CN106221629B - A kind of flame-retardant hot-melt pressure sensitive adhesive, preparation method and application - Google Patents
A kind of flame-retardant hot-melt pressure sensitive adhesive, preparation method and application Download PDFInfo
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- CN106221629B CN106221629B CN201610668724.2A CN201610668724A CN106221629B CN 106221629 B CN106221629 B CN 106221629B CN 201610668724 A CN201610668724 A CN 201610668724A CN 106221629 B CN106221629 B CN 106221629B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2423/00—Presence of polyolefin
- C09J2423/04—Presence of homo or copolymers of ethene
- C09J2423/046—Presence of homo or copolymers of ethene in the substrate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof, which is the product for waterproofing industry exploitation, and flame-retardant hot-melt pressure sensitive adhesive of the invention, the composition of raw materials of weight percentage, the pressure sensitive adhesive includes：Thermoplastic elastomer (TPE) 20~35%, amorphous polyolefin 0~5%, polyisobutene 5~10%, the first tackifying resin 25~40%, the second tackifying resin 5~10%, plasticizer 10~20%, coupling agent 0.1~1%, ultra-violet absorber 0.1~1%, antioxidant 0.1~1%, fire retardant 5~10%.Flame-retardant hot-melt pressure sensitive adhesive provided by the invention not only has excellent ultraviolet aging resistance, heat-resistant aging, low temperature resistant bending is good, has suitable cohesive force, peeling force, initial bonding strength, and has anti-flammability, the defect that the pre- laying water-proof coiled material of tradition can only construct at 0 DEG C or more can be solved perfectly.
Description
Technical field
The present invention relates to a kind of flame-retardant hot-melt pressure sensitive adhesive, preparation method and applications.
Background technology
With the acceleration of urbanization process, limited land resource has been difficult to accommodate more populations and build, exploitation work
It is dynamic.Then, developing and utilizing Underground Space Resource becomes the inevitable choice of numerous urban developments at present and in the future.Underground is empty at present
Between using having been directed to：Underground commerce facility, underground parking station, groundwater reservoir, subway, pipe gallery etc..But underground is anti-
Channeling water leakage and settlement influence in Hydraulic Projects are still a great problem for perplexing waterproof expert and user.It how to be structure coagulation
It is extremely challenging that soil provides directly completely viscous waterproofing protection.
At present pre-installed and inverted adhered waterproof roll substantially be modified pitch class adhesive, such as CN101694114A,
CN1900207, CN202023264U, CN2892857Y etc..Waterproof roll is overlay made of modified pitch adhesive following lack
Point：
1, it is known that pitch itself is a kind of hot-fluid cold-short material, therefore modified pitch class adhesive high temperature resistant and low temperature
Poor performance, this makes troubles for summer and winter construction；
2, foot is glued, worker can not be in coiled material surface assembling reinforcement in the surface of coiled material without processing；
3, coiled material surface unprotect layer under the action of ultraviolet light and wind and rain, loses the effect of bonding such as because of working-day claims
And lead to product rejection；
4, the bonding peel strength of modified pitch class adhesive is relatively low；
5, non-antiflaming property.
In recent years, it is proposed a kind of polymer membranes that can be firmly bonded with structural concrete in the market, by preventing
Adhesion coating, melt pressure sensitive glue-line, high-density polyethylene layer composition, when using constructing, melt pressure sensitive glue-line can avoid waterproof from rolling up
Bonding gap between material and structural concrete keeps it permanent securely full viscous, and the product technology performance and construction effect are very
It is good.Minstry of Housing and Urban-Rural Development of People Republic of China (MOHURD) has been included in " building cause Eleventh Five-Year Plan is promoted and applied using first popularization catalogue of technology ", and by
It is included in newest 2010《10 new technologies of construction industry》In widely popularize application.It may be said that waterproof coiled material effect quality and hot melt
Pressure-sensitive adhesive layer has vital relationship.
Pressure-sensitive adhesive agent is developed rapidly in the latest 20 years, and application has spread the every field of national economy,
And come into huge numbers of families, still, in terms of the applied basic research of pressure sensitive adhesive product and technological development, China still with prosperity
There is larger gap in country.The pressure sensitive adhesive that can apply to waterproofing industry will have high/low temperature, UV resistant and resistance to immersion, and
There is preferable adhesive property with sheet material and Cement Concrete.
But existing hot-fusible pressure-sensitive adhesive has the following disadvantages：1, most common is exactly that high- and low-temperature resistance is inadequate, resistance to immersion
Difference, substandard products are more；2, the cohesive force of hot melt adhesive is unstable, and variation is influenced sooner or later for temperature and humidity in by working environment, Bu Nengbao
Demonstrate,prove firmness；3, low temperature can be such that hot-fusible pressure-sensitive adhesive bonding force is substantially reduced, and coiled material can not construct；4, weatherability is inadequate, resistance to purple
Outside line is also an important indicator, and coiled material needs the aging phenomenon in view of the sunlight irradiation generation in construction；5 and existing
There are no the hot-fusible pressure-sensitive adhesives with flame retardant property in technology.
Invention content
The technical problem to be solved by the present invention is to overcome the deficiencies of the prior art and provide a kind of flame-retardant hot-melt pressure sensitive adhesive and
Preparation method, the flame-retardant hot-melt pressure sensitive adhesive have high- and low-temperature resistance performance good, and resistance to ag(e)ing is good, and peel strength is high, and with resistance
Combustion property, construction temperature is wide.
In order to solve the above technical problems, the present invention adopts the following technical scheme that：
A kind of flame-retardant hot-melt pressure sensitive adhesive, the composition of raw materials of weight percentage, the hot-fusible pressure-sensitive adhesive include：
Wherein, first tackifying resin is one in C5 Petropols, C5 hydrogenated petroleum resins, C9 hydrogenated petroleum resins
Kind or a variety of combinations；
Second tackifying resin includes rosin resin, pentalyn, rosin glycerides, terpene resin, phenolic aldehyde
One or more combinations in resin.
Preferably, first tackifying resin is C5 hydrogenated petroleum resins.
Preferably, the combination of one or both of second tackifying resin for rosin glycerides, in phenolic resin.
In the present invention, the thermoplastic elastomer (TPE) is s-B-S (SBS), styrene-isoprene-
One in styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), styrene ethylene-propylene-styrene (SEPS)
Kind or a variety of combinations.
Preferably, the thermoplastic elastomer (TPE) is styrene-isoprene-phenylethene (SIS).
It is further preferred that the mass content of polystyrene is 13-18% in the SIS elastomers, polystyrene-poly is different
The mass content of pentadiene diblock is 0%~80%.
In the present invention, the amorphous polyolefin is APAO.
In the present invention, the polyisobutene molecular weight is less than 2000, and pour point is 3 DEG C~-30 DEG C.
In the present invention, the plasticizer is one or more combinations in naphthenic oil, white oil, DOP, chlorinated paraffin.
Preferably, the combination of one or both of the plasticizer for naphthenic oil, in chlorinated paraffin.It is highly preferred that described
Plasticizer is chlorinated paraffin.
In the present invention, the coupling agent is silane coupling agent.
In the present invention, the ultra-violet absorber is one or more in triazines, benzotriazole, hindered amines
Combination.The ultra-violet absorber includes but not limited to one or more in UV-P, UV234, UV328, UV944, UV292
Combination.The combination of one or both preferably in UV-P, UV234.
In the present invention, the antioxidant, including but not limited to 1010,168,1076,264 it is one or more.
In the present invention, the fire retardant is environment friendly halogen-free fireproof agent.Preferably, the fire retardant is phosphorus-nitrogen containing flame retardant.
In the present invention, raw material described in whole can not have by commercially available and/or take known means and be prepared
When being illustrated, it is satisfied by the requirement of standard chemical products.
The another technical solution that the present invention takes is：A kind of preparation method of above-mentioned flame-retardant hot-melt pressure sensitive adhesive, the preparation
Method is：By formula, by the thermoplastic elastomer (TPE), amorphous polyolefin, polyisobutene, the first tackifying resin, the second thickening
Resin, plasticizer, coupling agent, ultra-violet absorber, antioxidant, fire retardant be mixed at a temperature of 150 DEG C~180 DEG C until
Material dissolution, both the flame-retardant hot-melt pressure sensitive adhesive.
Another technical solution that the present invention takes is：A kind of above-mentioned flame-retardant hot-melt pressure sensitive adhesive answering in waterproof roll
With.Application especially in non-bituminous based high molecular self-adhesion glued membrane waterproof roll.
Due to the implementation of above-mentioned technical proposal, the present invention has the following advantages that compared with prior art：
Flame-retardant hot-melt pressure sensitive adhesive of the present invention has excellent high- and low-temperature resistance performance, ageing-resistant performance.
Flame-retardant hot-melt pressure sensitive adhesive of the present invention greatly enriches pressure sensitive adhesive construction application temperature range.
Flame-retardant hot-melt pressure sensitive adhesive of the present invention has flame retardant property, improves the use scope of pressure sensitive adhesive.
Flame-retardant hot-melt pressure sensitive adhesive of the present invention has preferable water resistance, solves that traditional asphalt base overlays coiled material and market is general
Logical Macromolecular self-adhesive membrane waterproof roll channeling water, leakage problems.
The flame-retardant hot-melt pressure sensitive adhesive of the present invention is in the preparation by the way that the first tackifying resin, the are added into thermoplastic elastomer (TPE)
The ingredients such as two tackifying resins, plasticizer, hot-fusible pressure-sensitive adhesive obtained have certain needle penetration, can improve it and pour coagulation with after
The peel strength of soil.
Specific implementation mode
With reference to specific embodiment, the present invention will be further described in detail, but the present invention is not limited to following implementations
Example.
Embodiment 1
The present embodiment provides a kind of flame-retardant hot-melt pressure sensitive adhesive, the raw materials and consumption of use referring to table 1, wherein：
Thermoplastic elastomer (TPE) is SIS, is purchased from Kraton Polymers of the U.S., trade mark D1163.
Amorphous polyolefin is APAO, is purchased from Ying Chuan companies, and the trade mark is Vestoplast 408.
First tackifying resin is C5 hydrogenated petroleum resins
Second tackifying resin is by rosin glycerides, phenolic resin in mass ratio 1：1 composition, wherein rosin glycerides are purchased from
Song Chuan chemical companies, trade mark RE85, phenolic resin connect industrial corporation, the trade mark 2402 purchased from Shanghai three.
Plasticizer is by naphthenic oil and chlorinated paraffin in mass ratio 2：1 composition, wherein naphthenic oil is extraordinary purchased from Suzhou Sai Pahan
Oil product Co., Ltd, trade mark KN4010, chlorinated paraffin are purchased from Suzhou Sai Pahan specialty oils Co., Ltd, trade mark 52#.
Coupling agent is purchased from Nanjing connection chemistry of silicones Co., Ltd, trade mark KH560.
Ultra-violet absorber is UV-P and UV234 in mass ratio 1：1 composition.
Antioxidant is antioxidant 1010, is purchased from BASF AG.
Fire retardant is phosphorus-nitrogen containing flame retardant, is purchased from Suzhou An Hongtai new materials Co., Ltd, trade mark FR563.
The preparation method of flame-retardant hot-melt pressure sensitive adhesive is as follows：By the formula of embodiment 1, by thermoplastic elastomer (TPE), amorphous poly-
Alkene, polyisobutene, the first tackifying resin, the second tackifying resin, plasticizer, coupling agent, ultra-violet absorber, antioxidant, resistance
It fires agent to be added in closed container, high-speed stirred under the conditions of 170 DEG C, discharging is to get the flame-retardant hot-melt pressure after material dissolution
Quick glue.
Embodiment 2
The present embodiment provides a kind of flame-retardant hot-melt pressure sensitive adhesive, the raw materials and consumption of use removes thermoplastic elastic referring to table 1
Body, the first tackifying resin, the second tackifying resin, the raw material outside plasticizer are same as Example 1, wherein：
Thermoplastic elastomer (TPE) is SBS and SIS in mass ratio 1：2 compositions, SBS are purchased from Yueyang petro-chemical corporation, the trade mark 792.
First tackifying resin is C5 Petropols and C9 hydrogenated petroleum resins are 2 in mass ratio：1 composition, C5 Petropols
Purchased from Lanzhou Petrochemical Company, trade mark LH-100, C9 hydrotreated petroleum tree is purchased from Exxon Mobil Corporation, the trade mark 5400.
Second tackifying resin is terpene resin, connects industrial corporation, trade mark T80 purchased from Shanghai three.
Plasticizer is DOP, is purchased from Shanghai Sen Di chemical companies, trade mark JSSD-DOP.
The preparation method is the same as that of Example 1.
Embodiment 3
The present embodiment provides a kind of flame-retardant hot-melt pressure sensitive adhesives, and the raw materials and consumption of use is referring to table 1, except antioxidant, plasticising
Raw material outside agent is same as Example 1, wherein：
Antioxidant is irgasfos 168 and antioxidant 1076 in mass ratio 1：1 composition.
Plasticizer is chlorinated paraffin.
The preparation method is the same as that of Example 1.
Embodiment 4
The present embodiment provides a kind of flame-retardant hot-melt pressure sensitive adhesives, and the raw materials and consumption of use is referring to table 1, except the second thickening is set
Raw material outside fat, ultra-violet absorber is same as Example 1.
Second tackifying resin is rosin glycerides.
Ultra-violet absorber is UV328.
The preparation method is the same as that of Example 1.
Comparative example 1
This comparative example provides a kind of hot-fusible pressure-sensitive adhesive, and the raw materials and consumption of use is referring to table 1, in the formula of this comparative example not
Add fire retardant.
Table 1 is the raw material composition of Examples 1 to 4 and comparative example 1
The flame-retardant hot-melt pressure sensitive adhesive of Examples 1 to 4 and comparative example 1 is tested for the property, method is as follows：The hot melt is pressed
Quick glue is coated to macromolecule HDPE sheet materials, cooling for use, then tears isolation film, anti-sticking is uniformly sprinkled on glue-line
Grain, is made Macromolecular self-adhesive membrane waterproof roll, Y in wet-laying waterproof roll standard is overlay according to national standard GB/T 23457-2009
P classes carry out performance Indexs measure, and flame retardant property is carried out according to national standard GB8624-2012 construction materials and product burns grading performance
Detection, test result is referring to table 2.
Table 2 is the performance of the hot-fusible pressure-sensitive adhesive of Examples 1 to 4 and comparative example 1
The present invention is described in detail above, its object is to allow the personage for being familiar with this field technology that can understand this
The content of invention is simultaneously implemented, and it is not intended to limit the scope of the present invention, and the present invention is not limited to above-mentioned implementations
, equivalent change or modification made by all Spirit Essences according to the present invention should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of flame-retardant hot-melt pressure sensitive adhesive, it is characterised in that：The raw material of weight percentage, the hot-fusible pressure-sensitive adhesive is matched
Side includes：
Thermoplastic elastomer (TPE) 20~35%
Amorphous polyolefin 1~5%
Polyisobutene 5~10%
First tackifying resin 25~40%
Second tackifying resin 5~10%
Plasticizer 10~20%
Coupling agent 0.1~1%
Ultra-violet absorber 0.1~1%
Antioxidant 0.1~1%
Fire retardant 5~10%；
Wherein, first tackifying resin be C5 Petropols, C5 hydrogenated petroleum resins, one kind in C9 hydrogenated petroleum resins or
A variety of combinations；
Second tackifying resin includes rosin resin, pentalyn, rosin glycerides, terpene resin, phenolic resin
In one or more combinations；
The thermoplastic elastomer (TPE) is SIS；
The amorphous polyolefin is APAO.
2. flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：The polyisobutene molecular weight is less than
2000, pour point is 3 DEG C~-30 DEG C.
3. flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：The plasticizer be naphthenic oil, white oil,
One or more combinations in DOP, chlorinated paraffin.
4. flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：The coupling agent is silane coupling agent.
5. flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：The ultra-violet absorber be triazines,
One or more combinations in benzotriazole, hindered amines.
6. flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：The fire retardant is environment friendly halogen-free fireproof
Agent.
7. a kind of preparation method of flame-retardant hot-melt pressure sensitive adhesive as described in any one of claim 1 ~ 6 claim, feature
It is：The preparation method is that：By formula, by the thermoplastic elastomer (TPE), amorphous polyolefin, polyisobutene, the first thickening
Resin, the second tackifying resin, plasticizer, coupling agent, ultra-violet absorber, antioxidant, fire retardant are at a temperature of 150 DEG C ~ 180 DEG C
Be mixed until material dissolution, both the flame-retardant hot-melt pressure sensitive adhesive.
8. a kind of flame-retardant hot-melt pressure sensitive adhesive answering in waterproof roll as described in any one of claim 1 ~ 6 claim
With.
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| CN201610668724.2A CN106221629B (en) | 2016-08-15 | 2016-08-15 | A kind of flame-retardant hot-melt pressure sensitive adhesive, preparation method and application |
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| CN201610668724.2A CN106221629B (en) | 2016-08-15 | 2016-08-15 | A kind of flame-retardant hot-melt pressure sensitive adhesive, preparation method and application |
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| CN106221629B true CN106221629B (en) | 2018-10-30 |
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| CN104946178A (en) * | 2014-03-26 | 2015-09-30 | 江苏凯伦建材股份有限公司 | Novel hot-melt pressure-sensitive adhesive for waterproof materials and preparation method thereof |
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| CN104629651A (en) * | 2015-02-09 | 2015-05-20 | 北京东方雨虹防水技术股份有限公司 | Hot-melt pressure-sensitive adhesive as well as preparation method thereof and waterproof coiled material |
| CN105017984B (en) * | 2015-07-22 | 2018-08-17 | 江苏凯伦建材股份有限公司 | A kind of adhesive polymer adhesive tape, production method and its application |
| CN105295829B (en) * | 2015-11-25 | 2018-04-13 | 贵州蓝图新材料股份有限公司 | Environment-friendly type high intensity waterproof roll self-adhesive |
| CN105694776A (en) * | 2016-01-29 | 2016-06-22 | 惠州市能辉化工有限公司 | High-polymer waterproof coiled material hot-melt pressure-sensitive adhesive and preparation method thereof |
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| EP3917777A4 (en) * | 2019-01-31 | 2022-11-16 | Synthomer Adhesive Technologies LLC | Product assembly adhesives comprising low volatile tackifier compositions |
| EP3917775A4 (en) * | 2019-01-31 | 2022-11-16 | Synthomer Adhesive Technologies LLC | Processes for making low volatile tackifier compositions |
| EP3917774A4 (en) * | 2019-01-31 | 2023-02-22 | Synthomer Adhesive Technologies LLC | Packaging adhesives comprising low volatile tackifier compositions |
| EP3917778A4 (en) * | 2019-01-31 | 2023-03-22 | Synthomer Adhesive Technologies LLC | Low volatile tackifier compositions |
| US11787978B2 (en) | 2019-01-31 | 2023-10-17 | Synthomer Adhesive Technologies Llc | Product assembly adhesives comprising low volatile tackifier compositions |
| EP3832046A1 (en) * | 2019-12-03 | 2021-06-09 | Jiangsu Canlon Building Materials Co., Ltd. | Polymer pre-laid waterproof rolling material |
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| CN106221629A (en) | 2016-12-14 |
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