CN105540742B - A kind of mixed bed device that can be automatically drawn into acid solution, lye - Google Patents
A kind of mixed bed device that can be automatically drawn into acid solution, lye Download PDFInfo
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- CN105540742B CN105540742B CN201610015905.5A CN201610015905A CN105540742B CN 105540742 B CN105540742 B CN 105540742B CN 201610015905 A CN201610015905 A CN 201610015905A CN 105540742 B CN105540742 B CN 105540742B
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- mixed bed
- alkali
- inlet tube
- lye
- valve
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
- C02F2001/427—Treatment of water, waste water, or sewage by ion-exchange using mixed beds
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Water By Ion Exchange (AREA)
Abstract
The invention discloses a kind of mixed bed devices that can be automatically drawn into acid solution, lye, including mixed bed, lye tank, acid solution case, sour inlet tube, alkali inlet tube and siphon pipe, mixed bed is formed by mixed bed cabinet, water inlet distributor, into alkali device, zwitterion layer switching layer, baffle, the inside of mixed bed cabinet is successively arranged water inlet distributor, into alkali device, zwitterion layer switching layer, baffle from top to bottom, and water inlet distributor is connect with air door, inlet valve respectively by pipeline;The other end of inlet valve connects siphon pipe, and siphon pipe is separately connected sour inlet tube, alkali inlet tube, and another nozzle of sour inlet tube is located in lye tank, and another nozzle of alkali inlet tube is located in acid solution case.Structure of the invention is reasonable, compact.Its structure is simple, easy to process, low in cost, and when acid when regeneration, lye injection is not required to power.Have the characteristics that energy saving, laborsaving, easy, efficient.
Description
Technical field
The present invention relates to technical field of water treatment, specifically a kind of mixed bed device that can be automatically drawn into acid solution, lye.
Background technique
In water process production process, processed water passes through generated H after hybrid ionic exchange bed+And OH-It gives birth to immediately
At the very low water of solubility, counter ion when cation or anion exchange is seldom formed, exchange reaction can be made to carry out thorough.Institute
Reverse osmosis equipment is connected on mixed bed or level-one answers bed desalting system rear end, for producing for pure water and high purity water.
After a period of work, anions and canons can fail, and at this moment need the regeneration treatment for carrying out anions and canons, to realize again
The secondary requirement used, regeneration need to inject acid, lye, and acid, the lye that anions and canons need when regenerating need special configuration to pump, and produce
Increased costs, and cause the loss of the energy.
Summary of the invention
The purpose of the present invention is to provide a kind of mixed bed device that can be automatically drawn into acid solution, lye, processed water passes through
Hybrid ionic exchanges generated H after bed+And OH-Ion is immediately generated the very low water of solubility and is completed again using siphon principle
The injection of raw required acid, lye, realizes the purpose of automatic filling.
To achieve the above object, the invention provides the following technical scheme:
A kind of mixed bed device that can be automatically drawn into acid solution, lye, including mixed bed, lye tank, acid solution case, sour inlet tube, alkali
Inlet tube and siphon pipe, mixed bed are formed by mixed bed cabinet, water inlet distributor, into alkali device, zwitterion layer switching layer, baffle,
The inside of mixed bed cabinet is successively arranged water inlet distributor, into alkali device, zwitterion layer switching layer, baffle from top to bottom, intakes
Water distributor is connect with air door, inlet valve respectively by pipeline;The other end of inlet valve is connected by siphon tube valve
Siphon pipe, siphon pipe are separately connected sour inlet tube, alkali inlet tube, and another nozzle of sour inlet tube is located in lye tank, alkali feed liquor
Another nozzle of pipe is located in acid solution case;Be additionally provided with pipeline above into alkali device, the pipeline by alkali-feeding valve door connect alkali into
Liquid pipe is also provided with intermediate water discharging valve on mixed bed cabinet, and intermediate water discharging valve is located at dividing at zwitterion layer switching layer
On interface, the lower section of mixed bed cabinet is equipped with acid inlet valve door, and acid inlet valve door is also connect with sour inlet tube.
As a further solution of the present invention: zwitterion layer switching layer uses anion-cation exchange resin.
As a further solution of the present invention: further respectively had below mixed bed cabinet backwashing water valve, produce penstock,
Compressed air valve.
Compared with prior art, the beneficial effects of the present invention are:
Structure of the invention is reasonable, compact.Its structure is simple, easy to process, low in cost, acid, lye injection when regeneration
Shi Buxu power.Have the characteristics that energy saving, laborsaving, easy, efficient.Acid, lye needed for general anions and canons switch regeneration
Supply need to be equipped with special acid, alkali pump to realize, the present invention realizes this function using siphon principle.It is accessed on water inlet line
Siphon pipe, acid, alkali inlet tube are connected on siphon pipe, and lower end is simultaneously immersed in sour, lye tank, when controlling their work by valve
Between.When needing to inject acid, lye upon regeneration, quickly flowing water stream has directly been taken away in sour, alkali inlet tube in siphon pipe
Gas, acid form negative pressure in alkali inlet tube, and acid, lye are inhaled into acid, alkali feed liquor from acid, lye tank under the action of negative pressure
Guan Zhonghou is automatically into mixed bed.When acid, the liquid decline in lye tank reach acid, alkali inlet tube lower nozzle, gas from
Nozzle entrance destroys negative pressure sour, in alkali inlet tube, and acid, lye stop entering in mixed bed, completes sour, lye automatic
Function of injecting.Its structure is simple, and whole efficiency is high, does not need other power, so that it may realize by technique requirements realization periodicity into
Liquid function.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention.
In figure: 1- air door, 2- inlet valve, 3- siphon tube valve, 4- alkali-feeding valve door, 5- backwashing water valve, 6-
Acid inlet valve door, 7- produce penstock, 8- compressed air valve, the centre 9- water discharging valve, 10- mixed bed cabinet, 11- water inlet distributor, 12-
Into alkali device, 13- zwitterion layer switching layer, 14- baffle, 15- lye tank, 16- acid solution case, 17- acid inlet tube, 18- alkali into
Liquid pipe, 19- siphon pipe.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of mixed bed device that can be automatically drawn into acid solution, lye, including mixed bed, lye tank 15, acid
Liquid case 16, sour inlet tube 17, alkali inlet tube 18 and siphon pipe 19, mixed bed by mixed bed cabinet 10, water inlet distributor 11, into alkali device
12, zwitterion layer switching layer 13, baffle 14 form, and the inside of mixed bed cabinet 10 is successively arranged water inlet distributor from top to bottom
11, into alkali device 12, zwitterion layer switching layer 13, baffle 14, water inlet distributor 11 passes through on the top of mixed bed cabinet 10
Pipeline is connect with air door 1, inlet valve 2 respectively;The other end of inlet valve 2 connects siphon pipe by siphon tube valve 3
19, siphon pipe 19 is separately connected sour inlet tube 17, alkali inlet tube 18, and another nozzle of sour inlet tube 17 is located in lye tank 15,
Another nozzle of alkali inlet tube 18 is located in acid solution case 16.It is additionally provided with pipeline into the top of alkali device 12, the pipeline is by into alkali
Valve 4 connects alkali inlet tube 18.Intermediate water discharging valve 9 is also provided on mixed bed cabinet 10, intermediate water discharging valve 9 is also located at yin-yang
On interface at sheath switching layer 13, the lower section of mixed bed cabinet 10 further respectively have backwashing water valve 5, acid inlet valve door 6,
Penstock 7, compressed air valve 8 are produced, acid inlet valve door 6 is also connect with sour inlet tube 17.
The use process of preferred embodiment: when normal work water flow first continuously by inlet valve 2 into
Enter mixed bed 10, obtain the water of high-purity after zwitterion layer switching layer 13, is flowed out from penstock 7 is produced.When zwitterion layer
When the work certain time failure of switching layer 13, resin regeneration need to be carried out, 13 function of zwitterion layer switching layer is restored.Backwash water from
Backwashing water valve 5 enters mixed bed cabinet 10 by mixed bed bottom, while compressed air enters from compressed air valve 8, by yin, yang from
The layering of subtree rouge, backwash water raffinate are discharged from intermediate water discharging valve 9, and compressed gas is discharged from air door 1.Zwitterion layer is handed over
The anions and canons resin changed on layer 13 needed after standing injection acid, lye regenerated, at this moment open siphon tube valve 3, water from
Siphon pipe 19 quickly flows down, and takes away the gas in sour inlet tube 17 and alkali inlet tube 18, and alkali, acid solution are from lye tank 15 and acid solution case
16 are inhaled into sour inlet tube 17 and alkali inlet tube 18, are entered in mixed bed cabinet 10 by alkali-feeding valve door 4, acid inlet valve door 6, lye
The liquid level of case 15 and acid solution case 16 declines therewith.When liquid level drops to sour inlet tube 17 and alkali 18 lower nozzle of inlet tube, gas
Body enters in sour inlet tube 17 and alkali inlet tube 18 from nozzle, destroys the negative pressure in sour inlet tube 17 and alkali inlet tube 18, acid,
Lye stops entering mixed bed cabinet 10, and anions and canons resin regeneration is completed.Siphon tube valve 3 is closed, inlet valve 2 is opened, opens
Beginning is just washed, mixes rouge, and the regeneration of zwitterion layer switching layer 13 is completed.Treated water can be re-started after the completion of regeneration
Ion exchange process has started next working cycles.Adjust sour inlet tube 17 and 18 lower nozzle height of alkali inlet tube, so that it may
Acid, alkali number needed for adjustment regeneration.So circulation realizes the exchange of zwitterion layer switching layer 13 and regeneration function.
Mixed bed ion-exchange method is exactly that anion-cation exchange resin is placed in the same exchanger, they are mixed
It closes, bed is answered by the staggered multi-stag of countless anion-cation exchange resins so can regard as, the yin, yang of contained salt in water
Ion then by resins exchange, and obtains the water of high-purity by the exchanger.
Due to anion-cation exchange resin be it is mutually uniform, so the exchange reaction of its anions and canons almost simultaneously into
Row.The cation exchange and anion exchange of water are repeatedly staggeredly to carry out in other words.Generated H and OH is exchanged all through H-type
It cannot accumulate, substantially eliminate the influence of counter ion, exchange the ratio of progress more thoroughly.
Using internal method of reproduction.It is different using the specific gravity of two kinds of resins when regeneration, make anion and cation exchange resin with backwash
Complete separation, resin cation are deposited on down, and resin anion (R.A.) floats on above, then resin cation with hydrochloric acid (or sulfuric acid) again
It is raw, resin anion (R.A.) burning regeneration.
Top is equipped with water inlet distributor 11, into alkali device 12, the outstanding waste discharge acid in centre, salkali waste liquid device, lower part have into acid and
Water dispensing apparatus.It is from top water distribution when operation, lower part produces water;Be when regeneration from top into alkali, lower part into acid, intermediate row spent acid,
Spent lye, the water inlet distributor 11 on 13 top of zwitterion layer switching layer, enables to be uniformly distributed into water.
Anion exchange resin regeneration lye is sent by sour inlet tube 17.Cation regenerant exchanger resin acid solution by
Bottom alkali inlet tube 18 enters, and regenerated acid, alkali wasteliquid are discharged by intermediate water discharging valve 9.Intermediate water discharging valve 9 is arranged in yin-yang
On the interface of sheath switching layer 13, acid, alkali wasteliquid and flushing liquor when for draining regeneration.
Mixed bed regenerative process after efficiency lost resin is two-step method regeneration, specifically: backwash, stand (layering), into alkali, set
Change, backwash, layering, into acid, displacement, just washing, mixed rouge, just washing, one-step method regeneration can also be used, i.e., simultaneously into acid, alkali.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (3)
1. a kind of mixed bed device that can be automatically drawn into acid solution, lye, which is characterized in that including mixed bed, lye tank (15), acid solution case
(16), sour inlet tube (17), alkali inlet tube (18) and siphon pipe (19), mixed bed by mixed bed cabinet (10), water inlet distributor (11),
Into alkali device (12), zwitterion layer switching layer (13), baffle (14) composition, the inside of mixed bed cabinet (10) is from top to bottom successively
Equipped with water inlet distributor (11), into alkali device (12), zwitterion layer switching layer (13), baffle (14), water inlet distributor (11)
It is connect respectively with air door (1), inlet valve (2) by pipeline;The other end of inlet valve (2) passes through siphon tube valve
(3) siphon pipe (19) are connected, siphon pipe (19) is separately connected sour inlet tube (17), alkali inlet tube (18), sour inlet tube (17)
Another nozzle is located in acid solution case (16), and another nozzle of alkali inlet tube (18) is located in lye tank (15);Into alkali device (12)
Top be additionally provided with pipeline, by alkali-feeding valve door (4) connection alkali inlet tube (18), mixed bed cabinet is also provided with the pipeline on (10)
Intermediate water discharging valve (9), and intermediate water discharging valve (9) is located on the interface at zwitterion layer switching layer (13), mixed bed case
It is additionally provided with below body (10) acid inlet valve door (6), acid inlet valve door (6) is also connect with sour inlet tube (17).
2. the mixed bed device according to claim 1 that acid solution, lye can be automatically drawn into, which is characterized in that zwitterion layer
Switching layer (13) uses anion-cation exchange resin.
3. the mixed bed device according to claim 1 that acid solution, lye can be automatically drawn into, which is characterized in that mixed bed cabinet
(10) backwashing water valve (5) is further respectively had below, produces penstock (7) and compressed air valve (8).
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CN201610015905.5A CN105540742B (en) | 2016-01-11 | 2016-01-11 | A kind of mixed bed device that can be automatically drawn into acid solution, lye |
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CN105540742B true CN105540742B (en) | 2019-02-12 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107857338B (en) * | 2017-12-11 | 2019-03-08 | 淄博格瑞水处理工程有限公司 | A kind of zero-emission mixed bed equipment |
CN109502693A (en) * | 2018-12-20 | 2019-03-22 | 中电环保股份有限公司 | A kind of full-automatic softening plant and method applied to Treated sewage reusing processing system |
CN111420714B (en) * | 2020-05-23 | 2024-07-26 | 江阴江化微电子材料股份有限公司 | Mixed bed ion exchange equipment |
CN114620808B (en) * | 2022-04-12 | 2022-09-09 | 宁夏厚德环保科技有限公司 | Ion exchange water treatment device |
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CN201161191Y (en) * | 2008-01-24 | 2008-12-10 | 杭州美亚水处理科技有限公司 | Acid-alkali regenerative agent conserving mix bed regenerating unit |
CN201722178U (en) * | 2010-06-10 | 2011-01-26 | 厦门恩迪膜科技有限公司 | Automatic mixed bed device |
CN103145218A (en) * | 2013-03-29 | 2013-06-12 | 江苏格朗瑞科技有限公司 | Mixed bed structure of water treatment system |
CN103801411A (en) * | 2014-02-19 | 2014-05-21 | 内蒙古包钢钢联股份有限公司 | Demineralization water system mixed bed regeneration method |
CN203990661U (en) * | 2014-07-17 | 2014-12-10 | 上海大众祥源动力供应有限公司 | Energy-saving Na-ion exchanger regenerated liquid access to plant |
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN2250949Y (en) * | 1996-02-14 | 1997-04-02 | 孙建敏 | Combined equipment for softening hard water |
CN201161191Y (en) * | 2008-01-24 | 2008-12-10 | 杭州美亚水处理科技有限公司 | Acid-alkali regenerative agent conserving mix bed regenerating unit |
CN201722178U (en) * | 2010-06-10 | 2011-01-26 | 厦门恩迪膜科技有限公司 | Automatic mixed bed device |
CN103145218A (en) * | 2013-03-29 | 2013-06-12 | 江苏格朗瑞科技有限公司 | Mixed bed structure of water treatment system |
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Address after: 1202, Dachong building, No. 2009, Shahe West Road, Dachong community, Yuehai street, Nanshan District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Delan ecological environment Co., Ltd. Address before: 830013, the Xinjiang Uygur Autonomous Region Urumqi hi tech Zone (new urban area) North Zone Industrial Park, 216 blue sky road, 5 office building, 1 floor Patentee before: Xinjiang Environmental Engineering Technology Co., Ltd. |