CN106032426A - ABS wood-plastic material and preparing method thereof - Google Patents
ABS wood-plastic material and preparing method thereof Download PDFInfo
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- CN106032426A CN106032426A CN201610501667.9A CN201610501667A CN106032426A CN 106032426 A CN106032426 A CN 106032426A CN 201610501667 A CN201610501667 A CN 201610501667A CN 106032426 A CN106032426 A CN 106032426A
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- plastic material
- wood
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention provides an ABS wood-plastic material and a preparing method thereof. The ABS wood-plastic material is mainly prepared from 100 parts of ABS resin, 50-80 parts of 60-mesh bamboo powder, 8-12 parts of S-MA, 2-3 parts of stearic anhydride, 1-2 parts of dilauryl thiodipropionate, 0.5-1 part of glycidyl methacrylate, 0.2-0.5 part of carbon black and 1-2 parts of ethylene bisstearamide. The invention further provides the preparing method of the ABS wood-plastic material, and the problem of poor processing performance such as uneven wood powder dispersion and poor melt flowability in the processing process of an ABS wood-plastic material can be solved through the formula in cooperation with the preparing method.
Description
Technical field
The invention belongs to engineering material technical field, particularly relate to a kind of ABS Wood-plastic material and preparation method thereof.
Background technology
Wood plastic composite (WPC) has the premium properties of timber and thermoplastic concurrently, has that processing and forming is easy, water absorption is little, good stability of the dimension, has excellent weather resistance, uses and simple and convenient for maintenance.ABS has the rigidity of excellence, dimensional stability, low creep properties so that ABS Wood-plastic material has more the character close to timber, but the processing fluidity of ABS melt is poor, and the processing fluidity decline of the Wood-plastic material melt filling a large amount of wood powder becomes apparent from.Although improving temperature to be conducive to the mobility of melt, but the too high meeting of temperature causing wood powder coking.Therefore, 200 degrees Celsius of processing temperatures in, by the improvement of formula promote wood powder disperse, improve fluidity of molten, be current ABS Wood-plastic material field urgent problem in order to obtain higher processing characteristics.
Summary of the invention
The technical problem to be solved is to provide a kind of ABS Wood-plastic material and preparation method thereof, it is possible to solve the problem that in the ABS Wood-plastic material course of processing, the processing characteristicies such as wood powder dispersion is uneven, fluidity of molten is poor are weak.
In the present invention, " consumption ", " part " are all quality criterias, and the amount of each component is all on the basis of 100 parts of ABS resin.
For solving above-mentioned existing technical problem, the present invention uses following scheme:
A kind of ABS Wood-plastic material, mainly includes that following raw material is made: 100 parts of ABS resin powder, 60 mesh bamboo powder 50-80 parts, S-MA 8-12 part, stearic anhydride 2-3 part, dilauryl thiodipropionate 1-2 part, glycidyl methacrylate 0.5-1 part, carbon black 0.2-0.5 part, ethylene bis stearic acid amide 1-2 part.
As preferably, described 60 mesh bamboo powder water content ＜ 2wt%.
As preferably, described S-MA composition is styrene-maleic anhydride copolymer.
The preparation method of this ABS Wood-plastic material, comprises the following steps:
(1) according to proportioning raw materials, ABS resin powder, 60 mesh bamboo powder, S-MA, stearic anhydride being added stirrer for mixing, rotating speed is 500 revs/min, and the time is 5-10 minute, and temperature is 90 DEG C, obtains mixture standby；
(2) batch mixing that step (1) is obtained, adding dilauryl thiodipropionate, glycidyl methacrylate, carbon black, ethylene bis stearic acid amide continuation stirring, rotating speed is 1000 revs/min, and the time is 10-15 minute, temperature is 110 DEG C, obtains mixture standby；
(3) carry out pelletize at a temperature of the mixture obtained in step (2) being joined comminutor 130 DEG C, after the granulate cooling that will obtain, obtain a kind of ABS Wood-plastic material former material granule；
(4) the granular Wood-plastic material obtained in step (3) being passed through extruding production line, extrusion temperature controls between 160 DEG C-180 DEG C, and extruding production line makes the ABS Wood-plastic material of different size according to difform mould.
The beneficial effects of the present invention is: the present invention uses technique scheme to provide a kind of ABS Wood-plastic material and preparation method thereof, it is possible to solve the problem that in the ABS Wood-plastic material course of processing, the processing characteristicies such as wood powder dispersion is uneven, fluidity of molten is poor are weak.
Detailed description of the invention
Describing the present invention in detail below in conjunction with specific embodiment, illustrative examples and explanation in this present invention are used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1
A kind of ABS Wood-plastic material, mainly includes that following raw material is made: 100 parts of ABS resin powder, 60 mesh bamboo powder 50 parts, S-MA 8 parts, stearic anhydride 2 parts, dilauryl thiodipropionate 1 part, glycidyl methacrylate 0.5 part, carbon black 0.2 part, ethylene bis stearic acid amide 1.5 parts；Described 60 mesh bamboo powder water content ＜ 2wt%；Described S-MA composition is styrene-maleic anhydride copolymer.
The preparation method of this ABS Wood-plastic material, comprises the following steps:
(1) according to proportioning raw materials, ABS resin powder, 60 mesh bamboo powder, S-MA, stearic anhydride being added stirrer for mixing, rotating speed is 500 revs/min, and the time is 5 minutes, and temperature is 90 DEG C, obtains mixture standby；
(2) batch mixing that step (1) is obtained, adding dilauryl thiodipropionate, glycidyl methacrylate, carbon black, ethylene bis stearic acid amide continuation stirring, rotating speed is 1000 revs/min, and the time is 10 minutes, temperature is 110 DEG C, obtains mixture standby；
(3) carry out pelletize at a temperature of the mixture obtained in step (2) being joined comminutor 130 DEG C, after the granulate cooling that will obtain, obtain a kind of ABS Wood-plastic material former material granule；
(4) the granular Wood-plastic material obtained in step (3) being passed through extruding production line, extrusion temperature controls between 160 DEG C-180 DEG C, and extruding production line makes the ABS Wood-plastic material of different size according to difform mould.
Embodiment 2
A kind of ABS Wood-plastic material, mainly includes that following raw material is made: 100 parts of ABS resin powder, 60 mesh bamboo powder 60 parts, S-MA 10 parts, stearic anhydride 2.5 parts, dilauryl thiodipropionate 1.5 parts, glycidyl methacrylate 0.8 part, carbon black 0.3 part, ethylene bis stearic acid amide 1.5 parts；Described 60 mesh bamboo powder water content ＜ 2wt%；Described S-MA composition is styrene-maleic anhydride copolymer.
The preparation method of this ABS Wood-plastic material, comprises the following steps:
(1) according to proportioning raw materials, ABS resin powder, 60 mesh bamboo powder, S-MA, stearic anhydride being added stirrer for mixing, rotating speed is 500 revs/min, and the time is 8 minutes, and temperature is 90 DEG C, obtains mixture standby；
(2) batch mixing that step (1) is obtained, adding dilauryl thiodipropionate, glycidyl methacrylate, carbon black, ethylene bis stearic acid amide continuation stirring, rotating speed is 1000 revs/min, and the time is 12 minutes, temperature is 110 DEG C, obtains mixture standby；
(3) carry out pelletize at a temperature of the mixture obtained in step (2) being joined comminutor 130 DEG C, after the granulate cooling that will obtain, obtain a kind of ABS Wood-plastic material former material granule；
(4) the granular Wood-plastic material obtained in step (3) being passed through extruding production line, extrusion temperature controls between 160 DEG C-180 DEG C, and extruding production line makes the ABS Wood-plastic material of different size according to difform mould.
Embodiment 3
A kind of ABS Wood-plastic material, mainly includes that following raw material is made: 100 parts of ABS resin powder, 60 mesh bamboo powder 80 parts, S-MA 12 parts, stearic anhydride 3 parts, dilauryl thiodipropionate 2 parts, glycidyl methacrylate 1 part, carbon black 0.5 part, ethylene bis stearic acid amide 2 parts；Described 60 mesh bamboo powder water content ＜ 2wt%；Described S-MA composition is styrene-maleic anhydride copolymer.
The preparation method of this ABS Wood-plastic material, comprises the following steps:
(1) according to proportioning raw materials, ABS resin powder, 60 mesh bamboo powder, S-MA, stearic anhydride being added stirrer for mixing, rotating speed is 500 revs/min, and the time is 10 minutes, and temperature is 90 DEG C, obtains mixture standby；
(2) batch mixing that step (1) is obtained, adding dilauryl thiodipropionate, glycidyl methacrylate, carbon black, ethylene bis stearic acid amide continuation stirring, rotating speed is 1000 revs/min, and the time is 15 minutes, temperature is 110 DEG C, obtains mixture standby；
(3) carry out pelletize at a temperature of the mixture obtained in step (2) being joined comminutor 130 DEG C, after the granulate cooling that will obtain, obtain a kind of ABS Wood-plastic material former material granule；
(4) the granular Wood-plastic material obtained in step (3) being passed through extruding production line, extrusion temperature controls between 160 DEG C-180 DEG C, and extruding production line makes the ABS Wood-plastic material of different size according to difform mould.
The principle of above-described embodiment only illustrative present invention and effect thereof, not for limiting the present invention.Above-described embodiment all can be modified under the spirit and the scope of the present invention or change by any person skilled in the art.Therefore, art has all equivalence modification or changes that usually intellectual is completed under without departing from disclosed spirit and technological thought such as, must be contained by the claim of the present invention.
Claims (2)
1. an ABS Wood-plastic material, it is characterized in that, mainly include that following raw material is made: 100 parts of ABS resin powder, 60 mesh bamboo powder 50-80 parts, S-MA 8-12 part, stearic anhydride 2-3 part, dilauryl thiodipropionate 1-2 part, glycidyl methacrylate 0.5-1 part, carbon black 0.2-0.5 part, ethylene bis stearic acid amide 1-2 part；Described 60 mesh bamboo powder water content ＜ 2wt%；Described S-MA composition is styrene-maleic anhydride copolymer.
The preparation method of ABS Wood-plastic material the most according to claim 1, it is characterised in that comprise the following steps:
(1) according to proportioning raw materials, ABS resin powder, 60 mesh bamboo powder, S-MA, stearic anhydride being added stirrer for mixing, rotating speed is 500 revs/min, and the time is 5-10 minute, and temperature is 90 DEG C, obtains mixture standby；
(2) batch mixing that step (1) is obtained, adding dilauryl thiodipropionate, glycidyl methacrylate, carbon black, ethylene bis stearic acid amide continuation stirring, rotating speed is 1000 revs/min, and the time is 10-15 minute, temperature is 110 DEG C, obtains mixture standby；
(3) carry out pelletize at a temperature of the mixture obtained in step (2) being joined comminutor 130 DEG C, after the granulate cooling that will obtain, obtain a kind of ABS Wood-plastic material former material granule；
(4) the granular Wood-plastic material obtained in step (3) being passed through extruding production line, extrusion temperature controls between 160 DEG C-180 DEG C, and extruding production line makes the ABS Wood-plastic material of different size according to difform mould.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610501667.9A CN106032426A (en) | 2016-06-30 | 2016-06-30 | ABS wood-plastic material and preparing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610501667.9A CN106032426A (en) | 2016-06-30 | 2016-06-30 | ABS wood-plastic material and preparing method thereof |
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| CN106032426A true CN106032426A (en) | 2016-10-19 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610501667.9A Pending CN106032426A (en) | 2016-06-30 | 2016-06-30 | ABS wood-plastic material and preparing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109422995A (en) * | 2017-08-24 | 2019-03-05 | 合肥杰事杰新材料股份有限公司 | A kind of acrylonitrile-butadiene-styrene copolymer composition and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101525496A (en) * | 2009-03-27 | 2009-09-09 | 林朝枝 | Formulation of particles |
| CN102924940A (en) * | 2011-08-08 | 2013-02-13 | 深圳市格林美高新技术股份有限公司 | Anti-aging plastic wood composite material and preparation method thereof |
| CN104419108A (en) * | 2013-08-29 | 2015-03-18 | 合肥杰事杰新材料股份有限公司 | Bamboo powder/acrylonitrile-butadiene-styrene composite material and preparation method thereof |
-
2016
- 2016-06-30 CN CN201610501667.9A patent/CN106032426A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101525496A (en) * | 2009-03-27 | 2009-09-09 | 林朝枝 | Formulation of particles |
| CN102924940A (en) * | 2011-08-08 | 2013-02-13 | 深圳市格林美高新技术股份有限公司 | Anti-aging plastic wood composite material and preparation method thereof |
| CN104419108A (en) * | 2013-08-29 | 2015-03-18 | 合肥杰事杰新材料股份有限公司 | Bamboo powder/acrylonitrile-butadiene-styrene composite material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 陈寒娴，杨文斌: "《竹粉/ABS塑料复合材料的性能研究》", 《华东纸业》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109422995A (en) * | 2017-08-24 | 2019-03-05 | 合肥杰事杰新材料股份有限公司 | A kind of acrylonitrile-butadiene-styrene copolymer composition and preparation method thereof |
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