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CN105949014A - High-performance compound emulsifier for emulsified explosive - Google Patents

High-performance compound emulsifier for emulsified explosive Download PDF

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Publication number
CN105949014A
CN105949014A CN201610264595.0A CN201610264595A CN105949014A CN 105949014 A CN105949014 A CN 105949014A CN 201610264595 A CN201610264595 A CN 201610264595A CN 105949014 A CN105949014 A CN 105949014A
Authority
CN
China
Prior art keywords
diluent
emulsifying agent
acid ester
fatty acid
glycol fatty
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610264595.0A
Other languages
Chinese (zh)
Inventor
唐秋明
唐力
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shimen Success Macromolecule Material Manufacturing Co Ltd
Original Assignee
Shimen Success Macromolecule Material Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shimen Success Macromolecule Material Manufacturing Co Ltd filed Critical Shimen Success Macromolecule Material Manufacturing Co Ltd
Priority to CN201610264595.0A priority Critical patent/CN105949014A/en
Publication of CN105949014A publication Critical patent/CN105949014A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B23/00Compositions characterised by non-explosive or non-thermic constituents

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

The invention discloses a high-performance compound emulsifier for an emulsified explosive and a production method thereof. The composite emulsifier is formed by compounding of two or more of sorbitan monooleate, porpylene glycol fatty acid ester, soybean lecithin, polyisobutylene succinimide and a diluent. The composite emulsifier has procurement, transportation, storage, preparation and other production procedures and complex production technology processes greatly simplified; the prepared emulsified explosive has the advantages of easy charging, stable detonation velocity, good detonation sensitivity, relatively slow performance attenuation along with time, and long storage period.

Description

A kind of high performance Compound emulsifier for emulsion explosive
Technical field
The present invention relates to a kind of high-performance compound emulsifying agent for Emulsion Explosive Production.
Background technology
The emulsifying agent being currently used for Emulsion Explosive Production is broadly divided into two kinds: a kind of sorbester p17 for low cost and phospholipid Mixture;The another kind of polyisobutene succinimide being high cost but extending shelf life.But it is because National security specifies, reducing emulsifying rotating speed, the polyisobutene succinimide of high molecular often cannot reach Shearing force needed for emulsifying, and create more how-do-you-do.So, a kind of high performance emulsifying is exploded Required for the production of the more and more emulsified explosive of medicinal compound emulsifying agent.
Summary of the invention
The present invention is according to the deficiency of prior art, it is provided that a kind of high performance Compound emulsifier for emulsion explosive and Its production method, to solve the deficiency of existing emulsifying agent.This compound emulsifying agent has steady quality, produces work Skill is simple, be prone to the advantages such as emulsifying, and the emulsified detonator loading of production is easy, explosion velocity is stable, detonation sensitivity is good.
The high performance Compound emulsifier for emulsion explosive of the present invention, by sorbitan monooleate, propylene glycol Fatty acid ester, soybean phospholipid form with the two or more interworking in polyisobutene succinimide and diluent.
The present invention high performance Compound emulsifier for emulsion explosive preferred version is: in parts by weight, dehydration mountain Pears alcohol monoleate be 300-900 part, methyl glycol fatty acid ester 100-500 part, soybean phospholipid be 50-200 Part, polyisobutene succinimide be 30-150 part, diluent be 30-150 part.
The present invention high performance Compound emulsifier for emulsion explosive more preferably scheme is: in parts by weight, described Be 450-800 part, methyl glycol fatty acid ester 150-400 part, soybean phospholipid by sorbitan monooleate For 50-150 part, polyisobutene succinimide be 50-100 part, diluent be 50-150 part.
The compound emulsifying agent of the present invention has and is prone to emulsifying, and explosive property is stable, stores the advantages such as phase length.This Compound emulsifying agent enormously simplify buying, transport, deposit, production routine and the production technology of complexity such as preparation Process, institute's made emulsification blasting: powder charge is easy, explosion velocity is stable, detonation sensitivity is good, performance decays relatively in time Slowly the phase, is stored long.
Detailed description of the invention
Example 1
By 450kg sorbitan monooleate, 400kg methyl glycol fatty acid ester, 50kg polyisobutylene fourth Imidodicarbonic diamide and 100kg diluent put in reactor after measuring respectively, are warming up to 80-90 DEG C, stir, Constant temperature stands 2 hours, cold filtration blowing, and tank bucket is packed.
Example 2
By 750kg sorbitan monooleate, 150kg soybean phospholipid, 50kg polyisobutylene succinyl Asia Amine and 50kg diluent put in reactor after measuring respectively, are warming up to 80-90 DEG C, stir, constant temperature Standing 2 hours, cold filtration blowing, tank bucket is packed.
Example 3
By 800kg sorbitan monooleate, 50kg polyisobutene succinimide and 150kg diluent Putting in reactor after metering respectively, be warming up to 80-90 DEG C, stir, constant temperature stands 2 hours, cooling Filtering blowing, tank bucket is packed.
Example 4
By 550kg sorbitan monooleate, 300kg methyl glycol fatty acid ester, 50kg polyisobutylene fourth Imidodicarbonic diamide and 100kg diluent put in reactor after measuring respectively, are warming up to 80-90 DEG C, stir, Constant temperature stands 2 hours, cold filtration blowing, and tank bucket is packed.
Example 5
By 700kg sorbitan monooleate, 150kg methyl glycol fatty acid ester, 50kg soybean phospholipid, 50kg polyisobutene succinimide and 50kg diluent put in reactor after measuring respectively, are warming up to 80-90 DEG C, stirring, constant temperature stands 2 hours, cold filtration blowing, and tank bucket is packed.
The compound emulsifying agent of the present invention has and is prone to emulsifying, and explosive property is stable, stores the advantages such as phase length.This Compound emulsifying agent enormously simplify buying, transport, deposit, production routine and the production technology of complexity such as preparation Process, institute's made emulsification blasting: powder charge is easy, explosion velocity is stable, detonation sensitivity is good, performance decays relatively in time Slowly the phase, is stored long.

Claims (9)

1. a high performance Compound emulsifier for emulsion explosive, it is characterised in that: by anhydrous sorbitol list oleic acid Ester, methyl glycol fatty acid ester, soybean phospholipid and two kinds or many in polyisobutene succinimide and diluent Plant interworking to form.
Compound emulsifying agent the most according to claim 1, it is characterised in that: in parts by weight, described dehydration Sorbitol monooleate be 300-900 part, methyl glycol fatty acid ester 100-500 part, soybean phospholipid be 50-200 Part, polyisobutene succinimide be 30-150 part, diluent be 30-150 part.
Compound emulsifying agent the most according to claim 2, it is characterised in that: in parts by weight, described dehydration Sorbitol monooleate be 450-800 part, methyl glycol fatty acid ester 150-400 part, soybean phospholipid be 50-150 Part, polyisobutene succinimide be 50-100 part, diluent be 50-150 part.
Compound emulsifying agent the most according to claim 1, it is characterised in that:
By 450kg sorbitan monooleate, 400kg methyl glycol fatty acid ester, 50kg polyisobutylene succinyl Imines is prepared from 100kg diluent.
Compound emulsifying agent the most according to claim 1, it is characterised in that: by 750kg anhydrous sorbitol list oil Acid esters, 150kg soybean phospholipid, 50kg polyisobutene succinimide are prepared from 50kg diluent.
Compound emulsifying agent the most according to claim 1, it is characterised in that: by 800kg anhydrous sorbitol list oil Acid esters, 50kg polyisobutene succinimide are prepared from 150kg diluent.
Compound emulsifying agent the most according to claim 1, it is characterised in that: by 550kg anhydrous sorbitol list oil Acid esters, 300kg methyl glycol fatty acid ester, 50kg polyisobutene succinimide are prepared with 100kg diluent Form.
Compound emulsifying agent the most according to claim 1, it is characterised in that: by 700kg anhydrous sorbitol list oil Acid esters, 150kg methyl glycol fatty acid ester, 50kg soybean phospholipid, 50kg polyisobutene succinimide and 50kg Diluent is prepared from.
9. according to described compound emulsifying agent arbitrary in claim 1-8, it is characterised in that prepare with the following method: After weighing respectively by formula, putting in reactor, be warming up to 80-90 DEG C, stir, it is little that constant temperature stands 2 Time, cold filtration blowing, tank bucket is packed.
CN201610264595.0A 2016-04-26 2016-04-26 High-performance compound emulsifier for emulsified explosive Pending CN105949014A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610264595.0A CN105949014A (en) 2016-04-26 2016-04-26 High-performance compound emulsifier for emulsified explosive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610264595.0A CN105949014A (en) 2016-04-26 2016-04-26 High-performance compound emulsifier for emulsified explosive

Publications (1)

Publication Number Publication Date
CN105949014A true CN105949014A (en) 2016-09-21

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610264595.0A Pending CN105949014A (en) 2016-04-26 2016-04-26 High-performance compound emulsifier for emulsified explosive

Country Status (1)

Country Link
CN (1) CN105949014A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113387760A (en) * 2021-07-08 2021-09-14 新乡市瑞丰新材料股份有限公司 Novel composite emulsifier for emulsion explosive

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010275A (en) * 2010-10-26 2011-04-13 广东宏大爆破股份有限公司 Readily-foaming emulsifying agent
CN102731230A (en) * 2012-07-03 2012-10-17 保利民爆济南科技有限公司 Catalytic slurry oil type emulsion explosive
CN102992921A (en) * 2011-09-11 2013-03-27 江西铜业股份有限公司 Emulsifier used for pre-charge

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010275A (en) * 2010-10-26 2011-04-13 广东宏大爆破股份有限公司 Readily-foaming emulsifying agent
CN102992921A (en) * 2011-09-11 2013-03-27 江西铜业股份有限公司 Emulsifier used for pre-charge
CN102731230A (en) * 2012-07-03 2012-10-17 保利民爆济南科技有限公司 Catalytic slurry oil type emulsion explosive

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113387760A (en) * 2021-07-08 2021-09-14 新乡市瑞丰新材料股份有限公司 Novel composite emulsifier for emulsion explosive

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Application publication date: 20160921

RJ01 Rejection of invention patent application after publication