporting elements.
12. flexible plastic plastic material according to claim 1, it is characterised in that: at least one in two film layers Layer is rupture pressure disc, shellproof film or antiultraviolet film.
13. flexible plastic plastic material according to claim 1, it is characterised in that: the flexible plastic plastic material support It is component shape to be formed, or the combination for multiple components after rising.
14. flexible plastic plastic material according to claim 1, it is characterised in that: the flexible plastic plastic material support It is ship shape, house shape, device housings shape, table shape, chair shape, bed body shape, cabinet shape, fish jar shape after rising Shape, vase shape, tea table shape or gear shape.
15. flexible plastic plastic material described in any one of -14 according to claim 1, it is characterised in that: in the micro-capsule Uncured light-cured resin based composites in be mixed with pigment.
16. flexible plastic plastic material described in any one of -14 according to claim 1, it is characterised in that: described matrix Pigment is mixed in the uncured light-cured resin based composites filled between two film layers.
CN201610637494.3A 2012-04-13 2012-04-13 Flexible plastic plastic material and its application Expired - Fee Related CN106256524B (en)

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