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CN106118141A - A kind of inorganic polymeric coating with zeolite as adsorbent and preparation method - Google Patents

A kind of inorganic polymeric coating with zeolite as adsorbent and preparation method Download PDF

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Publication number
CN106118141A
CN106118141A CN201610438529.0A CN201610438529A CN106118141A CN 106118141 A CN106118141 A CN 106118141A CN 201610438529 A CN201610438529 A CN 201610438529A CN 106118141 A CN106118141 A CN 106118141A
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China
Prior art keywords
powder
zeolite
parts
adsorbent
inorganic polymeric
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Pending
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CN201610438529.0A
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Chinese (zh)
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王聚会
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Priority to CN201610438529.0A priority Critical patent/CN106118141A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/06Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement
    • C09D1/08Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement with organic additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of inorganic polymeric coating with zeolite as adsorbent, being that material mixes by sierozem power, dicalcium powder, natural zeolite powder, Pulvis Talci, white cement, titanium dioxide and methylcellulose, its proportioning is as follows: sierozem power 10 20 parts, dicalcium powder 15 25 parts, zeolite powder 10 20 parts, white cement 5 15 parts, Pulvis Talci 25 35 parts, titanium dioxide 5 15 parts, cellulose 12 parts, toner are appropriate.The present invention 1, unique environmental protection characteristic, nonpoisonous and tasteless, inorganic environment-friendly;2, scalable indoor air humidity;3, zeolite has bigger specific surface area, and the internal stress field produced can be adsorbed the harmful gass such as indoor formaldehyde, be purified the air of a room;4, mushroom and bryophyte spores can be killed;5, having heat insulation, the wearability of excellence, resistance to chemical attack ability is strong;6, resistance to sassafras washes performance by force, has the resistance to water of height;7, there is excellent workability;8, by force, inner-outer wall is constructed for good weatherability, resistance to water.

Description

A kind of inorganic polymeric coating with zeolite as adsorbent and preparation method
Technical field
The present invention relates to the decoration for building inside and outside wall, it is achieved the dry powder of the construction technologies such as blade coating, bullet painting, silk screen printing Polymeric coatings, a kind of inorganic polymeric coating with zeolite as adsorbent and preparation method.
Background technology
Zeolite group mineral is found in 1756, is by this special (Cronstedt) research Iceland Black Warrior of Sweden's mineralogist's crown Find in its hole during rock.It is named zeolite owing to foaming when it has fine idiomorphic crystal and blowpipe heating (Zeolite).Natural zeolite be by original aluminum silicate material magma late, hydrothermal alteration, contact metasomatism, deposition diagenesis, Go bad and air slaking hypergene process each stage, the mineral formed in the presence of water.Most important of which mineralizing process is middle acidity Volcanic glass material under the effect of alkaline aqueous medium through aquation, hydrolyze, react and crystallize into Piper pulicatulum C. D C. and become.
Natural zeolite has internal structure and the Crystallochemical Properties of uniqueness so that it is have water suction, absorption, acidproof and resistance to spoke The performance such as penetrate.A large amount of holes of zeolite crystal and passage make zeolite have the biggest specific surface area, and zeolite internal cavities has should The field of force, and the material of surrounding is had the strongest adsorption, the harmful gas in house ornamentation can be adsorbed.
Therefore, zeolite is applied to inorganic polymeric coating, has been a good problem to study.
Summary of the invention
In order to overcome above-mentioned deficiency of the prior art, the invention provides a kind of will have intensity high, water-fast, alkaline-resisting, The performance that fire-resistant, environmental protection etc. are excellent;Zeolite with adsorbing indoor harmful gases, can purify the effect of air as porous material simultaneously The inorganic polymeric coating with zeolite as adsorbent and preparation method.
The object of the present invention is achieved like this:
A kind of inorganic polymeric coating with zeolite as adsorbent, by sierozem power, dicalcium powder, natural zeolite powder, Pulvis Talci, white Cement, titanium dioxide and methylcellulose are that material mixes,
Its proportioning of described material is as follows: sierozem power 10-20 part, dicalcium powder 15-25 part, zeolite powder 10-20 part, white cement 5-15 part, Pulvis Talci 25-35 part, titanium dioxide 5-15 part, cellulose 1-2 part, toner are appropriate;
Described sierozem power is the 400 above powder body of mesh, and dicalcium powder is the 1250 above powder body of mesh, and zeolite powder is more than 1000 mesh Powder body;
The preparation method of the described inorganic polymeric coating with zeolite as adsorbent, by sierozem power, dicalcium powder, zeolite powder, White cement, Pulvis Talci, titanium dioxide are pressed configuration proportion and are added dry powder agitator stirring 10 minutes, make powder mix homogeneously to wrap Dress, prepares inorganic polymeric dry powder paint;
The using method of the described inorganic polymeric coating with zeolite as adsorbent, is 0.4-0.5 according to the solid weight ratio of water Weigh water, water can be used with powder mixing and stirring.
Actively beneficial effect: 1, unique environmental protection characteristic, nonpoisonous and tasteless, inorganic environment-friendly;2, room air can be regulated wet Degree;3, high adsorption: zeolite has bigger specific surface area, and the internal stress field produced can be adsorbed indoor formaldehyde etc. and be had Do harm to gas, purify the air of a room;4, mushroom and bryophyte spores can be killed, even if the most also will not rise mould for a long time Speckle;5, having heat insulation, the wearability of excellence, resistance to chemical attack ability is strong;6, resistance to sassafras washes performance by force, has height after the construction of this product The resistance to water of degree, available water is directly rinsed or wet rag is cleaned;7, there is excellent workability, it is possible to achieve multiple construction work Skill;8, by force, inner-outer wall is constructed for good weatherability, resistance to water.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further:
A kind of inorganic polymeric coating with zeolite as adsorbent, by sierozem power, dicalcium powder, natural zeolite powder, Pulvis Talci, white Cement, titanium dioxide and methylcellulose are that material mixes,
Its proportioning of described material is as follows: sierozem power 10-20 part, dicalcium powder 15-25 part, zeolite powder 10-20 part, white cement 5-15 part, Pulvis Talci 25-35 part, titanium dioxide 5-15 part, cellulose 1-2 part, toner are appropriate;
Described sierozem power is the 400 above powder body of mesh, and dicalcium powder is the 1250 above powder body of mesh, and zeolite powder is more than 1000 mesh Powder body;
The preparation method of the described inorganic polymeric coating with zeolite as adsorbent, by sierozem power, dicalcium powder, zeolite powder, White cement, Pulvis Talci, titanium dioxide are pressed configuration proportion and are added dry powder agitator stirring 10 minutes, make powder mix homogeneously to wrap Dress, prepares inorganic polymeric dry powder paint;
The using method of the described inorganic polymeric coating with zeolite as adsorbent, is 0.4-0.5 according to the solid weight ratio of water Weigh water, water can be used with powder mixing and stirring.
Embodiment 1
Ash calcium 20 parts, triple superphosphate 15 parts, 20 parts of zeolite, white cement 5 parts, Pulvis Talci 25 parts, titanium dioxide 15 parts, hydroxypropyl methyl Cellulose 1.5 parts, adds batch mixer, the nothing that stirring can be prepared by with zeolite as adsorbent for 10 minutes by each raw material of accurate measurement Machine polymeric coatings.By prepared inorganic polymeric coating according to coating: water is to add water at 1: 0.4, stirs and can construct.
Embodiment 2
Sierozem power 15 parts, dicalcium powder 20 parts, 20 parts of zeolite, white cement 10 parts, Pulvis Talci 35 parts, titanium dioxide 5 parts, toner 3 Part, hydroxypropyl methyl cellulose 1 part;Each raw material of accurate measurement is added batch mixer, stirs and can be prepared by with zeolite for 10 minutes Inorganic polymeric coating for adsorbent.By prepared inorganic polymeric coating according to coating: water is to add water at 1: 0.4, stirs i.e. Can construct.
The inorganic polymeric colour-wash prepared can use different construction technologies according to different requirements, can be used for scratching, bullet The construction technology such as painting, cloudy quarter, sun quarter, silk screen printing, it is achieved graceful decorative effect.
Grey calcium and white cement both materials in the present invention itself have the highest activity, are a kind of Binder Materials, ash Calcium is a kind of air hardening cementitious materials, and white cement is a kind of hydraulic cementing materials;Formed simultaneously because zeolite is slag The aluminium silicate mineral of a kind of rack-like structure, there is good Pozzolanic feature, ash calcium be mainly composed of calcium hydroxide, hydrogen-oxygen Change calcium and zeolite powder in overbasic solution by OH-Erosion, its screen work columnar structure start decompose, there is following reaction;
3+Si-O-Si3++6OH-→2[SiO(OH)3]-
3+Si-O-Al3++7OH-→[SiO(OH)3]-+[Al(OH)4]-
[SiO (OH) after depolymerization3]-[Al (OH)4]-Enter solution and Ca2+In conjunction with forming hydrated calcium silicate and aquation Calcium aluminate.Hydrated calcium silicate and drated calcium aluminate and white cement are all Binder Materials, are the inorganic filming substance matter of this product, have The excellent performances such as intensity is high, water-fast, alkaline-resisting, fire-resistant, environmental protection;Zeolite can be with gas harmful in adsorption chamber as porous material simultaneously Body, purifies the effect of air;
The products characteristics of the present invention: 1, unique environmental protection characteristic, nonpoisonous and tasteless, inorganic environment-friendly;2, Interior Space can be regulated Air humidity degree;3, high adsorption: zeolite has bigger specific surface area, and the internal stress field produced can adsorb indoor formaldehyde Etc. harmful gas, purify the air of a room;4, mushroom and bryophyte spores can be killed, even if the most also will not rise for a long time Mildew;5, having heat insulation, the wearability of excellence, resistance to chemical attack ability is strong;6, resistance to sassafras washes performance by force, has after the construction of this product The resistance to water of height, available water is directly rinsed or wet rag is cleaned;7, there is excellent workability, it is possible to achieve multiple construction Technique;8, by force, inner-outer wall is constructed for good weatherability, resistance to water.

Claims (5)

1. the inorganic polymeric coating with zeolite as adsorbent, it is characterised in that: by sierozem power, dicalcium powder, natural zeolite powder, Pulvis Talci, white cement, titanium dioxide and methylcellulose are that material mixes.
A kind of inorganic polymeric coating with zeolite as adsorbent the most according to claim 1, it is characterised in that: described thing Expect that its proportioning is as follows: sierozem power 10-20 part, dicalcium powder 15-25 part, zeolite powder 10-20 part, white cement 5-15 part, Pulvis Talci 25- 35 parts, titanium dioxide 5-15 part, cellulose 1-2 part, toner appropriate.
A kind of inorganic polymeric coating with zeolite as adsorbent the most according to claim 1, it is characterised in that: described ash Calcium powder is the 400 above powder body of mesh, and dicalcium powder is the 1250 above powder body of mesh, and zeolite powder is the 1000 above powder body of mesh.
4. the preparation method of the inorganic polymeric coating with zeolite as adsorbent as claimed in claim 1, it is characterised in that: by ash Calcium powder, dicalcium powder, zeolite powder, white cement, Pulvis Talci, titanium dioxide are pressed configuration proportion and are added dry powder agitator stirring 10 minutes, make Powder mix homogeneously can be packed, and prepares inorganic polymeric dry powder paint.
5. the using method of the inorganic polymeric coating with zeolite as adsorbent as claimed in claim 1, it is characterised in that: according to The solid weight ratio of water is that 0.4-0.5 weighs water, can be used with powder mixing and stirring by water.
CN201610438529.0A 2016-06-20 2016-06-20 A kind of inorganic polymeric coating with zeolite as adsorbent and preparation method Pending CN106118141A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107555848A (en) * 2017-09-09 2018-01-09 李长松 A kind of zeolite sea bubble slime paint
CN107663039A (en) * 2017-09-26 2018-02-06 浙江沃华环境科技有限公司 Novel healthy environment protection coating
CN108821679A (en) * 2018-06-26 2018-11-16 郑州高聚粉体科技有限公司 A kind of inorganic ecological wall material and preparation method thereof to be purified the air of a room by releasing negative oxygen ion
CN109351146A (en) * 2018-09-20 2019-02-19 郑州聚合缘新材料科技有限公司 Air purifying ball, the preparation method of air purifying ball and air purifier
CN111849335A (en) * 2020-08-11 2020-10-30 中科沸石(成都)科技有限公司 Negative ion zeolite coating film and preparation method thereof
CN111849358A (en) * 2020-08-11 2020-10-30 中科沸石(成都)科技有限公司 Environment-friendly negative ion zeolite surface coating agent and preparation method thereof
CN111876079A (en) * 2020-08-11 2020-11-03 中科沸石(成都)科技有限公司 Environment-friendly negative ion zeolite primer and preparation method thereof
CN112831229A (en) * 2021-02-01 2021-05-25 贵州中亚高科涂料有限公司 Multifunctional environment-friendly exterior wall paint

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1204671A (en) * 1997-07-04 1999-01-13 曹岩 Coating capable of waterproof seepage control and leakproof
CN103709799A (en) * 2013-12-13 2014-04-09 广州市维多纳环保科技有限公司 Inorganic multifunctional paint taking potassium silicate as film-forming substance, and preparation method thereof
CN104177975A (en) * 2013-05-24 2014-12-03 青岛极致节能环保有限公司 An environmental-friendly building external-wall coating material
CN105273480A (en) * 2015-10-23 2016-01-27 广西兴安县桂兴矿粉厂 Water-resistant putty powder as well as preparation and use methods thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1204671A (en) * 1997-07-04 1999-01-13 曹岩 Coating capable of waterproof seepage control and leakproof
CN104177975A (en) * 2013-05-24 2014-12-03 青岛极致节能环保有限公司 An environmental-friendly building external-wall coating material
CN103709799A (en) * 2013-12-13 2014-04-09 广州市维多纳环保科技有限公司 Inorganic multifunctional paint taking potassium silicate as film-forming substance, and preparation method thereof
CN105273480A (en) * 2015-10-23 2016-01-27 广西兴安县桂兴矿粉厂 Water-resistant putty powder as well as preparation and use methods thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107555848A (en) * 2017-09-09 2018-01-09 李长松 A kind of zeolite sea bubble slime paint
CN107663039A (en) * 2017-09-26 2018-02-06 浙江沃华环境科技有限公司 Novel healthy environment protection coating
CN108821679A (en) * 2018-06-26 2018-11-16 郑州高聚粉体科技有限公司 A kind of inorganic ecological wall material and preparation method thereof to be purified the air of a room by releasing negative oxygen ion
CN109351146A (en) * 2018-09-20 2019-02-19 郑州聚合缘新材料科技有限公司 Air purifying ball, the preparation method of air purifying ball and air purifier
CN111849335A (en) * 2020-08-11 2020-10-30 中科沸石(成都)科技有限公司 Negative ion zeolite coating film and preparation method thereof
CN111849358A (en) * 2020-08-11 2020-10-30 中科沸石(成都)科技有限公司 Environment-friendly negative ion zeolite surface coating agent and preparation method thereof
CN111876079A (en) * 2020-08-11 2020-11-03 中科沸石(成都)科技有限公司 Environment-friendly negative ion zeolite primer and preparation method thereof
CN112831229A (en) * 2021-02-01 2021-05-25 贵州中亚高科涂料有限公司 Multifunctional environment-friendly exterior wall paint

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Application publication date: 20161116