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CN106219907A - Mineral for sewage disposal loads biochemical materialization coupled processing method and system - Google Patents

Mineral for sewage disposal loads biochemical materialization coupled processing method and system Download PDF

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Publication number
CN106219907A
CN106219907A CN201610830471.4A CN201610830471A CN106219907A CN 106219907 A CN106219907 A CN 106219907A CN 201610830471 A CN201610830471 A CN 201610830471A CN 106219907 A CN106219907 A CN 106219907A
Authority
CN
China
Prior art keywords
materialization
mineral
sludge
sewage disposal
biochemical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610830471.4A
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Chinese (zh)
Inventor
霍槐槐
李哲
李茉
尹丽莎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Luoke Environmental Protection Technology Co Ltd
Original Assignee
Qingdao Luoke Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Luoke Environmental Protection Technology Co Ltd filed Critical Qingdao Luoke Environmental Protection Technology Co Ltd
Priority to CN201610830471.4A priority Critical patent/CN106219907A/en
Publication of CN106219907A publication Critical patent/CN106219907A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/488Treatment of water, waste water, or sewage with magnetic or electric fields for separation of magnetic materials, e.g. magnetic flocculation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1278Provisions for mixing or aeration of the mixed liquor

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Activated Sludge Processes (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention belongs to technical field of sewage, relate to biochemical materialization coupled processing method and system.Mineral for sewage disposal loads biochemical materialization coupled processing system, and this system includes: biochemistry pool, materialization pond, sedimentation tank, sludge pump and magnetic powder separator;Inlet channel is connected with biochemistry pool;It is connected by dividing plate between described biochemistry pool with materialization pond;Materialization pond is connected by pipeline with sedimentation tank;The bottom of sedimentation tank is connected with sludge pump;Described sludge pump is divided into two-way, and pipeline of leading up to is connected with water inlet pipe, and pipeline of leading up to is connected with magnetic separator;Described magnetic separator is arranged on above biological tank.The mineral for sewage disposal of the present invention loads biochemical materialization coupled processing method and system, has the beneficial effect that and improves 3~4 times than the sludge concentration of conventional activated sludge;Biochemistry pool biochemical efficiency and disposal ability improve 3~4 times, and sedimentation tank reduced footprint 3~4 times, outlet effect is far superior to conventional activated sludge process.

Description

Mineral for sewage disposal loads biochemical materialization coupled processing method and system
Technical field
The invention belongs to technical field of sewage, relate to biochemical materialization coupled processing method and system.
Background technology
Municipal sewage plant carries out biochemical treatment to remove in water body frequently with biochemical sludge technology to sewage Polluter.Routine biochemistry activated sludge technology sludge concentration is low, and settleability is poor, causes its water outlet to be taken up an area big, outlet effect one As, it is difficult to directly reach the one-level emission standard A in urban wastewater treatment firm pollutant emission standard (GB18918 2002).
Summary of the invention
In order to solve the deficiency that existing biochemical sludge technology exists, the present invention provides a kind of efficient sewage disposal Method and apparatus.
The present invention solves it and technical problem the technical scheme is that the mineral for sewage disposal loads biological Changing coupled processing system, this system includes: biochemistry pool, materialization pond, sedimentation tank, sludge pump and magnetic separator;Inlet channel and life Change pond to connect;It is connected by dividing plate between described biochemistry pool with materialization pond;Materialization pond is connected by pipeline with sedimentation tank;Precipitation The bottom in pond is connected with sludge pump;Described sludge pump is divided into two-way, and pipeline of leading up to is connected with water inlet pipe, leads up to pipe Road is connected with magnetic separator;Described magnetic separator is arranged on above biological tank.
It is provided with aerator bottom described biochemistry pool.
Described biochemistry pool, materialization pond be provided above medicament load pump.
Described sedimentation tank is internally provided with mud scraper, and bottom is provided with sludge bucket, and top arranges water outlet weir plate and catchments Groove;Mud scraper is connected with motor reducer;Sludge bucket is connected with sludge pump;Water outlet weir plate and water leg are connected with outlet pipe.
Described sludge pump includes sludge reflux pump and residual sludge pump, and sludge reflux pump is by pipeline with water inlet pipe even Connect;Residual sludge pump is connected with cutter, magnetic separator successively by pipeline.
The present invention also provides for a kind of mineral for sewage disposal and loads biochemical materialization coupled processing method, including following Step: 1, sanitary sewage enters biochemistry pool after pretreatment, carries out aeration in biochemistry, adds a modified mineral matter simultaneously Powder, stirring reaction 4~8h;2, enter into afterwards in materialization pond, materialization pond adds No. two mineral powder and No. three modified ore deposits Material powder, stirring reaction 2~5min;3, enter into precipitation about 1h in sedimentation tank, obtain flocky precipitate and supernatant;4, on By outlet pipe directly outer row after clear liquid is up to standard, a flocky precipitate part is back to biochemistry pool;A part by cutter and After magnetic separator reclaims a modified mineral matter powder, excess sludge is carried out is discharged into sludge treating block and carries out next step Process.
Component and the percent mass proportioning of a described modified mineral matter powder be: Fe3O490~94.18%, SiO2 1.78~2.26%, Al2 O3 0.87~1.1%, CaO 0.45~0.61%, S 0.29~0.46%, MgO 0.42~0.6%, remaining Amount is regulator;Proportion is 4.8~5.1g/cm3;Granularity: 200~350 mesh.
No. two described mineral powder are powdered activated carbon, granularity 200~350 mesh.
Component and the percent mass proportioning of No. three described modified mineral matter powder be: CaO 22.1~24.6%, SiO2 12 ~14%, Al2O311.1~15%, SO321.2~22.4%, Fe2O3 0.65~1.87%, MgO 1.34~2.84%, TiO20.56~0.66%, K2O 0.12~0.23%, MnO 0.04~0.05%, Na2O 0.20~0.24%, surplus is for adding Charging;Density is 2g/cm3Left and right.
In described step (1), the dosage of a modified mineral matter powder is 10000mg/L.
In described step (2), the dosage of No. two mineral powder is 10~20mg/L;Adding of No. three modified mineral matter powder Amount is 5~10mg/L.
The mineral for sewage disposal of the present invention loads biochemical materialization coupled processing method and system, with prior art Compare, have the advantages that and improve 3~4 times than the sludge concentration of conventional activated sludge;Biochemistry pool biochemical efficiency and place Reason ability improves 3~4 times, and sedimentation tank reduced footprint 3~4 times, outlet effect is far superior to traditional active sludge work Skill.
Accompanying drawing explanation
Fig. 1 is the structural representation of the biochemical materialization coupled processing system of mineral loading for sewage disposal of the present invention Figure.
Detailed description of the invention
As it is shown in figure 1, the mineral for sewage disposal of the present invention loads biochemical materialization coupled processing system, including entering Water pipe 1, biochemistry pool 2, materialization pond 3, sedimentation tank 4;Water inlet pipe 1 is connected with biochemistry pool;Between biochemistry pool 2 and materialization pond 3 by every Plate connects, i.e. the outlet of biochemistry pool is the import in materialization pond;Materialization pond 3 is connected by the central canal 13 of connecting tube 12 with sedimentation tank Connecing, central canal 13 is placed on sedimentation tank 4 middle.
The bottom of biochemistry pool 2 is provided with aerator 9, and aerator connects external air source.The top of biochemistry pool is provided with blender 15 and a modified mineral matter powder load pump 16.
The top in materialization pond 3 is also equipped with blender 15, and No. two mineral powder load pump 17 and No. three modified minerals Matter powder load pump 18.
Sedimentation tank 4 is cylindrical or square column type, and bottom is provided with sludge bucket 11.Sludge reflux pump 8 and residual sludge pump 5 are led to Piping is connected with sludge bucket 11, and residual sludge pump 5 is connected with magnetic separator 7 with high shear machine 6 successively by pipeline.Magneto separate Device 7 is arranged on biochemistry pool 2 top, the magnetic powder of magnetic separator 7 outlet alignment biochemistry pool, the excess sludge of magnetic separator 7 export into Enter and be further processed to sludge treating block.The top of sedimentation tank 4 is provided with water outlet weir plate and water leg 14.In sedimentation tank 4 Being provided with mud scraper 10, mud scraper 10 is connected with motor reducer (not shown).The bottom of sedimentation tank is additionally provided with scrapes mud Plate (not shown).
Blender in biochemistry pool 2 uses Double-curved-surface stirring device, and stirrer paddle is close at the bottom of pond.
Blender in materialization pond 3 uses Water wing type stirrer paddle, boosts.
Aerator 9 uses double-decker aeration tube.
Sludge reflux pump 8 and residual sludge pump 5 use Pulp pump.
High shear machine 6 uses pipeline-type high-shearing blender, its structure disclosed in the early stage patent of the applicant, Here is omitted.
Magnetic separator 7 uses reverse-flow magnetic separator.
The mineral for sewage disposal of the present invention loads biochemical materialization coupled processing method, and idiographic flow step is: 1, municipal wastewater enters in biochemistry pool by water inlet pipe, carries out aeration, the activated sludge concentration in biochemistry pool in biochemistry pool Controlling at 10000mg/L, dissolved oxygen controls 2~3mg/L, and blender rotating speed is at 120rpm, and the biochemical reaction time is 6h, Biochemistry pool adds modified mineral matter powder a: Fe3O4 94.18%、SiO2 2.26%、Al2 O3 0.87%、CaO 0.61%、S 0.29%, MgO 0.42%, surplus are regulator;Proportion is 4.8g/cm3;Granularity: 220 mesh;Controlled concentration is at 10000mg/ L。
2, during the water outlet of biochemistry pool enters into materialization pond, materialization pond adds No. two mineral powder: powdered activated carbon, throw Dosage 15mg/L;With No. 3 modified mineral matter powder: CaO 24.6%, SiO214%, Al2O311.1%, SO321.2%, Fe2O3 1.87%, MgO 2.84%, TiO20.66%, K2O 0.23%, MnO 0.05%, Na2O 0.24%, surplus is for adding Charging;Density is 2g/cm3Left and right;Dosage 8mg/L, additive is conventional additive, such as density adjuster, adsorbent (such as bentonite and/or activated carbon etc.).Blender uses Water wing type stirring, and stirring intensity controls more than 10 grades, upwards Agitation advances;Time of staying 5min.
3, the sewage after reaction is entered in sedimentation tank by connecting tube and precipitates, and sedimentation tank surface loading can value To 4m3/m2H, the sedimentation tank time of staying is 1h.
4, supernatant qualified discharge from water outlet weir plate and water leg, the activated sludge of precipitation is scraped into dirt through mud scraper Bucket, major part returns to water inlet pipe through sludge reflux pump afterwards, and return sludge ratio controls about 75%, in company with water inlet one With entering into biochemistry pool, mineral powder is reclaimed by a small amount of mud through high shear machine and magnetic separator, excess sludge discharge ratio Controlling about 4%, excess sludge carries out outer row.The mineral powder reclaimed re-enters in biological tank and recycles.
The mineral for sewage disposal of the present invention loads biochemical materialization coupled processing method, the mineral powder coupling of use Having closed special ore material powder, wherein the Main Function of a modified mineral matter powder is to improve sludge concentration and settleability, and No. one changes Property mineral powder recycles in systems, and the response rate is more than 90%.No. two mineral powder are mainly used to remove a huge sum of money in water body Belong to, and the material such as COD.No. three modified mineral matter powder are mainly used to remove the total phosphorus in water body, and float and ammonia nitrogen etc. pollute Material, and improve the conglomeration of mud, improve settleability.
The mineral for sewage disposal using the present invention loads biochemical materialization coupled processing method and system, intakes dense Degree is less than COD400mg/L, BOD200 mg/L, float 200 mg/L, TP8 mg/L, NH4-N35 mg/L, TN40 mg/L In the case of, the discharge standard of one-level A can be directly reached after treatment.Moreover, traditional active sludge processes technique life Change pond activated sludge general control between 2000~4000mg/L, the present invention can improve activated sludge concentration to 8000~ 12000mg/L;The sedimentation tank surface loading of traditional active sludge is 0.5~1m3/m2h, and the present invention can improve surface loading extremely 4m3/m2H, the traditional active sludge sedimentation time is 2h, and the present invention can shorten the sedimentation time to 1h.So, in same occupation of land face Under Ji, greatly improve efficiency.

Claims (10)

1. the mineral for sewage disposal loads biochemical materialization coupled processing system, it is characterised in that: this system includes biochemistry Pond, materialization pond, sedimentation tank, sludge pump and magnetic separator;Inlet channel is connected with biochemistry pool;Described biochemistry pool and materialization pond it Between connected by dividing plate;Materialization pond is connected by pipeline with sedimentation tank;The bottom of sedimentation tank is connected with sludge pump;Described mud Pump is divided into two-way, and pipeline of leading up to is connected with water inlet pipe, and pipeline of leading up to is connected with magnetic separator;Described magnetic separator It is arranged on above biological tank.
Mineral for sewage disposal the most according to claim 1 loads biochemical materialization coupled processing system, its feature It is: bottom described biochemistry pool, be provided with aerator.
Mineral for sewage disposal the most according to claim 2 loads biochemical materialization coupled processing system, its feature Be: described biochemistry pool, materialization pond be provided above medicament load pump.
4. load biochemical materialization coupling processing system according to the mineral for sewage disposal described in any one of claim 1-3 System, it is characterised in that: described sedimentation tank is internally provided with mud scraper, and bottom is provided with sludge bucket, and top arranges water outlet weir plate And water leg;Mud scraper is connected with motor reducer;Sludge bucket is connected with sludge pump;Water outlet weir plate and water leg are with outlet pipe even Connect.
5. load biochemical materialization coupling processing system according to the mineral for sewage disposal described in any one of claim 1-3 System, it is characterised in that: described sludge pump includes sludge reflux pump and residual sludge pump, and sludge reflux pump passes through pipeline and water inlet Pipe connects;Residual sludge pump is connected with cutter, magnetic separator successively by pipeline.
6. the mineral for sewage disposal loads biochemical materialization coupled processing method, it is characterised in that comprise the following steps: 1, Sanitary sewage enters biochemistry pool after pretreatment, carries out aeration in biochemistry, adds a modified mineral matter powder simultaneously, stirring Reaction 4~8h;2, enter into afterwards in materialization pond, materialization pond add No. two mineral powder and No. three modified mineral matter powder, Stirring reaction 2~5min;3, enter into precipitation about 1h in sedimentation tank, obtain flocky precipitate and supernatant;4, supernatant reaches By outlet pipe directly outer row after mark, a flocky precipitate part is back to biochemistry pool;A part is by cutter and Magneto separate After device reclaims a modified mineral matter powder, excess sludge is carried out being discharged into sludge treating block and is for further processing.
Mineral for sewage disposal the most according to claim 6 loads biochemical materialization coupled processing method, its feature Being, component and the percent mass proportioning of a described modified mineral matter powder be: Fe3O490~94.18%, SiO21.78~ 2.26%、Al2 O3 0.87~1.1%, CaO 0.45~0.61%, S 0.29~0.46%, MgO 0.42~0.6%, surplus for adjusting Joint agent;Proportion is 4.8~5.1g/cm3;Granularity: 200~350 mesh.
Mineral for sewage disposal the most according to claim 6 loads biochemical materialization coupled processing method, its feature Being, No. two described mineral powder are powdered activated carbon, granularity 200~350 mesh.
Mineral for sewage disposal the most according to claim 6 loads biochemical materialization coupled processing method, its feature Being, component and the percent mass proportioning of No. three described modified mineral matter powder be: CaO 22.1~24.6%, SiO212~ 14%, Al2O311.1~15%, SO321.2~22.4%, Fe2O3 0.65~1.87%, MgO 1.34~2.84%, TiO2 0.56~0.66%, K2O 0.12~0.23%, MnO 0.04~0.05%, Na2O 0.20~0.24%, surplus is additive; Density is 2g/cm3Left and right.
Mineral for sewage disposal the most according to claim 6 loads biochemical materialization coupled processing method, its feature Being: in described step (1), the dosage of a modified mineral matter powder is 10000mg/L;In described step (2), No. two mineral The dosage of matter powder is 10~20mg/L;The dosage of No. three modified mineral matter powder is 5~10mg/L.
CN201610830471.4A 2016-09-19 2016-09-19 Mineral for sewage disposal loads biochemical materialization coupled processing method and system Pending CN106219907A (en)

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CN201610830471.4A CN106219907A (en) 2016-09-19 2016-09-19 Mineral for sewage disposal loads biochemical materialization coupled processing method and system

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111018092A (en) * 2019-11-28 2020-04-17 国合恒新环保江苏有限公司 Activated sludge treatment equipment of loading magnetic
CN116448501A (en) * 2023-06-20 2023-07-18 生态环境部南京环境科学研究所 Biochemical sludge and materialized sludge separate sampling device during sludge attribute identification
US12098982B1 (en) 2023-10-18 2024-09-24 Nanjing Institute Of Environmental Sciences, Mee Biochemical sludge and physicochemical sludge separate sampling device for identifying attributes of sludge

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201648175U (en) * 2009-12-01 2010-11-24 北京市市政工程设计研究总院 Biological treatment magnetic coprecipitation system
CN104556350A (en) * 2014-12-12 2015-04-29 宁波高新区围海工程技术开发有限公司 Sewage treatment chemical agent
CN205501061U (en) * 2016-03-28 2016-08-24 煤科集团杭州环保研究院有限公司 A biological densification device for high salt organic chemical industry waste water
CN206051803U (en) * 2016-09-19 2017-03-29 青岛洛克环保科技有限公司 For the biochemical materialization coupled processing system of mineral loading of sewage disposal

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201648175U (en) * 2009-12-01 2010-11-24 北京市市政工程设计研究总院 Biological treatment magnetic coprecipitation system
CN104556350A (en) * 2014-12-12 2015-04-29 宁波高新区围海工程技术开发有限公司 Sewage treatment chemical agent
CN205501061U (en) * 2016-03-28 2016-08-24 煤科集团杭州环保研究院有限公司 A biological densification device for high salt organic chemical industry waste water
CN206051803U (en) * 2016-09-19 2017-03-29 青岛洛克环保科技有限公司 For the biochemical materialization coupled processing system of mineral loading of sewage disposal

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111018092A (en) * 2019-11-28 2020-04-17 国合恒新环保江苏有限公司 Activated sludge treatment equipment of loading magnetic
CN116448501A (en) * 2023-06-20 2023-07-18 生态环境部南京环境科学研究所 Biochemical sludge and materialized sludge separate sampling device during sludge attribute identification
CN116448501B (en) * 2023-06-20 2023-08-18 生态环境部南京环境科学研究所 Biochemical sludge and materialized sludge separate sampling device during sludge attribute identification
US12098982B1 (en) 2023-10-18 2024-09-24 Nanjing Institute Of Environmental Sciences, Mee Biochemical sludge and physicochemical sludge separate sampling device for identifying attributes of sludge

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