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CN105924970A - Heat-resistant rubber for digital electric appliance - Google Patents

Heat-resistant rubber for digital electric appliance Download PDF

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Publication number
CN105924970A
CN105924970A CN201610458514.0A CN201610458514A CN105924970A CN 105924970 A CN105924970 A CN 105924970A CN 201610458514 A CN201610458514 A CN 201610458514A CN 105924970 A CN105924970 A CN 105924970A
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China
Prior art keywords
parts
rubber
resistant rubber
electrical apparatus
heat resistant
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Application number
CN201610458514.0A
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Chinese (zh)
Inventor
梅秀枝
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Anqing Yinrui Trading Co Ltd
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Anqing Yinrui Trading Co Ltd
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Priority to CN201610458514.0A priority Critical patent/CN105924970A/en
Publication of CN105924970A publication Critical patent/CN105924970A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses heat-resistant rubber for a digital electric appliance. The heat-resistant rubber is prepared from the following raw materials including silicon rubber, fluorine rubber, neoprene rubber, ethylene propylene rubber, polyfluortetraethylene, ethylene propylene diene rubber, polymethylmethacrylate, polyfluortetraethylene, chlorinated polyethylene, ethyl carbamate, trihydrate alumina, zinc carbonate, zinc hydroxide, paraffin, trolamine, polyethyleneglycol, sodium stearate, white carbon black, nano-zinc oxide, limestone powder, mica powder, N, N'-m-phenylenedimaleimide, vinyltriethoxysilane, hydroquinone, silicone emulsion, promoting agents TMTD and modified multiwalled carbon nanotubes. The heat-resistant rubber for the digital electric appliance has the advantages of excellent heat resistance performance, good sealing performance and high toughness.

Description

A kind of digital electrical apparatus heat resistant rubber
Technical field
The present invention relates to rubber materials, particularly relate to a kind of digital electrical apparatus heat resistant rubber.
Background technology
Complex circuit in digital electrical apparatus, containing a lot of micro parts, at work, inside holds digital electrical apparatus very much Being easily generated the highest temperature, thus the heat resistance logarithmic code electrical equipment of the internal used rubber of digital electrical apparatus is just Often work creates directly impact, directly affects the quality of digital electrical apparatus, but digital in prior art Demand when cannot meet actually used by the heat resistance of rubber inside electrical equipment, therefore needs a kind of number of design badly Code electrical equipment heat resistant rubber solves the problems of the prior art.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of digital electrical apparatus heat resistant rubber, There is the heat resistance of excellence.
A kind of digital electrical apparatus heat resistant rubber that the present invention proposes, its raw material includes by weight: silicon rubber 30-90 part, fluorubber 20-60 part, neoprene 10-30 part, EP rubbers 5-15 part, polytetrafluoroethyl-ne Alkene 2-9 part, ethylene propylene diene rubber 4-8 part, polymethyl methacrylate 1-5 part, polytetrafluoroethylene (PTFE) 2-6 Part, haloflex 2-4 part, urethanes 3-5 part, aluminium hydroxide 1-4 part, zinc carbonate 2-5 Part, zinc hydroxide 3-6 part, paraffin 1-4 part, triethanolamine 2-5 part, polyethylene glycol 2-6 part, tristearin Acid sodium 1-3 part, white carbon 2-5 part, nano zine oxide 3-6 part, agstone 1-3 part, mica powder 2-4 Part, N, N '-penylene BMI 1-4 part, VTES 2-5 part, to benzene two Phenol 1-5 part, silicone emulsion 2-6 part, Vulcanization accelerator TMTD 1-4 part, modified multiwalled carbon nanotube 3-9 part.
Preferably, modified multiwalled carbon nanotube is prepared by following technique: multi-walled carbon nano-tubes is added nitre Acid solution, at the 100-110 DEG C of 6-18h that refluxes after ultrasonic disperse, washing to neutral and filter, dry after add Coupling agent and N, N-Dicyclohexylcarbodiimide, in the 75-85 DEG C of 12-36h that refluxes after ultrasonic disperse, filter, Drying modified multiwalled carbon nanotube.
Preferably, the molar concentration of salpeter solution is 1.2-2.8mol/L.
Preferably, coupling agent is Silane coupling agent KH550, silane coupler KH570 or silane coupler Si69.
Preferably, multi-walled carbon nano-tubes, salpeter solution, coupling agent and N, the matter of N-Dicyclohexylcarbodiimide Amount ratio is 5-15:2-6:1-3:2-6.
Preferably, its raw material includes by weight: silicon rubber 35-85 part, fluorubber 25-55 part, neoprene Rubber 15-25 part, EP rubbers 8-12 part, polytetrafluoroethylene (PTFE) 3-8 part, ethylene propylene diene rubber 5-7 part, Polymethyl methacrylate 2-4 part, polytetrafluoroethylene (PTFE) 3-5 part, haloflex 2.5-3.5 part, amino Ethyl formate 3.5-4.5 part, aluminium hydroxide 2-3 part, zinc carbonate 3-4 part, zinc hydroxide 4-5 part, stone Wax 2-3 part, triethanolamine 3-4 part, polyethylene glycol 3-5 part, odium stearate 1.5-2.5 part, white carbon 2.5-4.5 part, nano zine oxide 4-5 part, agstone 1.5-2.5 part, mica powder 2.5-3.5 part, N, N '-penylene BMI 2-3 part, VTES 3-4 part, hydroquinones 2-4 Part, silicone emulsion 3-5 part, Vulcanization accelerator TMTD 2-3 part, modified multiwalled carbon nanotube 4-8 part.
Preferably, its raw material includes by weight: 60 parts of silicon rubber, fluorubber 40 parts, neoprene 20 Part, 10 parts of EP rubbers, polytetrafluoroethylene (PTFE) 5.5 parts, ethylene propylene diene rubber 6 parts, poly-methyl methacrylate Ester 3 parts, polytetrafluoroethylene (PTFE) 4 parts, haloflex 3 parts, urethanes 4 parts, aluminium hydroxide 2.5 Part, zinc carbonate 3.5 parts, zinc hydroxide 4.5 parts, 2.5 parts of paraffin, triethanolamine 3.5 parts, poly-second two Alcohol 4 parts, odium stearate 2 parts, white carbon 3.5 parts, nano zine oxide 4.5 parts, agstone 2 parts, Mica powder 3 parts, N, N '-penylene BMI 2.5 parts, VTES 3.5 parts, Hydroquinones 3 parts, silicone emulsion 4 parts, Vulcanization accelerator TMTD 2.5 parts, modified multiwalled carbon nanotube 6 parts.
The raw material of the digital electrical apparatus heat resistant rubber in the present invention include silicon rubber, fluorubber, neoprene, EP rubbers, polytetrafluoroethylene (PTFE), ethylene propylene diene rubber, polymethyl methacrylate, polytetrafluoroethylene (PTFE), chlorine Change polyethylene, urethanes, aluminium hydroxide, zinc carbonate, zinc hydroxide, paraffin, triethanolamine, Polyethylene glycol, odium stearate, white carbon, nano zine oxide, agstone, mica powder, N, N '-isophthalic Support BMI, VTES, hydroquinones, silicone emulsion, Vulcanization accelerator TMTD and Modified multiwalled carbon nanotube, with silicon rubber as major ingredient, auxiliary add fluorubber, neoprene, EP rubbers, Polytetrafluoroethylene (PTFE) and ethylene propylene diene rubber, as the supporting material of silicon rubber, are effectively increased the number of the present invention The heat resistance of electrical equipment heat resistant rubber and toughness;Add aluminium hydroxide, zinc carbonate, zinc hydroxide, paraffin, Triethanolamine, polyethylene glycol, odium stearate, white carbon, nano zine oxide, agstone, mica powder and Modified multiwalled carbon nanotube as filler, is effectively increased digital electrical apparatus heat resistant rubber heat-resisting of the present invention Performance;The polymethyl methacrylate of interpolation, polytetrafluoroethylene (PTFE), haloflex, urethanes, N, A N '-penylene BMI, VTES, hydroquinones, silicone emulsion and promotion Agent TMTD, as auxiliary agent, is effectively increased heat resistance and the toughness of the digital electrical apparatus heat resistant rubber of the present invention.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for The bright present invention rather than be used for limiting the invention, any made on the basis of the present invention amendment, Equivalents etc. are the most within the scope of the present invention.
In detailed description of the invention, the weight portion of silicon rubber can be 30 parts, 35 parts, 40 parts, 45 parts, 50 Part, 55 parts, 60 parts, 65 parts, 70 parts, 75 parts, 80 parts, 85 parts, 90 parts;The weight of fluorubber Part can be 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts, 60 parts;Chlorine The weight portion of buna can be 10 parts, 15 parts, 20 parts, 25 parts, 30 parts;The weight portion of EP rubbers Can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 Part;The weight portion of polytetrafluoroethylene (PTFE) can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 Part, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 9 parts;The weight portion of ethylene propylene diene rubber It can be 4-8 part;The weight portion of polymethyl methacrylate can be 1-5 part;The weight of polytetrafluoroethylene (PTFE) Part can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts;The weight portion of haloflex can be 2 parts, 2.5 Part, 3 parts, 3.5 parts, 4 parts;The weight portion of urethanes can be 3 parts, 3.5 parts, 4 parts, 4.5 Part, 5 parts;The weight portion of aluminium hydroxide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts;The weight portion of zinc carbonate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight portion of zinc hydroxide can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts;Stone The weight portion of wax can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts;Triethanolamine Weight portion can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts;Polyethylene glycol Weight portion can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight portion of odium stearate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts;The weight portion of white carbon It can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts;The weight portion of nano zine oxide It can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts;The weight portion of agstone can Think 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts;The weight portion of mica powder can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts;N, N ' weight portion an of-penylene BMI can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts;The weight portion of VTES can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts;The weight portion of hydroquinones can be 1 part, 2 Part, 3 parts, 4 parts, 5 parts;The weight portion of silicone emulsion can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight portion of Vulcanization accelerator TMTD can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts; The weight portion of modified multiwalled carbon nanotube can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts.
Embodiment 1
A kind of digital electrical apparatus heat resistant rubber that the present invention proposes, its raw material includes by weight: silicon rubber 60 Part, fluorubber 40 parts, neoprene 20 parts, 10 parts of EP rubbers, polytetrafluoroethylene (PTFE) 5.5 parts, ternary 6 parts of EP rubbers, polymethyl methacrylate 3 parts, polytetrafluoroethylene (PTFE) 4 parts, haloflex 3 parts, Urethanes 4 parts, 2.5 parts of aluminium hydroxide, zinc carbonate 3.5 parts, zinc hydroxide 4.5 parts, paraffin 2.5 parts, triethanolamine 3.5 parts, polyethylene glycol 4 parts, odium stearate 2 parts, white carbon 3.5 parts, nanometer 4.5 parts of zinc oxide, agstone 2 parts, mica powder 3 parts, N, a N '-penylene BMI 2.5 Part, VTES 3.5 parts, hydroquinones 3 parts, silicone emulsion 4 parts, Vulcanization accelerator TMTD 2.5 Part, modified multiwalled carbon nanotube 6 parts.
Modified multiwalled carbon nanotube is prepared by following technique: added by 10 parts of multi-walled carbon nano-tubes by weight Entering 4 parts of molar concentrations is the salpeter solution of 2.0mol/L, in 105 DEG C of 12h that reflux, washing after ultrasonic disperse To neutral and filter, dry after add 2 parts of Silane coupling agent KH550s and 4 parts of N, N-dicyclohexyl phosphinylidynes are sub- Amine, in 80 DEG C of 24h that reflux, filtration, drying modified multiwalled carbon nanotube after ultrasonic disperse.
Embodiment 2
A kind of digital electrical apparatus heat resistant rubber that the present invention proposes, its raw material includes by weight: silicon rubber 30 Part, fluorubber 60 parts, neoprene 10 parts, 15 parts of EP rubbers, polytetrafluoroethylene (PTFE) 2 parts, ternary second Third rubber 8 parts, polymethyl methacrylate 1 part, polytetrafluoroethylene (PTFE) 6 parts, haloflex 2 parts, ammonia Base Ethyl formate 5 parts, 1 part of aluminium hydroxide, zinc carbonate 5 parts, zinc hydroxide 3 parts, 4 parts of paraffin, three Monoethanolamine 2 parts, polyethylene glycol 6 parts, odium stearate 1 part, white carbon 5 parts, nano zine oxide 3 parts, Agstone 3 parts, mica powder 2 parts, N, N '-penylene BMI 4 parts, vinyl three ethoxy Base silane 2 parts, hydroquinones 5 parts, silicone emulsion 2 parts, Vulcanization accelerator TMTD 4 parts, modified many walls carbon are received Mitron 3 parts.
Modified multiwalled carbon nanotube is prepared by following technique: added by 15 parts of multi-walled carbon nano-tubes by weight Entering 2 parts of molar concentrations is the salpeter solution of 2.8mol/L, in 100 DEG C of 18h that reflux, washing after ultrasonic disperse To neutral and filter, dry after add 1 part of silane coupler KH570 and 6 parts of N, N-dicyclohexyl phosphinylidynes are sub- Amine, in 75 DEG C of 36h that reflux, filtration, drying modified multiwalled carbon nanotube after ultrasonic disperse.
Embodiment 3
A kind of digital electrical apparatus heat resistant rubber that the present invention proposes, its raw material includes by weight: silicon rubber 90 Part, fluorubber 20 parts, neoprene 30 parts, 5 parts of EP rubbers, polytetrafluoroethylene (PTFE) 9 parts, ternary second Third rubber 4 parts, polymethyl methacrylate 5 parts, polytetrafluoroethylene (PTFE) 2 parts, haloflex 4 parts, ammonia Base Ethyl formate 3 parts, 4 parts of aluminium hydroxide, zinc carbonate 2 parts, zinc hydroxide 6 parts, 1 part of paraffin, three Monoethanolamine 5 parts, polyethylene glycol 2 parts, odium stearate 3 parts, white carbon 2 parts, nano zine oxide 6 parts, Agstone 1 part, mica powder 4 parts, N, N '-penylene BMI 1 part, vinyl three ethoxy Base silane 5 parts, hydroquinones 1 part, silicone emulsion 6 parts, Vulcanization accelerator TMTD 1 part, modified many walls carbon are received Mitron 9 parts.
Modified multiwalled carbon nanotube is prepared by following technique: added by 5 parts of multi-walled carbon nano-tubes by weight Entering 6 parts of molar concentrations is the salpeter solution of 1.2mol/L, and at 110 DEG C of 6h that reflux after ultrasonic disperse, washing is extremely Neutral and filter, dry after add 3 parts of silane coupler Si69 and 2 parts of N, N-Dicyclohexylcarbodiimide, In 85 DEG C of 12h that reflux, filtration, drying modified multiwalled carbon nanotube after ultrasonic disperse.
Embodiment 4
A kind of digital electrical apparatus heat resistant rubber that the present invention proposes, its raw material includes by weight: silicon rubber 35 Part, fluorubber 55 parts, neoprene 15 parts, 12 parts of EP rubbers, polytetrafluoroethylene (PTFE) 3 parts, ternary second Third rubber 7 parts, polymethyl methacrylate 2 parts, polytetrafluoroethylene (PTFE) 5 parts, haloflex 2.5 parts, Urethanes 4.5 parts, 2 parts of aluminium hydroxide, zinc carbonate 4 parts, zinc hydroxide 4 parts, 3 parts of paraffin, Triethanolamine 3 parts, polyethylene glycol 5 parts, odium stearate 1.5 parts, white carbon 4.5 parts, nano zine oxide 4 Part, agstone 2.5 parts, mica powder 2.5 parts, N, N '-penylene BMI 3 parts, ethene 3 parts of ethyl triethoxy silicane alkane, hydroquinones 4 parts, silicone emulsion 3 parts, Vulcanization accelerator TMTD 3 parts, modification Multi-walled carbon nano-tubes 4 parts.
Modified multiwalled carbon nanotube is prepared by following technique: added by 12 parts of multi-walled carbon nano-tubes by weight Entering 3 parts of molar concentrations is the salpeter solution of 2.6mol/L, in 102 DEG C of 16h that reflux, washing after ultrasonic disperse To neutral and filter, dry after add 1.5 parts of Silane coupling agent KH550s and 5 parts of N, N-dicyclohexyl phosphinylidynes Imines, in 78 DEG C of 34h that reflux, filtration, drying modified multiwalled carbon nanotube after ultrasonic disperse.
Embodiment 5
A kind of digital electrical apparatus heat resistant rubber that the present invention proposes, its raw material includes by weight: silicon rubber 85 Part, fluorubber 25 parts, neoprene 25 parts, 8 parts of EP rubbers, polytetrafluoroethylene (PTFE) 8 parts, ternary second Third rubber 5 parts, polymethyl methacrylate 4 parts, polytetrafluoroethylene (PTFE) 3 parts, haloflex 3.5 parts, Urethanes 3.5 parts, 3 parts of aluminium hydroxide, zinc carbonate 3 parts, zinc hydroxide 5 parts, 2 parts of paraffin, Triethanolamine 4 parts, polyethylene glycol 3 parts, odium stearate 2.5 parts, white carbon 2.5 parts, nano zine oxide 5 Part, agstone 1.5 parts, mica powder 3.5 parts, N, N '-penylene BMI 2 parts, ethene 4 parts of ethyl triethoxy silicane alkane, hydroquinones 2 parts, silicone emulsion 5 parts, Vulcanization accelerator TMTD 2 parts, modification Multi-walled carbon nano-tubes 8 parts.
Modified multiwalled carbon nanotube is prepared by following technique: added by 8 parts of multi-walled carbon nano-tubes by weight Entering 5 parts of molar concentrations is the salpeter solution of 1.4mol/L, and at 128 DEG C of 8h that reflux after ultrasonic disperse, washing is extremely Neutral and filter, dry after add 2.5 parts of silane coupler KH570 and 3 parts of N, N-dicyclohexyl phosphinylidynes are sub- Amine, in 82 DEG C of 14h that reflux, filtration, drying modified multiwalled carbon nanotube after ultrasonic disperse.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention not office Being limited to this, any those familiar with the art is in the technical scope that the invention discloses, according to this The technical scheme of invention and inventive concept thereof in addition equivalent or change, all should contain the protection in the present invention Within the scope of.

Claims (7)

1. a digital electrical apparatus heat resistant rubber, it is characterised in that its raw material includes by weight: silicon rubber 30-90 part, fluorubber 20-60 part, neoprene 10-30 part, EP rubbers 5-15 part, polytetrafluoroethyl-ne Alkene 2-9 part, ethylene propylene diene rubber 4-8 part, polymethyl methacrylate 1-5 part, polytetrafluoroethylene (PTFE) 2-6 Part, haloflex 2-4 part, urethanes 3-5 part, aluminium hydroxide 1-4 part, zinc carbonate 2-5 Part, zinc hydroxide 3-6 part, paraffin 1-4 part, triethanolamine 2-5 part, polyethylene glycol 2-6 part, tristearin Acid sodium 1-3 part, white carbon 2-5 part, nano zine oxide 3-6 part, agstone 1-3 part, mica powder 2-4 Part, N, N '-penylene BMI 1-4 part, VTES 2-5 part, to benzene two Phenol 1-5 part, silicone emulsion 2-6 part, Vulcanization accelerator TMTD 1-4 part, modified multiwalled carbon nanotube 3-9 part.
Digital electrical apparatus heat resistant rubber the most according to claim 1, it is characterised in that modified many walls carbon Nanotube is prepared by following technique: multi-walled carbon nano-tubes adds salpeter solution, after ultrasonic disperse 100-110 DEG C of backflow 6-18h, washing to neutral and filter, dry after add coupling agent and N, N-dicyclohexyl Carbimide, in the 75-85 DEG C of 12-36h that refluxes after ultrasonic disperse, filtration, the modified many walls carbon of drying are received Mitron.
Digital electrical apparatus heat resistant rubber the most according to claim 1 and 2, it is characterised in that nitric acid is molten The molar concentration of liquid is 1.2-2.8mol/L.
4. according to the digital electrical apparatus heat resistant rubber described in any one of claim 1-3, it is characterised in that even Connection agent is Silane coupling agent KH550, silane coupler KH570 or silane coupler Si69.
5. according to the digital electrical apparatus heat resistant rubber described in any one of claim 1-4, it is characterised in that many Wall carbon nano tube, salpeter solution, coupling agent and N, the mass ratio of N-Dicyclohexylcarbodiimide is 5-15:2-6: 1-3:2-6.
6. according to the digital electrical apparatus heat resistant rubber described in any one of claim 1-5, it is characterised in that its Raw material includes by weight: silicon rubber 35-85 part, fluorubber 25-55 part, neoprene 15-25 part, EP rubbers 8-12 part, polytetrafluoroethylene (PTFE) 3-8 part, ethylene propylene diene rubber 5-7 part, poly-methyl methacrylate Ester 2-4 part, polytetrafluoroethylene (PTFE) 3-5 part, haloflex 2.5-3.5 part, urethanes 3.5-4.5 Part, aluminium hydroxide 2-3 part, zinc carbonate 3-4 part, zinc hydroxide 4-5 part, paraffin 2-3 part, three ethanol Amine 3-4 part, polyethylene glycol 3-5 part, odium stearate 1.5-2.5 part, white carbon 2.5-4.5 part, nanometer Zinc oxide 4-5 part, agstone 1.5-2.5 part, mica powder 2.5-3.5 part, N, a N '-penylene span Come acid imide 2-3 part, VTES 3-4 part, hydroquinones 2-4 part, silicone emulsion 3-5 Part, Vulcanization accelerator TMTD 2-3 part, modified multiwalled carbon nanotube 4-8 part.
7. according to the digital electrical apparatus heat resistant rubber described in any one of claim 1-6, it is characterised in that its Raw material includes by weight: 60 parts of silicon rubber, fluorubber 40 parts, neoprene 20 parts, EP rubbers 10 parts, polytetrafluoroethylene (PTFE) 5.5 parts, ethylene propylene diene rubber 6 parts, polymethyl methacrylate 3 parts, poly-four PVF 4 parts, haloflex 3 parts, urethanes 4 parts, 2.5 parts of aluminium hydroxide, zinc carbonate 3.5 parts, zinc hydroxide 4.5 parts, 2.5 parts of paraffin, triethanolamine 3.5 parts, polyethylene glycol 4 parts, hard 2 parts of resin acid sodium, white carbon 3.5 parts, nano zine oxide 4.5 parts, agstone 2 parts, mica powder 3 parts, N, N '-penylene BMI 2.5 parts, VTES 3.5 parts, hydroquinones 3 Part, silicone emulsion 4 parts, Vulcanization accelerator TMTD 2.5 parts, modified multiwalled carbon nanotube 6 parts.
CN201610458514.0A 2016-06-23 2016-06-23 Heat-resistant rubber for digital electric appliance Pending CN105924970A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108192171A (en) * 2017-11-22 2018-06-22 安徽唯你储能技术有限公司 A kind of hot-water bottle anti-aging rubber
CN108641231A (en) * 2018-05-16 2018-10-12 安徽华鑫电线电缆有限公司 A kind of electrical special oilproof composite cable

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