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CN105796408B - Composition of plant extracts and its application in cosmetics and fluid composition and preparation method thereof of removing ornaments and formal dress - Google Patents

Composition of plant extracts and its application in cosmetics and fluid composition and preparation method thereof of removing ornaments and formal dress Download PDF

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Publication number
CN105796408B
CN105796408B CN201610151419.6A CN201610151419A CN105796408B CN 105796408 B CN105796408 B CN 105796408B CN 201610151419 A CN201610151419 A CN 201610151419A CN 105796408 B CN105796408 B CN 105796408B
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weight
extract
content
composition
makeup removing
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CN105796408A (en
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李春苗
吕雪梅
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Anhui Huachen Testing Technology Research Institute Co ltd
Guobiao Beijing Testing & Certification Co ltd
Yunnan Kewang Biotechnology Co ltd
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Thousand Mu Mu (beijing) Technology Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005Antimicrobial preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/008Preparations for oily skin

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Dermatology (AREA)
  • Epidemiology (AREA)
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  • Microbiology (AREA)
  • Botany (AREA)
  • Biotechnology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to cosmetic fields, and in particular to a kind of composition of plant extracts and its application in cosmetics, the composition of plant extracts contain camellia seed oil, soapberry seed oil, Thallus Laminariae (Thallus Eckloniae) extract, olive extract and aloe extract.Also disclose a kind of makeup removing fluid composition and preparation method thereof.Composition of plant extracts provided by the invention takes into account moisturizing, oil-control, the multiple efficacies such as firm skin and sterilization, and also has effects that collaboration between each component of the plant extracts, the effect of each component point is set to perform to maximum, makeup removing fluid composition moisturizing while perfection makeup removing being prepared into using it as effective component, felt immediately after use water ripple it is soft and smooth, firmly lock skin natural nutrient, lasting moisturizing, the through flesh bottom of makeup removing, the clean oil-control of deep layer, skin is set to keep elasticity, firm skin, also has effects that bactericidal antiphlogistic, to heavy make-up, color make-up is equally applicable.

Description

Composition of plant extracts and its application and makeup removing fluid composition in cosmetics And preparation method thereof
Technical field
The invention belongs to cosmetic fields, are related to a kind of composition of plant extracts and the composition of plant extracts Application in cosmetics further relates to a kind of makeup removing fluid composition and preparation method thereof.
Background technique
Present makeup removal products on the market are divided into makeup removing breast, make up remover, three kinds of makeup remover by quality.Difference is: oiliness is unloaded The molten oiliness of adornment product is stronger;Makeup removing breast and make up remover water and oil balance are moderate, and oil components can wash away dirt, and water composition It again can be with moisturizing.In fact, the product that effect should be selected different according to different skin quality.For example, the skin of oiliness partially is clear Clean increasingly important, preferably selecting can thoroughly clean, have the makeup removal products of oil-control effect again;And for partially dry skin, then it should select The makeup removal products of moist effect.Eye lip skin is very delicate, need to use the eye lip makeup removal products of profession, make it both can be thoroughly clear It is clean and sensitive skin can be protected.
Following two situation, needs using makeup remover.
1) water proof type, persistent form color make-up, or when having gone up many cosmetics with pigment on the face, need a large amount of makeup remover It could thoroughly dissolve, clean.
2) sun-proof articles, sun screen (product especially with modification colour of skin function) quality are all very dense, physical Sun-prevention component is a kind of oil-soluble acne, needs just unload using makeup remover clean.
Currently, commercially available makeup remover only remove ornaments and formal dress the effect of, therefore, like makeup personage with makeup remover remove ornaments and formal dress when It waits, makeup remover can be preferred to and contain firm skin, moisturizing, oil-control, sterilization and other effects.
Summary of the invention
It is an object of the invention to overcome the defect of the makeup remover of commercial type, providing one kind being capable of effective compact skin Skin, moisturizing, oil-control, sterilization composition of plant extracts, application and a kind of makeup remover group of the composition in cosmetics Close object and preparation method thereof.
In order to achieve the goal above, in a first aspect, the present invention provides a kind of composition of plant extracts, wherein the plant Object extractive composition contains camellia seed oil, soapberry seed oil, Thallus Laminariae (Thallus Eckloniae) extract, olive extract and aloe extract.
Second aspect, the present invention provides application of the composition of plant extracts as described above in cosmetics.
The third aspect, the present invention also provides a kind of makeup removing fluid compositions, wherein the makeup removing fluid composition contains institute as above The composition of plant extracts stated is as effective component, on the basis of the total weight of the makeup removing fluid composition, it is described effectively at The content divided is 1-60 weight %.
Preferably, also contain auxiliary material in the composition, the auxiliary material is tri- glyceryl isostearate of PEG-20, three pungent Acid/glycerol decanoate, white oil, octyl palmitate, Vitwas E and essence.
Fourth aspect, the present invention also provides a kind of preparation methods of fluid composition of removing ornaments and formal dress, this method comprises: by institute as above The effective component and auxiliary material as described above stated are mixed.
Composition of plant extracts provided by the invention takes into account the multiple efficacies such as moisturizing, oil-control, firm skin and sterilization, and And also have effects that collaboration between each component of the plant extracts, so that the effect of each component is performed to maximum, is with it The makeup removing fluid composition that effective component is prepared into moisturizing while perfection makeup removing, feels water immediately and ripples soft and smooth, firmly lock after use Skin natural nutrient, lasting moisturizing, through flesh bottom of removing ornaments and formal dress, the clean oil-control of deep layer make skin keep elasticity, firm skin, also have There is the effect of bactericidal antiphlogistic, it is equally applicable to heavy make-up, color make-up.
Other features and advantages of the present invention will the following detailed description will be given in the detailed implementation section.
Specific embodiment
Detailed description of the preferred embodiments below.It should be understood that described herein specific Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
In a first aspect, the present invention provides a kind of composition of plant extracts, wherein the composition of plant extracts contains Camellia seed oil, soapberry seed oil, Thallus Laminariae (Thallus Eckloniae) extract, olive extract and aloe extract;It is preferred that by camellia seed oil, soapberry seed Oil, Thallus Laminariae (Thallus Eckloniae) extract, olive extract and aloe extract composition.
Camellia (CAMELLIA JAPONICA), alias are also known as datura, Hai Shiliu, shallow lake overgrown with wild plants spring, mountain Chinese toon, resistance to winter, camellia oil Manufacturing process can for example be divided into: by drying camellia seed decladding, crush, (also known as, oil expression, filtering can obtain camellia seed oil Camellia oil, tea-seed oil, camellia seed oil).Camellia seed oil is full of nutrition, reduces blood pressure, blood lipid, prevents and treats heart disease and softening blood vessel The effects of.It can be by voluntarily preparing, can also be commercially available, for example, being purchased from Perfect (China) Co., Ltd..
The soapberry seed oil is preferably the seed oil of India's soapberry (SCHLEICHERA TRIJUGA), soapberry seed oil In sapindoside be a kind of natural nonionic surface active agent, the surface tension of water, foaming abundancy, feel can be reduced Exquisiteness, strong detergency have antibacterial, environmental protection, nuisanceless, foaming abundancy, take out stains, antibacterial beauty, tender skin, brighten and dispel The features such as spot, anti-acne, prevention and treatment skin disease.Its extraction process can be various techniques commonly used in the art, for example, can incite somebody to action Soapberry seed dries stoning, obtains soapberry pericarp, through the modern crafts such as Microwave Extraction extraction effective component, is spray dried to Powder obtains soapberry extract finished product.It can be commercially available, for example, can be super purchased from large-scale quotient, it can also purchase From companies such as three He Tian companies.
Thallus Laminariae (Thallus Eckloniae) extract is preferably sugared kelp (Laminaria Saccharina) extract, a kind of sugared kelp (brown algae Class) extract be it is known in the art, an example is to be gone out with trade name Féraud stamen gold by Marine Biotech, France The product sold.Another example is the product pacifying moist Bioisystech Co., Ltd and selling, and be can be used for such as osmotic protection film, certainly In the cosmetic composition acted on by base scavenger or resisting age of skin.
Olive extract of the present invention is preferably the extract of olive (Canarium Album) seed, that is, olive Olive oil with anticancer, anti-aging and sharp intelligent and strengthening brain, radiation protection, improves digestive system function, into bile secretion and intensifies pancreatin Vigor, so as to play the role of prevention and control gastric ulcer, duodenal ulcer and disease of biliary tract, bone can be enhanced to minerals The absorption of calcium can promote infant's nerve and skeleton development, can enhance skin elasticity.It can purchase exceeding the amount stipulated in large-scale quotient and can buy, It can also voluntarily prepare, for example, passing through squeezing process.
Aloe extract is preferably aloe barbadensis Miller (Aloe Barbadensis) extract, the anthraquinone analog compound of aloe With making skin contraction, softness, the performance of moisturizing, anti-inflammatory, bleaching.There are also release hardening, angling, improvement scar effect, It can not only prevent small wrinkle, eye pouch, cutis laxa, moreover it is possible to skin wet, delicate is kept, at the same time it can also treat scytitis, Also there is good curative effect to acne, freckle, acne and scald, knife wound, insect bite etc..It is similarly effective to hair, hair can be made Holding moistens smooth, prevents hair loss.Preparation method can be various preparation methods well known in the art, for example, traditional endures Process processed, current Cobble and Coats heat treating process and McAnalley and Coats cold-treating process, also or according to It is prepared by the method in the master thesis of " preparation process and quality standard research of aloe extract " Zhang Cuili, or It is available from the companies such as the gloomy Biotechnology Co., Ltd in Anyuan.
Although various composition as above is sent out with the use of good synergistic effect, the present inventor can be realized Existing, on the basis of the total weight of the composition of plant extracts, the content of the camellia seed oil is 1-95 weight %, the nothing The content for suffering from sub- seed oil is 1-95 weight %, and the content of the Thallus Laminariae (Thallus Eckloniae) extract is 1-95 weight %, the olive extract Content is 1-95 weight %, and the content of the aloe extract is 1-95 weight %;Preferably, with plant extracts combination On the basis of the total weight of object, the content of the camellia seed oil is 15-60 weight %, and the content of the soapberry seed oil is 10-45 Weight %, the content of the Thallus Laminariae (Thallus Eckloniae) extract are 5-40 weight %, and the content of the olive extract is 10-45 weight %, institute The content for stating aloe extract is 15-60 weight %;It is furthermore preferred that using the total weight of the composition of plant extracts as base Standard, the content of the camellia seed oil are 20-40 weight %, and the content of the soapberry seed oil is 15-30 weight %, the kelp The content of extract is 10-20 weight %, and the content of the olive extract is 15-30 weight %, the aloe extract Content is 20-40 weight %.In range preferred in this way, the synergy between various composition can be mentioned further It rises.
It was found by the inventors of the present invention that although the effective component, which carries out cooperation according to proportion as above, can realize this The purpose of invention, but when the weight ratio of camellia seed oil, soapberry seed oil, Thallus Laminariae (Thallus Eckloniae) extract, olive extract and aloe extract Preferably 1:(0.1-10): (0.1-10): (0.1-10): (0.1-10), more preferably 1:(0.3-1.5): (0.2-1): (0.3- 1.5): (0.5-2), further preferably 1:(0.5-1): (0.5-0.8): (0.5-1): when (0.8-1.5), gained synergy It can further be promoted.
Based on the beneficial effect of composition of plant extracts as above, second aspect, the present invention also provides as described above Application of the composition of plant extracts in cosmetics.
Wherein, the cosmetics can be the various cosmetics of this field routine, for example, shampoo, hair conditioner, makeup removing Oil, creams, toner etc..But it was found by the inventors of the present invention that composition of plant extracts as described above is especially suitable for system For at makeup remover.
Based on this, the third aspect, the present invention provides a kind of makeup removing fluid compositions, wherein the makeup removing fluid composition contains Composition of plant extracts as described above is as effective component, on the basis of the total weight of the makeup remover, it is described effectively at The content divided is 1-60 weight %, preferably 10-40 weight %.
According to the present invention, auxiliary material is also contained in the makeup removing fluid composition, the auxiliary material can be commonly used in the art Various auxiliary materials, the present invention is not particularly limited.For example, the auxiliary material can for tri- glyceryl isostearate of PEG-20, One of three caprylic/capric glyceride, white oil, octyl palmitate, Vitwas E and essence are a variety of, it is furthermore preferred that The auxiliary material is tri- glyceryl isostearate of PEG-20, three caprylic/capric glyceride, white oil, octyl palmitate, vitamin E vinegar Acid esters and essence.When auxiliary material of the invention preferably as above each ingredient, the makeup removing fluid composition can be further increased Performance.Wherein, the white oil is preferably the 3# white oil of cosmetics-stage.
The present invention is not particularly limited the content of the auxiliary material, can be the content of the auxiliary material of this field routine, Preferably, the content of the auxiliary material is 40-99 weight %, more preferably 60-90 weight %.
It is further preferred that on the basis of the total weight of the auxiliary material, the content of tri- glyceryl isostearate of PEG-20 is 1-10 weight %, three caprylic/capric glyceride content be 5-30 weight %, the content of white oil is 30-50 weight %, palmitinic acid The content of monooctyl ester is 30-50 weight %, the content of Vitwas E is 0.5-1.5 weight %, and the content of essence is 0.1- 0.5 weight %;Still more preferably, on the basis of the total weight of the auxiliary material, tri- glyceryl isostearate of PEG-20 contains Amount is 4-6 weight %, the content of three caprylic/capric glyceride is 10-20 weight %, the content of white oil is 35-45 weight %, palm fibre The content of the misery ester of palmitic acid is 35-45 weight %, the content of Vitwas E is 0.8-1.2 weight %, and the content of essence is 0.2-0.3 weight %.
Wherein, the essence can be various essence commonly used in the art, can be selected according to actual needs The addition of selecting property, for example, the essence can for green cucumber essence, flavoring rose essence, osmanthus flower fragrance, peach flavor, lemon extract, One of flavoring pineapple essence and cream jasmin france are a variety of.
Fourth aspect, the present invention also provides a kind of preparation methods of fluid composition of removing ornaments and formal dress, this method comprises: by institute as above The effective component and auxiliary material as described above stated are mixed.
A specific embodiment of the invention described in detail below.
In following embodiment and comparative example,
The camellia seed oil is purchased from Perfect (China) Co., Ltd.;
Soapberry seed oil is purchased from three He Tian companies;
Sugar Thallus Laminariae (Thallus Eckloniae) extract is purchased from the moist Bioisystech Co., Ltd of peace;
It is super that olive bank up the roots of seedlings extract is purchased from large-scale quotient;
Aloe extract is purchased from the gloomy Biotechnology Co., Ltd in Anyuan.
Embodiment 1-5 and comparative example 1-2
For illustrating fluid composition and preparation method thereof of removing ornaments and formal dress
According in table 1 each ingredient and its dosage plant extracts and auxiliary material mixed, uniformly after obtain the present invention Makeup removing fluid composition.
Table 1
Comparative example 3
Makeup removing fluid composition and preparation method thereof for illustrating reference
Makeup removing fluid composition is prepared according to the method for embodiment 1, unlike, it is added without any plant extracts.
Test case 1
(1) estimation of stability
The makeup removing fluid composition of 10g embodiment 1-5 and comparative example 1-3 are respectively taken, and is respectively placed in incubation at room temperature case, 50 DEG C In incubator and in -10-40 DEG C of temperature cycling case, observation in 6 months is then carried out to its stability.Observation result is shown in In the following table 2.
Table 2
(2) irritation test, anaphylaxis experiment
8 backs of small white mouse cut off hair, are smeared respectively by the makeup remover prepared in embodiment 1-5 and comparative example 1-3 in cutting Plucked position, and do not apply position and be compared, as a result without irritation and allergic reaction.
Test case 2: moisture retention test
80 30-40 years old makeup women are chosen, are divided into 8 groups, every group of 10 people use 1-5 of the embodiment of the present invention and comparison Makeup remover in example 1-3 is removed ornaments and formal dress, and does not smear other skin care item after makeup removing.Use moisture of skin tester The skin moisture content of (CM820courage Khazaka electronic GmbH, Germany) each subject of measurement.Makeup removing Before, it is measured under conditions of steady temperature and constant humidity (24 DEG C and 40% humidity) using moisture of skin tester each tested The skin moisture content of person, and as reference value, 0 hour, 2 hours, 4 hours and 8 hours and 12 hours skin water after makeup removing Divide the variation of content.Measurement result is shown in the following table 3.
Table 3
It can be seen from the result in upper table 3 in the case where applying the cosmetic composition of embodiment 1-5, after application At once skin moisture content is increased more than comparative example 4 and 5, and increased skin moisture-keeping performance continue 12 hours or For more time.And the effect in 1-3 of the embodiment of the present invention is more preferable.
Test case 3
Subject as above carries out subject using the makeup removing fluid composition of 1 month embodiment 1-5 and comparative example 1-3 Questionnaire survey in relation to makeup removing fluid composition to dry skin, the effect for improving skin elasticity and oil-control is alleviated.Use 5 points etc. Grade assesses the effect, is averaged and is shown in the following table 4 to assessed value (5 grades).Wherein, 5: highly effective;4: slightly having Effect;3: moderate;2: almost without effect;1: there is no effect.
Table 4
Test material Alleviate the effect of dry skin Oil-control effect Skin elasticity
Embodiment 1 4.4 4.6 4.8
Embodiment 2 4.3 4.5 4.6
Embodiment 3 4.6 4.4 4.5
Embodiment 4 4.0 4.2 4.1
Embodiment 5 4.1 3.9 4.0
Comparative example 1 2.8 3.5 2.9
Comparative example 2 2.5 3.3 2.7
Comparative example 3 1.0 2.0 1.8
Makeup removing fluid composition of the invention, which has, it can be seen from the result in upper table 4 preferably alleviates dry skin, control Fat secretion processed and the effect for improving skin elasticity, and the better effect of makeup removing fluid composition in the preferred range Obviously.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above Detail within the scope of the technical concept of the present invention can be with various simple variants of the technical solution of the present invention are made, this A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance In the case where shield, it can be combined in any appropriate way.In order to avoid unnecessary repetition, the present invention to it is various can No further explanation will be given for the combination of energy.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally The thought of invention, it should also be regarded as the disclosure of the present invention.

Claims (6)

1. a kind of makeup removing fluid composition, which is characterized in that the makeup removing fluid composition contains composition of plant extracts as effective Ingredient, on the basis of the total weight of the makeup removing fluid composition, the content of the effective component is 1-60 weight %;
The composition of plant extracts is extracted by camellia seed oil, soapberry seed oil, Thallus Laminariae (Thallus Eckloniae) extract, olive extract and aloe Object composition;On the basis of the total weight of the composition of plant extracts, the content of the camellia seed oil is 20-40 weight %, The content of the soapberry seed oil is 15-30 weight %, and the content of the Thallus Laminariae (Thallus Eckloniae) extract is 10-20 weight %, the olive The content of extract is 15-30 weight %, and the content of the aloe extract is 20-40 weight %;
Wherein, the weight ratio of camellia seed oil, soapberry seed oil, Thallus Laminariae (Thallus Eckloniae) extract, olive extract and aloe extract is 1: (0.5-1): (0.5-0.8): (0.5-1): (0.8-1.5).
2. composition according to claim 1, wherein the soapberry seed oil is India's soapberry seed oil, the kelp Extract is sugar Thallus Laminariae (Thallus Eckloniae) extract, and the aloe extract is aloe vera extract, and the olive extract is olive seed Oil.
3. makeup removing fluid composition according to claim 1, wherein the makeup removing fluid composition also contains auxiliary material, described auxiliary Material is selected from tri- glyceryl isostearate of PEG-20, three caprylic/capric glyceride, white oil, octyl palmitate, Vitwas E With one of essence or a variety of.
4. makeup removing fluid composition according to claim 3, wherein on the basis of the total weight of the makeup removing fluid composition, The content of the auxiliary material is 40-99 weight %.
5. makeup removing fluid composition according to claim 3 or 4, wherein the auxiliary material is tri- isostearic acid glycerol of PEG-20 Ester, three caprylic/capric glyceride, white oil, octyl palmitate, Vitwas E and essence;
Wherein, on the basis of the total weight of the auxiliary material, the content of tri- glyceryl isostearate of PEG-20 is 1-10 weight %, three The content of caprylic/capric glyceride is 5-30 weight %, the content of white oil is 30-50 weight %, the content of octyl palmitate is 30-50 weight %, Vitwas E content be 0.5-1.5 weight %, the content of essence is 0.1-0.5 weight %.
6. the preparation method for fluid composition of removing ornaments and formal dress described in any one of claim 3-5, this method comprises: by the plant Extract and the auxiliary material are mixed.
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CN112891287A (en) * 2021-03-29 2021-06-04 广东韩朵生物科技有限公司 Makeup removing composition for moisturizing, controlling oil and nourishing skin
CN114504538B (en) * 2021-12-29 2023-07-21 武汉轻工大学 Cleansing oil containing soapberry oil and preparation method thereof

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CN104288027A (en) * 2014-09-26 2015-01-21 天津天狮生物发展有限公司 Eye and lip cleansing lotion and preparation method thereof
CN104906009A (en) * 2015-06-30 2015-09-16 广州市洁宝日用品有限公司 Makeup removing cream and preparation method thereof
CN105193659A (en) * 2015-10-14 2015-12-30 台山美环健芦荟制品有限公司 Aloe-containing composition for controlling oil and removing acnes
CN105316135A (en) * 2015-11-09 2016-02-10 重庆琥珀茶油有限公司 Tea-seed-oil acne-removing facial soap

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