CN106226380A - There is the electrolysis unit of scale, electrolytic process automatic analysis system based on X-ray imaging - Google Patents
There is the electrolysis unit of scale, electrolytic process automatic analysis system based on X-ray imaging Download PDFInfo
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Abstract
There is the electrolysis unit of scale, including equalizing reservoir (10), the first container (11), second container (12), first row blank pipe (110), second row blank pipe (120), first emptying valve (F1), second emptying valve (F2), the first electrode (DJ1), the second electrode (DJ2)；Electrolysis unit also includes liquid feed valve (F4), liquid feed valve (F4)；Liquid feed valve (F4) is positioned on the pipeline of feed tube (14), and the liquid in feed tube (14) can be flowed in equalizing reservoir (10);Electrolysis unit also includes scale (2)；The yardstick extension direction of scale (2) is identical with the axial direction of second container (12).The present invention is with low cost, application is flexible, length in service life, be hardly damaged, reliable and stable, analyze fast and reliable.
Description
Technical field
The invention belongs to electricity field, be specifically related to the electrolysis unit with scale.
Background technology
During using the liquid electrolytic of solid state electrode, the rising of the bubble near electrode surface, merging, easily have influence on electrode
Surface contacts with liquid, affects the motion of liquid intermediate ion, causes electrode surface to cause electricity with the contact area reduction of liquid
Solving the generation of efficiency bottle neck, scientific research personnel studies this process and is conducive to breaking through electrolytic efficiency bottleneck.
During using the liquid electrolytic of solid state electrode, the merging of the bubble near electrode surface and explosion, easily in office
Portion's high temperature and powerful impulsive force, cause solid state electrode to be corroded, and affects the life-span of electrode, and scientific research personnel studies this process to be had
It is beneficial to research and develop the electrolysis electrode that the most existing electrolysis electrode is more long-lived.
Scientific research personnel analyze exist when solid state electrode electrolyte is the state on surface (i.e. solid liquid interface) of electrode all
The most inconvenient；If there is a kind of system being capable of electrode process carries out automatical analysis, then can improve scientific research personnel
Efficiency of research and development to electrolysis electrode.
Summary of the invention
For solving the problem of narration in technical background, the present invention proposes solid liquid interface electrode process based on image procossing
Automatic analysis system, present system is capable of the automatical analysis of electrode process, improves scientific research efficiency.
The present invention has following technology contents.
1, there is the electrolysis unit of scale, it is characterised in that: include equalizing reservoir (10), the first container (11), the second appearance
Device (12), first row blank pipe (110), second row blank pipe (120), first emptying valve (F1), second emptying valve (F2), the first electrode
(DJ1), the second electrode (DJ2)；
Equalizing reservoir (10) is column, the upper end open of equalizing reservoir (10)；
First container (11) is column, and the upper end of the first container (11) communicates with first row blank pipe (110)；
Second container (12) is column, and the upper end of second container (12) communicates with second row blank pipe (120)；
Equalizing reservoir (10), the first container (11), second container (12) bottom communicates；In electrolysis unit: first emptying valve (F1)
Being positioned on the pipeline of first row blank pipe (110), first emptying valve (F1) can control the break-make situation of first row blank pipe (110)；
Second emptying valve (F2) is positioned on the pipeline of second row blank pipe (120), and second emptying valve (F2) can control the second emptying
The break-make situation of pipe (120)；
First electrode (DJ1) is positioned at the first container (11)；Second electrode (DJ2) is positioned at second container (12);
Electrolysis unit also includes liquid feed valve (F4), liquid feed valve (F4)；Liquid feed valve (F4) is positioned on the pipeline of feed tube (14), feed liquor
Liquid in pipe (14) can be flowed in equalizing reservoir (10);
Electrolysis unit also includes scale (2)；The yardstick extension direction of scale (2) is identical with the axial direction of second container (12).
2, the electrolysis unit with scale as described in technology contents 1, it is characterised in that: equalizing reservoir (10) uses glass system
Become.
3, the electrolysis unit with scale as described in technology contents 1, it is characterised in that: the first container of electrolysis unit
(11) glass is used to make.
4, the electrolysis unit with scale as described in technology contents 1, it is characterised in that: the scale (2) of electrolysis unit makes
Make with metallic lead.
5, the electrolysis unit with scale as described in technology contents 1, it is characterised in that: the first emptying valve of electrolysis unit
(F1) it is electromagnetic valve.
6, the electrolysis unit with scale as described in technology contents 1, it is characterised in that: the liquid feed valve (F4) of electrolysis unit
For electromagnetic valve.
7, electrolytic process automatic analysis system based on X-ray imaging, it is characterised in that: have as described in technology contents 1
There is the electrolysis unit of scale.
Technology contents explanation and beneficial effect thereof.
The present invention is with low cost, application is flexible, length in service life, be hardly damaged, reliable and stable, analyze fast and reliable..
Accompanying drawing explanation
Fig. 1,2,3 are the schematic diagram of the electrolysis unit of embodiment 1；Fig. 1 for top view, Fig. 2 be ray or
Light or ray that the side view equipment 3 of the equipment 3 of ray is launched pass equalizing reservoir (10), the first container (11), the second appearance
In device (12), at least one container is for the imaging of photographic head 4；Fig. 3 is that the lateral view of embodiment 1 wherein depicts control
System, this is to embody annexation intuitively.
Fig. 4 is the schematic diagram of the operating process of embodiment 1.
Fig. 5,6 it is the abstract representations schematic diagram that the auxiliary ' electrode analysis algorithm ' of embodiment 1 explains orally.
Fig. 7 is the schematic diagram of the preparing hydrogen, generating power module of embodiment 1.
Fig. 8 is the schematic diagram of the electrolysis unit of embodiment 4.
It is embodied as example
Below in conjunction with embodiment, the present invention will be described.
Embodiment 1, as shown in figs. 1-7 solid liquid interface electrode process automatic analysis system based on image procossing, it is special
Levy and be: include electrolysis unit, control system, preparing hydrogen, generating power module, camera head；
Electrolysis unit includes: equalizing reservoir (10), the first container (11), second container (12), first row blank pipe (110), second
Evacuated tube (120), first emptying valve (F1), second emptying valve (F2), the first electrode (DJ1), the second electrode (DJ2)；
In electrolysis unit: equalizing reservoir (10) is column, the upper end open of equalizing reservoir (10)；
In electrolysis unit: the first container (11) is column, the upper end of the first container (11) communicates with first row blank pipe (110)；
In electrolysis unit: second container (12) is column, the upper end of second container (12) communicates with second row blank pipe (120)；
In electrolysis unit: equalizing reservoir (10), the first container (11), second container (12) bottom communicates；In electrolysis unit: the
One exhaust-valve (F1) is positioned on the pipeline of first row blank pipe (110), and first emptying valve (F1) can control first row blank pipe (110)
Break-make situation；
In electrolysis unit: second emptying valve (F2) is positioned on the pipeline of second row blank pipe (120), second emptying valve (F2) can be controlled
The break-make situation of second row blank pipe (120) processed；
In electrolysis unit: the first electrode (DJ1) is positioned at the first container (11)；Second electrode (DJ2) is positioned at second container (12)
In.
Electrolysis unit also includes liquid feed valve (F4), liquid feed valve (F4)；Liquid feed valve (F4) is positioned on the pipeline of feed tube (14),
Liquid in feed tube (14) can be flowed in equalizing reservoir (10).
Electrolysis unit also includes tapping valve (F3)；Tapping valve (F3) be arranged on one end communicate with equalizing reservoir (10) one end with
On the pipeline that outside communicates, tapping valve (F3) is used for drained liquid, and the flat height of the liquid of tapping valve (F3) is less than the first container (11)
The top of cavity volume.
Electrolysis unit also includes scale (2)；The yardstick extension direction of scale (2) and the axial direction phase of second container (12)
With.
Control system includes control module, programmable power supply, and control module the most directly has with programmable power supply and is electrically connected, and controls mould
Block can control programmable power supply；Having between camera head and control system and be electrically connected, camera head can be to control module
Transmission image data, the lens shooting of camera head is the first container (11), the radial direction of second container (12), camera head
The image in the first container (11) can be shot.
Have between the control module of control system and first emptying valve (F1) and be electrically connected, the control module of control system
First emptying valve (F1) can be controlled；Have between the control module of control system and second emptying valve (F2) and be electrically connected, control
The control module of system processed can control second emptying valve (F2).
The control module of control system also and has between tapping valve (F3) and is electrically connected, the control module energy of control system
Enough control tapping valve (F3)；Have between the control module of control system and liquid feed valve (F4) and be electrically connected, the control of control system
Molding block can control liquid feed valve (F4).
Control system employs autocontrol method；Autocontrol method, is characterised by: comprise the following steps,
Step 1, inaccessible drain valve (F3)
Step 2, open first emptying valve (F1) and second emptying valve (F2)；
Step 3, open liquid feed valve (F4) make liquid to be electrolysed flow into equalizing reservoir (10);
Step 4, judging first emptying valve (F1) or second emptying valve (F2) whether overflowing liquid, if overflowed, entering step 5,
If do not overflowed, circulation reenters this step；
Step 5, inaccessible first emptying valve (F1) and second emptying valve (F2)；
Step 6, from the information bank of stored current data extract current information, current information including but not limited to current intensity,
Waveform, cycle, the longest energization period；
Step 7, startup image identification function；
Step 8, the current data control programmable power supply output electric current gone according to step 6 tune；
Step 9, judging whether to arrive maximum energization period, if reaching maximum energization period, entering step 11, without
Reach maximum energization period and then enter step 10；
Step 10, read gas column height by image identification function, and judge whether gas column height exceedes warning value, if gas column
Highly exceed warning value and then enter step 11, if gas column height is not above warning value, enter step 9；
Step 11, make programmable power supply stop electric current output；
Step 12, judged gas column height by image identification function, and preserve gas column height value.
Step 13, end.
Having electroanalysis method in the control module of control system, electroanalysis method obtains from camera head based on control module
Image and be analyzed, camera head utilizes laser or X-ray imaging, and in image, alveolate region liquid is to laser or X
The absorption of light is the fewest, and correspondence image regional exposure is strong, with the side away from electrode as X-axis, with electrode bottom as Y-axis, with X
The intersection point of axle and Y-axis is initial point；Process step is as follows:
Walk 1, formation image is carried out gray proces, expose the strongest area grayscale numerical value the highest；
Step 2, the color gray value of each point cumulative obtain assay value with the product of point to electrode surface distance, and assay value is the most stingy
Steep the least with the impact contacted of liquid on electrode surface.
Preparing hydrogen, generating power module, it is characterised in that: include anti-mixing arrangement (LXQ), the first container (L1), second container (L2), fill
The mouth of a river, filling valve (F3), the first electrode (DJ1), the second electrode (DJ2), the first pipeline (GD1), second pipe (GD2), first
Air pump (B1), the second air pump (B2), the first check valve (DF1), the second check valve (DF2), the first gas tank (Q1), the second gas tank
(Q2), the first entrance air valve (F1), the second entrance air valve (F2), the first pressure maintaining valve (W1), the second pressure maintaining valve (W2), hydrogen fuel electricity
Pond (BAT1), the 3rd pipeline (GD3), the 4th pipeline (GD4), circulating valve (F4), degasification container (YLG)；
The anti-mixing arrangement of preparing hydrogen, generating power module includes housing (LXQ), spiral tube chamber (LXG), the first tube chamber (ZG1), the second pipe
Chamber (ZG2)；Spiral tube chamber (LXG) is helical form, and spiral tube chamber (LXG) has the first end and the second end；First tube chamber (ZG1)
Axis direction is identical with the axis of screw direction of spiral tube chamber (LXG), and the first tube chamber (ZG1) is positioned at the spiral shell of spiral tube chamber (LXG)
Within spin line, the length of the first tube chamber (ZG1) more than spiral tube chamber (LXG) two end points places with spiral tube chamber (LXG)
The distance in the face that axis is vertical；First tube chamber (ZG1) has connection end and opening (JK1)；The connection end of the first tube chamber (ZG1)
Communicate with the first end of spiral tube chamber (LXG)；First tube chamber (ZG1) is through whole spiral tube chamber (LXG) section, and the first tube chamber
(ZG1) opening (JK1) is beyond the second end of spiral tube chamber (LXG)；The axis direction of the second tube chamber (ZG1) and spiral tube chamber
(LXG) axis of screw direction is identical, within the second tube chamber (ZG1) is positioned at the helix of spiral tube chamber (LXG), and the second tube chamber
(ZG1) length more than spiral tube chamber (LXG) two end points places the face vertical with spiral tube chamber (LXG) axis away from
From；Second tube chamber (ZG1) has connection end and opening (JK1)；The connection end of the second tube chamber (ZG1) and spiral tube chamber (LXG)
The second end communicate；Second tube chamber (ZG1) is through whole spiral tube chamber (LXG) section, and the opening of the second tube chamber (ZG1)
(JK1) beyond the first end of spiral tube chamber (LXG).
In preparing hydrogen, generating power module: the bottom of the first container (L1) communicates with one end of anti-mixing arrangement (LXQ), second container
(L2) bottom communicate with the other end of anti-mixing arrangement (LXQ)；That is the first container (L1) bottom, second hold
Device (L2) bottom communicated by anti-mixing arrangement (LXQ)；
In preparing hydrogen, generating power module: the first electrode (DJ1) device is in the cavity volume of the first container (L1), and the first electrode (DJ1) is
The horizontal level of lower end communicates the horizontal level of interface higher than the first container (L1) with anti-mixing arrangement (LXQ)；
In preparing hydrogen, generating power module: the second electrode (DJ2) device is in the cavity volume of second container (L2), and the second electrode (DJ2) is
The horizontal level of lower end communicates the horizontal level of interface higher than second container (L2) with anti-mixing arrangement (LXQ)；When the first container
(L1) cell reaction can be terminated owing to liquid departs from electrode when, draught head is the biggest during second container (L2) electrolysis；
In preparing hydrogen, generating power module: the first pipeline (GD1) is passed through via the first air pump (B1), the first list in the top of the first container (L1)
Communicate with the first gas tank (Q1) to valve (DF1), the first air pump (B1) by the gas-powered in the first container (L1) to the first gas tank
(Q1), in, the first check valve (DF1) allows the gas in the first container (L1) to flow to the first gas tank (Q1), the first check valve
(DF1) the first gas tank (Q1) is not allowed to flow in the first container (L1)；
In preparing hydrogen, generating power module: second pipe (GD2) is passed through via the second air pump (B2), the second list in the top of second container (L2)
Communicate with the second gas tank (Q2) to valve (DF2), the second air pump (B2) by the gas-powered in second container (L2) to the second gas tank
(Q2), in, the second check valve (DF2) allows the gas in second container (L2) to flow to the second gas tank (Q2), the second check valve
(DF2) the second gas tank (Q2) is not allowed to flow in second container (L2)；
In preparing hydrogen, generating power module: the first gas tank (Q1) is connected with an inlet channel of hydrogen fuel cell (BAT1), the first gas tank
(Q1) with on the communication path of hydrogen fuel cell (BAT1), there is the first pressure maintaining valve (W1), the first pressure maintaining valve (W1) allow fluid from
First gas tank (Q1) flows to hydrogen fuel cell (BAT1), and the first pressure maintaining valve (W1) does not allow fluid to flow from hydrogen fuel cell (BAT1)
To the first gas tank (Q1), the first pressure maintaining valve (W1) can control the one of the hydrogen fuel cell (BAT1) that the first gas tank (Q1) is connected
The air pressure of individual inlet channel；
In preparing hydrogen, generating power module: the second gas tank (Q2) is connected with an inlet channel of hydrogen fuel cell (BAT1), the second gas tank
(Q2) with on the communication path of hydrogen fuel cell (BAT1), there is the second pressure maintaining valve (W2), the second pressure maintaining valve (W2) allow fluid from
Second gas tank (Q2) flows to hydrogen fuel cell (BAT1), and the second pressure maintaining valve (W2) does not allow fluid to flow from hydrogen fuel cell (BAT1)
To the second gas tank (Q2), the second pressure maintaining valve (W2) can control the one of the hydrogen fuel cell (BAT1) that the second gas tank (Q2) is connected
The air pressure of individual inlet channel；
In preparing hydrogen, generating power module: the upper end of the 3rd pipeline (GD3) communicates with the discharge outlet of hydrogen fuel cell (BAT1), the 3rd pipeline
(GD3) lower end communicates with the cavity volume of degasification container (YLG)；The upper end of the 4th pipeline (GD4) and the cavity volume of degasification container (YLG)
Communicating, the lower end of the 4th pipeline (GD4) communicates with the first container (L1) via circulating valve (F4) so that hydrogen fuel cell (BAT1)
The electrolysis cavity volume that product water can back flow back into the first container (L1), second container (L2) is constituted in, recycle；3rd pipe
The horizontal level of the lower ending opening in road (GD3), less than the horizontal level of the upper end open of the 4th pipeline (GD4), is possible to prevent gas
Enter the first container (L1), in electrolysis cavity volume that second container (L2) is constituted；
In preparing hydrogen, generating power module: also have supersonic generator (C1), supersonic generator (C1) is positioned at degasification container (YLG)
Portion；Also having air vent, degasification container (YLG) is communicated with steam vent by the 5th pipeline (GD5), the stream of the 5th pipeline (GD5)
Body path also has the 5th pump (B5), air bleeding valve (F5)；Send out at ultrasound wave during by controlling degasification container (YLG) degasification operation
Open air bleeding valve (F5) while raw device (C1) and open the air pressure of the 5th pump (B5) reduction degasification container (YLG), making so that hydrogen
The gas abjection dissolved in the product water of fuel cell (BAT1), reduces degasification container while supersonic generator (C1) degassing
(YLG) design of the air pressure hardware cost that makes to deaerate is the lowest and effect is fine；
In preparing hydrogen, generating power module: hydrogen fuel cell (BAT1) has power supply output point (VCC1), power supply place (GND1)；
Preparing hydrogen, generating power module is connected as electrical energy storage device, preparing hydrogen, generating power module and program-controlled electric with the control module of control system
Source connected devices, can tackle the situation of unexpected power-off.
Embodiment 2, amendment control system based on embodiment 1 control module in there is electroanalysis method；Electrolysis point
Image that analysis method obtains from camera head based on control module and be analyzed, camera head utilizes laser or X-ray imaging, figure
In Xiang, alveolate region liquid is the fewest to the absorption of laser or X-ray, and correspondence image regional exposure is strong, with away from the one of electrode
Side is X-axis, with electrode bottom as Y-axis, with the intersection point of X-axis and Y-axis as initial point；Process step is as follows:
Step 1, image carrying out gray proces, it is the highest expose the strongest area grayscale numerical value, and minima is more than zero, and maximum is Z；
Walk 2, each gray scale put of image is carried out computing S=S%Z；
Step 3, the cumulative color gray value of each point obtain assay value with the product of Y-coordinate value, and assay value gets over air pocket to electrode
Surface is the least with the impact contacted of liquid.
Embodiment 3, amendment control system based on embodiment 1 control module in there is electroanalysis method；Electrolysis point
Image that analysis method obtains from camera head based on control module and be analyzed, camera head utilizes laser or X-ray imaging, figure
In Xiang, alveolate region liquid is the fewest to the absorption of laser or X-ray, and correspondence image regional exposure is strong, with near the one of electrode
Side is X-axis, with electrode bottom as Y-axis, with the intersection point of X-axis and Y-axis as initial point；Process step is as follows:
Step 1, carrying out gray proces to forming image, it is the highest expose the strongest area grayscale numerical value, minima more than zero, maximum
For Z；
Walk 2, each gray scale S put of image is carried out computing S=S%Z；
Step 3, the color gray value of each point cumulative obtain assay value with the product of point to electrode surface distance, and assay value gets over air
Steep the least with the impact contacted of liquid on electrode surface.
Increasing anti-mixing arrangement for electrolysis unit on the basis of embodiment 4, embodiment 1, anti-mixing arrangement includes housing
(LXQ), spiral tube chamber (LXG), the first tube chamber (ZG1), the second tube chamber (ZG2), spiral tube chamber (LXG) is helical form, serpentine pipe
Chamber (LXG) has the axis of screw side of the first end and the second end, the axis direction of the first tube chamber (ZG1) and spiral tube chamber (LXG)
To identical, within the first tube chamber (ZG1) is positioned at the helix of spiral tube chamber (LXG), the length of the first tube chamber (ZG1) is more than spiral
The distance in the face vertical with spiral tube chamber (LXG) axis at two end points places of tube chamber (LXG), the first tube chamber (ZG1) has
Connecting end and opening (JK1), the connection end of the first tube chamber (ZG1) communicates with the first end of spiral tube chamber (LXG), the first tube chamber
(ZG1) it is through whole spiral tube chamber (LXG) section, and the opening (JK1) of the first tube chamber (ZG1) is beyond spiral tube chamber (LXG)
Second end, the axis direction of the second tube chamber (ZG1) is identical with the axis of screw direction of spiral tube chamber (LXG), the second tube chamber
(ZG1), within being positioned at the helix of spiral tube chamber (LXG), the length of the second tube chamber (ZG1) is more than two of spiral tube chamber (LXG)
The distance in the face vertical with spiral tube chamber (LXG) axis at end points place, the second tube chamber (ZG1) has connection end and opening
(JK1), the connection end of the second tube chamber (ZG1) communicates with the second end of spiral tube chamber (LXG), and the second tube chamber (ZG1) is through whole
Spiral tube chamber (LXG) section, and the opening (JK1) of the second tube chamber (ZG1) is beyond the first end of spiral tube chamber (LXG)；Electrolysis dress
First end of the anti-mixing arrangement put communicates with the first container of electrolysis unit；Second end of the anti-mixing arrangement of electrolysis unit
Communicate with the second container of electrolysis unit.
At hydrogen fuel cell (BAT1), there is power supply output point (VCC1), power supply ground on the basis of embodiment 5, embodiment 1
A filter capacitor, filter capacitor one end power supply output point (VCC1) other end and power supply place is connected between point (GND1)
(GND1) it is connected.
On the basis of embodiment 6, embodiment 1, the control module of control system also includes that CUDA processes hardware.
The not quite clear place of this explanation is prior art or common knowledge, therefore does not repeats.
Claims (7)
1. there is the electrolysis unit of scale, it is characterised in that: include equalizing reservoir (10), the first container (11), second container
(12), first row blank pipe (110), second row blank pipe (120), first emptying valve (F1), second emptying valve (F2), the first electrode
(DJ1), the second electrode (DJ2)；
Equalizing reservoir (10) is column, the upper end open of equalizing reservoir (10)；
First container (11) is column, and the upper end of the first container (11) communicates with first row blank pipe (110)；
Second container (12) is column, and the upper end of second container (12) communicates with second row blank pipe (120)；
Equalizing reservoir (10), the first container (11), second container (12) bottom communicates；In electrolysis unit: first emptying valve (F1)
Being positioned on the pipeline of first row blank pipe (110), first emptying valve (F1) can control the break-make situation of first row blank pipe (110)；
Second emptying valve (F2) is positioned on the pipeline of second row blank pipe (120), and second emptying valve (F2) can control the second emptying
The break-make situation of pipe (120)；
First electrode (DJ1) is positioned at the first container (11)；Second electrode (DJ2) is positioned at second container (12);
Electrolysis unit also includes liquid feed valve (F4), liquid feed valve (F4)；Liquid feed valve (F4) is positioned on the pipeline of feed tube (14), feed liquor
Liquid in pipe (14) can be flowed in equalizing reservoir (10);
Electrolysis unit also includes scale (2)；The yardstick extension direction of scale (2) is identical with the axial direction of second container (12).
There is the electrolysis unit of scale the most as claimed in claim 1, it is characterised in that: equalizing reservoir (10) uses glass system
Become.
There is the electrolysis unit of scale the most as claimed in claim 1, it is characterised in that: first container (11) of electrolysis unit makes
Make with glass.
There is the electrolysis unit of scale the most as claimed in claim 1, it is characterised in that: the scale (2) of electrolysis unit uses gold
Belong to lead to make.
There is the electrolysis unit of scale the most as claimed in claim 1, it is characterised in that: the first emptying valve (F1) of electrolysis unit
For electromagnetic valve.
There is the electrolysis unit of scale the most as claimed in claim 1, it is characterised in that: the liquid feed valve (F4) of electrolysis unit is electricity
Magnet valve.
7. electrolytic process automatic analysis system based on X-ray imaging, it is characterised in that: have and have as claimed in claim 1
The electrolysis unit of scale.
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| CN201610590490.4A CN106226380A (en) | 2016-07-26 | 2016-07-26 | There is the electrolysis unit of scale, electrolytic process automatic analysis system based on X-ray imaging |
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Application publication date: 20161214 |