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CN105540742B - A kind of mixed bed device that can be automatically drawn into acid solution, lye - Google Patents

A kind of mixed bed device that can be automatically drawn into acid solution, lye Download PDF

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Publication number
CN105540742B
CN105540742B CN201610015905.5A CN201610015905A CN105540742B CN 105540742 B CN105540742 B CN 105540742B CN 201610015905 A CN201610015905 A CN 201610015905A CN 105540742 B CN105540742 B CN 105540742B
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China
Prior art keywords
mixed bed
alkali
inlet tube
lye
valve
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CN201610015905.5A
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CN105540742A (en
Inventor
潘洪涛
曾凡付
景永峰
艾山·玉素莆
刘啸泉
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Shenzhen Delan ecological environment Co., Ltd.
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XINJIANG ENVIRONMENTAL ENGINEERING TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • C02F2001/427Treatment of water, waste water, or sewage by ion-exchange using mixed beds

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The invention discloses a kind of mixed bed devices that can be automatically drawn into acid solution, lye, including mixed bed, lye tank, acid solution case, sour inlet tube, alkali inlet tube and siphon pipe, mixed bed is formed by mixed bed cabinet, water inlet distributor, into alkali device, zwitterion layer switching layer, baffle, the inside of mixed bed cabinet is successively arranged water inlet distributor, into alkali device, zwitterion layer switching layer, baffle from top to bottom, and water inlet distributor is connect with air door, inlet valve respectively by pipeline;The other end of inlet valve connects siphon pipe, and siphon pipe is separately connected sour inlet tube, alkali inlet tube, and another nozzle of sour inlet tube is located in lye tank, and another nozzle of alkali inlet tube is located in acid solution case.Structure of the invention is reasonable, compact.Its structure is simple, easy to process, low in cost, and when acid when regeneration, lye injection is not required to power.Have the characteristics that energy saving, laborsaving, easy, efficient.

Description

A kind of mixed bed device that can be automatically drawn into acid solution, lye
Technical field
The present invention relates to technical field of water treatment, specifically a kind of mixed bed device that can be automatically drawn into acid solution, lye.
Background technique
In water process production process, processed water passes through generated H after hybrid ionic exchange bed+And OH-It gives birth to immediately At the very low water of solubility, counter ion when cation or anion exchange is seldom formed, exchange reaction can be made to carry out thorough.Institute Reverse osmosis equipment is connected on mixed bed or level-one answers bed desalting system rear end, for producing for pure water and high purity water.
After a period of work, anions and canons can fail, and at this moment need the regeneration treatment for carrying out anions and canons, to realize again The secondary requirement used, regeneration need to inject acid, lye, and acid, the lye that anions and canons need when regenerating need special configuration to pump, and produce Increased costs, and cause the loss of the energy.
Summary of the invention
The purpose of the present invention is to provide a kind of mixed bed device that can be automatically drawn into acid solution, lye, processed water passes through Hybrid ionic exchanges generated H after bed+And OH-Ion is immediately generated the very low water of solubility and is completed again using siphon principle The injection of raw required acid, lye, realizes the purpose of automatic filling.
To achieve the above object, the invention provides the following technical scheme:
A kind of mixed bed device that can be automatically drawn into acid solution, lye, including mixed bed, lye tank, acid solution case, sour inlet tube, alkali Inlet tube and siphon pipe, mixed bed are formed by mixed bed cabinet, water inlet distributor, into alkali device, zwitterion layer switching layer, baffle, The inside of mixed bed cabinet is successively arranged water inlet distributor, into alkali device, zwitterion layer switching layer, baffle from top to bottom, intakes Water distributor is connect with air door, inlet valve respectively by pipeline;The other end of inlet valve is connected by siphon tube valve Siphon pipe, siphon pipe are separately connected sour inlet tube, alkali inlet tube, and another nozzle of sour inlet tube is located in lye tank, alkali feed liquor Another nozzle of pipe is located in acid solution case;Be additionally provided with pipeline above into alkali device, the pipeline by alkali-feeding valve door connect alkali into Liquid pipe is also provided with intermediate water discharging valve on mixed bed cabinet, and intermediate water discharging valve is located at dividing at zwitterion layer switching layer On interface, the lower section of mixed bed cabinet is equipped with acid inlet valve door, and acid inlet valve door is also connect with sour inlet tube.
As a further solution of the present invention: zwitterion layer switching layer uses anion-cation exchange resin.
As a further solution of the present invention: further respectively had below mixed bed cabinet backwashing water valve, produce penstock, Compressed air valve.
Compared with prior art, the beneficial effects of the present invention are:
Structure of the invention is reasonable, compact.Its structure is simple, easy to process, low in cost, acid, lye injection when regeneration Shi Buxu power.Have the characteristics that energy saving, laborsaving, easy, efficient.Acid, lye needed for general anions and canons switch regeneration Supply need to be equipped with special acid, alkali pump to realize, the present invention realizes this function using siphon principle.It is accessed on water inlet line Siphon pipe, acid, alkali inlet tube are connected on siphon pipe, and lower end is simultaneously immersed in sour, lye tank, when controlling their work by valve Between.When needing to inject acid, lye upon regeneration, quickly flowing water stream has directly been taken away in sour, alkali inlet tube in siphon pipe Gas, acid form negative pressure in alkali inlet tube, and acid, lye are inhaled into acid, alkali feed liquor from acid, lye tank under the action of negative pressure Guan Zhonghou is automatically into mixed bed.When acid, the liquid decline in lye tank reach acid, alkali inlet tube lower nozzle, gas from Nozzle entrance destroys negative pressure sour, in alkali inlet tube, and acid, lye stop entering in mixed bed, completes sour, lye automatic Function of injecting.Its structure is simple, and whole efficiency is high, does not need other power, so that it may realize by technique requirements realization periodicity into Liquid function.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention.
In figure: 1- air door, 2- inlet valve, 3- siphon tube valve, 4- alkali-feeding valve door, 5- backwashing water valve, 6- Acid inlet valve door, 7- produce penstock, 8- compressed air valve, the centre 9- water discharging valve, 10- mixed bed cabinet, 11- water inlet distributor, 12- Into alkali device, 13- zwitterion layer switching layer, 14- baffle, 15- lye tank, 16- acid solution case, 17- acid inlet tube, 18- alkali into Liquid pipe, 19- siphon pipe.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described, Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of mixed bed device that can be automatically drawn into acid solution, lye, including mixed bed, lye tank 15, acid Liquid case 16, sour inlet tube 17, alkali inlet tube 18 and siphon pipe 19, mixed bed by mixed bed cabinet 10, water inlet distributor 11, into alkali device 12, zwitterion layer switching layer 13, baffle 14 form, and the inside of mixed bed cabinet 10 is successively arranged water inlet distributor from top to bottom 11, into alkali device 12, zwitterion layer switching layer 13, baffle 14, water inlet distributor 11 passes through on the top of mixed bed cabinet 10 Pipeline is connect with air door 1, inlet valve 2 respectively;The other end of inlet valve 2 connects siphon pipe by siphon tube valve 3 19, siphon pipe 19 is separately connected sour inlet tube 17, alkali inlet tube 18, and another nozzle of sour inlet tube 17 is located in lye tank 15, Another nozzle of alkali inlet tube 18 is located in acid solution case 16.It is additionally provided with pipeline into the top of alkali device 12, the pipeline is by into alkali Valve 4 connects alkali inlet tube 18.Intermediate water discharging valve 9 is also provided on mixed bed cabinet 10, intermediate water discharging valve 9 is also located at yin-yang On interface at sheath switching layer 13, the lower section of mixed bed cabinet 10 further respectively have backwashing water valve 5, acid inlet valve door 6, Penstock 7, compressed air valve 8 are produced, acid inlet valve door 6 is also connect with sour inlet tube 17.
The use process of preferred embodiment: when normal work water flow first continuously by inlet valve 2 into Enter mixed bed 10, obtain the water of high-purity after zwitterion layer switching layer 13, is flowed out from penstock 7 is produced.When zwitterion layer When the work certain time failure of switching layer 13, resin regeneration need to be carried out, 13 function of zwitterion layer switching layer is restored.Backwash water from Backwashing water valve 5 enters mixed bed cabinet 10 by mixed bed bottom, while compressed air enters from compressed air valve 8, by yin, yang from The layering of subtree rouge, backwash water raffinate are discharged from intermediate water discharging valve 9, and compressed gas is discharged from air door 1.Zwitterion layer is handed over The anions and canons resin changed on layer 13 needed after standing injection acid, lye regenerated, at this moment open siphon tube valve 3, water from Siphon pipe 19 quickly flows down, and takes away the gas in sour inlet tube 17 and alkali inlet tube 18, and alkali, acid solution are from lye tank 15 and acid solution case 16 are inhaled into sour inlet tube 17 and alkali inlet tube 18, are entered in mixed bed cabinet 10 by alkali-feeding valve door 4, acid inlet valve door 6, lye The liquid level of case 15 and acid solution case 16 declines therewith.When liquid level drops to sour inlet tube 17 and alkali 18 lower nozzle of inlet tube, gas Body enters in sour inlet tube 17 and alkali inlet tube 18 from nozzle, destroys the negative pressure in sour inlet tube 17 and alkali inlet tube 18, acid, Lye stops entering mixed bed cabinet 10, and anions and canons resin regeneration is completed.Siphon tube valve 3 is closed, inlet valve 2 is opened, opens Beginning is just washed, mixes rouge, and the regeneration of zwitterion layer switching layer 13 is completed.Treated water can be re-started after the completion of regeneration Ion exchange process has started next working cycles.Adjust sour inlet tube 17 and 18 lower nozzle height of alkali inlet tube, so that it may Acid, alkali number needed for adjustment regeneration.So circulation realizes the exchange of zwitterion layer switching layer 13 and regeneration function.
Mixed bed ion-exchange method is exactly that anion-cation exchange resin is placed in the same exchanger, they are mixed It closes, bed is answered by the staggered multi-stag of countless anion-cation exchange resins so can regard as, the yin, yang of contained salt in water Ion then by resins exchange, and obtains the water of high-purity by the exchanger.
Due to anion-cation exchange resin be it is mutually uniform, so the exchange reaction of its anions and canons almost simultaneously into Row.The cation exchange and anion exchange of water are repeatedly staggeredly to carry out in other words.Generated H and OH is exchanged all through H-type It cannot accumulate, substantially eliminate the influence of counter ion, exchange the ratio of progress more thoroughly.
Using internal method of reproduction.It is different using the specific gravity of two kinds of resins when regeneration, make anion and cation exchange resin with backwash Complete separation, resin cation are deposited on down, and resin anion (R.A.) floats on above, then resin cation with hydrochloric acid (or sulfuric acid) again It is raw, resin anion (R.A.) burning regeneration.
Top is equipped with water inlet distributor 11, into alkali device 12, the outstanding waste discharge acid in centre, salkali waste liquid device, lower part have into acid and Water dispensing apparatus.It is from top water distribution when operation, lower part produces water;Be when regeneration from top into alkali, lower part into acid, intermediate row spent acid, Spent lye, the water inlet distributor 11 on 13 top of zwitterion layer switching layer, enables to be uniformly distributed into water.
Anion exchange resin regeneration lye is sent by sour inlet tube 17.Cation regenerant exchanger resin acid solution by Bottom alkali inlet tube 18 enters, and regenerated acid, alkali wasteliquid are discharged by intermediate water discharging valve 9.Intermediate water discharging valve 9 is arranged in yin-yang On the interface of sheath switching layer 13, acid, alkali wasteliquid and flushing liquor when for draining regeneration.
Mixed bed regenerative process after efficiency lost resin is two-step method regeneration, specifically: backwash, stand (layering), into alkali, set Change, backwash, layering, into acid, displacement, just washing, mixed rouge, just washing, one-step method regeneration can also be used, i.e., simultaneously into acid, alkali.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (3)

1. a kind of mixed bed device that can be automatically drawn into acid solution, lye, which is characterized in that including mixed bed, lye tank (15), acid solution case (16), sour inlet tube (17), alkali inlet tube (18) and siphon pipe (19), mixed bed by mixed bed cabinet (10), water inlet distributor (11), Into alkali device (12), zwitterion layer switching layer (13), baffle (14) composition, the inside of mixed bed cabinet (10) is from top to bottom successively Equipped with water inlet distributor (11), into alkali device (12), zwitterion layer switching layer (13), baffle (14), water inlet distributor (11) It is connect respectively with air door (1), inlet valve (2) by pipeline;The other end of inlet valve (2) passes through siphon tube valve (3) siphon pipe (19) are connected, siphon pipe (19) is separately connected sour inlet tube (17), alkali inlet tube (18), sour inlet tube (17) Another nozzle is located in acid solution case (16), and another nozzle of alkali inlet tube (18) is located in lye tank (15);Into alkali device (12) Top be additionally provided with pipeline, by alkali-feeding valve door (4) connection alkali inlet tube (18), mixed bed cabinet is also provided with the pipeline on (10) Intermediate water discharging valve (9), and intermediate water discharging valve (9) is located on the interface at zwitterion layer switching layer (13), mixed bed case It is additionally provided with below body (10) acid inlet valve door (6), acid inlet valve door (6) is also connect with sour inlet tube (17).
2. the mixed bed device according to claim 1 that acid solution, lye can be automatically drawn into, which is characterized in that zwitterion layer Switching layer (13) uses anion-cation exchange resin.
3. the mixed bed device according to claim 1 that acid solution, lye can be automatically drawn into, which is characterized in that mixed bed cabinet (10) backwashing water valve (5) is further respectively had below, produces penstock (7) and compressed air valve (8).
CN201610015905.5A 2016-01-11 2016-01-11 A kind of mixed bed device that can be automatically drawn into acid solution, lye Active CN105540742B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107857338B (en) * 2017-12-11 2019-03-08 淄博格瑞水处理工程有限公司 A kind of zero-emission mixed bed equipment
CN109502693A (en) * 2018-12-20 2019-03-22 中电环保股份有限公司 A kind of full-automatic softening plant and method applied to Treated sewage reusing processing system
CN111420714B (en) * 2020-05-23 2024-07-26 江阴江化微电子材料股份有限公司 Mixed bed ion exchange equipment
CN114620808B (en) * 2022-04-12 2022-09-09 宁夏厚德环保科技有限公司 Ion exchange water treatment device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2250949Y (en) * 1996-02-14 1997-04-02 孙建敏 Combined equipment for softening hard water
CN201161191Y (en) * 2008-01-24 2008-12-10 杭州美亚水处理科技有限公司 Acid-alkali regenerative agent conserving mix bed regenerating unit
CN201722178U (en) * 2010-06-10 2011-01-26 厦门恩迪膜科技有限公司 Automatic mixed bed device
CN103145218A (en) * 2013-03-29 2013-06-12 江苏格朗瑞科技有限公司 Mixed bed structure of water treatment system
CN103801411A (en) * 2014-02-19 2014-05-21 内蒙古包钢钢联股份有限公司 Demineralization water system mixed bed regeneration method
CN203990661U (en) * 2014-07-17 2014-12-10 上海大众祥源动力供应有限公司 Energy-saving Na-ion exchanger regenerated liquid access to plant

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2250949Y (en) * 1996-02-14 1997-04-02 孙建敏 Combined equipment for softening hard water
CN201161191Y (en) * 2008-01-24 2008-12-10 杭州美亚水处理科技有限公司 Acid-alkali regenerative agent conserving mix bed regenerating unit
CN201722178U (en) * 2010-06-10 2011-01-26 厦门恩迪膜科技有限公司 Automatic mixed bed device
CN103145218A (en) * 2013-03-29 2013-06-12 江苏格朗瑞科技有限公司 Mixed bed structure of water treatment system
CN103801411A (en) * 2014-02-19 2014-05-21 内蒙古包钢钢联股份有限公司 Demineralization water system mixed bed regeneration method
CN203990661U (en) * 2014-07-17 2014-12-10 上海大众祥源动力供应有限公司 Energy-saving Na-ion exchanger regenerated liquid access to plant

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Address after: 1202, Dachong building, No. 2009, Shahe West Road, Dachong community, Yuehai street, Nanshan District, Shenzhen City, Guangdong Province

Patentee after: Shenzhen Delan ecological environment Co., Ltd.

Address before: 830013, the Xinjiang Uygur Autonomous Region Urumqi hi tech Zone (new urban area) North Zone Industrial Park, 216 blue sky road, 5 office building, 1 floor

Patentee before: Xinjiang Environmental Engineering Technology Co., Ltd.