CN105552254A - Corrosion-prevention and compression-resistant lithium battery shell and production method therefor - Google Patents
Corrosion-prevention and compression-resistant lithium battery shell and production method therefor Download PDFInfo
- Publication number
- CN105552254A CN105552254A CN201610118290.9A CN201610118290A CN105552254A CN 105552254 A CN105552254 A CN 105552254A CN 201610118290 A CN201610118290 A CN 201610118290A CN 105552254 A CN105552254 A CN 105552254A
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- CN
- China
- Prior art keywords
- parylene
- layer
- parylene layer
- lithium battery
- battery shell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 238000004519 manufacturing process Methods 0.000 title claims description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title abstract description 12
- 229910052744 lithium Inorganic materials 0.000 title abstract description 12
- 230000006835 compression Effects 0.000 title abstract 3
- 238000007906 compression Methods 0.000 title abstract 3
- 238000005536 corrosion prevention Methods 0.000 title abstract 3
- 229920000052 poly(p-xylylene) Polymers 0.000 claims abstract description 53
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 23
- 230000008569 process Effects 0.000 claims abstract description 19
- 239000004411 aluminium Substances 0.000 claims description 14
- 238000003475 lamination Methods 0.000 claims description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 8
- 238000007747 plating Methods 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 7
- 230000004913 activation Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- 230000002950 deficient Effects 0.000 claims description 6
- 238000010790 dilution Methods 0.000 claims description 6
- 239000012895 dilution Substances 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000007767 bonding agent Substances 0.000 claims description 3
- 230000001680 brushing effect Effects 0.000 claims description 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- 239000007822 coupling agent Substances 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- 238000005137 deposition process Methods 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 150000002334 glycols Chemical class 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 238000002372 labelling Methods 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 238000005488 sandblasting Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000003466 welding Methods 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 230000002159 abnormal effect Effects 0.000 abstract description 2
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000003247 decreasing effect Effects 0.000 abstract 2
- 238000005562 fading Methods 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 230000004888 barrier function Effects 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Secondary Cells (AREA)
- Sealing Battery Cases Or Jackets (AREA)
Abstract
The invention provides a corrosion-prevention and compression-resistant lithium battery shell. The lithium battery shell is characterized by comprising an aluminum layer, a parylene layer and a hard anti-scratch layer, wherein the aluminum layer is manufactured into the main body part of the battery shell; the parylene layer is plated on the outer side of the aluminum layer, and then the aluminum layer is coated with the hard anti-scratch layer; and the parylene layer is plated on the inner side of the aluminum layer. The corrosion-prevention and compression-resistant lithium battery shell has the beneficial effects that the service life of the lithium battery is greatly prolonged, the probability of bulging, capacity fading and other abnormal accidents in the use process of the lithium battery is lowered, the cracked area of the battery shell after the battery is extruded is decreased, the contact area between a cell and external oxygen is decreased, and the safety of the lithium battery in use is improved.
Description
Technical field
The present invention relates to a kind of battery case, it is specifically related to a kind of anticorrosion withstand voltage li battery shell and production method thereof.
Background technology
Lithium battery is high with its specific energy, fail safe good, have extended cycle life, the field such as advantages of environment protection is widely used in electronics, communication, electric tool, motor vehicle, energy storage, Aero-Space.Lithium ion battery comprises positive pole, collector, barrier film, electrolyte and negative pole in battery case and battery case, and battery case, mainly for the protection of inside battery battery core, prevents extraneous oxygen and moisture etc. and the material such as inside battery electrode and electrolyte.Existing most of li battery shell adopts the metal shell such as box hat, aluminum hull, aluminum plastic film flexible package shell or plastic casing, but metal shell weight is large, corrosion resistance and electrical insulating property bad; Although plastic casing is lightweight, corrosion resistance and electrical insulating property good, but the material adopted due to battery case is modified polymer material, this macromolecular material affects by the mobility of polymer segment and the free volume of molecule segment, it is bad to the barrier of outside moisture and oxygen, thus makes battery easily produce bulging and electrode corrosion; Although aluminum plastic film flexible package shell good barrier property is still unsuitable for large-capacity power lithium battery.
Summary of the invention
The object of the invention is to propose a kind of anticorrosion withstand voltage li battery shell and production method thereof, the battery case provided has superior antiseptic property, and it has good impact resistance and reliable insulating properties.
In order to solve the problem, the invention provides anticorrosion withstand voltage li battery shell and have employed following technical scheme:
A kind of anticorrosion withstand voltage li battery shell, it is characterized in that: comprise aluminium lamination, parylene layer, hard anti-scratch layers, described aluminium lamination is made as the main part of battery case, the outside of described aluminium lamination is first plated parylene layer and is then applied hard anti-scratch layers, the inner side plating parylene layer of described aluminium lamination, described parylene layer comprises C type parylene layer and N-type parylene layer, and both composite beds, described parylene layer comprises Parylene and a chloro Parylene, the thickness of described C type parylene layer is 20-40 μm, the thickness of described N-type parylene layer is 20-40 μm, described C type parylene layer and the gross thickness of N-type parylene layer are 55 μm.
The production method of above-mentioned a kind of anticorrosion withstand voltage li battery shell is as follows:
The first step: surface preparation: first carry out sandblasting pretreatment to each surface of workpiece, carries out polishing, deburring to the surface of workpiece, avoids later stage plated film to occur uneven phenomenon, after acceptance(check), is for further processing;
Second step: cleaning, activation: carry out processed after being cleaned by pretreated for previous step workpiece, then dry, cleans up the greasy dirt of surface of the work and other impurity; Then coupling agent is used to carry out activation processing as activator the surface of the work after oven dry; After acceptance(check), be for further processing;
3rd step: mask: the process or apply appropriate glue process of being taped in pending for the workpiece after previous step process face, leaves standstill after 0.5-1 hour, checked whether and leakage to have covered and mistake covers phenomenon, be put in defective products box pending after defective products arrow labeling shows;
4th step: plated film: adopt vapour deposition process to be workpiece plating Parylene film, Parylene raw material, at 130 DEG C ~ 140 DEG C, evaporates under being less than 100Pa condition; Be 10 in vacuum degree
-2-10
2deposit in the vacuum chamber of Pa, deposition rate 0.1-2 μm/h; Residual gas is reclaimed by cold-trap;
5th step: use sol-gal process to apply hard anti-scratch layers: use sol-gal process at Parylene film outer surface coating 5-10 μm of SiO
2layer, described sol-gal process applies hard anti-scratch layers technique and is: first, by alcohol dilutions such as inorganic agent use water, isopropyl alcohol, butyl glycols; Then, by dilution after inorganic agent and bonding agent, auxiliary agent tego-wet280 and acrylic resin composite; Then, by spraying, dipping, the modes such as brushing are coated in aluminum hull surface; Last drying at room temperature is after at least 20 minutes, and under 150 ~ 220 degree of conditions, baking forms complete cross-linked state, keeps thickness between 0.5 ~ 50 μm;
6th step: remove mask: torn off by mask in the 3rd step, the product of gained gets final product directly and other accessory carries out welding assembly.
Beneficial effect of the present invention is: it has superior anti-electrolytic corrosion performance to provide a kind of anticorrosion withstand voltage li battery shell, and has good impact resistance and reliable insulating properties.Shell wall surfaces externally and internally because of its aluminium shell is all coated with C layer and the N layer of parylene, and be coated with hard anti-scratch layers at parylene layer skin, like this then there is no exposed metal/bare metal on the surface of li battery shell shell wall, enhance insulating reliability and the corrosion resistance of li battery shell, and further increase the barrier of li battery shell, significantly improve the useful life of lithium battery, reduce the abnormal accident probability such as the bulging in lithium battery use procedure, capacity attenuation; Simultaneously due to the stop of hard anti-scratch layers, reduce battery and the Strain energy of battery case after extruding and surperficial scratching occurs, ensure that dependability, reduce the contact area of battery core and external oxygen, thus reduce the probability that burning occurs high capacity cell, improve the fail safe of lithium battery.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of anticorrosion withstand voltage li battery shell provided by the invention.
Embodiment
The technical scheme provided for a more clear understanding of the present invention, is described further below in conjunction with accompanying drawing and specific embodiment.
As shown in Figure 1, the preferred embodiment of anticorrosion withstand voltage li battery shell provided by the invention, it is characterized in that: comprise aluminium lamination 1, parylene layer 2, hard anti-scratch layers 3, described aluminium lamination 1 is made as the main part of battery case, the hard anti-scratch layers 3 of coating after the outside plating parylene layer 2 of described aluminium lamination 1, the inner side plating parylene layer 2 of described aluminium lamination 1, described parylene layer 2 comprises C type parylene layer 21 and N-type parylene layer 22, and both composite beds 23, described parylene layer 2 comprises Parylene and a chloro Parylene, the thickness of described C type parylene layer 21 is 20-40 μm, the thickness of described N-type parylene layer 22 is 20-40 μm, described C type parylene layer 21 and the gross thickness of N-type parylene layer 22 are 55 μm.
Embodiment 1:
The production method of above-mentioned a kind of anticorrosion withstand voltage li battery shell is as follows:
The first step: surface preparation: first sandblasting pretreatment is carried out to each surface of the main part of the battery case that aluminium lamination 1 makes, polishing, deburring are carried out to the surface of workpiece, avoid later stage plated film to occur uneven phenomenon, after acceptance(check), be for further processing;
Second step: cleaning, activation: carry out processed after being cleaned by pretreated for previous step workpiece, then dry, cleans up the greasy dirt of surface of the work and other impurity; Then coupling agent is used to carry out activation processing as activator the surface of the work after oven dry; After acceptance(check), be for further processing;
3rd step: mask: the process or apply appropriate glue process of being taped in pending for the workpiece after previous step process face, leaves standstill after 0.5-1 hour, checked whether and leakage to have covered and mistake covers phenomenon, be put in defective products box pending after defective products arrow labeling shows;
4th step: plated film: adopt vapour deposition process to be workpiece plating Parylene film, Parylene raw material, at 130 DEG C ~ 140 DEG C, evaporates under being less than 100Pa condition; Be 10 in vacuum degree
-2-10
2deposit in the vacuum chamber of Pa, deposition rate 0.1-2 μm/h; Residual gas is reclaimed by cold-trap;
5th step: use sol-gal process to apply hard anti-scratch layers: use sol-gal process at Parylene film outer surface coating 5-10 μm of SiO
2layer;
6th step: remove mask: torn off by mask in the 3rd step, the product of gained gets final product directly and other accessory carries out welding assembly.
It is as follows that described sol-gal process applies hard anti-scratch layers technique:
1. by alcohol dilutions such as inorganic agent use water, isopropyl alcohol, butyl glycols;
2. again by dilution after inorganic agent and bonding agent, auxiliary agent (as tego-wet280) and resin (as acrylic resin) composite;
3., by spraying, dipping, the modes such as brushing are coated in aluminum hull surface;
4. first drying at room temperature at least 20 minutes, then under 150 ~ 220 degree of conditions, baking forms complete cross-linked state, and final film thickness is between 0.5 ~ 50um.
To the insulation of being correlated with through aforementioned production method processing battery case, the test of corrosion-resistant, high-temp resisting high-humidity resisting corrosive nature, method of testing and result as follows:
Insulation: by shell local coatings remove after connect voltage resistant instrument negative pole, voltage resistant instrument positive contact battery case and inside coating surface, voltage 1000V/3000V or other require voltage, leakage current 0.005A, 5 seconds testing times, test passes;
Corrosion-resistant: the battery case entirety after coating soaked in the electrolytic solution, under normal temperature air condition under (25 degree, 60RH% humidity) condition, through 38 days, non-corroding produces, and without obscission, after cleaning, drying, insulation property do not decline;
High-temp resisting high-humidity resisting corrodes: the battery case entirety after coating soaked in the electrolytic solution, under hot and humid condition under (60 degree, 90-95RH% humidity) condition, through 28 days, non-corroding produces, and without obscission, after cleaning, drying, insulation property do not decline.
Claims (2)
1. an anticorrosion withstand voltage li battery shell, it is characterized in that: comprise aluminium lamination, parylene layer, hard anti-scratch layers, described aluminium lamination is made as the main part of battery case, hard anti-scratch layers is applied after the outside plating parylene layer of described aluminium lamination, the inner side plating parylene layer of described aluminium lamination, described parylene layer comprises C type parylene layer and N-type parylene layer, and both composite beds, described parylene layer comprises Parylene and a chloro Parylene, the thickness of described C type parylene layer is 20-40 μm, the thickness of described N-type parylene layer is 20-40 μm, described C type parylene layer and the gross thickness of N-type parylene layer are 55 μm.
2. a production method for anticorrosion withstand voltage li battery shell according to claim 1, is characterized in that:
The first step: surface preparation: first carry out sandblasting pretreatment to each surface of workpiece, carries out polishing, deburring to the surface of workpiece, avoids later stage plated film to occur uneven phenomenon, after acceptance(check), is for further processing;
Second step: cleaning, activation: carry out processed after being cleaned by pretreated for previous step workpiece, then dry, cleans up the greasy dirt of surface of the work and other impurity; Then coupling agent is used to carry out activation processing as activator the surface of the work after oven dry; After acceptance(check), be for further processing;
3rd step: mask: the process or apply appropriate glue process of being taped in pending for the workpiece after previous step process face, leaves standstill after 0.5-1 hour, checked whether and leakage to have covered and mistake covers phenomenon, be put in defective products box pending after defective products arrow labeling shows;
4th step: plated film: adopt vapour deposition process to be workpiece plating Parylene film, Parylene raw material, at 130 DEG C ~ 140 DEG C, evaporates under being less than 100Pa condition; Be 10 in vacuum degree
-2-10
2deposit in the vacuum chamber of Pa, deposition rate 0.1-2 μm/h; Residual gas is reclaimed by cold-trap;
5th step: use sol-gal process to apply hard anti-scratch layers: use sol-gal process at Parylene film outer surface coating 5-10 μm of SiO
2layer, described sol-gal process applies hard anti-scratch layers technique and is: first, by alcohol dilutions such as inorganic agent use water, isopropyl alcohol, butyl glycols; Then, by dilution after inorganic agent and bonding agent, auxiliary agent tego-wet280 and acrylic resin composite; Then, by spraying, dipping, the modes such as brushing are coated in aluminum hull surface; Last drying at room temperature is after at least 20 minutes, and under 150 ~ 220 degree of conditions, baking forms complete cross-linked state, keeps thickness between 0.5 ~ 50 μm;
6th step: remove mask: torn off by mask in the 3rd step, the product of gained gets final product directly and other accessory carries out welding assembly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610118290.9A CN105552254A (en) | 2016-03-02 | 2016-03-02 | Corrosion-prevention and compression-resistant lithium battery shell and production method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610118290.9A CN105552254A (en) | 2016-03-02 | 2016-03-02 | Corrosion-prevention and compression-resistant lithium battery shell and production method therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105552254A true CN105552254A (en) | 2016-05-04 |
Family
ID=55831324
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610118290.9A Withdrawn CN105552254A (en) | 2016-03-02 | 2016-03-02 | Corrosion-prevention and compression-resistant lithium battery shell and production method therefor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105552254A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019002768A1 (en) * | 2017-06-29 | 2019-01-03 | I-Ten | Encapsulation system for electronic components and batteries |
| FR3068830A1 (en) * | 2017-07-06 | 2019-01-11 | I-Ten | ENCAPSULATION SYSTEM FOR ELECTRONIC COMPONENTS AND BATTERIES |
| JP2022106800A (en) * | 2017-01-02 | 2022-07-20 | ３ディーバッテリーズ リミテッド | Energy storage devices and systems |
| US11664550B2 (en) | 2019-12-23 | 2023-05-30 | I-Ten | Encapsulation system for electronic components and batteries |
| US11967694B2 (en) | 2018-05-07 | 2024-04-23 | I-Ten | Porous electrodes for electrochemical devices |
-
2016
- 2016-03-02 CN CN201610118290.9A patent/CN105552254A/en not_active Withdrawn
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2022106800A (en) * | 2017-01-02 | 2022-07-20 | ３ディーバッテリーズ リミテッド | Energy storage devices and systems |
| WO2019002768A1 (en) * | 2017-06-29 | 2019-01-03 | I-Ten | Encapsulation system for electronic components and batteries |
| EP3840110A1 (en) * | 2017-06-29 | 2021-06-23 | I-Ten | Encapsulation system for electronic components and batteries |
| US11469464B2 (en) | 2017-06-29 | 2022-10-11 | I-Ten | Encapsulation system for electronic components and batteries |
| FR3068830A1 (en) * | 2017-07-06 | 2019-01-11 | I-Ten | ENCAPSULATION SYSTEM FOR ELECTRONIC COMPONENTS AND BATTERIES |
| US11967694B2 (en) | 2018-05-07 | 2024-04-23 | I-Ten | Porous electrodes for electrochemical devices |
| US11664550B2 (en) | 2019-12-23 | 2023-05-30 | I-Ten | Encapsulation system for electronic components and batteries |
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Application publication date: 20160504 |
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