CN105941440A - Sterilization composition containing Bixafen and zineb and application thereof - Google Patents
Sterilization composition containing Bixafen and zineb and application thereof Download PDFInfo
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- CN105941440A CN105941440A CN201610356598.7A CN201610356598A CN105941440A CN 105941440 A CN105941440 A CN 105941440A CN 201610356598 A CN201610356598 A CN 201610356598A CN 105941440 A CN105941440 A CN 105941440A
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- zineb
- bacterium amine
- pyrrole bacterium
- biphenyl pyrrole
- bactericidal composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
- A01N47/14—Di-thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
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Abstract
The invention discloses a sterilization composition containing Bixafen and zineb and application thereof. The sterilization composition takes the Bixafen and the zineb as main effective ingredients, wherein the mass ratio of the Bixafen to the zineb is (1-70):(1-50). The sterilization composition can be used for preventing and curing cereal, fruit tree and vegetable diseases, has a higher synergistic interaction action, overcomes and delays the drug resistance of bacteria, has the advantages of high sterilization speed and long lasting period and lowers application cost, and the prevention and cure effect of the sterilization composition is obviously superior to the prevention and cure effect brought when the Bixafen or the zineb is singly used. The sterilization composition can be used for preventing and curing fungi on crops, and can be especially used for preventing and curing fungal diseases including wheat powdery mildew, grape downy mildew, stripe rust of wheat and barley, corn northern leaf blight, tea red scab, tobacco seedling dry rot and the like, and the effect of the sterilization composition is obviously superior to the effect brought when the Bixafen or the zineb is singly used.
Description
Technical field:
The present invention relates to a kind of bactericidal composition and application thereof, especially one live with biphenyl pyrrole bacterium amine and zineb for main
The bactericidal composition of property composition and application thereof.
Background technology
Biphenyl pyrrole bacterium amine (Bixafen), chemical formula: C18H12Cl2F3N3O, chemical name: N-(3 ', 4 '-two chloro-5-
Fluorine hexichol-2-base)-3-(difluoromethyl)-1-methylpyrazole-4-Methanamide.Structural formula:
Biphenyl pyrrole bacterium amine is pyrazoles antibacterial, is that the interior absorption that a kind of novel wide spectrum, protection and therapeutic activity have concurrently is killed
Microbial inoculum.
Zineb (Zineb), molecular formula: C4H6N2S4Zn, chemical name: zinc ethylene bisdithiocarbamate.
Structural formula:
Zineb is broad spectrum activity, protective fungicide.Can be used for preventing and treating Oryza sativa L., wheat and barley, vegetable, Fructus Vitis viniferae, fruit tree, cigarette
The multiple diseases of the crops such as grass, such as wheat rust, the leaf blight of corn, tea rust, Nicotiana tabacum L. damping-off, anthrax, flower
Raw brown spot, potato blight, shot hole, tar spot and Fructus Mali pumilae, pears, Fructus Persicae, Citrus, Fructus Vitis viniferae, vegetable etc. are multiple
Disease.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, along with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty strengthens；
On the other hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality,
Control of plant disease is faced with significant challenge.
Summary of the invention
It is an object of the invention to provide a kind of applied widely, low cost for above-mentioned technical problem, effective containing biphenyl
Pyrrole bacterium amine and the plant bactericidal composition of zineb.
It is a still further object of the present invention to provide this bactericidal composition and cause the application on fungal disease at preventing and treating plant epiphyte,
Especially stand withered preventing and treating wheat powdery mildew, downy mildew of garpe, wheat rust, the leaf blight of corn, tea rust, Nicotiana tabacum L.
Purposes on the fungal diseases such as disease.
It is an object of the invention to be achieved through the following technical solutions
A kind of containing biphenyl pyrrole bacterium amine and the bactericidal composition of zineb, this bactericidal composition with biphenyl pyrrole bacterium amine with zineb is
Principle active component, wherein biphenyl pyrrole bacterium amine is 1～70:1～50 with the mass ratio of zineb, wherein in bactericidal composition
Active ingredient is present in compositions with enhancing effective amount.
Described bactericidal composition, wherein biphenyl pyrrole bacterium amine is preferably 1～50:1～50 with the mass ratio of zineb, enters one
Step preferably 1～30:1～30, the most preferably 1～10:1～30, biphenyl pyrrole bacterium amine and the preferred mass of zineb
Proportioning can also be: 70:1,50:1,30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:
4,1:6,1:10,1:20,1:30,1:50.
In the compositions of the present invention, the weight/mass percentage composition accounting for compositions both biphenyl pyrrole bacterium amine and zineb is 2～80%.
Preferably 5～70%.
Described bactericidal composition, wherein with biphenyl pyrrole bacterium amine and zineb for principle active component and known auxiliary agent and tax
Shape agent is re-dubbed on pesticide any one dosage form allowed.Auxiliary agent known to these, excipient have dispersant, diffusant,
Defoamer, wetting agent, disintegrating agent etc., can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, benzylphenol
Polyoxyethylene ether, phenethyl phenol polyethenoxy ether, fatty alcohol-polyoxyethylene ether and similar products, aliphatic amine polyoxyethylene
Ether, fatty acid ethylene oxide addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, nonyl
Phenol polyethenoxy ether, TWEEN Series, fatty alcohol-polyoxyethylene ether, Polyethylene Glycol series, Sulfonates, carboxylate, sulfur
Hydrochlorate, phosphate, phosphite, lignosulfonates, xanthan gum, phenol formaldehyde condensate, ammonium salt, quaternary etc.
In one or more combinations, excipient includes that Ketohexamethylene, dimethylbenzene, various solvent naphtha, water, antifreezing agent are (such as the third two
Alcohol), deionized water etc..Above auxiliary agent, excipient and other adjuvant can be alone or and use.
Described bactericidal composition, its dosage form is cream, wettable powder, suspending agent, aqueous emulsion or water dispersion granule.
The application on preparation preventing and treating fungal diseases of plants medicine of the above-mentioned bactericidal composition.Especially preventing and treating Cereal,
Application in terms of fruit tree, vegetable crop disease has significant effect.
Above-mentioned application, described fungal diseases of plants is that wheat powdery mildew, downy mildew of garpe, wheat rust, Semen Maydis are big
At least one in pinta, tea rust, Nicotiana tabacum L. damping-off.
The feature of bactericidal composition of the present invention:
1, the biphenyl pyrrole bacterium amine used by the present invention and zineb, the mechanism of action is different, and mutual mixture will not produce low touching,
Can Synergistic, reduce dosage, reduce cost.
2, the present composition scope of application increases, it is adaptable to preventing and treating Cereal, fruit tree, the refractory fungal disease of vegetable,
Particularly prevent and treat wheat powdery mildew, downy mildew of garpe, wheat rust, the leaf blight of corn, tea rust, Nicotiana tabacum L. damping-off
Deng all there being significant effect.Ascomycetes, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease are had by bactericidal composition of the present invention
There is good prevention effect；And suppress insect or fungus or antibacterial to unitary agent (biphenyl pyrrole bacterium amine and zineb are arbitrary)
Drug-fast generation.Bactericidal composition of the present invention can produce higher synergistic function, and the consumption of this mixture
Being substantially reduced than the consumption of independent reactive compound, i.e. the activity of mixture is more than the activity of independent component.
Compared with prior art beneficial effects of the present invention: (1), compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as wheat powdery mildew, downy mildew of garpe, wheat rust, the leaf blight of corn, tea rust, Nicotiana tabacum L. damping-off
Having obvious synergistic function, overcome and delayed Drug resistance, expanding prevention is composed, hence it is evident that improve prevention effect；(2)
Reduce preventing and treating recruitment, drug cost；(3) alternative routine and the pesticide being easily generated resistance；(4) compared with single dose, raw
Produce and use cost reduces；(5) the suppression drug-fast generation of fungus, its effect uses apparently higher than its single dose.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, and in embodiment, the preparation method of dosage form is conventional method,
" % " of the present invention is mass percent.
Indoor biometrics is tested:
In indoor employing mycelial growth rate method, measure the different agents EC to bacterial strain50Value, uses co-toxicity coefficient calculating side
Method, calculates the co-toxicity coefficient (CTC) of mixture, determines the building performance of mixture, and circular is as follows:
In mixture, a certain single dose (is generally selected EC as standard agent50Junior), calculate:
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × A the single dose of theoretical toxicity index=A single dose in mixture the toxicity index of proportion+B single dose ×
B single dose proportion in mixture
The EC of actual measurement toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theory toxicity index × 100
When co-toxicity coefficient classification: CTC is more than 120, mixture has synergetic, is antagonism when CTC is less than 80, CTC
It it is summation action between 80-120.
According to effective ingredient biphenyl pyrrole bacterium amine (A): zineb (B) quality proportioning is: 80:1,70:1,50:1,
30:1,20:1,10:1,5:1,2.5:1,1:1,1:2,1:4,1:6,1:10,1:20,1:
30,1:50,1:60,1:70 test, and measure it to the leaf blight of corn (HelminthosporiumturcicumPass.)
Co-toxicity coefficient.
Table 1: biphenyl pyrrole bacterium amine+zineb different ratio indoor biometrics result to the leaf blight of corn
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 10% biphenyl pyrrole bacterium amine WP | Y=3.520+3.625X | 2.560 | - |
| 80% zineb WP | Y=4.156+1.201X | 5.042 | - |
| A:B=80:1 | Y=3.996+1.526X | 4.552 | 111.45 |
| A:B=70:1 | Y=3.744+2.535X | 3.130 | 162.20 |
| A:B=50:1 | Y=3.097+3.628X | 3.345 | 152.21 |
| A:B=30:1 | Y=3.175+3.632X | 3.180 | 161.12 |
| A:B=20:1 | Y=4.314+1.214X | 3.674 | 140.54 |
| A:B=10:1 | Y=3.925+2.021X | 3.404 | 155.08 |
| A:B=5:1 | Y=3.626+2.605X | 3.369 | 163.02 |
| A:B=2.5:1 | Y=2.428+4.021X | 4.362 | 134.51 |
| A:B=1:1 | Y=4.307+1.254X | 3.568 | 187.45 |
| A:B=1:2 | Y=2.419+3.623X | 5.157 | 145.52 |
| A:B=1:4 | Y=2.967+2.896X | 5.035 | 165.20 |
| A:B=1:6 | Y=3.845+1.562X | 5.490 | 158.89 |
| A:B=1:10 | Y=2.784+3.029X | 5.390 | 169.32 |
| A:B=1:20 | Y=4.004+1.211X | 6.645 | 142.85 |
| A:B=1:30 | Y=1.295+4.822X | 5.866 | 164.15 |
| A:B=1:50 | Y=2.919+2.368X | 7.567 | 128.79 |
| A:B=1:60 | Y=0.812+4.510X | 8.485 | 115.20 |
| A:B=1:70 | Y=1.988+3.202X | 8.724 | 112.30 |
Field control effectiveness test:
The pesticidal preparations prepared with above-described embodiment prevents and treats leaf blight of corn test.
1, test processes: this test medicine consumption sets three concentration for the treatment of respectively according to the difference of each composition, compares medicine
Agent is pesticide single dose 10% biphenyl pyrrole bacterium amine WP and 80% zineb WP and blank clean water experiment respectively.
2, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect after investigating before dispenser and preventing and treating
Method is: in test treatment region, (every takes 5m to randomization 5 point2), enter according to country's field test relevant criterion
Row severity Scaling, calculates preventive effect.Result of the test is shown in Table 2:
Table 2 field test effect
Being shown by indoor biometrics and field efficacy result, biphenyl pyrrole bacterium amine and zineb compositions have the most collaborative increasing
Effect effect, the prevention effect of compositions is excellent, and prevention effect is all better than single dose kind, has application valency in agricultural is applied
Value.
Two kinds of reactive compounds can be processed into any one dosage form of permission, illustrates that two kinds have with specific embodiment below
The preparation that effect composition is processed into, but the preparation that these two kinds of active component can be processed is not limited only to set forth below.
Embodiment 1:15% biphenyl pyrrole bacterium amine Zineb wettable powder (1:2)
By biphenyl pyrrole bacterium amine 5g, zineb 10g, detergent LS (to methoxyl group fatty acid amido benzene sulfonic acid sodium salt) 2g,
Dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, Kaolin adds to 100g mixture and carries out air-flow powder
Broken, preparing effective ingredient mass percent is 15% biphenyl pyrrole bacterium amine Zineb wettable powder.
Embodiment 2:15% biphenyl pyrrole bacterium amine Zineb wettable powder (1:4)
By biphenyl pyrrole bacterium amine 3g, zineb 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g,
Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent was 15% biphenyl pyrrole bacterium amine generation
Gloomy zinc wettable powder.
Embodiment 3:14% biphenyl pyrrole bacterium amine Zineb wettable powder (1:6)
By biphenyl pyrrole bacterium amine 2g, zineb 12g, sodium lauryl sulphate 3g, dispersing agent NNO 4g, white carbon 5g,
Kaolin adds to 100g mixture and carries out comminution by gas stream, and preparing effective ingredient mass percent was 14% biphenyl pyrrole bacterium amine generation
Gloomy zinc wettable powder.
Embodiment 4:20% biphenyl pyrrole bacterium amine zineb suspending agent (1:1)
Weigh 10g biphenyl pyrrole bacterium amine, 10g zineb, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof,
Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand mill
Effect under to make effective Ingredient percent be 20% biphenyl pyrrole bacterium amine zineb suspending agent.
Embodiment 5:55% biphenyl pyrrole bacterium amine zineb aqueous emulsion (1:10)
Weigh 5g biphenyl pyrrole bacterium amine, 50g zineb, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g,
Alkylphenol polyoxyethylene 1g, 150# solvent naphtha 13g, add water to 100g.Above raw material is prepared aqueous emulsion routinely
Method puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 55% biphenyl pyrrole bacterium amine zineb water and milk
Agent.
Embodiment 6:42% biphenyl pyrrole bacterium amine zineb cream (1:20)
Weigh 2g biphenyl pyrrole bacterium amine, 40g zineb, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g,
150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effectively one-tenth
Point mass percent is 42% biphenyl pyrrole bacterium amine zineb cream.
Embodiment 7:70% biphenyl pyrrole bacterium amine zineb cream (2.5:1)
Weigh 50g biphenyl pyrrole bacterium amine, 20g zineb, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g,
Castor oil polyoxyethylene ether 2g, 150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixed
Closing in still and mix, making effective Ingredient percent is 70% biphenyl pyrrole bacterium amine zineb cream.
Embodiment 8:18% biphenyl pyrrole bacterium amine zineb water dispersion granule (5:1)
Weigh 15g biphenyl pyrrole bacterium amine, 3g zineb, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, kieselguhr complements to 100g, and by water dispersible granular agent method, above raw material is formed with effect
Ingredient percent is 17% biphenyl pyrrole bacterium amine zineb water dispersion granule.
Embodiment 9:11% biphenyl pyrrole bacterium amine zineb cream (10:1)
Weigh 10g biphenyl pyrrole bacterium amine, 1g zineb, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g,
150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effectively one-tenth
Point mass percent is 11% biphenyl pyrrole bacterium amine zineb cream.
Embodiment 10:31.5% biphenyl pyrrole bacterium amine zineb microemulsion (20:1)
Weigh 30g biphenyl pyrrole bacterium amine, 1.5g zineb, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material
The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 31.5% biphenyl pyrrole
Bacterium amine zineb microemulsion.
Embodiment 11:31% biphenyl pyrrole bacterium amine zineb cream (30:1)
Weigh 30g biphenyl pyrrole bacterium amine, 1g zineb, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g,
150# solvent naphtha is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, makes effectively one-tenth
Point mass percent is 31% biphenyl pyrrole bacterium amine zineb cream.
Embodiment 12:51% biphenyl pyrrole bacterium amine zineb suspending agent (50:1)
Weigh 50g biphenyl pyrrole bacterium amine, 1g zineb, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof,
Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand mill
Effect under to make effective Ingredient percent be 51% biphenyl pyrrole bacterium amine zineb suspending agent.
Embodiment 13:32% biphenyl pyrrole bacterium amine zineb microemulsion (1:15)
Weigh 2g biphenyl pyrrole bacterium amine, 30g zineb, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material
The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 32% biphenyl pyrrole bacterium
Amine zineb microemulsion.
Embodiment 14:6% biphenyl pyrrole bacterium amine zineb aqueous emulsion (1:5)
Weigh 1g biphenyl pyrrole bacterium amine, 5g zineb, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkane
Base phenol polyethenoxy ether 1g, 150# solvent naphtha 13g, adds water to 100g.Above raw material is prepared routinely the side of aqueous emulsion
Method puts into the mixing of mixing kettle high speed, and making effective Ingredient percent is 6% biphenyl pyrrole bacterium amine zineb aqueous emulsion.
Embodiment 15:62% biphenyl pyrrole bacterium amine zineb microemulsion (1:30)
Weigh 2g biphenyl pyrrole bacterium amine, 60g zineb, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphorus
Acid esters 3g, agriculture breast 33#2g, alkylphenol polyoxyethylene 1g, isopropanol 10g, add water to 100g.By above raw material
The method preparing microemulsion routinely puts into mixing in mixing kettle, and making effective Ingredient percent is 62% biphenyl pyrrole bacterium
Amine zineb microemulsion.
Embodiment 16:51% biphenyl pyrrole bacterium amine zineb suspending agent (1:50)
Weigh 1g biphenyl pyrrole bacterium amine, 50g zineb, lignin 2g, polyoxyethylene poly-oxygen propylene aether and sulfate 4g thereof,
Xanthan gum 0.15g, ethylene glycol 5g, siloxanes 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, at sand mill
Effect under to make effective Ingredient percent be 51% biphenyl pyrrole bacterium amine zineb suspending agent.
Embodiment 17:7% biphenyl pyrrole bacterium amine zineb water dispersion granule (1:2.5)
Weigh 2g biphenyl pyrrole bacterium amine, 5g zineb, wooden sodium sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, white carbon 3g, kieselguhr complement to 100g, above raw material are pressed water dispersion granule side
It is 7% biphenyl pyrrole bacterium amine zineb water dispersion granule that method makes effective ingredient mass percent.
Claims (10)
1. one kind contains biphenyl pyrrole bacterium amine and the bactericidal composition of zineb, it is characterised in that this bactericidal composition is with biphenyl pyrrole
Bacterium amine and zineb are principle active component, and wherein biphenyl pyrrole bacterium amine is 1～70:1～50 with the mass ratio of zineb.
Bactericidal composition the most according to claim 1, it is characterised in that described biphenyl pyrrole bacterium amine and the matter of zineb
Amount ratio is 1～50:1～50.
Bactericidal composition the most according to claim 2, it is characterised in that described biphenyl pyrrole bacterium amine and the matter of zineb
Amount ratio is 1～30:1～30.
Bactericidal composition the most according to claim 3, it is characterised in that described biphenyl pyrrole bacterium amine and the matter of zineb
Amount ratio is 1～10:1～30.
Bactericidal composition the most according to claim 1, it is characterised in that described biphenyl pyrrole bacterium amine and zineb two
It is 2-80% that person accounts for the weight/mass percentage composition of compositions.
Bactericidal composition the most according to claim 5, it is characterised in that described biphenyl pyrrole bacterium amine and zineb two
It is 5-70% that person accounts for the weight/mass percentage composition of compositions.
Bactericidal composition the most according to claim 1, it is characterised in that be main with biphenyl pyrrole bacterium amine and zineb
Effective ingredient and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.
Bactericidal composition the most according to claim 7, it is characterised in that described dosage form be cream, suspending agent,
Aqueous emulsion, wettable powder or water dispersion granule.
9. the application on preparation preventing and treating fungal diseases of plants medicine of the bactericidal composition described in claim 1.
Application the most according to claim 9, it is characterised in that described fungal diseases of plants be wheat powdery mildew,
At least one in downy mildew of garpe, wheat rust, the leaf blight of corn, tea rust, Nicotiana tabacum L. damping-off.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106719742A (en) * | 2017-04-01 | 2017-05-31 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing biphenyl pyrrole bacterium amine and its application |
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| EP2220937A2 (en) * | 2003-10-10 | 2010-08-25 | Bayer CropScience AG | Synergistic fungicidal combinations |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106719742A (en) * | 2017-04-01 | 2017-05-31 | 深圳诺普信农化股份有限公司 | A kind of bactericidal composition containing biphenyl pyrrole bacterium amine and its application |
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