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CN105572202A - Bionic detection device and method for electronic nose time-space smell information - Google Patents

Bionic detection device and method for electronic nose time-space smell information Download PDF

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CN105572202A
CN105572202A CN201510913020.2A CN201510913020A CN105572202A CN 105572202 A CN105572202 A CN 105572202A CN 201510913020 A CN201510913020 A CN 201510913020A CN 105572202 A CN105572202 A CN 105572202A
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CN105572202B (en
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傅均
章铁飞
俞吉峰
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Zhejiang Gongshang University
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Abstract

本发明涉及一种电子鼻时空气味信息的仿生检测装置及方法,它结合温度调制技术和膜延迟技术构建气敏传感阵列和仿生气室,获取各种待识别物质的气味信息数据,供后续模式识别算法分类识别。本发明采用温度调制技术改变传感器对不同气味成分的敏感度和选择性,形成一种对复杂气味不同成分的扫描式响应过程,获取阵列中不同传感器丰富的时间序列信号;在气路中设置不同透气膜/半透膜,根据其对各种气味成分扩散传输率的差异特性,模仿生物鼻腔和黏液功能,用分布于不同位置的传感器获取此差异性,即反映气味在气室传播的空间信息。综上方法获取复杂气味成分的时空信息,奠定复杂气味精细辨识的信号基础。

The present invention relates to a device and method for bionic detection of temporal and air odor information of an electronic nose, which combines temperature modulation technology and membrane delay technology to construct a gas sensitive sensor array and an imitation air chamber to obtain odor information data of various substances to be identified for subsequent use. Pattern recognition algorithm classification recognition. The invention uses temperature modulation technology to change the sensitivity and selectivity of sensors to different odor components, forms a scanning response process to different components of complex odors, and obtains rich time series signals of different sensors in the array; Breathable membrane/semipermeable membrane, according to its differential characteristics of the diffusion transmission rate of various odor components, imitates the function of biological nasal cavity and mucus, and uses sensors distributed in different positions to obtain this difference, which reflects the spatial information of odor transmission in the air chamber . In summary, the above method obtains the spatio-temporal information of complex odor components and lays the signal foundation for fine identification of complex odors.

Description

一种电子鼻时空气味信息的仿生检测装置及方法A bionic detection device and method for temporal and air odor information of an electronic nose

技术领域 technical field

本发明涉及一种电子鼻时空气味信息的仿生检测装置及方法。 The invention relates to a bionic detection device and method for temporal and air odor information of an electronic nose.

背景技术 Background technique

电子鼻是模拟生物嗅觉原理构建的智能仪器,如申请号为201410502332.X的中国专利。电子鼻通常由交叉敏感的气敏传感阵列和合适的模式识别算法组成,自动完成对气味的定性或定量辨识。它在食品加工、医学诊断、环境监测和公共安全等诸多领域具有广泛的应用前景。电子鼻发展40多年一直不能从实验室真正走向生产生活实际场合,或者只能在既定场合简单识别少数几种特定气味,远远少于人类鼻子上千种气味的辨识能力。 The electronic nose is an intelligent instrument constructed by simulating the principle of biological smell, such as the Chinese patent application number 201410502332.X. The electronic nose usually consists of a cross-sensitive gas sensor array and a suitable pattern recognition algorithm to automatically complete the qualitative or quantitative identification of odors. It has broad application prospects in many fields such as food processing, medical diagnosis, environmental monitoring and public safety. The electronic nose has been developed for more than 40 years and has not been able to move from the laboratory to the actual situation of production and life, or can only simply identify a few specific odors in a given occasion, which is far less than the human nose's ability to identify thousands of odors.

通用电子鼻为了达到分辨不同复杂气味细微差别的目标,希望像生物嗅觉中嗅神经元那样,有大量且不同类型的气敏传感器构成混合阵列,以获取丰富的气味信息。但目前技术成熟的气敏传感器类型单一、种类不多,而且不是针对电子鼻专门生产,这样导致不能为模式识别阶段提供足够的原始气味信息,只能实现少量模式种类的粗略辨识。 In order to achieve the goal of distinguishing the nuances of different complex odors, the universal electronic nose hopes to have a large number of different types of gas sensors to form a mixed array to obtain rich odor information like the olfactory neurons in biological olfaction. However, the currently mature gas sensors have a single type and a small number of types, and they are not specially produced for electronic noses. As a result, they cannot provide enough original odor information for the pattern recognition stage, and can only achieve rough identification of a small number of pattern types.

目前在电子鼻中使用的气敏传感器包括金属氧化物半导体MOS型、石英晶体微天平QCM型、声表面波SAW型和导电聚合物CP型等多种,但在使用寿命、稳定性和一致性上除了MOS型外其他类型很难满足电子鼻实际应用的要求。MOS型传感器通常需要300-500℃的工作温度,一些报道研究了温度调制方法来提高传感器敏感性和选择性,但是在电子鼻中没有直接利用所获取的整个时间序列信息,也没有有效的模型算法作相应处理,通常做法是将所获取的时间序列信息进行特征提取,将原始数据进行大幅度降维以适应普通模式识别算法,从而丢失了大量的气味细节信息,不利于对大量和相近气味的精细分类。 Gas sensors currently used in electronic noses include metal oxide semiconductor MOS type, quartz crystal microbalance QCM type, surface acoustic wave SAW type and conductive polymer CP type, etc., but in terms of service life, stability and consistency In addition to the MOS type, other types are difficult to meet the requirements of the practical application of the electronic nose. MOS-type sensors usually require an operating temperature of 300–500 °C, and some reports have investigated temperature modulation methods to improve sensor sensitivity and selectivity, but there is no direct utilization of the entire time-series information acquired in the electronic nose, and no effective models The algorithm is used to deal with it accordingly. The usual method is to extract the features of the acquired time series information, and greatly reduce the dimensionality of the original data to adapt to the common pattern recognition algorithm, thus losing a large amount of odor detail information, which is not conducive to the detection of a large number of similar odors. fine classification.

另一方面,在生物鼻中,嗅神经元并不是直接暴露在气味环境中,而是位于具有独特解剖结构和表面覆盖黏液的鼻腔内,通过吸气以对流和扩散的方式将气味分子传入,该过程取决于鼻腔结构、气流速度场、气味分子在空气和粘膜层中的扩散性和吸附性以及组织厚度等,相关文献已经从不同角度提出多种理论模型。同样,电子鼻中各传感器所处位置的气体反应动力学特性也取决于采样装置中气味分子传递过程,受电子鼻气室结构、气流速度、传递形式等的影响。但是将这些影响因素用于构建电子鼻系统气室和传感阵列,以更贴近生物嗅觉实际,获取更丰富的气味信息,在目前文献中鲜有报道。 On the other hand, in the biological nose, the olfactory neurons are not directly exposed to the odor environment, but are located in the nasal cavity with a unique anatomical structure and surface covered with mucus, and the odor molecules are introduced into the air by convection and diffusion through inhalation. , the process depends on the structure of the nasal cavity, the airflow velocity field, the diffusivity and adsorption of odor molecules in the air and mucous membrane layer, and the tissue thickness. Various theoretical models have been proposed from different perspectives in relevant literature. Similarly, the kinetic characteristics of the gas reaction at the positions of the sensors in the electronic nose also depend on the transfer process of odor molecules in the sampling device, and are affected by the structure of the electronic nose air chamber, airflow velocity, and transfer form. However, there are few reports in the current literature that these influencing factors are used to construct the air chamber and sensor array of the electronic nose system, so as to be closer to the biological olfactory reality and obtain richer odor information.

发明内容 Contents of the invention

本发明的目的在于克服现有技术中存在的上述不足,而提供一种设计合理、结合温度调制技术和膜延迟技术的电子鼻时空气味信息的仿生检测装置及方法。 The purpose of the present invention is to overcome the above-mentioned deficiencies in the prior art, and provide a bionic detection device and method for temporal and air odor information of an electronic nose with reasonable design and combination of temperature modulation technology and membrane delay technology.

本发明解决上述问题所采用的技术方案是:一种电子鼻时空气味信息的仿生检测装置,其特征在于:包括仿生气室、气敏传感器和控制模块; The technical solution adopted by the present invention to solve the above problems is: a bionic detection device for time and air odor information of an electronic nose, which is characterized in that it includes a bionic gas chamber, a gas sensor and a control module;

仿生气室包括进气接头、出气接头、管体和透气膜/半透膜;管体两端封住;进气接头和出气接头分别安装在管体的两端,并与管体的管腔连通;管体包括S形管道和反S形管道;S形管道的管口与反S形管道的管口固定并连通,使S形管道的管腔与反S形管道的管腔连通构成气路;所述的S形管道和反S形管道为多个,间隔连接,多个S形管道和反S形管道依次连接以构成更长的气路;相连的S形管道和反S形管道,在连接处的管口上覆盖有透气膜/半透膜,透气膜/半透膜将该S形管道的管腔和反S形管道的管腔隔开;在S形管道和反S形管道的管壁上开有安装孔,气敏传感器安装在安装孔中,气敏传感器的传感部位伸入S形管道和反S形管道的管腔中;安装在S形管道和反S形管道上的气敏传感器构成传感阵列; The bionic air chamber includes an air inlet joint, an air outlet joint, a tube body and a gas permeable membrane/semi-permeable membrane; both ends of the tube body are sealed; the air inlet joint and the air outlet joint are respectively installed at both ends of the tube body, and are connected to the lumen of the tube body Connected; the pipe body includes S-shaped pipes and reverse S-shaped pipes; the nozzle of the S-shaped pipe is fixed and communicated with the nozzle of the reverse S-shaped pipe, so that the lumen of the S-shaped pipe and the lumen of the reverse S-shaped pipe are connected to form a gas Road; the S-shaped pipeline and the reverse S-shaped pipeline are multiple, connected at intervals, and the multiple S-shaped pipelines and the reverse S-shaped pipeline are connected in sequence to form a longer gas path; the connected S-shaped pipeline and the reverse S-shaped pipeline , the mouth of the joint is covered with a gas permeable membrane/semipermeable membrane, which separates the lumen of the S-shaped duct from the lumen of the reverse S-shaped duct; between the S-shaped duct and the reverse S-shaped duct There is a mounting hole on the pipe wall, and the gas sensor is installed in the mounting hole, and the sensing part of the gas sensor extends into the lumen of the S-shaped pipe and the reverse S-shaped pipe; it is installed on the S-shaped pipe and the reverse S-shaped pipe The gas sensor on the top constitutes a sensing array;

控制模块包括处理模块、工作温度调制模块和传感阵列信号采集模块;处理模块与工作温度调制模块和传感阵列信号采集模块连接;工作温度调制模块和传感阵列信号采集模块与气敏传感器连接;控制模块包括处理模块、工作温度调制模块和传感阵列信号采集模块;处理模块与工作温度调制模块和传感阵列信号采集模块连接;传感阵列信号采集模块与气敏传感器连接;工作温度调制模块与MOS型气敏传感器匹配,所述的气敏传感器为MOS型气敏传感器时,工作温度调制模块与MOS型气敏传感器连接,可对MOS型气敏传感器进行工作温度调制。 The control module includes a processing module, a working temperature modulation module and a sensor array signal acquisition module; the processing module is connected to the working temperature modulation module and the sensing array signal acquisition module; the working temperature modulation module and the sensing array signal acquisition module are connected to the gas sensor ; The control module includes a processing module, a working temperature modulation module and a sensor array signal acquisition module; the processing module is connected to the working temperature modulation module and the sensor array signal acquisition module; the sensing array signal acquisition module is connected to the gas sensor; the working temperature modulation The module is matched with a MOS type gas sensor. When the gas sensor is a MOS type gas sensor, the working temperature modulation module is connected with the MOS type gas sensor, and the working temperature of the MOS type gas sensor can be modulated.

本发明所述的工作温度调制模块包括数模转换器、电压跟随器和功率放大模块;传感阵列信号采集模块包括四号电阻、五号电阻、六号电阻、仪表放大器和模数转换器;处理模块、数模转换器、电压跟随器、功率放大模块依次连接;MOS型气敏传感器的加热电阻与功率放大模块连接;MOS型气敏传感器的敏感电阻与四号电阻、五号电阻、六号电阻构成惠斯通电桥,惠斯通电桥、仪表放大器、模数转换器、处理模块依次连接; The working temperature modulation module of the present invention includes a digital-to-analog converter, a voltage follower and a power amplification module; the sensor array signal acquisition module includes No. 4 resistors, No. 5 resistors, No. 6 resistors, instrument amplifiers and analog-to-digital converters; The processing module, digital-to-analog converter, voltage follower, and power amplifier module are connected in sequence; the heating resistor of the MOS gas sensor is connected to the power amplifier module; the sensitive resistor of the MOS gas sensor is connected to the fourth resistor, the fifth resistor, and the sixth resistor. No. resistors form a Wheatstone bridge, and the Wheatstone bridge, instrumentation amplifier, analog-to-digital converter, and processing module are connected in sequence;

处理模块的嵌入式程序预设多种温度调制驱动信号,温度调制驱动信号经过数模转换器转换成模拟信号,再通过电压跟随器,由功率放大模块功率放大后输给加热电阻,可实现工作温度调制;惠斯通电桥输出电压通过仪表放大器放大,并转换成单极信号,再由模数转换器转换成数字信号给处理模块。 The embedded program of the processing module presets a variety of temperature modulation driving signals. The temperature modulation driving signal is converted into an analog signal through a digital-to-analog converter, and then through a voltage follower, the power is amplified by the power amplifier module and then output to the heating resistor, which can realize the work. Temperature modulation; the output voltage of the Wheatstone bridge is amplified by the instrumentation amplifier and converted into a unipolar signal, and then converted into a digital signal by an analog-to-digital converter for the processing module.

本发明所述的管体包括封头;管体两端用封头封住。 The pipe body of the present invention includes a sealing head; both ends of the pipe body are sealed with the sealing head.

本发明还包括气体采样泵和排废泵,采样泵和排废泵与控制模块连接;进气接头与气体采样泵连接,出气接头与排废泵连接。 The invention also includes a gas sampling pump and a waste discharge pump, the sampling pump and the waste discharge pump are connected with the control module; the air inlet joint is connected with the gas sampling pump, and the gas outlet joint is connected with the waste discharge pump.

本发明所述的气敏传感阵列包含多种原理和类型构建的混合传感阵列。 The gas sensitive sensing array of the present invention includes a mixed sensing array constructed on various principles and types.

本发明所述的处理模块可采用单片机或者微处理器。 The processing module described in the present invention may adopt a single-chip microcomputer or a microprocessor.

本发明所述的功率放大模块由达林顿管构成,或者采用集成芯片。 The power amplifying module of the present invention is composed of a Darlington tube, or an integrated chip is used.

本发明所述的电压跟随器由运算放大器构成。 The voltage follower of the present invention is composed of an operational amplifier.

本发明如果某些安装孔无需安装气敏传感器,可以用的塞头堵住这些安装孔。 In the present invention, if some mounting holes do not need to install gas sensors, plugs can be used to block these mounting holes.

采用权利要求1~9任一权利要求所述的仿生检测装置;气味通过进气接头进入仿生气室,然后依次流过各管道,最后从出气接头排出;混合气味中的不同气体分子在流过透气膜/半透膜时在透气膜/半透膜中进行扩散,不同气体分子在气相和透气膜/半透膜中扩散传输率不同,导致它们在气路中不同位置存在组分和浓度差异,通过不同位置的气敏传感器获取其对应的差异性信号,即反映气味在仿生气室中传播的空间信息;工作温度调制模块不断改变MOS型气敏传感器加热电压幅值与频率来调制其工作温度,从而改变MOS型气敏传感器对不同气味成分的敏感度和选择性,形成一种对复杂气味内不同成分的扫描式响应过程,即可获取阵列中不同传感器丰富的时间序列信号;空间信息和时间序列信号构成气味时空信息;传感阵列信号采集模块获取传感阵列中不同传感器的气味时空信息;控制模块将传感阵列中的气味时空信息上传并保存至上位机。 Adopt the bionic detection device described in any one of claims 1 to 9; the smell enters the bionic air chamber through the inlet joint, then flows through each pipeline in turn, and finally is discharged from the air outlet joint; the different gas molecules in the mixed smell are flowing through When the gas permeable membrane/semipermeable membrane diffuses in the gas permeable membrane/semipermeable membrane, the diffusion and transmission rates of different gas molecules in the gas phase and the gas permeable membrane/semipermeable membrane are different, resulting in differences in their composition and concentration at different positions in the gas path , Obtain the corresponding differential signals through the gas sensors at different positions, that is, reflect the spatial information of the odor propagating in the bionic air chamber; the working temperature modulation module constantly changes the heating voltage amplitude and frequency of the MOS gas sensor to modulate its work Temperature, thereby changing the sensitivity and selectivity of the MOS gas sensor to different odor components, forming a scanning response process to different components in complex odors, and obtaining rich time series signals of different sensors in the array; spatial information and time series signals to form odor spatio-temporal information; the sensor array signal acquisition module acquires the odor spatio-temporal information of different sensors in the sensor array; the control module uploads and saves the odor spatio-temporal information in the sensor array to the host computer.

本发明与现有技术相比,具有以下优点和效果:本发明结合温度调制技术和膜延迟技术构建仿生气敏传感阵列和气室,以获取复杂气味成分的时空信息。与传统的单一工作温度气敏传感阵列和不考虑气味反应动力学影响的气室相比,能在有限数量和类型的气敏传感器条件下获取更丰富的气味指纹信息,从而奠定复杂气味精细辨识的信号基础。 Compared with the prior art, the present invention has the following advantages and effects: the present invention combines temperature modulation technology and film delay technology to construct an imitation air-sensitive sensing array and an air chamber to obtain spatiotemporal information of complex odor components. Compared with the traditional gas sensor array with a single working temperature and the air chamber that does not consider the influence of odor reaction kinetics, it can obtain richer odor fingerprint information under the condition of a limited number and type of gas sensor, thus laying a foundation for complex odor finesse. Signal basis for identification.

本发明以生物嗅觉机理为理论基础,以工程实际为技术基础,改变了传统电子鼻系统气味信息检测方法和手段,不仅能改进电子鼻的气味识别能力,而且突破了传统电子鼻有限仿生结构,期望催生突破电子鼻技术瓶颈的新思维,促进人工嗅觉的理论发展。 Based on the biological olfactory mechanism as the theoretical basis and engineering practice as the technical basis, the invention changes the odor information detection method and means of the traditional electronic nose system, not only can improve the odor recognition ability of the electronic nose, but also breaks through the limited bionic structure of the traditional electronic nose, It is expected to give birth to new thinking that breaks through the bottleneck of electronic nose technology and promote the theoretical development of artificial olfaction.

附图说明 Description of drawings

图1为本发明实施例的工作示意图。 Fig. 1 is a working schematic diagram of an embodiment of the present invention.

图2为本发明实施例的仿生气室、传感阵列及控制模块示意图。 Fig. 2 is a schematic diagram of an imitation air chamber, a sensor array and a control module according to an embodiment of the present invention.

图3为本发明实施例MOS型气敏传感器工作温度调制模块和传感阵列信号采集模块电路图。 Fig. 3 is a circuit diagram of the working temperature modulation module of the MOS gas sensor and the sensor array signal acquisition module according to the embodiment of the present invention.

具体实施方式 detailed description

下面结合附图并通过实施例对本发明作进一步的详细说明,以下实施例是对本发明的解释而本发明并不局限于以下实施例。 The present invention will be further described in detail below in conjunction with the accompanying drawings and examples. The following examples are explanations of the present invention and the present invention is not limited to the following examples.

仿生气室11包括进气接头8、出气接头10、管体和透气膜/半透膜5。 The bionic air chamber 11 includes an air inlet joint 8 , an air outlet joint 10 , a pipe body and a gas permeable membrane/semipermeable membrane 5 .

管体包括S形管道1、反S形管道2和封头3。 The pipe body includes an S-shaped pipe 1 , a reverse S-shaped pipe 2 and a head 3 .

管体两端用封头3封住,它们之间通过螺栓螺母4固定,可以拆卸。进气接头8和出气接头10分别安装在管体的两端,并与管体的管腔连通。 Both ends of the pipe body are sealed with heads 3, and they are fixed by bolts and nuts 4, which can be disassembled. The air inlet joint 8 and the air outlet joint 10 are respectively installed at both ends of the tube body and communicate with the lumen of the tube body.

S形管道1的管口和反S形管道2的管口上均安装有法兰,S形管道1的管口与反S形管道2的管口通过法兰固定,它们之间通过螺栓螺母固定,可以拆卸。S形管道1的管口与反S形管道2的管口连通,使S形管道1的管腔与反S形管道2的管腔连通构成气路。 Both the nozzle of S-shaped pipe 1 and the nozzle of reverse S-shaped pipe 2 are equipped with flanges, the nozzle of S-shaped pipe 1 and the nozzle of reverse S-shaped pipe 2 are fixed by flanges, and they are fixed by bolts and nuts , can be disassembled. The nozzle of the S-shaped pipeline 1 communicates with the nozzle of the reverse S-shaped pipeline 2, so that the lumen of the S-shaped pipeline 1 communicates with the lumen of the reverse S-shaped pipeline 2 to form an air path.

S形管道1和反S形管道2为多个,间隔连接,这样就可以进行扩展,以构成更长的气路。 There are multiple S-shaped pipes 1 and reverse S-shaped pipes 2, which are connected at intervals, so that they can be expanded to form a longer gas path.

S形管道1、反S形管道2和封头3都采用聚四氟乙烯材料制成,以防止待测气体对仿生气室11的腐蚀,并保障最小程度的气体吸附残余。 The S-shaped pipe 1 , the reverse S-shaped pipe 2 and the head 3 are all made of polytetrafluoroethylene to prevent the gas to be measured from corroding the imitation gas chamber 11 and ensure the minimum gas adsorption residue.

相连的S形管道1和反S形管道2,在连接处的管口上覆盖有透气膜/半透膜5,透气膜/半透膜5将这两根S形管道1和反S形管道2的管腔隔开。必要时可以再夹裹密封圈以有效固定防止漏气。 The connected S-shaped pipe 1 and the reverse S-shaped pipe 2 are covered with a gas-permeable membrane/semi-permeable membrane 5 at the mouth of the connection, and the gas-permeable membrane/semi-permeable membrane 5 connects the two S-shaped pipes 1 and the reverse S-shaped pipe 2 lumen separated. If necessary, the sealing ring can be clamped again to effectively fix and prevent air leakage.

在S形管道1和反S形管道2的管壁上均匀开有安装孔6,安装孔6直径与气敏传感器7相仿,气敏传感器7可以插入这些安装孔6中固定,气敏传感器7的传感部位伸入S形管道1和反S形管道2的管腔中;也可以再夹裹密封圈以有效固定防止漏气。如果某些安装孔6无需插入气敏传感器7,可以用聚四氟乙烯制成的塞头9堵住这些安装孔6。气敏传感器7用电源线和信号线直接连接到附近的控制模块14中的传感阵列信号采集模块,也可以自带一定的信号调理或驱动电路。 On the pipe wall of the S-shaped pipe 1 and the reverse S-shaped pipe 2, there are evenly installed holes 6. The diameter of the installed holes 6 is similar to that of the gas sensor 7. The gas sensor 7 can be inserted into these mounting holes 6 and fixed. The gas sensor 7 The sensing part extends into the lumen of the S-shaped pipe 1 and the reverse S-shaped pipe 2; the sealing ring can also be clamped to effectively fix and prevent air leakage. If some installation holes 6 do not need to be inserted into the gas sensor 7, these installation holes 6 can be blocked with a plug 9 made of polytetrafluoroethylene. The gas sensor 7 is directly connected to the sensor array signal acquisition module in the nearby control module 14 with a power line and a signal line, and may also have a certain signal conditioning or driving circuit.

安装在S形管道1和反S形管道2上的气敏传感器7构成传感阵列。 The gas sensor 7 installed on the S-shaped pipeline 1 and the reverse S-shaped pipeline 2 constitutes a sensing array.

本发明根据电子鼻气室构造对气味反应的动力学影响,对气味采样和气室装置进行改进,在仿生气室11中各传感器之间的气路上安置覆盖一层或多层多孔透气膜/半透膜5。气相中的扩散对气体分子来说几乎是毫无困难。但在透气膜/半透膜5中就不同,由于分子尺寸和极性的差异,不同气味分子在膜内相对传递速率也有差异,有些膜对某些气味分子还具有选择性。因此采用不同透气膜/半透膜5,根据其对各种气味成分扩散传输率的差异特性,一定程度上模仿了生物鼻腔和黏液功能,用分布于不同位置(直线或平面或立体)的传感器获取此差异性,即反映气味在气室传播的空间信息,从而大大提高系统对复杂气味的识别能力。可用计算机软件对腔室构造、进气泵和排气泵工作状况与气流场关系进行仿真分析,并且选择聚四氟乙烯等合适材料制作气室,达到废气排除完全、腔壁吸附少等效果。 The present invention improves the odor sampling and the air chamber device according to the kinetic influence of the air chamber structure of the electronic nose on the odor response, and places one or more layers of porous air-permeable membranes/semi- Transmembrane 5. Diffusion in the gas phase presents almost no difficulties for gas molecules. However, it is different in the gas permeable membrane/semipermeable membrane 5. Due to the difference in molecular size and polarity, the relative transfer rate of different odor molecules in the membrane is also different, and some membranes are also selective for certain odor molecules. Therefore, different gas permeable membranes/semipermeable membranes 5 are used, and according to their differences in the diffusion and transmission rates of various odor components, the functions of the biological nasal cavity and mucus are imitated to a certain extent, and sensors distributed in different positions (linear or plane or three-dimensional) are used. Obtaining this difference, which reflects the spatial information of the odor propagating in the air chamber, greatly improves the system's ability to recognize complex odors. Computer software can be used to simulate and analyze the relationship between the chamber structure, the working conditions of the intake pump and exhaust pump, and the airflow field, and select suitable materials such as polytetrafluoroethylene to make the air chamber, so as to achieve the effects of complete exhaust gas removal and less adsorption on the chamber wall.

进气接头8与气体采样泵12连接,出气接头10与排废泵13连接。两泵的开启、关闭以及流速由控制模块14实现。气味可以通过采样泵12进入进气接头8后进入第一个S形管道1,然后依次流过各管道,最后从出气接头10排出;在流过透气膜/半透膜5时在透气膜/半透膜5中进行自由扩散;也可以开启排废泵13,在后段管道形成一定负压,加速扩散。 The air inlet joint 8 is connected to a gas sampling pump 12 , and the gas outlet joint 10 is connected to a waste discharge pump 13 . The opening, closing and flow rate of the two pumps are realized by the control module 14 . The smell can enter the first S-shaped pipeline 1 after entering the air inlet joint 8 through the sampling pump 12, then flow through each pipeline in turn, and finally discharge from the air outlet joint 10; Free diffusion is carried out in the semi-permeable membrane 5; the waste discharge pump 13 can also be turned on to form a certain negative pressure in the rear pipeline to accelerate the diffusion.

控制模块14包括处理模块15、工作温度调制模块和传感阵列信号采集模块。处理模块15与工作温度调制模块和传感阵列信号采集模块连接;传感阵列信号采集模块与气敏传感器7连接。处理模块可采用单片机或者微处理器。工作温度调制模块与MOS型气敏传感器匹配;气敏传感器7为MOS型气敏传感器时,工作温度调制模块与MOS型气敏传感器连接,可对MOS型气敏传感器进行工作温度调制。 The control module 14 includes a processing module 15, a working temperature modulation module and a sensor array signal acquisition module. The processing module 15 is connected with the working temperature modulation module and the sensor array signal acquisition module; the sensor array signal acquisition module is connected with the gas sensor 7 . The processing module can adopt single-chip microcomputer or microprocessor. The working temperature modulation module is matched with the MOS type gas sensor; when the gas sensor 7 is a MOS type gas sensor, the working temperature modulation module is connected with the MOS type gas sensor, and the working temperature of the MOS type gas sensor can be modulated.

工作温度调制模块包括数模转换器DAC、电压跟随器和功率放大模块;传感阵列信号采集模块包括四号电阻R4、五号电阻R5、六号电阻R6、仪表放大器IA和模数转换器ADC。 The working temperature modulation module includes a digital-to-analog converter DAC, a voltage follower and a power amplification module; the sensing array signal acquisition module includes a fourth resistor R4, a fifth resistor R5, a sixth resistor R6, an instrumentation amplifier IA and an analog-to-digital converter ADC .

处理模块15、数模转换器DAC、电压跟随器、功率放大模块依次连接。MOS型气敏传感器的加热电阻Rh与功率放大模块连接。MOS型气敏传感器的敏感电阻Rs与四号电阻R4、五号电阻R5、六号电阻R6构成惠斯通电桥,惠斯通电桥、仪表放大器IA、模数转换器ADC、处理模块15依次连接。 The processing module 15, the digital-to-analog converter DAC, the voltage follower, and the power amplification module are connected in sequence. The heating resistor Rh of the MOS type gas sensor is connected with the power amplifier module. The sensitive resistor Rs of the MOS type gas sensor forms a Wheatstone bridge with No. 4 resistor R4, No. 5 resistor R5, and No. 6 resistor R6, and the Wheatstone bridge, instrumentation amplifier IA, analog-to-digital converter ADC, and processing module 15 are connected in sequence .

处理模块15嵌入式程序预设多种温度调制驱动信号,可根据需要选择产生不同幅度和频率的正弦波、三角波或方波等,然后经过数模转换器DAC转换成模拟信号,通过运算放大器OP构成的跟随器,由功率放大模块功率放大后输给加热电阻Rh,便可实现工作温度调制。 The embedded program of the processing module 15 presets a variety of temperature-modulated driving signals, which can be selected to generate sine waves, triangle waves or square waves with different amplitudes and frequencies according to needs, and then converted into analog signals by the digital-to-analog converter DAC, and then passed through the operational amplifier OP The formed follower is amplified by the power amplifier module and then sent to the heating resistor Rh to realize working temperature modulation.

功率放大模块由达林顿管(双NPN三极管T1和T2构成)构成,也可用集成芯片,例如ULN2804等。 The power amplifier module is composed of Darlington tubes (double NPN transistors T1 and T2), and integrated chips such as ULN2804 can also be used.

惠斯通电桥输出电压通过仪表放大器IA放大,并转换成单极信号,再由模数转换器ADC转换成数字信号给处理模块15。通过对MOS型气敏传感器的工作温度进行调制,获取传感阵列中不同传感器丰富的时间序列信号。 The output voltage of the Wheatstone bridge is amplified by the instrumentation amplifier IA and converted into a unipolar signal, and then converted into a digital signal by the analog-to-digital converter ADC to the processing module 15 . By modulating the working temperature of the MOS gas sensor, the rich time series signals of different sensors in the sensing array are obtained.

MOS型气敏传感器是根据一定温度下敏感材料的电导率随环境气体浓度和性质的改变而变化原理制成,并在敏感材料中掺杂不同金属做催化剂,以提高其灵敏度、选择性和稳定性。这类传感器商业化程度较高,市场上可以获取多种型号的产品,例如日本Figaro公司和我国的河南汉威电子等。 The MOS type gas sensor is made according to the principle that the conductivity of the sensitive material changes with the change of the ambient gas concentration and properties at a certain temperature, and the sensitive material is doped with different metals as catalysts to improve its sensitivity, selectivity and stability. sex. This type of sensor has a high degree of commercialization, and various types of products can be obtained in the market, such as Figaro Company in Japan and Hanwei Electronics in my country.

本发明通过不断改变MOS型气敏传感器加热电压幅值与频率来调制其工作温度,从而改变MOS型传感器对不同气味成分的敏感度和选择性,形成一种对复杂气味内不同成分的扫描式响应过程,获取阵列中不同传感器丰富的时间序列信号。调制加热电压可以通过脉冲宽度调制PWM方式从微处理器数字端口输出,也可以通过微处理器和数模转换器DAC产生,并经由达林顿管电流放大。调制加热电压可以集中或独立激励不同的气敏传感器,同时用模数转换器ADC和微处理器获取传感器对气味的响应信号。加热电压的变化应该在传感器标称的工作范围内,而调制频率可以通过具体试验优化。 The present invention modulates the working temperature by constantly changing the heating voltage amplitude and frequency of the MOS type gas sensor, thereby changing the sensitivity and selectivity of the MOS type sensor to different odor components, and forming a scanning method for different components in complex odors. In response to the process, a rich time-series signal of the different sensors in the array is acquired. The modulated heating voltage can be output from the digital port of the microprocessor by means of pulse width modulation PWM, or can be generated by the microprocessor and the digital-to-analog converter DAC, and amplified by the Darlington tube current. Different gas sensors can be stimulated centrally or independently by modulating the heating voltage, and at the same time, the sensor's response signal to the odor is acquired with an analog-to-digital converter ADC and a microprocessor. The variation of the heating voltage should be within the nominal working range of the sensor, while the modulation frequency can be optimized through specific experiments.

气味在仿生气室11扩散过程中,与管体中不同位置的气敏传感器7发生化学反应,转换成电信号,通过各自的信号线传至控制模块14的传感阵列信号采集模块,空间信息和时间序列信号构成的气味时空信息经由处理模块15传至计算机或者其他嵌入式上位机进行信号处理及模式识别。 During the diffusion of the odor in the bionic air chamber 11, it reacts chemically with the gas sensors 7 at different positions in the pipe body, converts them into electrical signals, and transmits them to the sensor array signal acquisition module of the control module 14 through their respective signal lines, and the spatial information The odor spatio-temporal information formed with the time series signal is transmitted to a computer or other embedded host computer through the processing module 15 for signal processing and pattern recognition.

对于某些类型的气敏传感器7,比如QCM型或者SAW型,无需模数转换器,而是通过频率计获取数据,相应地,可以在控制模块上布置频率计模块,通常可以用可编程逻辑器件CPLD/FPGA设计成多通道信号采集电路。而对于MOS型气敏传感器,则由控制模块14中的处理模块15和工作温度调制模块产生驱动信号,对气敏传感器7进行工作温度调制。驱动信号可以由处理模块15和数模转换器DAC产生,并经由功率放大模块进行电路放大。这种驱动信号可以是具有一定偏置的正弦波、三角波、方波等,通常信号的频率较低(比如2~10Hz),而幅度在传感器额定加热电压上下,具体应由所使用的气敏传感器及试验而定。驱动信号也可以是数字IO口的脉冲宽度调制PWM输出。 For some types of gas sensor 7, such as QCM type or SAW type, no analog-to-digital converter is needed, but the data is obtained through a frequency meter. Correspondingly, a frequency meter module can be arranged on the control module, usually with a programmable logic The device CPLD/FPGA is designed as a multi-channel signal acquisition circuit. As for the MOS type gas sensor, the processing module 15 and the working temperature modulation module in the control module 14 generate a driving signal to modulate the working temperature of the gas sensor 7 . The driving signal can be generated by the processing module 15 and the digital-to-analog converter DAC, and amplified by a power amplifier module. This driving signal can be a sine wave, triangular wave, square wave, etc. with a certain offset. Generally, the frequency of the signal is low (such as 2-10Hz), and the amplitude is around the rated heating voltage of the sensor. Depends on sensor and test. The driving signal can also be the pulse width modulation PWM output of the digital IO port.

气味在仿生气室11中与气敏传感器7进行一段时间反应,由起初的动态信号逐渐转为较为稳定的稳态信号,或者自行决定反应时间,生成时间序列信号。控制模块将传感阵列获取的气味时间序列信号和气味空间信息保存至上位机。此时应开启气体采样泵12和排废泵13进行管道”冲洗”,直至有足够的新鲜空气进入,而管道中残余的待测气体很少为止,接下来可以进行第二次气味检测。 The smell reacts with the gas sensor 7 in the bionic air chamber 11 for a period of time, and gradually changes from the initial dynamic signal to a relatively stable steady state signal, or decides the reaction time by itself to generate a time series signal. The control module saves the odor time series signal and odor spatial information acquired by the sensor array to the host computer. At this time, the gas sampling pump 12 and the exhaust pump 13 should be turned on to "flush" the pipeline until enough fresh air enters, and the remaining gas to be tested is very little in the pipeline, and then the second odor detection can be carried out.

上位机可以对上述过程获取的由时间序列信号和空间信息构成的时空气味信息进行进一步处理,比如进行数字滤波、归一化等,然后经过特征提取,输入到各种模式识别算法进行分类识别。另外为了保持这些时空气味信息的丰富动力学过程,也可以不经特征提取直接输入到一种基于生物嗅觉机理的嗅觉神经网络KIII模型进行记忆与识别,详细工作流程可以参考发明人已经公开发布的论文[傅均,李光,FreemanWJ.基于嗅觉神经网络采用时间序列的电子鼻模式分类方法.传感技术学报,2007,20(9):1958-1962]。 The upper computer can further process the spatio-temporal odor information composed of time series signals and spatial information acquired in the above process, such as digital filtering, normalization, etc., and then extract features and input them to various pattern recognition algorithms for classification and recognition. In addition, in order to maintain the rich dynamic process of these spatio-temporal odor information, it can also be directly input to an olfactory neural network KIII model based on biological olfactory mechanism for memory and recognition without feature extraction. For detailed workflow, please refer to the inventor's published Paper [Fu Jun, Li Guang, FreemanWJ. Electronic nose pattern classification method using time series based on olfactory neural network. Journal of Sensing Technology, 2007,20(9):1958-1962].

本发明利用气路中透气膜/半透膜5对气体分子的膜延迟和选择性构建仿生气室11,利用不同工作温度下气敏传感器对气体的不同选择性和敏感性构建仿生的传感阵列,通过处理模块、模数转换器ADC、数模转换器DAC、信号调理和驱动等相关电子电路控制气流和传感器工作温度,并获取传感阵列中所有气敏传感器在不同调制温度下对待测物品的气味响应数据,供后续模式识别算法分类识别。这种结合温度调制技术和膜延迟技术获取的传感阵列时空信息,反映了复杂气味各组分在仿生气室11中传播和反应动力学特性,是一种更丰富更体现待测物品气味特点的时空气味信息。这种时空气味信息可以不经特征提取直接输入某些具有时空模式处理的人工神经网络处理,再由分类器进行分类识别,得到判别决策结果。 The present invention utilizes the film delay and selectivity of the gas permeable membrane/semipermeable membrane 5 in the gas circuit to construct a bionic gas chamber 11, and utilizes the different selectivity and sensitivity of the gas sensor to gas at different working temperatures to construct a bionic sensor Array, through the processing module, analog-to-digital converter ADC, digital-to-analog converter DAC, signal conditioning and driving and other related electronic circuits to control the airflow and sensor operating temperature, and obtain all the gas sensors in the sensing array to be tested at different modulation temperatures The odor response data of the item is used for classification and identification by the subsequent pattern recognition algorithm. The sensor array spatiotemporal information obtained by combining temperature modulation technology and membrane delay technology reflects the propagation and reaction kinetics of components of complex odors in the bionic air chamber 11, and is a richer and more reflective odor characteristic of the object to be tested. space-time odor information. This kind of spatio-temporal odor information can be directly input into some artificial neural networks with spatio-temporal pattern processing without feature extraction, and then classified and identified by classifiers to obtain discriminative decision results.

本发明在待测气味经过的气路中布置多道不同材料的透气膜/半透膜5,并且在气路不同直线/平面/立体位置布置各种气敏传感器7。不同气味分子在气相和透气膜/半透膜5中扩散传输率不同,导致它们在气路中不同位置存在组分和浓度差异,通过不同位置的气敏传感器7可以获取其对应的信号,即反映气味在仿生气室11中传播的空间信息。 In the present invention, multiple air-permeable membranes/semi-permeable membranes 5 of different materials are arranged in the air path through which the odor to be tested passes, and various gas sensors 7 are arranged in different linear/plane/stereoscopic positions of the air path. Different odor molecules have different diffusion and transmission rates in the gas phase and the gas permeable membrane/semipermeable membrane 5, resulting in differences in their composition and concentration at different positions in the gas path, and the corresponding signals can be obtained through the gas sensor 7 at different positions, namely It reflects the spatial information of the smell propagating in the bionic air chamber 11.

通常气敏传感器7的选择性比较差,即使是标称为检测某气体的气敏传感器,也对大多数气体敏感,电子鼻也正好是利用了气敏传感器的广谱交叉敏感特性。特别是本发明在面向通用的电子鼻系统中,在气路中布置的气敏传感器可以是不同传感原理(例如MOS型、QCM型、CP型等)或者某一传感原理但不同工艺不同型号(例如Figaro公司的各类TGS-MOS型)。不同种类和类型的传感器由相应的电子电路来驱动、信号调理和数据采集。 Generally, the selectivity of the gas sensor 7 is relatively poor. Even a gas sensor labeled to detect a certain gas is sensitive to most gases. The electronic nose just utilizes the broad-spectrum cross-sensitivity characteristic of the gas sensor. In particular, in the general-purpose electronic nose system of the present invention, the gas sensors arranged in the air circuit can be of different sensing principles (such as MOS type, QCM type, CP type, etc.) or a certain sensing principle but with different processes. Model (for example, various TGS-MOS types of Figaro Company). Different kinds and types of sensors are driven by corresponding electronic circuits, signal conditioning and data acquisition.

此外,需要说明的是,本说明书中所描述的具体实施例,其零、部件的形状、所取名称等可以不同,本说明书中所描述的以上内容仅仅是对本发明结构所作的举例说明。 In addition, it should be noted that the specific embodiments described in this specification may be different in parts, shapes and names of parts, and the above content described in this specification is only an illustration of the structure of the present invention.

Claims (10)

1.一种电子鼻时空气味信息的仿生检测装置,其特征在于:包括仿生气室、气敏传感器和控制模块; 1. A bionic detection device for temporal and air odor information of an electronic nose, characterized in that: comprising a bionic air chamber, a gas sensor and a control module; 仿生气室包括进气接头、出气接头、管体和透气膜/半透膜;管体两端封住;进气接头和出气接头分别安装在管体的两端,并与管体的管腔连通;管体包括S形管道和反S形管道;S形管道的管口与反S形管道的管口固定并连通,使S形管道的管腔与反S形管道的管腔连通构成气路;所述的S形管道和反S形管道为多个,间隔连接,多个S形管道和反S形管道依次连接以构成更长的气路;相连的S形管道和反S形管道,在连接处的管口上覆盖有透气膜/半透膜,透气膜/半透膜将该S形管道的管腔和反S形管道的管腔隔开;在S形管道和反S形管道的管壁上开有安装孔,气敏传感器安装在安装孔中,气敏传感器的传感部位伸入S形管道和反S形管道的管腔中;安装在S形管道和反S形管道上的气敏传感器构成传感阵列; The bionic air chamber includes an air inlet joint, an air outlet joint, a tube body and a gas permeable membrane/semi-permeable membrane; both ends of the tube body are sealed; the air inlet joint and the air outlet joint are respectively installed at both ends of the tube body, and are connected to the lumen of the tube body Connected; the pipe body includes S-shaped pipes and reverse S-shaped pipes; the nozzle of the S-shaped pipe is fixed and communicated with the nozzle of the reverse S-shaped pipe, so that the lumen of the S-shaped pipe and the lumen of the reverse S-shaped pipe are connected to form a gas Road; the S-shaped pipeline and the reverse S-shaped pipeline are multiple, connected at intervals, and the multiple S-shaped pipelines and the reverse S-shaped pipeline are connected in sequence to form a longer gas path; the connected S-shaped pipeline and the reverse S-shaped pipeline , the mouth of the joint is covered with a gas permeable membrane/semipermeable membrane, which separates the lumen of the S-shaped duct from the lumen of the reverse S-shaped duct; between the S-shaped duct and the reverse S-shaped duct There is a mounting hole on the pipe wall, and the gas sensor is installed in the mounting hole, and the sensing part of the gas sensor extends into the lumen of the S-shaped pipe and the reverse S-shaped pipe; it is installed on the S-shaped pipe and the reverse S-shaped pipe The gas sensor on the top constitutes a sensing array; 控制模块包括处理模块、工作温度调制模块和传感阵列信号采集模块;处理模块与工作温度调制模块和传感阵列信号采集模块连接;传感阵列信号采集模块与气敏传感器连接;工作温度调制模块与MOS型气敏传感器匹配,所述的气敏传感器为MOS型气敏传感器时,工作温度调制模块与MOS型气敏传感器连接,可对MOS型气敏传感器进行工作温度调制。 The control module includes a processing module, a working temperature modulation module and a sensor array signal acquisition module; the processing module is connected to the working temperature modulation module and the sensor array signal acquisition module; the sensor array signal acquisition module is connected to the gas sensor; the working temperature modulation module It is matched with a MOS type gas sensor, and when the gas sensor is a MOS type gas sensor, the working temperature modulation module is connected with the MOS type gas sensor, so that the working temperature of the MOS type gas sensor can be modulated. 2.根据权利要求1所述的电子鼻时空气味信息的仿生检测装置,其特征在于:所述的工作温度调制模块包括数模转换器、电压跟随器和功率放大模块;传感阵列信号采集模块包括四号电阻、五号电阻、六号电阻、仪表放大器和模数转换器;处理模块、数模转换器、电压跟随器、功率放大模块依次连接;MOS型气敏传感器的加热电阻与功率放大模块连接;MOS型气敏传感器的敏感电阻与四号电阻、五号电阻、六号电阻构成惠斯通电桥,惠斯通电桥、仪表放大器、模数转换器、处理模块依次连接; 2. The bionic detection device of time-air odor information of electronic nose according to claim 1, characterized in that: said operating temperature modulation module comprises a digital-to-analog converter, a voltage follower and a power amplification module; a sensing array signal acquisition module Including resistor No. 4, resistor No. 5, resistor No. 6, instrument amplifier and analog-to-digital converter; processing module, digital-to-analog converter, voltage follower, and power amplifier module are connected in sequence; heating resistor and power amplifier of MOS gas sensor Module connection; the sensitive resistor of the MOS gas sensor forms a Wheatstone bridge with No. 4 resistor, No. 5 resistor, and No. 6 resistor, and the Wheatstone bridge, instrument amplifier, analog-to-digital converter, and processing module are connected in sequence; 处理模块的嵌入式程序预设多种温度调制驱动信号,温度调制驱动信号经过数模转换器转换成模拟信号,再通过电压跟随器,由功率放大模块功率放大后输给加热电阻,可实现工作温度调制;惠斯通电桥输出电压通过仪表放大器放大,并转换成单极信号,再由模数转换器转换成数字信号给处理模块。 The embedded program of the processing module presets a variety of temperature modulation driving signals. The temperature modulation driving signal is converted into an analog signal through a digital-to-analog converter, and then through a voltage follower, the power is amplified by the power amplifier module and then output to the heating resistor, which can realize the work. Temperature modulation; the output voltage of the Wheatstone bridge is amplified by the instrumentation amplifier and converted into a unipolar signal, and then converted into a digital signal by an analog-to-digital converter for the processing module. 3.根据权利要求1或2所述的电子鼻时空气味信息的仿生检测装置,其特征在于:所述的管体包括封头;管体两端用封头封住。 3. The biomimetic detection device for temporal and air odor information of an electronic nose according to claim 1 or 2, characterized in that: the tube body includes a cap; both ends of the tube body are sealed with caps. 4.根据权利要求1或2所述的电子鼻时空气味信息的仿生检测装置,其特征在于:还包括气体采样泵和排废泵,采样泵和排废泵与控制模块连接;进气接头与气体采样泵连接,出气接头与排废泵连接。 4. according to claim 1 and the bionic detection device of air odor information of electronic nose, it is characterized in that: also comprise gas sampling pump and exhaust pump, sampling pump and exhaust pump are connected with control module; The gas sampling pump is connected, and the gas outlet joint is connected to the exhaust pump. 5.根据权利要求1或2所述的电子鼻时空气味信息的仿生检测装置,其特征在于:所述的气敏传感阵列包含多种原理和类型构建的混合传感阵列。 5. The biomimetic detection device for temporal and air odor information of the electronic nose according to claim 1 or 2, characterized in that: the gas sensing array includes a hybrid sensing array constructed with various principles and types. 6.根据权利要求1或2所述的电子鼻时空气味信息的仿生检测装置,其特征在于:所述的处理模块可采用单片机或者微处理器。 6. The device for bionic detection of temporal and air odor information of the electronic nose according to claim 1 or 2, characterized in that: the processing module can adopt a single-chip microcomputer or a microprocessor. 7.根据权利要求1或2所述的电子鼻时空气味信息的仿生检测装置,其特征在于:所述的功率放大模块由达林顿管构成,或者采用集成芯片。 7. The biomimetic detection device for temporal and air odor information of an electronic nose according to claim 1 or 2, characterized in that: said power amplification module is made of a Darlington tube, or an integrated chip is used. 8.根据权利要求1或2所述的电子鼻时空气味信息的仿生检测装置,其特征在于:所述的电压跟随器由运算放大器构成。 8. The device for bionic detection of temporal and air odor information of an electronic nose according to claim 1 or 2, characterized in that: said voltage follower is composed of an operational amplifier. 9.根据权利要求1或2所述的电子鼻时空气味信息的仿生检测装置,其特征在于:如果某些安装孔无需安装气敏传感器,可以用的塞头堵住这些安装孔。 9. The biomimetic detection device for temporal and air odor information of the electronic nose according to claim 1 or 2, characterized in that: if some installation holes do not need to install gas sensors, plugs can be used to block these installation holes. 10.一种电子鼻时空气味信息的仿生检测方法,其特征在于:采用权利要求1~9任一权利要求所述的仿生检测装置;气味通过进气接头进入仿生气室,然后依次流过各管道,最后从出气接头排出;混合气味中的不同气体分子在流过透气膜/半透膜时在透气膜/半透膜中进行扩散,不同气体分子在气相和透气膜/半透膜中扩散传输率不同,导致它们在气路中不同位置存在组分和浓度差异,通过不同位置的气敏传感器获取其对应的差异性信号,即反映气味在仿生气室中传播的空间信息;工作温度调制模块不断改变气敏传感器加热电压幅值与频率来调制其工作温度,从而改变气敏传感器对不同气味成分的敏感度和选择性,形成一种对复杂气味内不同成分的扫描式响应过程,即可获取阵列中不同传感器丰富的时间序列信号;空间信息和时间序列信号构成气味时空信息;传感阵列信号采集模块获取传感阵列中不同传感器的气味时空信息;控制模块将传感阵列中的气味时空信息上传并保存至上位机。 10. A bionic detection method for air odor information in an electronic nose, characterized in that: the bionic detection device according to any one of claims 1 to 9 is adopted; the smell enters the bionic air chamber through the air inlet joint, and then flows through each Pipeline, finally discharged from the gas outlet joint; different gas molecules in the mixed odor diffuse in the gas-permeable/semi-permeable membrane when they flow through the gas-permeable/semi-permeable membrane, and different gas molecules diffuse in the gas phase and the gas-permeable/semi-permeable membrane Different transmission rates lead to differences in composition and concentration at different positions in the gas circuit, and the corresponding differential signals are obtained through gas sensors at different positions, which reflect the spatial information of the odor propagating in the imitation air chamber; working temperature modulation The module continuously changes the heating voltage amplitude and frequency of the gas sensor to modulate its working temperature, thereby changing the sensitivity and selectivity of the gas sensor to different odor components, forming a scanning response process to different components in complex odors, namely The rich time series signals of different sensors in the array can be obtained; spatial information and time series signals constitute the space-time information of smell; the sensor array signal acquisition module obtains the space-time information of smell from different sensors in the sensor array; the control module will sense the smell in the array The spatio-temporal information is uploaded and saved to the host computer.
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