CN106098389B - The preparation method containing platinum electrode that automobile batteries uses - Google Patents
The preparation method containing platinum electrode that automobile batteries uses Download PDFInfo
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- CN106098389B CN106098389B CN201610535846.4A CN201610535846A CN106098389B CN 106098389 B CN106098389 B CN 106098389B CN 201610535846 A CN201610535846 A CN 201610535846A CN 106098389 B CN106098389 B CN 106098389B
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims abstract description 140
- 229910052697 platinum Inorganic materials 0.000 title claims abstract description 70
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 55
- 239000010931 gold Substances 0.000 claims abstract description 55
- 229910052737 gold Inorganic materials 0.000 claims abstract description 55
- 239000011521 glass Substances 0.000 claims abstract description 53
- 239000000758 substrate Substances 0.000 claims abstract description 53
- 239000010409 thin film Substances 0.000 claims abstract description 28
- 238000004544 sputter deposition Methods 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000007921 spray Substances 0.000 claims abstract description 14
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 52
- -1 dimethyl methyl Chemical group 0.000 claims description 37
- 239000002253 acid Substances 0.000 claims description 26
- 150000001412 amines Chemical class 0.000 claims description 26
- 238000007789 sealing Methods 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000002245 particle Substances 0.000 claims description 13
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 13
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 13
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical compound OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 claims description 13
- 229940048102 triphosphoric acid Drugs 0.000 claims description 13
- 230000005611 electricity Effects 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract description 52
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract description 13
- 239000011248 coating agent Substances 0.000 abstract description 13
- 238000000576 coating method Methods 0.000 abstract description 13
- 238000000151 deposition Methods 0.000 abstract description 13
- 230000008021 deposition Effects 0.000 abstract description 13
- 229910052731 fluorine Inorganic materials 0.000 abstract description 13
- 239000011737 fluorine Substances 0.000 abstract description 13
- 150000007513 acids Chemical class 0.000 description 22
- 239000007788 liquid Substances 0.000 description 11
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- DWCSHJVWTDQUCJ-UHFFFAOYSA-N prop-1-ene;pyrrolidin-2-one Chemical class CC=C.O=C1CCCN1 DWCSHJVWTDQUCJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
- H01G9/2063—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution comprising a mixture of two or more dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Hybrid Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
- Chemically Coating (AREA)
Abstract
The preparation method containing platinum electrode that a kind of automobile batteries uses:Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass is the SnO2 transparent conducting glass (SnO2 for adulterating fluorine：F), referred to as FTO）The metal gold thin film of upper one layer of coating, used instrument is 1010 ion sputtering instruments of HitachiE, and the parameter of setting is 12 Pa of pressure, 14 mA of electric current, 25 s of time, the purpose of one layer of gold thin film of spray are to make subsequent platinum deposition that can be grown since the surface of FTO using gold as seed.
Description
Technical field
The present invention relates to a kind of battery electrodes, are particularly applied to the preparation method containing platinum electrode of automobile batteries.
Background technology
Metal platinum has very strong corrosion resistance, after covering on electrode, can promote battery performance and service life, but existing
Complex process of the preparation containing platinum electrode, energy consumption is high, is unfavorable for heavy industrialization.
Invention content
The technical problem to be solved by the present invention is to propose a kind of completely new preparation method, simplification of flowsheet is improved and is prepared
Efficiency.
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.1mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Specific embodiment
Embodiment 1:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.1mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 2:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.2mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 3:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.3mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 4:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.4mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 5:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.5mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 6:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.6mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 7:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.7mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 8:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.8mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 9:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.9mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 10:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 2.0mL chloroplatinic acids（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL methylamine solutions
（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is become gradually by water white transparency
For yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL chloroplatinic acids（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polypropylene pyrroles
Alkanone, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, it is molten
Liquid graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Embodiment 11:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1：By ion sputtering process in FTO conducting glass substrates（FTO electro-conductive glass, which is that the SnO2 of doping fluorine is transparent, leads
Electric glass (SnO2：F), referred to as FTO）One layer of metal gold thin film of upper coating, used instrument for HitachiE-1010 from
Sub- sputter, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, and the purpose of one layer of gold thin film of spray is using gold as kind
Son makes subsequent platinum deposition that can be grown since the surface of FTO；
Step 2：By 1.0mL（It can also be selected from following amounts：1.1ml, 1.2ml, 1.3ml, 1.4ml, 1.5ml,
1.6ml.1.7ml, 1.8ml, 1.9ml, 2.0ml）Chloroplatinic acid（A concentration of 20mg/mL）, 0.4g polyvinylpyrrolidones, 0.2mL
Methylamine solution（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is uniformly mixed, solution is by colourless
It is bright to graduate into yellow turbid solution；
Step 3：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while prepared by step 1
The FTO substrate of glass containing gold particle be face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, is contained so as to which primary be made
Platinum electrode.
Step 5：By 1.0mL（It can also be selected from following amounts：1.1ml, 1.2ml, 1.3ml, 1.4ml, 1.5ml,
1.6ml.1.7ml, 1.8ml, 1.9ml, 2.0ml）Chloroplatinic acid（A concentration of 20mg/mL）, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g gathers
Propylene pyrrolidones, 0.2mL methylamine solutions（A concentration of 20mg/mL）With 20mL dimethyl methyl phthalein amine（A concentration of 10mg/mL）It is mixed
It closes uniformly, solution graduates into yellow turbid solution by water white transparency；
Step 6：Above-mentioned mixed liquor is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while prepared by step 4
Primary be face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to which finished product contains
Platinum electrode.
Claims (2)
1. a kind of preparation method containing platinum electrode that automobile batteries uses:
Step 1：One layer of metal gold thin film, used instrument are coated on FTO conducting glass substrates by ion sputtering process
For HitachiE-1010 ion sputtering instruments, the parameter of setting is pressure 12Pa, electric current 14mA, time 25s, sprays one layer of gold thin film
Purpose be to deposit subsequent platinum as seed gold to grow since the surface of FTO；
Step 2：By the chloroplatinic acid of a concentration of 20mg/mL of 1.1mL, 0.4g polyvinylpyrrolidones, a concentration of 20mg/mL of 0.2mL
Methylamine solution be uniformly mixed with the dimethyl methyl phthalein amine of a concentration of 10mg/mL of 20mL, solution graduates into yellow by water white transparency
Color turbid solution；
Step 3：The mixed liquor that step 2 is prepared is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 60mL, while will step
The rapid 1 FTO substrate of glass containing gold particle prepared is face-up put into autoclave, it is made to be completely submerged in reaction solution；
Step 4：The autoclave of sealing is positioned over constant temperature in 150 DEG C of baking ovens to be kept for 2 hours, so as to which primary platiniferous electricity be made
Pole；
Step 5：By the chloroplatinic acid of a concentration of 20mg/mL of 1.0mL, tri- Phosphoric acid monohexadecyl esters of 0.6g, 0.2g polyvinyl pyrilodones,
The methylamine solution of a concentration of 20mg/mL of 0.2mL is uniformly mixed with the dimethyl methyl phthalein amine of a concentration of 10mg/mL of 20mL, solution by
Water white transparency graduates into yellow turbid solution；
Step 6：The mixed liquor that step 5 is prepared is put into the autoclave of the polytetrafluoroethylsubstrate substrate of 70mL, while will step
Rapid 4 primary prepared are face-up put into autoclave containing platinum electrode, it is made to be completely submerged in reaction solution；
Step 7：The autoclave of sealing is positioned over constant temperature in 180 DEG C of baking ovens to be kept for 1 hour, so as to finished product platiniferous electricity
Pole.
2. preparation method according to claim 1 is in the application in electric vehicle field.
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| CN102166518A (en) * | 2011-03-21 | 2011-08-31 | 天津大学 | Method for preparing electrocatalytic noble metal nanomaterial with three-dimensional network structure |
| CN102189267A (en) * | 2011-04-26 | 2011-09-21 | 浙江理工大学 | Method for preparing highly-dispersed regular octahedral platinum nano particles |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102166518A (en) * | 2011-03-21 | 2011-08-31 | 天津大学 | Method for preparing electrocatalytic noble metal nanomaterial with three-dimensional network structure |
| CN102189267A (en) * | 2011-04-26 | 2011-09-21 | 浙江理工大学 | Method for preparing highly-dispersed regular octahedral platinum nano particles |
Non-Patent Citations (2)
| Title |
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| Fabrication of high performance Pt counter electrodes on conductive plastic substrate for flexible dye-sensitized solar cells;Lili Chen 等;《Electrochimica Acta》;20100206;第55卷;第3721–3726页 * |
| Synthesis and application in surface-enhanced Raman scattering property of fist-like platinum microparticles;Xiumei Feng等;《Materials Letters》;20090719;第63卷;第2171-2174页 * |
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