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CN106084621A - Graphene helmet preparation technology - Google Patents

Graphene helmet preparation technology Download PDF

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Publication number
CN106084621A
CN106084621A CN201610386543.0A CN201610386543A CN106084621A CN 106084621 A CN106084621 A CN 106084621A CN 201610386543 A CN201610386543 A CN 201610386543A CN 106084621 A CN106084621 A CN 106084621A
Authority
CN
China
Prior art keywords
graphene
abs
helmet
antioxidant
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610386543.0A
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Chinese (zh)
Inventor
徐明虎
李海龙
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangyin Dafeima Automobile Accessory Technology Co Ltd
Original Assignee
Jiangyin Dafeima Automobile Accessory Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangyin Dafeima Automobile Accessory Technology Co Ltd filed Critical Jiangyin Dafeima Automobile Accessory Technology Co Ltd
Priority to CN201610386543.0A priority Critical patent/CN106084621A/en
Publication of CN106084621A publication Critical patent/CN106084621A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • AHUMAN NECESSITIES
    • A42HEADWEAR
    • A42BHATS; HEAD COVERINGS
    • A42B3/00Helmets; Helmet covers ; Other protective head coverings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K3/2279Oxides; Hydroxides of metals of antimony
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2055/00Use of specific polymers obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of main groups B29K2023/00 - B29K2049/00, e.g. having a vinyl group, as moulding material
    • B29K2055/02ABS polymers, i.e. acrylonitrile-butadiene-styrene polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009Sulfides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

One Graphene helmet preparation technology of the present invention, it is characterised in that: described technique includes following steps: step one, batch mixing: ABS material and Graphene powder are mixed post-heating;By weight, putting into component is: ABS 100 parts, Graphene 1 ~ 6 part;And while putting into ABS material, add 0.1 0.3 parts of antioxidant, antimony oxide 35 parts, lubricant 0.1 0.5 parts;Step 2, shaping: the compound after heating is carried out injection molded;Step 3, discharging: the helmet discharging after shaping.One Graphene helmet preparation technology of the present invention, production efficiency is high and enables to Graphene and ABS material is sufficiently mixed the production high flame retardant helmet.

Description

Graphene helmet preparation technology
Technical field
The present invention relates to a kind of preparation technology, especially relate to a kind of preparation technology for producing the helmet, belong to the helmet Technical field.
Background technology
As the thinnest, a kind of novel nano-material that maximum intensity, heat conductivility are the strongest that have now been found that, Graphene is claimed For " dark fund ", being " king of new material ", scientist even foretells that Graphene " will thoroughly change 21 century ";Very likely start one The subversiveness new technique new industrial revolution have swept the globe in field;Therefore in helmet preparation process, Graphene is added to improve its intensity A research direction in industry is become with heat dispersion;But the helmet injection machine preparation technology production efficiency of routine is low Under and ABS material and Graphene powder cannot be made to carry out the helmet being sufficiently mixed to prepare high intensity, high heat dispersion;With Time, the fire resistance of the helmet that conventional ABS material is made is poor, and during the generation condition of a fire, security performance is the highest.
Summary of the invention
It is an object of the invention to overcome above-mentioned deficiency, it is provided that a kind of production efficiency is high and enables to Graphene and ABS Material is sufficiently mixed the Graphene helmet preparation technology producing the high flame retardant helmet.
The object of the present invention is achieved like this:
A kind of Graphene helmet preparation technology, described technique includes following steps:
Step one, batch mixing: ABS material and Graphene powder are mixed post-heating;
By weight, putting into component is: ABS 100 parts, Graphene 1 ~ 6 part;And while putting into ABS material, add antioxygen Agent 0.1-0.3 part, antimony oxide 3-5 part, lubricant 0.1-0.5 part;
Wherein, ABS is the terpolymer that three kinds of monomers of acrylonitrile-butadiene-styrene (ABS) are polymerized, acrylonitrile in ABS Parts by weight are 20-30 part, and the parts by weight of butadiene are 10 ~ 15 parts, and cinnamic parts by weight are 60-70 part;
Described antioxidant is the one in antioxidant 1010 or antioxidant 330;The composition of antioxidant 1010 be four [β- (3 ', 5 '-base-4 '-base phenyl) propanoic acid] pentaerythritol ester, antioxidant 330 is 1,3,5-trimethyl-2,4,6-tri- (3,5-di-tert-butyl-4-hydroxyl benzyl) benzene;
Described lubricant is the one in MoS2 or Ti 3SiC2, and MoS 2 and Ti 3SiC2 has excellent self lubricity Can and electric conductivity, in Graphene-ABS composite, add this lubricant, improve lubricity same of this composite Time, it is also possible to strengthen the electric conductivity of this composite;Described antimony oxide be added on this composite burning time and graphite Alkene plays the effect of cooperative flame retardant;
Step 2, shaping: the compound after heating is carried out injection molded;
Step 3, discharging: the helmet discharging after shaping;
Described step one uses injection machine to realize, and described step 2 uses feeding mechanism to realize, and described step 3 uses blanking machine Structure realizes, and above-mentioned injection machine, feeding mechanism and cutting agency constitute Graphene helmet preparation facilities,
Described feeding mechanism includes blender, and the top feed end of described blender connects ABS feed hopper and Graphene Feed hopper, described blender bottom discharge end is connected to the feed end of heating furnace, and the discharge end of described heating furnace is connected to injection Machine, described cutting agency is installed on by injection machine, and described cutting agency includes two supports be arrangeding in parallel, on described support The mobile bottom being provided with crossbeam described in crossbeam is provided with montant vertically downwards, and connecting bottom described montant has revolution case, described On revolution case, cross bar is installed, described cross bar is provided with sucker;Described crossbeam two ends are provided with motor-driven roller, described Cradle top is provided with the groove for roller walking along its length;Shifting chute it is provided with along its length bottom described crossbeam, Being provided with supporting plate on the cell wall of described shifting chute, described supporting plate is provided with tooth bar, described montant top is provided with traversing motor, Described traversing motor is twin shaft output motor, and is all set with, on two output shafts of traversing motor, the tooth being meshed with tooth bar Wheel;The bottom outer rim of described montant is provided with the flange of a loop configuration, is provided with electric rotating machine, described rotation bottom described montant The output shaft of rotating motor vertically downwards, and is set with swing pinion on the output shaft of electric rotating machine, in the tank wall of described revolution case Portion is provided with the draw-in groove embedded for flange, and the tank wall inner bottom part of described revolution case is provided with rotary teeth set, and above-mentioned swing pinion is inserted It is placed in rotary teeth set Inside gear drive.
Compared with prior art, the invention has the beneficial effects as follows:
ABS material and Graphene are sufficiently mixed by the present invention by blender, and are passed through injection machine after heating it and become Type, it is ensured that the quality of the helmet, and carry out automatization's discharging by cutting agency, it is ensured that production efficiency.
Accompanying drawing explanation
Fig. 1 is the structural representation of Graphene helmet preparation facilities in the present invention a kind of Graphene helmet preparation technology.
Fig. 2 is the office in the present invention a kind of Graphene helmet preparation technology at the montant top of Graphene helmet preparation facilities Portion's structure sectional view.
Fig. 3 is the office located bottom the montant of Graphene helmet preparation facilities in the present invention a kind of Graphene helmet preparation technology Portion's structure sectional view.
Wherein:
Injection machine 1, feeding mechanism 2, cutting agency 3;
Blender 2.1, ABS feed hopper 2.2, Graphene feed hopper 2.3, heating furnace 2.4;
Support 3.1, crossbeam 3.2, montant 3.3, revolution case 3.4, cross bar 3.5, sucker 3.6;
Shifting chute 3.2.1, supporting plate 3.2.2, tooth bar 3.2.3;
Traversing motor 3.3.1, gear 3.3.2, electric rotating machine 3.3.3, swing pinion 3.3.4, flange 3.3.5;
Draw-in groove 3.4.1, rotary teeth set 3.4.2.
Detailed description of the invention
See Fig. 1 ~ 3, the present invention relates to a kind of Graphene helmet preparation technology,
Described technique includes following steps:
Step one, batch mixing: ABS material and Graphene powder are mixed post-heating;
By weight, putting into component is: ABS 100 parts, Graphene 1 ~ 6 part;And while putting into ABS material, add antioxygen Agent 0.1-0.3 part, antimony oxide 3-5 part, lubricant 0.1-0.5 part;
Wherein, ABS is the terpolymer that three kinds of monomers of acrylonitrile-butadiene-styrene (ABS) are polymerized, acrylonitrile in ABS Parts by weight are 20-30 part, and the parts by weight of butadiene are 10 ~ 15 parts, and cinnamic parts by weight are 60-70 part;
Described antioxidant is the one in antioxidant 1010 or antioxidant 330;The composition of antioxidant 1010 be four [β- (3 ', 5 '-base-4 '-base phenyl) propanoic acid] pentaerythritol ester, antioxidant 330 is 1,3,5-trimethyl-2,4,6-tri- (3,5-di-tert-butyl-4-hydroxyl benzyl) benzene;
Described lubricant is the one in MoS2 or Ti 3SiC2, and MoS 2 and Ti 3SiC2 has excellent self lubricity Can and electric conductivity, in Graphene-ABS composite, add this lubricant, improve lubricity same of this composite Time, it is also possible to strengthen the electric conductivity of this composite;Described antimony oxide be added on this composite burning time and graphite Alkene plays the effect of cooperative flame retardant;
Step 2, shaping: the compound after heating is carried out injection molded;
Step 3, discharging: the helmet discharging after shaping;
Described step one uses injection machine 1 to realize, and described step 2 uses feeding mechanism 2 to realize, and described step 3 uses blanking Mechanism 3 realizes, and above-mentioned injection machine 1, feeding mechanism 2 and cutting agency 3 constitute Graphene helmet preparation facilities,
Described feeding mechanism 2 includes blender 2.1, and the top feed end of described blender 2.1 connects ABS feed hopper 2.2 and Graphene feed hopper 2.3, described blender 2.1 bottom discharge end is connected to the feed end of heating furnace 2.4, described heating The discharge end of stove 2.4 is connected to injection machine 1, and it is other that described cutting agency 3 is installed on injection machine 1, and described cutting agency 3 includes two The support 3.1 that bar be arranged in parallel, on described support 3.1, movement is provided with crossbeam 3.2 two ends described in crossbeam 3.2(and is provided with motor The roller driven, described support 3.1 top is provided with the groove for roller walking along its length);The end of described crossbeam 3.2 Portion is provided with montant 3.3 vertically downwards, connects and has revolution case 3.4, described revolution case 3.4 is provided with bottom described montant 3.3 Cross bar 3.5, described cross bar 3.5 is provided with sucker 3.6;By sucker 3.6, the helmet prepared on injection machine 1 is absorbed Material, thus not only efficiency is high, and be burned without having to worry about operator, improve security performance;
Further, shifting chute 3.2.1 it is provided with bottom described crossbeam 3.2 along its length, on the cell wall of described shifting chute 3.2.1 Being provided with supporting plate 3.2.2, described supporting plate 3.2.2 is provided with tooth bar 3.2.3, described montant 3.3 top is provided with traversing motor 3.3.1, described traversing motor 3.3.1 is twin shaft output motor, and be all set with on two output shafts of traversing motor 3.3.1 with The gear 3.3.2 that tooth bar 3.2.3 is meshed;
The bottom outer rim of described montant 3.3 is provided with the flange 3.3.5 of a loop configuration, is provided with rotation bottom described montant 3.3 Rotating motor 3.3.3, the output shaft of described electric rotating machine 3.3.3 vertically downwards, and is set with on the output shaft of electric rotating machine 3.3.3 Swing pinion 3.3.4, the tank wall of described revolution case 3.4 be internally provided with for flange 3.3.5 embed draw-in groove 3.4.1, described time Turn the tank wall inner bottom part of case 3.4 rotary teeth set 3.4.2, above-mentioned swing pinion 3.3.4 are installed to be inserted in rotary teeth set 3.4.2 Engaged transmission;
Thus when blanking, run to correct position by before and after montant 3.3, then revolution case 3.4 rotarily drives sucker 3.6 and inhales Live the helmet, get final product discharging subsequently, thus the occasion of size injection machine 1 of not reaching the same goal can be used, have more versatility;
Additionally: it should be noted that above-mentioned detailed description of the invention is only a prioritization scheme of this patent, those skilled in the art Any change of being done according to above-mentioned design of member or improvement, all within the protection domain of this patent.

Claims (2)

1. a Graphene helmet preparation technology, it is characterised in that:
Described technique includes following steps:
Step one, batch mixing: ABS material and Graphene powder are mixed post-heating;
By weight, putting into component is: ABS 100 parts, Graphene 1 ~ 6 part;And while putting into ABS material, add antioxygen Agent 0.1-0.3 part, antimony oxide 3-5 part, lubricant 0.1-0.5 part;
Step 2, shaping: the compound after heating is carried out injection molded;
Step 3, discharging: the helmet discharging after shaping;
Described step one uses injection machine 1 to realize, and described step 2 uses feeding mechanism 2 to realize, and described step 3 uses blanking Mechanism 3 realizes, and above-mentioned injection machine 1, feeding mechanism 2 and cutting agency 3 constitute Graphene helmet preparation facilities;
Described feeding mechanism (2) includes blender (2.1), and the top feed end of described blender (2.1) connects has ABS to enter Hopper (2.2) and Graphene feed hopper (2.3), described blender (2.1) bottom discharge end is connected to the charging of heating furnace (2.4) End, the discharge end of described heating furnace (2.4) is connected to injection machine (1);
It is other that described cutting agency (3) is installed on injection machine (1), and described cutting agency (3) includes two supports be arrangeding in parallel (3.1), the upper mobile bottom being provided with crossbeam (3.2) described crossbeam (3.2) of described support (3.1) is provided with montant vertically downwards (3.3), described montant (3.3) bottom connects revolution case (3.4), and described revolution case (3.4) is provided with cross bar (3.5), institute State and sucker (3.6) is installed on cross bar (3.5);Described crossbeam (3.2) two ends are provided with motor-driven roller, described support (3.1) top is provided with the groove for roller walking along its length;Described crossbeam (3.2) bottom is provided with shifting along its length Dynamic groove (3.2.1), the cell wall of described shifting chute (3.2.1) is provided with supporting plate (3.2.2), and described supporting plate (3.2.2) is upper to be installed Having tooth bar (3.2.3), described montant (3.3) top to be provided with traversing motor (3.3.1), described traversing motor (3.3.1) is double The gear being meshed with tooth bar (3.2.3) all it is set with on axle output motor, and two output shafts of traversing motor (3.3.1) (3.3.2);The bottom outer rim of described montant (3.3) is provided with the flange (3.3.5) of a loop configuration, described montant (3.3) end Portion is provided with electric rotating machine (3.3.3), the output shaft of described electric rotating machine (3.3.3) vertically downwards, and electric rotating machine (3.3.3) Output shaft on be set with swing pinion (3.3.4), the tank wall of described revolution case (3.4) be internally provided with for flange (3.3.5) The draw-in groove (3.4.1) embedded, the tank wall inner bottom part of described revolution case (3.4) is provided with rotary teeth set (3.4.2), above-mentioned rotary teeth Wheel (3.3.4) is inserted in rotary teeth set (3.4.2) Inside gear drive.
2. a kind of Graphene helmet preparation technology, it is characterised in that: ABS is acrylonitrile-butadiene-benzene The terpolymer that three kinds of monomers of ethylene are polymerized, in ABS, the parts by weight of acrylonitrile are 20-30 part, the weight of butadiene Amount number is 10 ~ 15 parts, and cinnamic parts by weight are 60-70 part;
Described antioxidant is the one in antioxidant 1010 or antioxidant 330;The composition of antioxidant 1010 be four [β- (3 ', 5 '-base-4 '-base phenyl) propanoic acid] pentaerythritol ester, antioxidant 330 is 1,3,5-trimethyl-2,4,6-tri- (3,5-di-tert-butyl-4-hydroxyl benzyl) benzene;
Described lubricant is the one in MoS2 or Ti 3SiC2.
CN201610386543.0A 2016-06-04 2016-06-04 Graphene helmet preparation technology Pending CN106084621A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610386543.0A CN106084621A (en) 2016-06-04 2016-06-04 Graphene helmet preparation technology

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610386543.0A CN106084621A (en) 2016-06-04 2016-06-04 Graphene helmet preparation technology

Publications (1)

Publication Number Publication Date
CN106084621A true CN106084621A (en) 2016-11-09

Family

ID=57446952

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610386543.0A Pending CN106084621A (en) 2016-06-04 2016-06-04 Graphene helmet preparation technology

Country Status (1)

Country Link
CN (1) CN106084621A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114931261A (en) * 2022-06-10 2022-08-23 钰亨达橡塑制品(惠州)有限公司 Multifunctional composite helmet and forming process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1640134A1 (en) * 2004-09-24 2006-03-29 EMS-Chemie AG Injection moulding method for producing plastic parts
CN101417489A (en) * 2008-11-14 2009-04-29 联塑(杭州)机械有限公司 Helmet manufacture method and products thereof
WO2015085294A1 (en) * 2013-12-06 2015-06-11 Bell Sports, Inc. Flexible multi-layer helmet and method for making the same
CN104974462A (en) * 2015-07-27 2015-10-14 苏州荣昌复合材料有限公司 Graphene-ABS composite flame-retardant plastic and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1640134A1 (en) * 2004-09-24 2006-03-29 EMS-Chemie AG Injection moulding method for producing plastic parts
CN101417489A (en) * 2008-11-14 2009-04-29 联塑(杭州)机械有限公司 Helmet manufacture method and products thereof
WO2015085294A1 (en) * 2013-12-06 2015-06-11 Bell Sports, Inc. Flexible multi-layer helmet and method for making the same
CN104974462A (en) * 2015-07-27 2015-10-14 苏州荣昌复合材料有限公司 Graphene-ABS composite flame-retardant plastic and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114931261A (en) * 2022-06-10 2022-08-23 钰亨达橡塑制品(惠州)有限公司 Multifunctional composite helmet and forming process thereof

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Application publication date: 20161109

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