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CN106119729A - A kind of hot investment casting bearing steel - Google Patents

A kind of hot investment casting bearing steel Download PDF

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Publication number
CN106119729A
CN106119729A CN201610679406.6A CN201610679406A CN106119729A CN 106119729 A CN106119729 A CN 106119729A CN 201610679406 A CN201610679406 A CN 201610679406A CN 106119729 A CN106119729 A CN 106119729A
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CN
China
Prior art keywords
bearing steel
steel
investment casting
hot investment
bearing
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Pending
Application number
CN201610679406.6A
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Chinese (zh)
Inventor
娄土岭
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Individual
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Individual
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Priority to CN201610679406.6A priority Critical patent/CN106119729A/en
Publication of CN106119729A publication Critical patent/CN106119729A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Rolling Contact Bearings (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention discloses a kind of hot investment casting bearing steel, it is to comprise the following components in percentage by weight: C:0.95 1.02%, Si:0.15 0.25%, Mn:0.55 0.75%, S:0.03 0.05%, Cr:14 17%, P:0.01 0.02%, Al:0.020 0.035%, N:0.30 0.40%, Mo:0.8 1.0%, surplus is Fe and inevitable impurity, its decay resistance of bearing steel of the prior art and the performance such as wear-resisting all can not meet use requirement, the present invention is by carbon, nitrogen, chromium, molybdenum rational proportion, material is made well to be provided with corrosion-proof wear heat resistance, good mechanical performance and fatigue strength.

Description

A kind of hot investment casting bearing steel
Technical field
The invention belongs to bearing steel field, be specifically related to a kind of hot investment casting bearing steel.
Background technology
Bearing is the device allowing to carry out between two parts constrained relative motion.It is widely used in Aeronautics and Astronautics, state The fields such as anti-, heavy mechanical equipment, most important parts in various mechanical mechanisms.Bearing life is to pass judgment on bearing quality key Index, current bearing commonly uses casting method molding, and precision casting is a kind of to exempt from processing or the least foundry goods of allowance Product, prescription is higher.Bearing is connection member parts important in mechanical part.But, the bearing precision of prior art There is following point in casting: the metallographic of product and hardness, intensity and elongation percentage all do not reach use requirement.
Along with present equipment manufacture industry develops, bearing is gradually by the research of the research steering material of precision, so the highest End bearing research is basically the research of bearing material.Along with machinery manufacturing industry, particularly automobile, aviation, atomic energy industry Deng develop rapidly, the performance requirement of bearing is improved constantly, if desired for high temperature, at a high speed, under high load capacity, the harsh conditions such as anti-corrosion The special bearing of work.For adapting to the demand of these bearings, various countries in succession develop and develop a collection of has the new of property Steel grade, defines the bearing materials such as high-carbon-chromium bearing steel, carburizing bearing steel, stainless bearing steel, high-temperature bearing steel.
Roll shaft parts to contract containing interior raceway and outer raceway and the rolling part being disposed there between in a large number.Different zero Part, to rolling contact fatigue, abrasion and creep toleration, depends on required product made from steel application, and modern steel uses ferrum and alloy unit Element various combinations and manufacture.Although common stainless bearing steel anticorrosion effect in air and weak corrosive medium is pretty good, and tool There are good resistance to elevated temperatures and contact fatigue strength, but under some badly applying working condition, its decay resistance and wear-resisting Performance all can not meet use requirement.
At present, the bearing material being on active service in a corrosive environment, the hardness of major part austenitic stainless steel is low, even if cold-working Hardening, hardness is the highest, and producting process difficulty is big;Precipitation-hardening stainless steel, its hardness can not meet use, heat treatment very well Complex process, this two classes steel can not meet the requirement of service condition under corrosive atmosphere.Partial martensite stainless bearing steel is stainless Although steel has the feature that hardness is high, but phosphorus content is higher, and in tissue, eutectic carbide is formed more, and granule is thick, skewness Even, major part is distributed on crystal boundary, and eutectic carbide peels off from finished surface, forms pit, affects surface quality and processing essence Degree, and in use, form stress at eutectic carbide and concentrate and produce fatigue crack.
Summary of the invention
Defect based on prior art, it is an object of the invention to provide and a kind of can improve the wear-resisting of bearing, corrosion-resistant, resistance to High temperature, low cost, easily the rust-proofing hot investment casting bearing steel of processing.
In order to achieve the above object, the present invention is by the following technical solutions: a kind of hot investment casting bearing steel, it is by following The component composition of percentage by weight: C:0.95-1.02%, Si:0.15-0.25%, Mn:0.55-0.75%, S:0.035-0.05%, Cr:14-17%, P:0.01-0.02%, Al:0.020-0.035%, N:0.30-0.40%, Mo:0.8-1.0%, surplus is Fe and not Evitable impurity.
The most described hot investment casting bearing steel, it is to comprise the following components in percentage by weight: C:0.99%, Si: 0.20%, Mn:0.65%, S:0.04%, Cr:15%, P:0.015%, Al:0.025%, N:0.35%, Mo:0.9%, surplus be Fe and Inevitably impurity.
Preferred described hot investment casting bearing steel is to sequentially pass through 910-1000 DEG C of quenching, 165 DEG C of tempering heat treatment, tempering Tissue matrix is tempered martensite, Dispersed precipitate eutectic carbide on tempered martensite matrix.
The effect of its each component of the bearing steel of the present invention and the restriction reason of scope are as described below:
Carbon: the carbon content hardness to the parts of bearings after quenching, maintains the intensity under parts of bearings room temperature, high temperature, and improves The necessary element of cold-workability.The relation that Carbon Solubility and chromium concn are inversely proportional to, inventor finds through overtesting: if carbon weight Percentage ratio increases, then the carbon content in final composition is likely to reduced, when the carbon content in bearing steel is more than 0.95%, Without introducing substantial amounts of carbon in steel by heat treatment, also can obtain the amount of enough hardness and carbide, when carbon content exceedes When 1.02%, forming big carbide when the manufacture of steel, this carbide can have a strong impact on the rolling contact fatigue characteristic of parts of bearings And mar proof.
Silicon: the element that silicon is useful with improving hardenability to the solution strengthening of base material, inventor finds through overtesting: work as bearing The hold-up of the hydrogen in steel can be made when silicone content in steel is 0.15%-0.25% to increase and accelerate hydrogen embrittlement, and when in bearing steel When silicone content is more than 0.25%, hydrogen is easily accessible in steel, is susceptible to the peeling caused by hydrogen embrittlement, and cold-workability significantly reduces.
Manganese: manganese is the solution strengthening to base material and improves the useful element of hardenability, before manganese is to the quenching degree of steel and quenching The hardness of steel have contribution.Inventor finds through overtesting: when Fe content is 0.55%-0.75%, and the hardness of quenched materials is high, When Fe content is more than 0.75%, cold-workability reduces.
Phosphorus: phosphorus is the element contained as inevitable impurity, and it is at cyrystal boundary segregation, makes cold-workability low, should use up Amount reduces the content of phosphorus, but, too much reduction can cause steel cost processed to increase, and the phosphorus selected by the present invention is in the range of 0.01- 0.02%, the bearing steel combination property prepared is optimum.
Sulfur: sulfur is the element contained as inevitable impurity, it separates out at crystal boundary as FeS, is to make cold working The element that property is low.It addition, the chemical bonding such as sulfur and manganese, forming the non-metallic inclusions such as such as Manganese monosulfide. and separate out, this is nonmetal Field trash can have a strong impact on the life-span of bearing, makes rolling contact fatigue characteristic low, therefore, should reduce its content as far as possible, but, mistake Many reductions can cause steel cost processed to increase, and the phosphorus selected by the present invention is in the range of 0.035-0.05%, and prepared bearing steel is comprehensive Can be optimum.
Chromium: chromium is conventional alloying element, for against corrosion and rust-proofing.Chromium and carbon combine and form carbide, are that raising is wear-resisting Damage property and the element of cold-workability, chromium is the element of easy segregation, and therefore, when chromium content is more than 17%, thick carbide is raw Becoming, rolling contact fatigue characteristic is the lowest.
Aluminum: aluminum is effective as deoxidant element, reduces the oxygen amount in steel, has the effect improving rolling contact fatigue characteristic, improves The element of rolling contact fatigue characteristic, control Al content is in the range of 0.020 0.035%, in the effect ensureing Al crystal grain thinning While, be unlikely to have too much Al, form oxide, nitride reduces the performance of material.
Molybdenum: molybdenum gives the toughness of the bearing steel in heavy service, and provides heat-resisting alloy especially.Inventor is through examination Issuing after examination and approval existing: when molybdenum content is 0.8-1.0%, molybdenum can combine other alloying elements, improves bearing steel mechanical performance such as hardness Deng.
Nitrogen: nitrogen forms nitride non-metallic inclusion by being combined with aluminum, makes austenite crystal miniaturization, thus carries High tenacity and rolling fatigue life characteristic, when high temperature, during steel processing, the nitrogen concentration in austenite depends on chromium, manganese and molybdenum Concentration, therefore, it is difficult to introduce in compositions by more nitrogen, unless increased the content of these alloying elements.Inventor is through examination Issue after examination and approval existing: when adding more than 0.4%, steel exists nitride field trash in large quantities, therefore causes rolling fatigue life Characteristic reduces.It addition, there is the nitrogen not generated with nitride form in steel in large quantities, thus toughness is caused to reduce.
The present invention, by carbon, nitrogen, chromium, molybdenum rational proportion, makes material well be provided with corrosion-proof wear heat resistance, Reasonable The carbon of ratio can guarantee that quench tempering hardness and the toughness of material, for increasing the hardness of the steel part formed, the nitrogen of rational proportion Solid solution strength and the corrosion resisting property of steel can be improved, be simultaneously introduced appropriate chromium, molybdenum further increases the intensity of steel, hardness, anti-corrosion, The physico mechanical characteristics such as heatproof, while ensureing cryogenic property, also ensure that good hardness and wearability, and good Mechanical performance and fatigue strength;By to constituting the chromium that bearing steel interpolation is appropriate, it is possible to suppression fragility is peeled off, therefore, it is possible to real The prolongation of existing bearing life, and it is capable of reducing the effect of cost;Stainless bearing steel of the present invention is through 910- 1000 DEG C of hardening heats, under the temperature of 165 DEG C, have stable Rockwell hardness, and meansigma methods maintains 60 HRC;This Bright bearing steel also has excellent resistance to rolling characteristic, it is possible to meets the manufacture of the bearing steel of various functional requirement, thus brings Industrially beneficial effect.And bearing steel structural homogenity is good, machining accuracy is high;Compared with other high alloy materials, The cost of the bearing steel of the present invention is relatively low.
Detailed description of the invention
Being described in further details the present invention below by embodiment, embodiment is only used for the present invention is described, does not limit The scope of the present invention processed.
Embodiment 1: a kind of hot investment casting bearing steel, it is to comprise the following components in percentage by weight: C:0.95%, Si: 0.15%, Mn:0.55%, S:0.035%, Cr:14%, P:0.01%, Al:0.020%, N:0.30%, Mo:0.8%, surplus be Fe and Inevitably impurity, described hot investment casting bearing steel is to sequentially pass through 910 DEG C of quenchings, 165 DEG C of tempering heat treatment, tempered structure Matrix is tempered martensite, Dispersed precipitate eutectic carbide on tempered martensite matrix.
Embodiment 2: a kind of hot investment casting bearing steel, it is to comprise the following components in percentage by weight: C:0.99%, Si: 0.20%, Mn:0.65%, S:0.04%, Cr:15%, P:0.015%, Al:0.025%, N:0.35%, Mo:0.9%, surplus be Fe and Inevitably impurity, described hot investment casting bearing steel is to sequentially pass through 990 DEG C of quenchings, 165 DEG C of tempering heat treatment, tempered structure Matrix is tempered martensite, Dispersed precipitate eutectic carbide on tempered martensite matrix.
Embodiment 3: a kind of hot investment casting bearing steel, it is to comprise the following components in percentage by weight: C:1.02%, Si: 0.25%, Mn:0.75%, S:0.05%, Cr:17%, P:0.02%, Al:0.035%, N:0.40%, Mo:1.0%, surplus is Fe and not Evitable impurity, described hot investment casting bearing steel is to sequentially pass through 1000 DEG C of quenchings, 165 DEG C of tempering heat treatment, tempered structure Matrix is tempered martensite, Dispersed precipitate eutectic carbide on tempered martensite matrix.
Embodiment 4: this embodiment is widely used conventional bearings steel 9Cr18 in prior art, and it is by following weight The component composition of percentage ratio: C:0.9-1.0%, Si :≤0.8, Mn :≤0.8, S :≤0.030, Cr:17.00-19.00%, surplus For Fe and inevitable impurity.
Table one is the contact fatigue life of each embodiment bearing steel, decay resistance result of the test:
Table one
The performance test results of the embodiment 1,2,3,4 from table one it can be seen that embodiment of the present invention 1,2,3 not Rust Contact Fatigue Life of Bearing Steel is far above the 9Cr18 bearing steel of embodiment 4, and corrosion resistance is also superior to comparative example's 4 9Cr18 bearing steel.

Claims (3)

1. a hot investment casting bearing steel, it is characterised in that it is to comprise the following components in percentage by weight: C:0.95- 1.02%, Si:0.15-0.25%, Mn:0.55-0.75%, S:0.035-0.05%, Cr:14-17%, P:0.01-0.02%, Al: 0.020-0.035%, N:0.30-0.40%, Mo:0.8-1.0%, surplus is Fe and inevitable impurity.
Hot investment casting bearing steel the most according to claim 1, it is characterised in that it is by the group of following weight percents It is grouped into: C:0.99%, Si:0.20%, Mn:0.65%, S:0.04%, Cr:15%, P:0.015%, Al:0.025%, N:0.35%, Mo:0.9%, surplus is Fe and inevitable impurity.
The bearing steel of hot investment casting the most according to claim 1, it is characterised in that: described hot investment casting bearing steel is successively Through 910-1000 DEG C of quenching, 165 DEG C of tempering heat treatment, tempered structure matrix is tempered martensite, on tempered martensite matrix Dispersed precipitate eutectic carbide.
CN201610679406.6A 2016-08-18 2016-08-18 A kind of hot investment casting bearing steel Pending CN106119729A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115109891A (en) * 2022-07-14 2022-09-27 中北大学 High-carbon high-chromium nitrogen-containing martensitic stainless steel and carbide refining method thereof
CN117778894A (en) * 2024-02-01 2024-03-29 扬州三劦紧固件有限公司 Heat-resistant high-strength fastener material and preparation system thereof

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Publication number Priority date Publication date Assignee Title
JP2000226641A (en) * 1999-02-05 2000-08-15 Nsk Ltd Rolling device
US6143425A (en) * 1995-10-19 2000-11-07 Nsk Ltd. Rolling bearing and rolling device
CN1458983A (en) * 2000-07-17 2003-11-26 株式会社理研 Piston ring excellent in resistance to scuffing, cracking and fatigue and method for producing same, and combination of piston ring and cylinder block
CN101033527A (en) * 2007-04-16 2007-09-12 大连伯新特钢制品有限公司 High-chromium medium-carbon stainless steel and manufacturing method thereof
CN101376948A (en) * 2007-08-27 2009-03-04 宝山钢铁股份有限公司 Low-cost high-purity medium carbon bearing steel for automobile hub and manufacturing method thereof
CN102766814A (en) * 2012-01-29 2012-11-07 宝山钢铁股份有限公司 Stainless bearing steel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143425A (en) * 1995-10-19 2000-11-07 Nsk Ltd. Rolling bearing and rolling device
JP2000226641A (en) * 1999-02-05 2000-08-15 Nsk Ltd Rolling device
CN1458983A (en) * 2000-07-17 2003-11-26 株式会社理研 Piston ring excellent in resistance to scuffing, cracking and fatigue and method for producing same, and combination of piston ring and cylinder block
CN101033527A (en) * 2007-04-16 2007-09-12 大连伯新特钢制品有限公司 High-chromium medium-carbon stainless steel and manufacturing method thereof
CN101376948A (en) * 2007-08-27 2009-03-04 宝山钢铁股份有限公司 Low-cost high-purity medium carbon bearing steel for automobile hub and manufacturing method thereof
CN102766814A (en) * 2012-01-29 2012-11-07 宝山钢铁股份有限公司 Stainless bearing steel

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郑滔: "高氮不锈轴承钢的组织与性能研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115109891A (en) * 2022-07-14 2022-09-27 中北大学 High-carbon high-chromium nitrogen-containing martensitic stainless steel and carbide refining method thereof
CN115109891B (en) * 2022-07-14 2022-12-20 中北大学 High-carbon high-chromium nitrogen-containing martensitic stainless steel and carbide refining method thereof
CN117778894A (en) * 2024-02-01 2024-03-29 扬州三劦紧固件有限公司 Heat-resistant high-strength fastener material and preparation system thereof

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Application publication date: 20161116