CN105838060A - Crystal fiber mixed heat conduction plastic material and preparation method thereof - Google Patents
Crystal fiber mixed heat conduction plastic material and preparation method thereof Download PDFInfo
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- CN105838060A CN105838060A CN201510753362.2A CN201510753362A CN105838060A CN 105838060 A CN105838060 A CN 105838060A CN 201510753362 A CN201510753362 A CN 201510753362A CN 105838060 A CN105838060 A CN 105838060A
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- 239000000463 material Substances 0.000 title claims abstract description 28
- 239000013078 crystal Substances 0.000 title claims abstract description 21
- 239000004033 plastic Substances 0.000 title claims abstract description 20
- 229920003023 plastic Polymers 0.000 title claims abstract description 20
- 239000000835 fiber Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229910052582 BN Inorganic materials 0.000 claims abstract description 9
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004952 Polyamide Substances 0.000 claims abstract description 9
- 239000003365 glass fiber Substances 0.000 claims abstract description 9
- 229920002647 polyamide Polymers 0.000 claims abstract description 9
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 7
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 6
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- -1 Merlon Polymers 0.000 claims description 10
- 229910017083 AlN Inorganic materials 0.000 claims description 8
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000002250 absorbent Substances 0.000 claims description 5
- 230000002745 absorbent Effects 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 235000010215 titanium dioxide Nutrition 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 239000003431 cross linking reagent Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000003063 flame retardant Substances 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000012745 toughening agent Substances 0.000 claims description 3
- 239000012744 reinforcing agent Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000006096 absorbing agent Substances 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 abstract 1
- 238000002955 isolation Methods 0.000 abstract 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 1
- 239000012815 thermoplastic material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910003978 SiClx Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000007743 anodising Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/28—Nitrogen-containing compounds
- C08K2003/282—Binary compounds of nitrogen with aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of plastic production and discloses a crystal fiber mixed heat conduction plastic material and a preparation method thereof. The crystal fiber mixed heat conduction plastic material comprises 20-50 parts of polyamide, 5-20 parts of glass fibers, 5-40 parts of silicon carbide, 5-15 parts of aluminum nitride, 5-15 parts of boron nitride, 0.2-2 parts of an anti-oxidant, 0.3-1 part of a UV absorber and 1-9 parts of other auxiliary agents. The crystal fiber mixed heat conduction plastic material realizes high efficiency, a low production cost, good electrical isolation effects and stable performances.
Description
Technical field:
The present invention relates to plastic cement production technical field, refer in particular to crystal fibre mixed type heat conduction plastic cement
Material and preparation method thereof.
Background technology:
Current LED radiator typically uses metal material, and radiator is by die casting, punching press
Pickling, anodising etc. is needed after stretching out；The most not only to environment,
And inefficiency, cost is high, and light fixture product weight is big, electric insulating effect is poor, and heat conduction is moulded
The unstable properties of glue material.
Summary of the invention:
It is an object of the invention to for the deficiencies in the prior art, and provide crystal fibre mixed type to lead
Thermoplastic material and preparation method thereof, the present invention solves prior art existing problems, efficiency
Height, production cost is low, and electric insulating effect is good, the stable performance of heat conductive plastic material.
For achieving the above object, the present invention adopts the following technical scheme that, crystal fibre mixed type is led
Thermoplastic material, its component and parts by weight are:
Its component and parts by weight are:
Described polyamide can be with a kind of replacement in materials described below: polyester (PBT, PET)
Merlon, polypropylene, polyethylene, polystyrene, epoxy resin, polyurethane etc..
Described glass fiber diameter is more than 8um.
Described carborundum, boron nitride, aluminium nitride belong to crystal structure.
Other auxiliary agents described are selected from filler (such as titanium dioxide), cross-linking agent, toughener, enhancing
One or more mixing in agent, age resister, dispersant, stabilizer, fire retardant.
Its preparation method of crystal fibre mixed type heat conductive plastic material, following steps:
(1) raw material is weighed by weight percentage: polyamide 40 parts, glass fibre 8 parts, carbon
SiClx 30 parts, aluminium nitride 10 parts, boron nitride 10 parts；
(2) take 0.2 part of antioxidant and UV absorbent 0.2 part, add homogenizer
In, stir 25-60 minute；
(3) take titanium white part 1.6 parts, add in homogenizer, stir 15-30 minute；
(4) by mixing in homogenizer in step (2) and step (3), 20-50 is stirred
After minute, obtain compound；
(5) compound that step (4) obtains is placed in double screw extruder, material melts
After, carry out pelletize；
(6) material prepared in step (5) is carried out injection mo(u)lding.
Present invention have the beneficial effect that efficiency is high, production cost is low, and electric insulating effect is good, leads
The stable performance of thermoplastic material.
Detailed description of the invention:
Crystal fibre mixed type heat conductive plastic material of the present invention, its component and parts by weight are:
Its component and parts by weight are:
Can be with a kind of replacement in materials described below described in described polyamide: polyester (PBT, PET)
Merlon, polypropylene, polyethylene, polystyrene, epoxy resin, polyurethane etc..
Described glass fiber diameter is more than 8um.
Described carborundum, boron nitride, aluminium nitride belong to crystal structure.
Other auxiliary agents described are selected from filler (such as titanium dioxide), cross-linking agent, toughener, enhancing
One or more mixing in agent, age resister, dispersant, stabilizer, fire retardant.
Embodiment 1
Its preparation method of crystal fibre mixed type heat conductive plastic material, following steps:
(1) raw material is weighed by weight percentage: polyamide 40 parts, glass fibre 8 parts, carbon
SiClx 30 parts, aluminium nitride 10 parts, boron nitride 10 parts；
(2) take 0.2 part of antioxidant and UV absorbent 0.2 part, add homogenizer
In, stir 25-60 minute；
(3) take titanium white part 1.6 parts, add in homogenizer, stir 15-30 minute；
(4) by mixing in homogenizer in step (2) and step (3), 20-50 is stirred
After minute, obtain compound；
(5) compound that step (4) obtains is placed in double screw extruder, material melts
After, carry out pelletize；
(6) material prepared in step (5) is carried out injection mo(u)lding.
The performance test results:
In embodiment 1, the impact resistance of product is 280J/M, and tensile property is 60Mpa.Product
Being respectively provided with good shock resistance and stretch-proof performance, electric insulating effect is good, heat conductive plastic material
Stable performance.
The above is only presently preferred embodiments of the present invention, therefore all according to present patent application model
Enclose equivalence change or modification that described structure, feature and principle is done, be all included in this
In bright patent claim.
Claims (7)
1. crystal fibre mixed type heat conductive plastic material, it is characterised in that its component and parts by weight are:
Polyamide 20-50 part；
Glass fibre 5-20 part；
Carborundum 5-40 part；
Aluminium nitride 5-15 part；
Boron nitride 5-15 part；
Antioxidant 0.2-2 part；
UV absorbent 0.3-1 part
Other auxiliary agents: 1-9 part.
Crystal fibre mixed type heat conductive plastic material the most according to claim 1, it is characterised in that: its component and parts by weight are:
Polyamide 40 parts；
Glass fibre 8 parts；
Carborundum 30 parts；
Aluminium nitride 10 parts；
Boron nitride 10 parts；
0.2 part of antioxidant；
UV absorbent 0.2 part
Titanium dioxide 1.6%.
Crystal fibre mixed type heat conductive plastic material the most according to claim 1, it is characterised in that: described polyamide can be with a kind of replacement in materials described below: polyester (PBT, PET), Merlon, polypropylene, polyethylene, polystyrene, epoxy resin, polyurethane etc..
Crystal fibre mixed type heat conductive plastic material the most according to claim 1, it is characterised in that: described glass fiber diameter is more than 8um.
Crystal fibre mixed type heat conductive plastic material the most according to claim 1, it is characterised in that: described carborundum, boron nitride, aluminium nitride belong to crystal structure.
Crystal fibre mixed type heat conductive plastic material the most according to claim 1, it is characterised in that: other described auxiliary agents one or more mixing in filler (such as titanium dioxide), cross-linking agent, toughener, reinforcing agent, age resister, dispersant, stabilizer, fire retardant.
7. its preparation method of crystal fibre mixed type heat conductive plastic material, it is characterised in that: preparation method following steps:
(1) raw material is weighed by weight percentage: polyamide 40 parts, glass fibre 8 parts, carborundum 30 parts, aluminium nitride 10 parts, boron nitride 10 parts；
(2) take 0.2 part of antioxidant and UV absorbent 0.2 part, add in homogenizer, stir 25-60 minute；
(3) take titanium white part 1.6 parts, add in homogenizer, stir 15-30 minute；
(4) by mixing in homogenizer in step (2) and step (3), after stirring 20-50 minute, compound is obtained；
(5) compound that step (4) obtains is placed in double screw extruder, after material melts, carries out pelletize；
(6) material prepared in step (5) is carried out injection mo(u)lding.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510753362.2A CN105838060A (en) | 2015-11-05 | 2015-11-05 | Crystal fiber mixed heat conduction plastic material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510753362.2A CN105838060A (en) | 2015-11-05 | 2015-11-05 | Crystal fiber mixed heat conduction plastic material and preparation method thereof |
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| CN105838060A true CN105838060A (en) | 2016-08-10 |
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| CN201510753362.2A Pending CN105838060A (en) | 2015-11-05 | 2015-11-05 | Crystal fiber mixed heat conduction plastic material and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221200A (en) * | 2016-08-18 | 2016-12-14 | 桐城市弘业塑胶有限公司 | A kind of wear-resisting ventilative heat conductive plastic material |
| CN106433101A (en) * | 2016-08-18 | 2017-02-22 | 桐城市弘业塑胶有限公司 | Refractory wear-resistant plastic material |
| CN107383850A (en) * | 2017-08-25 | 2017-11-24 | 佛山市彩贵新型材料有限公司 | The preparation method of high-strength anti-flaming composite |
| CN108653822A (en) * | 2018-04-28 | 2018-10-16 | 温州市中心医院 | A kind of degradable visual inner locking type femoral interlocking nail |
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| CN103059565A (en) * | 2013-01-25 | 2013-04-24 | 本松工程塑料（杭州）有限公司 | Heat-conducting nylon composite material, preparation method and application thereof |
| CN103602060A (en) * | 2013-11-06 | 2014-02-26 | 上海大学 | Heat-conducting, wear-resistant and insulated nylon 6 composite material and preparation method thereof |
| CN104387761A (en) * | 2014-11-11 | 2015-03-04 | 惠州市沃特新材料有限公司 | High-thermal conductivity polyamide composite material and preparation method thereof |
| CN104610738A (en) * | 2014-12-16 | 2015-05-13 | 惠州力王佐信科技有限公司 | High performance heat dissipation composite material |
-
2015
- 2015-11-05 CN CN201510753362.2A patent/CN105838060A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102719099A (en) * | 2012-06-08 | 2012-10-10 | 金发科技股份有限公司 | Thermal conductive molding compound and preparation method thereof |
| CN103059565A (en) * | 2013-01-25 | 2013-04-24 | 本松工程塑料（杭州）有限公司 | Heat-conducting nylon composite material, preparation method and application thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221200A (en) * | 2016-08-18 | 2016-12-14 | 桐城市弘业塑胶有限公司 | A kind of wear-resisting ventilative heat conductive plastic material |
| CN106433101A (en) * | 2016-08-18 | 2017-02-22 | 桐城市弘业塑胶有限公司 | Refractory wear-resistant plastic material |
| CN107383850A (en) * | 2017-08-25 | 2017-11-24 | 佛山市彩贵新型材料有限公司 | The preparation method of high-strength anti-flaming composite |
| CN108653822A (en) * | 2018-04-28 | 2018-10-16 | 温州市中心医院 | A kind of degradable visual inner locking type femoral interlocking nail |
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