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CN105572078B - A kind of double-core photonic crystal fiber SRP refractive index sensing models - Google Patents

A kind of double-core photonic crystal fiber SRP refractive index sensing models Download PDF

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CN105572078B
CN105572078B CN201610057845.3A CN201610057845A CN105572078B CN 105572078 B CN105572078 B CN 105572078B CN 201610057845 A CN201610057845 A CN 201610057845A CN 105572078 B CN105572078 B CN 105572078B
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refractive index
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CN105572078A (en
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刘云凤
刘彬
何兴道
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Nanchang Hangkong University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/55Specular reflectivity
    • G01N21/552Attenuated total reflection
    • G01N21/553Attenuated total reflection and using surface plasmons
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/02295Microstructured optical fibre
    • G02B6/02314Plurality of longitudinal structures extending along optical fibre axis, e.g. holes
    • G02B6/02319Plurality of longitudinal structures extending along optical fibre axis, e.g. holes characterised by core or core-cladding interface features

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Abstract

本发明公开了一种双芯光子晶体光纤SPR折射率传感模型,其横截面为圆形,包括基底1、纤芯和包层空气孔2,纤芯周围为包层空气孔,所述的纤芯设置为右侧纤芯3和左侧纤芯4;所述的右侧纤芯3为实心基底材料;所述的左侧纤芯4包括银膜5、检测孔6;其优点是,采用双芯和椭圆检测孔SPR折射率传感结构,在一定折射率范围内过滤高阶SPP模式,确定传感共振波峰不需要模式辨别,可以达到高线性和高灵敏度传感,对于折射率动态变化的溶液可实时监测,大大提高传感效率。

The invention discloses a dual-core photonic crystal fiber SPR refractive index sensing model, which has a circular cross section and includes a base 1, a fiber core and cladding air holes 2, and cladding air holes are around the fiber core. The fiber core is set to the right side fiber core 3 and the left side fiber core 4; the right side fiber core 3 is a solid base material; the left side fiber core 4 includes a silver film 5 and a detection hole 6; its advantages are, Adopt double-core and elliptical detection hole SPR refractive index sensing structure, filter high-order SPP mode within a certain range of refractive index, determine the sensing resonance peak without mode discrimination, can achieve high linearity and high sensitivity sensing, for refractive index dynamics The changing solution can be monitored in real time, greatly improving the sensing efficiency.

Description

一种双芯光子晶体光纤SRP折射率传感模型A Refractive Index Sensing Model of Dual-Core Photonic Crystal Fiber SRP

技术领域technical field

本发明属于光子晶体光纤传感领域,尤其是涉及到光纤SPR传感技术,具The invention belongs to the field of photonic crystal optical fiber sensing, in particular relates to optical fiber SPR sensing technology, with

体说是一种双芯光子晶体光纤SPR折射率传感模型。The body is a dual-core photonic crystal fiber SPR refractive index sensing model.

背景技术Background technique

表面等离子体共振(SPR)行为是一种物理光学现象,表述了金属或者参杂半导体中表面等离子体(SPP)的共振现象,具有对附着在金属表面电介质的折射率变化非常敏感的特性,具有实时和快速检测、无须标记、耗样量少等特点,因此在化学、生物、环境及医药等领域具有非常广阔的应用前景,成为近年来研究光学探测传感技术新领域。Surface plasmon resonance (SPR) behavior is a physical optical phenomenon, which describes the resonance phenomenon of surface plasmon (SPP) in metals or doped semiconductors. It is very sensitive to the refractive index change of the dielectric attached to the metal surface. Real-time and rapid detection, no labeling, less sample consumption, etc., so it has very broad application prospects in the fields of chemistry, biology, environment and medicine, and has become a new field of research in optical detection and sensing technology in recent years.

光纤SPR传感领域随着光子晶体光纤(PCF)的出现,其优良特性如无截止单模特性、高双折射、可控色散、高非线性、结构设计灵活可控等,受到了研究人员的广泛关注,在SPR传感领展现出了巨大的潜在应用价值。With the emergence of photonic crystal fiber (PCF) in the field of optical fiber SPR sensing, its excellent characteristics such as unlimited single-mode characteristics, high birefringence, controllable dispersion, high nonlinearity, flexible and controllable structure design, etc., have been favored by researchers. Widely concerned, it has shown great potential application value in the field of SPR sensing.

国家专利局于2012年7月以公开号为CN 102590148 A公开了“一种易于实现相位匹配的光子晶体光纤SPR传感模型”的发明专利申请。该发明专利申请采用纤芯包层结构,材料为石英玻璃,纤芯中心设有纤芯空气孔,包层中设有六个呈正六边形排列的包层空气孔,其中两个位置中心对称的包层空气孔内表面镀有金膜的内部结构模地,较好地解决了传统光纤中纤芯与SPP模式相位匹配问题。但是,在实际运用中,该光子晶体光纤基础纤芯模式与高阶SPP模式耦合会引起多个共振峰,由于高阶SPP模式的干扰,在实际测量中需要先进行模式辨别,找出所需测量共振峰再得出折射率,对于介质折射率变化的传感,这不仅使的传感过程较复杂还降低了传感效率。In July 2012, the National Patent Office published an invention patent application for "a photonic crystal fiber SPR sensing model that is easy to achieve phase matching" with the publication number CN 102590148 A. The invention patent application adopts the core cladding structure, the material is quartz glass, the core air hole is set in the center of the fiber core, and the cladding is provided with six cladding air holes arranged in a regular hexagon, two of which are symmetrical to the center The inner surface of the air hole in the cladding is coated with a gold film, which better solves the phase matching problem between the core and the SPP mode in the traditional optical fiber. However, in practical applications, the coupling between the basic core mode of the photonic crystal fiber and the high-order SPP mode will cause multiple resonance peaks. Due to the interference of the high-order SPP mode, it is necessary to conduct mode discrimination in actual measurement to find the The refractive index is obtained by measuring the resonance peak. For the sensing of the change of the refractive index of the medium, this not only makes the sensing process more complicated but also reduces the sensing efficiency.

发明内容Contents of the invention

本发明要解决的技术问题是,针对上述现有技术存在的不足或缺陷,提供一种双芯光子晶体光纤SPR折射率传感模型。该模型采用双芯和椭圆检测孔结构,有效地解决了高阶SPP模式对测量共振峰的影响,并且具有高线性传感和高灵敏度的特性。The technical problem to be solved by the present invention is to provide a dual-core photonic crystal fiber SPR refraction index sensing model for the above-mentioned deficiencies or defects in the prior art. The model adopts a double-core and elliptical detection hole structure, which effectively solves the influence of high-order SPP modes on the measurement resonance peak, and has the characteristics of high linear sensing and high sensitivity.

本发明的技术解决方案是:Technical solution of the present invention is:

一种双芯光子晶体光纤SPR折射率传感模型,其横截面为圆形,包括基底、纤芯和包层空气孔,纤芯周围为包层空气孔,其特征在于,所述的纤芯设置为右侧纤芯和左侧纤芯;所述的右侧纤芯为实心基底材料;所述的左侧纤芯包括银膜、检测孔。A dual-core photonic crystal fiber SPR refractive index sensing model, which has a circular cross section, includes a base, a core, and cladding air holes, and cladding air holes around the core. It is characterized in that the core It is set as a right fiber core and a left fiber core; the right fiber core is a solid base material; the left fiber core includes a silver film and a detection hole.

基底和右侧纤芯的材料为二氧化硅,其折射率为1.45。The material of the base and the right core is silica with a refractive index of 1.45.

包层空气孔以正六边形周期排列,包层空气孔相邻间距为2um,包层空气孔直径为1um。The cladding air holes are periodically arranged in a regular hexagon, the distance between adjacent cladding air holes is 2um, and the diameter of the cladding air holes is 1um.

检测孔为椭圆形,检测孔长轴为1.6um,短轴尺寸为1.18um,检测孔用于放置待测溶液。The detection hole is elliptical, the long axis of the detection hole is 1.6um, and the short axis is 1.18um. The detection hole is used to place the solution to be tested.

所述银膜厚度为40nm。The thickness of the silver film is 40nm.

采用以上结构后,与现有技术相比,本发明的优点是:采用双芯和椭圆检测孔SPR折射率传感结构,在一定折射率范围内过滤高阶SPP模式,确定传感共振波峰不需要模式辨别,可以达到高线性和高灵敏度传感,对于折射率动态变化的溶液可实时监测,大大提高传感效率。After adopting the above structure, compared with the prior art, the advantages of the present invention are: adopt the SPR refractive index sensing structure with double cores and elliptical detection holes, filter high-order SPP modes within a certain range of refractive index, and determine whether the sensing resonance peak is Mode discrimination is required, high linearity and high sensitivity sensing can be achieved, real-time monitoring is possible for solutions with dynamic changes in refractive index, and the sensing efficiency is greatly improved.

附图说明Description of drawings

图1是本发明一种双芯光子晶体光纤SPR折射率传感模型内部结构示意图;Fig. 1 is a schematic diagram of the internal structure of a dual-core photonic crystal fiber SPR refractive index sensing model of the present invention;

图2是本发明一种双芯光子晶体光纤SPR折射率传感模型传感特性曲线;Fig. 2 is a sensing characteristic curve of a dual-core photonic crystal fiber SPR refractive index sensing model of the present invention;

图3是待测溶液折射率为1.45时在900nm-1800nm波段出现的各SPP模式与右侧纤芯模式色散曲线;Figure 3 is the dispersion curve of each SPP mode and the right core mode appearing in the 900nm-1800nm band when the refractive index of the solution to be tested is 1.45;

图4是待测溶液折射率为1.50时在900nm-1800nm波段出现的各SPP模式与右侧纤芯模式色散曲线;Figure 4 is the dispersion curve of each SPP mode and the right core mode appearing in the 900nm-1800nm band when the refractive index of the solution to be measured is 1.50;

图中:1.基底,2.包层空气孔,3.右侧纤芯,4.左侧纤芯,5.银膜,6.检测孔。In the figure: 1. Substrate, 2. Cladding air hole, 3. Right fiber core, 4. Left fiber core, 5. Silver film, 6. Detection hole.

具体实施方式Detailed ways

下面结合附图和具体实施方式对本发明作进一步说明:The present invention will be further described below in conjunction with accompanying drawing and specific embodiment:

一种双芯光子晶体光纤SPR折射率传感模型,其横截面为圆形,包括基底1、纤芯和包层空气孔2,纤芯周围为包层空气孔2,其特征在于,所述的纤芯设置为右侧纤芯3和左侧纤芯4;所述的右侧纤芯3为实心基底材料;所述的左侧纤芯4包括银膜5、检测孔6。A dual-core photonic crystal fiber SPR refractive index sensing model, the cross-section of which is circular, includes a substrate 1, a core and cladding air holes 2, and cladding air holes 2 around the core, characterized in that the The fiber cores are set as the right fiber core 3 and the left fiber core 4; the right fiber core 3 is a solid base material; the left fiber core 4 includes a silver film 5 and a detection hole 6.

所述基底1和右侧纤芯3的材料为二氧化硅,其折射率为1.45。The material of the base 1 and the right core 3 is silicon dioxide with a refractive index of 1.45.

所述包层空气孔2以正六边形周期排列,相邻间距为2um,包层空气孔2直径为1um。The cladding air holes 2 are periodically arranged in regular hexagons, the distance between adjacent ones is 2um, and the diameter of the cladding air holes 2 is 1um.

所述检测孔6为椭圆形,检测孔6长轴为1.6um,短轴尺寸为1.18um,检测孔6用于放置待测溶液。The detection hole 6 is elliptical, the long axis of the detection hole 6 is 1.6um, and the short axis is 1.18um. The detection hole 6 is used to place the solution to be tested.

所述银膜5厚度为40nm。The thickness of the silver film 5 is 40nm.

本发明采用的双芯和椭圆侧芯的光子晶体光纤的SPR折射率传感模型,利用右侧纤芯3基膜与左侧纤芯4中的SPP模式耦合,在相位匹配条件下达到共振耦合,局域在右侧纤芯3的光被左侧纤芯4中的银膜5大量吸收,传输损耗达到峰值。利用共振波长对金属表面介质折射率变化非常敏感这一特性实现对介质折射率的检测。传感特性曲线如图2所示,在待测孔6中溶液折射率为1.45-1.50范围内,具有超高线性特性,灵敏度达到10412nm/RIU。The SPR refractive index sensing model of the photonic crystal fiber with dual cores and elliptical side cores used in the present invention uses the base film of the right core 3 to couple with the SPP mode in the left core 4 to achieve resonance coupling under phase matching conditions , the light localized in the right core 3 is largely absorbed by the silver film 5 in the left core 4, and the transmission loss reaches a peak value. The detection of the refractive index of the medium is realized by utilizing the characteristic that the resonance wavelength is very sensitive to the change of the refractive index of the metal surface medium. The sensing characteristic curve is shown in FIG. 2 . The refractive index of the solution in the hole 6 to be tested is within the range of 1.45-1.50, and has ultra-high linearity, and the sensitivity reaches 10412nm/RIU.

检测孔6为椭圆形能有效过滤高阶SPP模式,如图3和图4所示,分别代表了900nm-1800nm波段内,待测孔6中溶液折射率为1.45和1.5时出现的所有左侧纤芯4中SPP模式以及和右侧纤芯3基膜色散曲线,当SPP模式与基膜色散相同时为相位匹配点,结合图3与图4可得出在1112.37nm-1376.35nm波段以及1387.4nm- 1633.75nm波段内只存在所需要测量的SPP1模式。所对应折射率范围为1.45-1.472和1.474-1.5,在该折射率范围内进行SPR传感时无需进行模式分辨,可以有效的简化传感步骤。The detection hole 6 is elliptical and can effectively filter the high-order SPP mode, as shown in Figure 3 and Figure 4, which respectively represent all the left side of the solution in the hole 6 to be tested when the refractive index of 1.45 and 1.5 in the 900nm-1800nm band SPP mode in core 4 and the basement film dispersion curve of core 3 on the right. When the SPP mode and basement film dispersion are the same, it is the phase matching point. Combining Figure 3 and Figure 4, it can be obtained that in the 1112.37nm-1376.35nm band and 1387.4 Only the SPP1 mode that needs to be measured exists in the nm-1633.75nm band. The corresponding ranges of the refractive index are 1.45-1.472 and 1.474-1.5, and no mode resolution is required for SPR sensing in the range of the refractive index, which can effectively simplify the sensing steps.

本发明的一种双芯光子晶体光纤SPR折射率传感模型,采用金属银作为激发表面等离子体金属,灵敏度可达到10412nm/RIU,在1.45-1.50折射率范围内具有超高线性特性,检测孔为椭圆形状在一定折射率范围内实现无需模式辨别直接测量共振峰得到对于折射率,大大简化了传感步骤,增加传感效率。所得到的这一特性对未来光子晶体光纤传感领域具有良好的应用价值。A dual-core photonic crystal fiber SPR refractive index sensing model of the present invention uses metallic silver as the excited surface plasmon metal, the sensitivity can reach 10412nm/RIU, and it has ultra-high linearity in the range of 1.45-1.50 refractive index. The detection hole For the elliptical shape within a certain range of refractive index, the resonant peak can be directly measured without mode discrimination to obtain the refractive index, which greatly simplifies the sensing steps and increases the sensing efficiency. The obtained characteristic has good application value in the field of photonic crystal fiber sensing in the future.

以上内容是结合具体的优选实施方式对本发明所作的进一步详细说明,不能认定本发明的具体实施只局限于这些说明。对于本发明所属技术领域的普通技术人员来说,在不脱离本发明构思的前提下做出若干等同替代或明显变型,而且性能或用途相同,则应当视为属于本发明所提交的权利要求书确定的保护范围。The above content is a further detailed description of the present invention in conjunction with specific preferred embodiments, and it cannot be assumed that the specific implementation of the present invention is limited to these descriptions. For those of ordinary skill in the technical field to which the present invention belongs, those who make several equivalent substitutions or obvious modifications without departing from the concept of the present invention, and have the same performance or use, shall be deemed to belong to the claims submitted by the present invention defined scope of protection.

Claims (2)

1. a kind of double-core photonic crystal fiber SPR refractive index sensing models, its cross section is circle, including substrate (1), fibre core and Covering airport (2), fiber core are covering airport (2), it is characterised in that described fibre core is arranged to right side fibre core (3) With left side fibre core (4);Described right side fibre core (3) is solid base material;Described left side fibre core (4) includes silverskin (5), inspection The material of gaging hole (6), described substrate (1) and right side fibre core (3) is silica, and its refractive index is 1.45, described covering Airport (2) is with regular hexagon periodic arrangement, and covering airport (2) adjacent spacing is 2 μm, a diameter of 1 μ of covering airport (2) M, described detection hole (6) are ellipse, and detection hole (6) major axis is 1.6 μm, and minor axis dimension is 1.18 μm, and detection hole (6) is used for Place solution to be measured.
2. a kind of double-core photonic crystal fiber SPR refractive index sensing models as claimed in claim 1, it is characterised in that described Silverskin (5) thickness is 40nm.
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