CN106121716A - A kind of New Mine filling additive - Google Patents
A kind of New Mine filling additive Download PDFInfo
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- CN106121716A CN106121716A CN201610415726.0A CN201610415726A CN106121716A CN 106121716 A CN106121716 A CN 106121716A CN 201610415726 A CN201610415726 A CN 201610415726A CN 106121716 A CN106121716 A CN 106121716A
- Authority
- CN
- China
- Prior art keywords
- additive
- filling
- new mine
- mine filling
- slip
- Prior art date
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- Granted
Links
- 238000011049 filling Methods 0.000 title claims abstract description 46
- 230000000996 additive effect Effects 0.000 title claims abstract description 44
- 239000000654 additive Substances 0.000 title claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000003112 inhibitor Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 238000007665 sagging Methods 0.000 claims abstract description 13
- 230000002708 enhancing effect Effects 0.000 claims abstract description 7
- 238000002360 preparation method Methods 0.000 claims abstract description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 11
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 11
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical group O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 11
- 229940080314 sodium bentonite Drugs 0.000 claims description 11
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 11
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004115 Sodium Silicate Substances 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 10
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical group [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 9
- 239000003638 chemical reducing agent Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004606 Fillers/Extenders Substances 0.000 claims description 4
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims 2
- 239000002002 slurry Substances 0.000 abstract description 15
- 230000018044 dehydration Effects 0.000 abstract description 4
- 238000006297 dehydration reaction Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000005995 Aluminium silicate Substances 0.000 description 9
- 235000012211 aluminium silicate Nutrition 0.000 description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 9
- 239000002956 ash Substances 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 229920005551 calcium lignosulfonate Polymers 0.000 description 3
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229940092782 bentonite Drugs 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000010881 fly ash Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- -1 Aluminum ions Chemical class 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 206010008190 Cerebrovascular accident Diseases 0.000 description 1
- 208000006011 Stroke Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000002742 anti-folding effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21F—SAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
- E21F15/00—Methods or devices for placing filling-up materials in underground workings
- E21F15/005—Methods or devices for placing filling-up materials in underground workings characterised by the kind or composition of the backfilling material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention discloses a kind of New Mine filling additive and preparation method thereof, described New Mine filling additive is made up of pulp density regulator, fluid loss additive, sagging inhibitor, enhancing compacting agent, and the percentage by weight of its each component is as follows: pulp density regulator 35%～65%；Fluid loss additive 5～15%；Sagging inhibitor 10～20%, strengthens compacting agent 10～25%.New Mine filling additive of the present invention can significantly improve the workability of filling slurry, after adding this additive, slip the most still has good transportation performance, slip enters behind goaf and needs not move through a large amount of dehydration, and under same gel material content, slip early strength rises very fast and final comprcssive strength and can increase substantially.Filling in mine Additive Properties high efficient technology of the present invention is simple, and uses low raw-material cost, is suitable to popularization and application in filling in mine.
Description
Technical field
The present invention relates to a kind of new additive agent in filling in mine material, be specifically related to a kind of for improving filling in mine
Slip workability and the additive of each age comprcssive strength.
Background technology
The application in mining of the filling method mining technique is increasingly wider, during filling filling slurry by gravity flow or
By Pipeline transport to goaf under certain pumping pressure, due to the bleeding of filling slurry, the most easily blocking filling pipeline.
The main component of general filling slurry is filling major ingredient (tailings, flyash, gangue, building waste etc.), Binder Materials (water
Mud, rubber solid material) and water.In order to improve the workability energy of slip in stowing operation, generally require the Binder Materials that regulation adds
With the amount of water, during filling, the concentration of slip often controls within the scope of relatively low at one, thus it is mined out to cause slip to enter
Qu Houhui experiences a dehydration, and Binder Materials also can run off a part, and obturator early strength rises slow and the strongest
Degree is also greatly affected.
Slip to meet the requirement that workability is good and the early strength fast final strength of rising is high simultaneously, it is necessary to adds suitably
Additive.The features such as volume is big, concentration is low, Binder Materials volume is low, current market is there is due to filling slurry during filling in mine
Additive have that volume is big, cost is high, to improving the shortcomings such as obturator early strength effect is undesirable, limit it on a large scale
Application.
Summary of the invention
It is an object of the invention to provide a kind of new additive agent in a kind of filling in mine material, casting resin can be significantly improved
The workability of slurry, after adding this additive, slip the most still has good transportation performance, and slip enters and adopts
Needing not move through a large amount of dehydration behind dead zone, under same gel material content, slip early strength rises very fast and final
Comprcssive strength can increase substantially.
The present invention is achieved by the following technical solutions:
A kind of New Mine filling additive, by pulp density regulator, fluid loss additive, sagging inhibitor, enhancing compacting agent
Composition.
The percentage by weight of its each component is as follows: pulp density regulator 35%～65%；Fluid loss additive 5～15%；Anti-
Sedimentation agent 10～20%, strengthens compacting agent 10～25%.
Preferably, above-mentioned New Mine filling additive, the percentage by weight of its each component is as follows: pulp density regulator
40%～60%；Fluid loss additive 5～12%；Sagging inhibitor 10～15%, strengthens compacting agent 15～20%.
Preferably, above-mentioned New Mine filling additive, the percentage by weight of its each component is as follows: pulp density regulator
45%～55%；Fluid loss additive 8～10%；Sagging inhibitor 12～15%, strengthens compacting agent 15～20%.
The above pulp density regulator is lignosulfonates, naphthalenesulfonate formaldehyde condensation compound water reducer, polycarboxylic acids
One or more mixture in salt water reducer are by the mixing of any proportioning；Fluid loss additive is sodium carboxymethyl cellulose and sodium silicate
Mixture, during mixing, the quality of sodium carboxymethyl cellulose and sodium silicate is (1～2) than ratio: (2～5)；Sagging inhibitor is sodium
Base bentonite and one or both mixture kaolinic, mixed by any proportioning；Enhancing compacting agent be aluminum sulfate, sodium carbonate and
The mixture of silicon ash, during mixing, quality is aluminum sulfate than ratio: sodium carbonate: silicon ash=(3～5): (1～2): (2～5).
The preparation method of above-mentioned additive, comprises the following steps: is added with design proportioning by above-mentioned each clock raw material and is dry mixed
Machine stirring 5～10min gets product.
The application in improving filling in mine slip workability and each age comprcssive strength of the above-mentioned additive, described interpolation
Addition quality is Binder Materials in described filling slurry 0.5%～the 3% of agent.
Wherein, described concentration regulator all uses anion surfactant, in extender paste after incorporation of concentration regulator, dense
Degree regulator in hydrophobic group oriented adsorption gelling material particles surface in filling slurry, and hydrophilic group point to water-soluble
Liquid, constitutes unimolecule or multilayer adsorption film.Due to the oriented adsorption of surfactant, make filling slurry micelle surface with
The electric charge of same-sign, then under the effect that the same sex is repelled each other, not only can make filling slurry-aqueous systems be in metastable outstanding
Floating state, and, filling slurry can be made to disintegrate at the flocculence structure disperses that the initial stage of adding water is formed, discharge the freedom of parcel
Water, thus increase considerably extender paste mobility.Meanwhile, the interpolation of concentration regulator is possible not only to make the workability of extender paste to change
Kind, and owing to the filling slurry ratio of mud has decline by a relatively large margin so that it is interior pore volume significantly reduces, so that filler
Slurry solidification after obturator comprcssive strength significantly improve.
Described fluid loss additive is the mixture of sodium carboxymethyl cellulose and sodium silicate, and carboxymethyl cellulose is nonpoisonous and tasteless
White flock powder, stable performance, soluble in water, sodium carboxymethyl cellulose is that cellulose ether apoplexy due to endogenous wind yield is maximum, purposes
Extensively, using product the most easily, it is placed in slip water-retaining property and the intensity being remarkably improved slip, and sodium silicate is as one
Planting ore deposit adhesive, cohesive force is strong, intensity is higher, and under its wet environment, in absorbable slurry, moisture makes self to be in expansion shape
State, thus accelerate slip consolidation.
Described sagging inhibitor is sodium bentonite and kaolinic mixture, and sodium bentonite and Kaolin are non-as two kinds
Mineral metal products, industrially tool has been widely used, and in the present invention, sodium bentonite and Kaolin are as sagging inhibitor, institute
Mainly sodium bentonite and the kaolinic characterization of adsorption relied on, in the application the sodium carboxymethyl cellulose in fluid loss additive with
Sodium silicate one end is adsorbed onto sodium bentonite and kaolin particle surface, and the other end is dissolved in the Free water in slip, so that
Form the effect of a kind of overseas Chinese federation between sodium bentonite and kaolin particle and hydrone, reduce the Free water in slip, sodium in addition
The good peptizaiton that base bentonite and kaolin particle itself are had, it is possible to effectively prevent the gathering of slip granule, make
Obtain slip granule to be uniformly distributed, ensure the sedimentation stability of slip.It is further preferred that sodium bentonite has with Kaolin
There is the dilatancy of excellence, and the expansion volume of mine filler is by the size limitation in space, goaf, limited rear right expanding
Periphery rock mass produces certain prestressing force, and this prestressing force is possible not only to be effectively improved the intensity of ore pillar, and can effectively change
Stress distribution in kind rock mass.
Described enhancing compacting agent is aluminum sulfate, sodium carbonate and the mixture of silicon ash, and the addition of aluminum sulfate can significantly improve
Aluminum ions content in filling slurry, can significantly improve strength of filling mass especially early strength.Sodium carbonate can show after adding
Write the basicity improving serosity, the lateral reactivity of excited cementing material, be effectively improved the comprcssive strength of obturator.In silicon ash, fineness is little
Accounting for more than 80% in 1 μm, mean diameter in 0.1～0.3 μm, specific surface area is: 20～28m2/ g, its fineness and specific surface area
It is about 80～100 times of cement, 50～70 times of flyash.The hole between slip granule can be effectively filled after adding silicon ash
Gap, is combined generation gelinite simultaneously, thus improves the shoes of Binder Materials and intensity with Binder Materials hydrated product, thus aobvious
Write performances such as improving resistance to compression, anti-folding, impervious and shock resistance.
The present invention achieves following beneficial effect:
(1) the various raw material drawing of the present invention is convenient, and the prices of raw materials are cheap, need not through high temperature after the mixing of each raw material
Calcining, stirring and evenly mixing at normal temperatures, convenient enforcement；
(2) present invention is made up of pulp density regulator, fluid loss additive, sagging inhibitor, enhancing compacting agent, each constituent
Reasonable mixture ratio, cooperates and plays a role, and experimentation shows, additive of the present invention can significantly improve filling slurry and easy
Property, when this additive presses 0.5%～3% incorporation of Binder Materials in slip, slip the most still has well
Transportation performance, slip enters behind goaf and needs not move through a large amount of dehydration, slip under same gel material content
Early strength rises very fast and final comprcssive strength and can increase substantially, and without detrimental effect.
In a word, filling in mine Additive Properties high efficient technology of the present invention is simple, and uses low raw-material cost, is suitable to
Popularization and application in filling in mine.
Detailed description of the invention
Embodiment 1
By following percentage by weight preparation raw material: calcium lignosulfonate 5kg, naphthalenesulfonate formaldehyde condensation compound water reducer
55kg, sodium carboxymethyl cellulose 1kg, sodium silicate 4kg, sodium bentonite 8kg, Kaolin 7kg, aluminum sulfate 10kg, sodium carbonate
3kg, silicon ash 7kg, mix 5～10min in dry-mixed machine by above each raw material and obtain finished product.
1 material experiment index of table
Note: this experiment tailings used is the ultra-fine tailings of Zibo Jin Ling iron mine.
Embodiment 2
By following percentage by weight preparation raw material: calcium lignosulfonate 10kg, naphthalenesulfonate formaldehyde condensation compound water reducer
40kg, sodium carboxymethyl cellulose 2kg, sodium silicate 8kg, sodium bentonite 8kg, Kaolin 7kg, aluminum sulfate 8kg, sodium carbonate 3kg,
Silicon ash 6kg, mixes 5～10min in dry-mixed machine by above each raw material and obtains finished product.
2 material experiment indexs of table
Note: this experiment tailings used is the ultra-fine tailings of Zibo Jin Ling iron mine.
Embodiment 3
By following percentage by weight preparation raw material: calcium lignosulfonate 5kg, naphthalenesulfonate formaldehyde condensation compound water reducer
15kg, polycarboxylate dehydragent 40kg, sodium carboxymethyl cellulose 2kg, sodium silicate 8kg, sodium bentonite 5kg, Kaolin 5kg,
Aluminum sulfate 11kg, sodium carbonate 4kg, silicon ash 5kg, above each raw material is mixed 5～10min in dry-mixed machine and obtains finished product.
3 material experiment indexs of table
Note: this experiment tailings used is the ultra-fine tailings of Zibo Jin Ling iron mine.
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not by above-described embodiment
Limiting, one of ordinary skill in the art should be understood that, on the basis of technical scheme, those skilled in the art need not
Pay various amendments or deformation that creative work can make still in protection scope of the present invention.
Claims (10)
1. a New Mine filling additive, it is characterised in that by pulp density regulator, fluid loss additive, sagging inhibitor, increasing
Strong compacting agent composition, the percentage by weight of its each component is as follows: described pulp density regulator 35%～65%, described filtrate reducing
Agent 5～15%, described sagging inhibitor 10～20%, described enhancing compacting agent 10～25%.
2. a kind of New Mine filling additive as claimed in claim 1, it is characterised in that the percentage by weight of its each component
As follows: pulp density regulator 40%～60%；Fluid loss additive 8～12%；Sagging inhibitor 10～15%, strengthen compacting agent 15～
20%.
3. a kind of New Mine filling additive as claimed in claim 1, it is characterised in that the percentage by weight of its each component
As follows: pulp density regulator 55%～60%；Fluid loss additive 8～10%；Sagging inhibitor 12～15%, strengthen compacting agent 15～
20%.
4. a kind of New Mine filling additive as described in claim 1-3 any one, it is characterised in that described slip is dense
Degree regulator is one or more in lignosulfonates, naphthalenesulfonate formaldehyde condensation compound water reducer, polycarboxylate dehydragent
Mixture is by the mixing of any proportioning.
5. a kind of New Mine filling additive as described in claim 1-3 any one, it is characterised in that described filtrate reducing
Agent is the mixture of sodium carboxymethyl cellulose and sodium silicate, and the quality of described sodium carboxymethyl cellulose and sodium silicate is (1 than ratio
～2): (2～5).
6. a kind of New Mine filling additive as described in claim 1-3 any one, it is characterised in that described anti-settling
Agent is sodium bentonite and one or both mixture kaolinic, mixes by any proportioning.
7. a kind of New Mine filling additive as described in claim 1-3 any one, it is characterised in that described enhancing is close
Real agent is aluminum sulfate, sodium carbonate and the mixture of silicon ash, the quality of described aluminum sulfate, sodium carbonate and silicon ash than ratio be (3～
5): (1～2): (2～5).
8. the preparation method of a kind of New Mine filling additive as described in claim 1-7 any one, it is characterised in that
Take each raw material by weight adding dry-mixed machine mixing 5～10min.
9. a kind of New Mine filling additive as described in claim 1-7 any one is improving filling in mine slip with easy
Application in property and each age comprcssive strength.
10. a kind of application as claimed in claim 9, it is characterised in that the addition quality of described additive is that described mine is filled
In extender paste the 0.5%～3% of Binder Materials.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610415726.0A CN106121716B (en) | 2016-06-13 | 2016-06-13 | A kind of New Mine fills additive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610415726.0A CN106121716B (en) | 2016-06-13 | 2016-06-13 | A kind of New Mine fills additive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106121716A true CN106121716A (en) | 2016-11-16 |
| CN106121716B CN106121716B (en) | 2018-04-06 |
Family
ID=57270684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610415726.0A Active CN106121716B (en) | 2016-06-13 | 2016-06-13 | A kind of New Mine fills additive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106121716B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107725106A (en) * | 2017-11-21 | 2018-02-23 | 铜陵有色金属集团股份有限公司 | A kind of method and its application for strengthening tailings mobility |
| CN109987869A (en) * | 2019-03-13 | 2019-07-09 | 金泰成环境资源股份有限公司 | A kind of New Mine filling enhanced additive of rapid hardening |
| CN116283032A (en) * | 2022-07-29 | 2023-06-23 | 顺裕（龙岩）混凝土有限公司 | Preparation process of additive for improving workability of concrete |
| CN116515468A (en) * | 2023-04-03 | 2023-08-01 | 北京中煤矿山工程有限公司 | Coal mine goaf gangue returning slurry and preparation method thereof |
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|---|---|---|---|---|
| WO2009068380A1 (en) * | 2007-11-29 | 2009-06-04 | Construction Research & Technology Gmbh | Tunnel backfilling method |
| CN101555122A (en) * | 2009-05-20 | 2009-10-14 | 中国水利水电建设集团公司 | Antiseepage and reinforcing material of concrete |
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| CN116283032A (en) * | 2022-07-29 | 2023-06-23 | 顺裕（龙岩）混凝土有限公司 | Preparation process of additive for improving workability of concrete |
| CN116283032B (en) * | 2022-07-29 | 2024-02-27 | 顺裕（龙岩）混凝土有限公司 | Preparation process of additive for improving workability of concrete |
| CN116515468A (en) * | 2023-04-03 | 2023-08-01 | 北京中煤矿山工程有限公司 | Coal mine goaf gangue returning slurry and preparation method thereof |
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