CN105820817A - 一种钪酸盐绿色荧光粉及其制备方法 - Google Patents
一种钪酸盐绿色荧光粉及其制备方法 Download PDFInfo
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- CN105820817A CN105820817A CN201610226919.1A CN201610226919A CN105820817A CN 105820817 A CN105820817 A CN 105820817A CN 201610226919 A CN201610226919 A CN 201610226919A CN 105820817 A CN105820817 A CN 105820817A
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- presoma
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 91
- 239000000126 substance Substances 0.000 claims abstract description 18
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 238000003746 solid phase reaction Methods 0.000 claims abstract description 6
- 238000005245 sintering Methods 0.000 claims description 24
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 18
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 229910002651 NO3 Inorganic materials 0.000 claims description 15
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 15
- 150000003891 oxalate salts Chemical class 0.000 claims description 14
- 229910052712 strontium Inorganic materials 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 229910052706 scandium Inorganic materials 0.000 claims description 5
- 238000010671 solid-state reaction Methods 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 2
- 238000007906 compression Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 16
- 239000000843 powder Substances 0.000 abstract description 14
- 238000002156 mixing Methods 0.000 abstract description 7
- 238000009877 rendering Methods 0.000 abstract description 7
- 239000012190 activator Substances 0.000 abstract description 5
- 239000002243 precursor Substances 0.000 abstract 4
- 239000012695 Ce precursor Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 14
- 239000002994 raw material Substances 0.000 description 14
- 239000013078 crystal Substances 0.000 description 12
- 238000000295 emission spectrum Methods 0.000 description 12
- 239000011734 sodium Substances 0.000 description 11
- 238000001816 cooling Methods 0.000 description 8
- 238000001228 spectrum Methods 0.000 description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- HYXGAEYDKFCVMU-UHFFFAOYSA-N scandium(III) oxide Inorganic materials O=[Sc]O[Sc]=O HYXGAEYDKFCVMU-UHFFFAOYSA-N 0.000 description 7
- LEDMRZGFZIAGGB-UHFFFAOYSA-L strontium carbonate Chemical compound [Sr+2].[O-]C([O-])=O LEDMRZGFZIAGGB-UHFFFAOYSA-L 0.000 description 7
- 229910000018 strontium carbonate Inorganic materials 0.000 description 7
- QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 description 6
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 6
- 230000005284 excitation Effects 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000003086 colorant Substances 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 238000002447 crystallographic data Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 3
- 229910052808 lithium carbonate Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 241001269238 Data Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000005424 photoluminescence Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7766—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
- C09K11/7767—Chalcogenides
- C09K11/7768—Chalcogenides with alkaline earth metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/77—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
- C09K11/7701—Chalogenides
- C09K11/7702—Chalogenides with zinc or cadmium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/50—Wavelength conversion elements
- H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
- H01L33/502—Wavelength conversion materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Power Engineering (AREA)
- Luminescent Compositions (AREA)
Abstract
Description
Claims (10)
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CN201610226919.1A CN105820817B (zh) | 2016-04-13 | 2016-04-13 | 一种钪酸盐绿色荧光粉及其制备方法 |
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CN201610226919.1A CN105820817B (zh) | 2016-04-13 | 2016-04-13 | 一种钪酸盐绿色荧光粉及其制备方法 |
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CN105820817A true CN105820817A (zh) | 2016-08-03 |
CN105820817B CN105820817B (zh) | 2018-11-06 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107903896A (zh) * | 2017-11-13 | 2018-04-13 | 河北紫旭节能环保技术咨询有限公司 | 一种绿色荧光粉及其制备方法 |
CN109135745A (zh) * | 2018-09-13 | 2019-01-04 | 济南大学 | 一种白光led用黄色荧光粉的制备方法及其应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009161576A (ja) * | 2007-12-28 | 2009-07-23 | Mitsubishi Chemicals Corp | 蛍光体及びそれを用いた発光装置 |
CN103451600A (zh) * | 2012-05-30 | 2013-12-18 | 海洋王照明科技股份有限公司 | 铈掺杂碱金属钪酸盐发光薄膜、其制备方法和应用 |
-
2016
- 2016-04-13 CN CN201610226919.1A patent/CN105820817B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009161576A (ja) * | 2007-12-28 | 2009-07-23 | Mitsubishi Chemicals Corp | 蛍光体及びそれを用いた発光装置 |
CN103451600A (zh) * | 2012-05-30 | 2013-12-18 | 海洋王照明科技股份有限公司 | 铈掺杂碱金属钪酸盐发光薄膜、其制备方法和应用 |
Non-Patent Citations (2)
Title |
---|
VON HK. MULLER-BUSCEBA等: "Zur Verbindungsbildunq von MeO:M2O3. Ein neuer Bautyp : SrCa2Sc6O12", 《Z. ANORG. ALLG. CHEM.》 * |
YASUO SHIMOMURA等: "Photoluminescence and Crystal Structure of Green-Emitting Phosphor CaSc2O4:Ce3+", 《JOURNAL OF THE ELECTROCHEMICAL SOCIETY》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107903896A (zh) * | 2017-11-13 | 2018-04-13 | 河北紫旭节能环保技术咨询有限公司 | 一种绿色荧光粉及其制备方法 |
CN109135745A (zh) * | 2018-09-13 | 2019-01-04 | 济南大学 | 一种白光led用黄色荧光粉的制备方法及其应用 |
CN109135745B (zh) * | 2018-09-13 | 2021-12-14 | 济南大学 | 一种白光led用黄色荧光粉的制备方法及其应用 |
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CN105820817B (zh) | 2018-11-06 |
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Inventor after: Jie Rongjun Inventor after: Zhou Tianliang Inventor after: Li Ye Inventor after: Zhuang Yixi Inventor before: Jie Rongjun Inventor before: Zhou Tianliang Inventor before: Zhuang Yixi Inventor before: Li Ye |
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CB03 | Change of inventor or designer information |
Inventor after: Zhou Tianliang Inventor after: Li Ye Inventor after: Zhuang Yixi Inventor before: Jie Rongjun Inventor before: Zhou Tianliang Inventor before: Li Ye Inventor before: Zhuang Yixi |
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Granted publication date: 20181106 Termination date: 20200413 |