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CN105567111A - High stable-peel-force antiadherent film - Google Patents

High stable-peel-force antiadherent film Download PDF

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Publication number
CN105567111A
CN105567111A CN201510979627.0A CN201510979627A CN105567111A CN 105567111 A CN105567111 A CN 105567111A CN 201510979627 A CN201510979627 A CN 201510979627A CN 105567111 A CN105567111 A CN 105567111A
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CN
China
Prior art keywords
static coating
surface anti
layer
high stable
cloudy surface
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510979627.0A
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Chinese (zh)
Inventor
金闯
张庆杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sidike New Materials Jiangsu Co Ltd
Original Assignee
Sidike New Materials Jiangsu Co Ltd
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Filing date
Publication date
Application filed by Sidike New Materials Jiangsu Co Ltd filed Critical Sidike New Materials Jiangsu Co Ltd
Publication of CN105567111A publication Critical patent/CN105567111A/en
Pending legal-status Critical Current

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    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
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Abstract

The present invention discloses a high stable-peel-force antiadherent film, the surface of the high stable-peel-force antiadherent film is coated with a matte-surface anti-static coating layer with the thickness of 0.2 to 2 microns; the other surface of the matte-surface anti-static coating layer is coated with a silicone oil layer; and the matte-surface anti-static coating layer comprises the following components by mass: 6% of silica particles, 25% of an acrylic polyol with an average molecular weight of 500 to 2000, 37% of polyoxyalkylene series polyol resin with an average molecular weight of 200 to 2500, 17% of polyethylene glycol, 8% of cyclomethylsiloxane and 7% of 1-hydroxy cyclohexyl phenyl ketone-photoinitiator 184. The high stable-peel-force antiadherent film solves the not high adhesion and unstable g peel force of a release paper lamination layer and a release agent coating, can improve film surface antistatic properties, and also improves the resistance scratch resistance.

Description

High stable peeling force antiadhesion barrier
Technical field
The present invention relates to a kind of antiadhesion barrier, particularly a kind of high stable peeling force antiadhesion barrier.
Background technology
Existing antiadhesion barrier is generally the surperficial film one deck leaching membrane layer (material of employing mainly contains polyethylene) at separate-type paper ground paper layer, then obtains separate-type paper in surface coated one deck parting agent coating (material of employing is mainly silicone oil) of leaching membrane layer.But because leaching membrane layer planeness is high, poor adhesive force between parting agent coating and leaching membrane layer, when separate-type paper attaches with the pad pasting being coated with trowel adhesive, the parting agent coating in separate-type paper is easily caused to be taken away by the tackiness agent that adhesive power is larger, thus form in the local surfaces of pad pasting the parting agent coating area being difficult to clean out, destroy pure, the consistence of pad pasting entirety.And due to production process electrostatic excessive, causes the local unfairness of release coating layer, not only affect product peeling force stability, and easily generation static sparking causes fire.
Summary of the invention
The object of the invention is to provide a kind of high stable peeling force antiadhesion barrier, this high stable peeling force antiadhesion barrier had both solved the leaching membrane layer of separate-type paper and parting agent coating binding force is not high, peeling force is unstable, turn improve film surface anti-static performance, and also improve scratch resistance performance simultaneously.
For achieving the above object, the technical solution used in the present invention is: a kind of high stable peeling force antiadhesion barrier, in described high stable peeling force antiadhesion barrier, thin film layer one surface coated a layer thickness is the cloudy surface anti-static coating of 0.2 ~ 2 micron, and another surface-coated of cloudy surface anti-static coating has silicon layer; The surface that described cloudy surface anti-static coating contacts with silicon layer has some sags and crests;
Described cloudy surface anti-static coating is made up of the component of following masses percentage composition:
Silica granule 6%,
Molecular-weight average is the acrylic polyol 25% of 500 ~ 2000,
Molecular-weight average is the resin 37% of the polyoxyalkylene series polyvalent alcohol of 200 ~ 2500,
Polyoxyethylene glycol 17%,
Cyclomethicone 8%,
1-hydroxycyclohexyl phenyl ketone-light trigger 1847%;
The particle diameter of described silica granule is that in the size-grade distribution measured by laser diffraction and scattering method, particle diameter has peak value respectively and median size is 4 μm or following in the scope of 0.1 ~ 2 μm and 1.5 ~ 5 μm;
Described cloudy surface anti-static coating adopts ultra-violet bands to be 280nm ~ 350nm, and illumination is 1200mW/cm 2, described cloudy surface anti-static coating is irradiated, makes described component under the effect of 1-hydroxycyclohexyl phenyl ketone-light trigger 184, carry out polyreaction and obtain cloudy surface anti-static coating.
In technique scheme, further improved plan is as follows:
1, in such scheme, described ultra-violet bands is 280nm ~ 350nm.
2, in such scheme, described thin film layer is the one in film layer or polyvinyl chloride layer, pet film layer, layer of polypropylene foil.
Because technique scheme is used, the present invention compared with prior art has following advantages and effect:
1, high stable peeling force antiadhesion barrier of the present invention, its adopt 20 ~ 30% molecular-weight average be 500 ~ 2000 acrylic polyol and 30 ~ 40% molecular-weight average be 200 ~ 2500 polyoxyalkylene series polyvalent alcohol resin polymerization urethane resin after and mix with cyclomethicone 4 ~ 8%, molecular-weight average be 500 ~ 2000 acrylic polyol and molecular-weight average be that chain in the resin of the polyoxyalkylene series polyvalent alcohol of 200 ~ 2500 improves film surface anti-static performance, and also improve scratch resistance performance simultaneously; Its polyalcohol acrylate monomer has the molecular-weight average of 500 ~ 2000, if molecular weight is less than 500, the wear resistance of film is tending towards reducing, if molecular-weight average is more than 2000, during film-forming, suitability is deteriorated.If polyalcohol acrylate monomer is in particular ethylene glycol, consider water-retaining capacity, the present invention select molecular-weight average be 200 ~ 1000 polyoxyethylene glycol, make use of the ability of its superior absorption Bound moisture, further increase anti-static effect.Have the ability of the water of absorption Bound moisture form superior especially due to this acrylic polyol monomer, have anti-static effect, polyalcohol acrylate monomer all can use this monomer.
2, the present invention is first to the surface coated cloudy surface anti-static coating of thin film layer, by the surface after composition and engineering process, there is some even concaveconvex structures and anti-static effect through cloudy surface anti-static coating, then in this surface coated silicon parting agent coating coating, the bottom surface of silicon parting agent coating coating infiltrates the notch place on described cloudy surface anti-static coating surface in the liquid state, silicon parting agent coating coating is fixedly linked by notch place and cloudy surface anti-static coating after solidification, therefore, bonding force more firmly, reliably.And due to anti-electrostatic process, can eliminate electrostatic to the unstable impact brought of silicone oil coating, release peeling force can be very stable, also avoids the generation of production process static sparking.
3, adopt light trigger 1-hydroxycyclohexyl phenyl ketone to cause in the present invention, mainly consider that it is under wave band is 320-400nm UV-irradiation, can instantaneous solidification film forming, can deep cure be reached, there is good planarization and intensity.Described light trigger is 1-hydroxycyclohexyl phenyl ketone-light trigger 184, is a kind of ultraviolet initiator of efficient non yellowing, and for causing the UV polyreaction of unsaturated prepolymerization system, its mass content is 5 ~ 10%.
4, high stable peeling force antiadhesion barrier of the present invention, described silica granule to be particle diameter be in the size-grade distribution measured by laser diffraction and scattering method particle diameter has peak value respectively in the scope of 0.1 ~ 2 μm and 1.5 ~ 5 μm and median size is 4 μm or following silica granule, both substantially increase atomized surface effect, in turn ensure that solidification effect.
5, the power of medium ultraviolet light of the present invention adopts 1200mW/cm 2if mainly power is lower than 1200mW/cm 2, film not exclusively solidifies, and wear resistance reduces; If if power is higher than 1200mW/cm 2, affect film planeness, suitability declines.Employing ultra-violet bands is 320 ~ 400nm, and illumination is 1200mW/cm 2described cloudy surface coating-forming agent is irradiated, make described component carry out polyreaction under the effect of the specific 1-hydroxycyclohexyl phenyl ketone as light trigger of the present invention and obtain cloudy surface coating, thickness is 4 ~ 10 μm, there is anti-static effect, then obtain cloudy surface release layer in surface-coated one deck parting agent coating of described cloudy surface coating.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
Embodiment: a kind of high stable peeling force antiadhesion barrier, in described high stable peeling force antiadhesion barrier, thin film layer one surface coated a layer thickness is the cloudy surface anti-static coating of 0.2 ~ 2 micron, and another surface-coated of cloudy surface anti-static coating has silicon layer; The surface that described cloudy surface anti-static coating contacts with silicon layer has some sags and crests;
Described cloudy surface anti-static coating is made up of the component of following masses percentage composition:
Silica granule 6%,
Molecular-weight average is the acrylic polyol 25% of 500 ~ 2000,
Molecular-weight average is the resin 37% of the polyoxyalkylene series polyvalent alcohol of 200 ~ 2500,
Polyoxyethylene glycol 17%,
Cyclomethicone 8%,
1-hydroxycyclohexyl phenyl ketone-light trigger 1847%;
The particle diameter of described silica granule is that in the size-grade distribution measured by laser diffraction and scattering method, particle diameter has peak value respectively and median size is 4 μm or following in the scope of 0.1 ~ 2 μm and 1.5 ~ 5 μm;
Described cloudy surface anti-static coating adopts ultra-violet bands to be 280nm ~ 350nm, and illumination is 1200mW/cm 2, described cloudy surface anti-static coating is irradiated, makes described component under the effect of 1-hydroxycyclohexyl phenyl ketone-light trigger 184, carry out polyreaction and obtain cloudy surface anti-static coating.
Cloudy-surface release paper is stacked gradually by leaching membrane layer, separate-type paper body paper, adhesive layer, thin film layer, cloudy surface anti-static coating and parting agent coating six layers and forms, and the surfaceness on the surface of described cloudy surface anti-static coating and parting agent coating layer touch is 2.821 μm ~ 3.324 μm.Testing standard: ISO4287:1998.Roughness tester: the TR200 Manual roughness devices of Beijing epoch peak Science and Technology Ltd. production.
Described cloudy surface anti-static coating is polyester cloudy surface coating.First be the leaching membrane layer of PE to the one side film material of separate-type paper body paper, another side is coated with one deck adhesive layer, to fit on adhesive layer again thin film layer, then at the surface coated cloudy surface anti-static coating (material is polyester) of thin film layer, surface has some even concaveconvex structures after treatment, then in the release parting agent coating of this surface coated silicon, the bottom surface of silicon release parting agent coating infiltrates the notch place on described cloudy surface anti-static coating surface in the liquid state, the release parting agent coating of silicon is fixedly linked by notch and cloudy surface anti-static coating after solidification, therefore, bonding force is more firm, reliably.But also by regulating the mist degree (i.e. roughness) of cloudy surface anti-static coating, can freely adjust the size of peeling force between the release parting agent coating of silicon and separate-type paper body paper.
Performance index are as shown in table 1:
Table 1
(1), ocular estimate: evaluated by the existence of visual detection to outward appearance, transparency and crackle.No problem film is rated as satisfactory (O), and problematic film is rated as unsatisfactory (X);
(2), private seal by release aspect private seal 10 times, be qualified without delustring, delustring is defective;
(3), hundred lattice test cross-cut testers tests without coming off for qualified product, come off for substandard product;
(4) (1 kilogram back and forth by adhesive tape crimping, to peel off voltage roller, speed 0.3m/min) in release face, thereafter, (10m/min) is peeled off by quick-moving speed, the maximum value that adhesive tape glues the stripping static voltage of release face is read with electrostatic field tester (model: SIMCOFMX-003), it is qualified product that static voltage is less than 0.3KV, and it is substandard product that static voltage is greater than 0.3KV;
(5), surface resistance value surface resistivity tester G two, face parallel copper electrodes is placed in the arbitrary place of sample surfaces, presses black A key, waits about 30 seconds, and LED shows test place resistance, and ambient temperature and humidity, notes down.Display surface resistance <1.0E+10 Ω/sq, (65%RH, 23 DEG C) are for qualified; Display surface resistance >1.0E+10 Ω/sq, (65%RH, 23 DEG C) are defective.
(6) wearability test is at the 500g/cm of steel wire face (#0000) 2the pressure that adds rub after 30 times to hard coat face, to not having scar to be denoted as O, be denoted as X to there being scar.
(7) pencil hardness test evaluates the pencil hardness of hard coating film according to GB/T6739-2006.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its object is to person skilled in the art can be understood content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalences done according to spirit of the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (3)

1. a high stable peeling force antiadhesion barrier, is characterized in that: in described high stable peeling force antiadhesion barrier, thin film layer one surface coated a layer thickness is the cloudy surface anti-static coating of 0.2 ~ 2 micron, and another surface-coated of cloudy surface anti-static coating has silicon layer; The surface that described cloudy surface anti-static coating contacts with silicon layer has some sags and crests;
Described cloudy surface anti-static coating is made up of the component of following masses percentage composition:
Silica granule 6%,
Molecular-weight average is the acrylic polyol 25% of 500 ~ 2000,
Molecular-weight average is the resin 37% of the polyoxyalkylene series polyvalent alcohol of 200 ~ 2500,
Polyoxyethylene glycol 17%,
Cyclomethicone 8%,
1-hydroxycyclohexyl phenyl ketone-light trigger 1847%;
The particle diameter of described silica granule is that in the size-grade distribution measured by laser diffraction and scattering method, particle diameter has peak value respectively and median size is 4 μm or following in the scope of 0.1 ~ 2 μm and 1.5 ~ 5 μm;
Described cloudy surface anti-static coating adopts ultra-violet bands to be 280nm ~ 350nm, and illumination is 1200mW/cm 2, described cloudy surface anti-static coating is irradiated, makes described component under the effect of 1-hydroxycyclohexyl phenyl ketone-light trigger 184, carry out polyreaction and obtain cloudy surface anti-static coating.
2. high stable peeling force antiadhesion barrier according to claim 1, is characterized in that: described ultra-violet bands is 280nm ~ 350nm.
3. high stable peeling force antiadhesion barrier according to claim 1, is characterized in that: described thin film layer is the one in film layer or polyvinyl chloride layer, pet film layer, layer of polypropylene foil.
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