CN105494408B - A kind of Efficient insecticidal composition and its application method containing hydroprene - Google Patents
A kind of Efficient insecticidal composition and its application method containing hydroprene Download PDFInfo
- Publication number
- CN105494408B CN105494408B CN201510880481.4A CN201510880481A CN105494408B CN 105494408 B CN105494408 B CN 105494408B CN 201510880481 A CN201510880481 A CN 201510880481A CN 105494408 B CN105494408 B CN 105494408B
- Authority
- CN
- China
- Prior art keywords
- oil
- effective dose
- pesticidal combination
- pest
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Insects & Arthropods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of Pesticidal combinations, the composition includes the mixture of one or more of hydroprene and amide insecticides, the mechanism of action of two kinds of insecticides is different, by reasonably compounding or mixture can achieve expansion insecticidal spectrum, control efficiency is improved, extends the optimum period for applying fertilizer, reduces dosage, reduce phytotoxicity, reduce residual, delay the good effects such as the generation of pest resistance and drug resistance and development.
Description
Technical field
The invention belongs to technical field of pesticide, be related to it is a kind of containing hydroprene and Tolfenpyrad, in ethiprole or butene-fipronil
A kind of synergistic complex composition.
Background technique
Due to being widely used in those early years chemical pesticide, although many pest and disease damages are under control, also with chemistry
The accumulative use of pesticide, most pest and disease damages all produce corresponding resistance.Moreover most of agricultures we using only 30%,
Remaining medicine not only increases agricultural cost, also polluted soil and ecological environment.
For being rationally asking for a urgent need to resolve efficiently with pesticide how under the premise of China's national conditions at this stage
Topic.One side pesticide is constantly updating, and effective component mu dosage drops to tens grams even several grams from several hectograms, reduces
The dosage of chemical pesticide, reduction are lost to dosage in environment.On the other hand, different cultivars ingredient is compounded, and is prevention and treatment resistance
The very common method of pest.Heterogeneity is compounded, according to practical application effect, to judge that certain compounding is synergy, adduction
Or antagonism.
And as the juvenoid of novel pesticide (such as hydroprene), there is interior suction transfer activity, low toxicity, hold
The effect phase is long, and to crop safety, the advantage small to eco-environmental impact receives extensive attention always, approve and praise highly.It is same to make
For new high-efficiency insecticide pyrazoles (such as Tolfenpyrad), followed since it blocks or destroy a large amount of Physiology and biochemistry in insect bodies
Ring and conclusion are able to small dosage, obtain good effect.With organic phosphates, pyrethroid, juvenoid
Cross resistance problem is not present in the main insecticide such as class.Its mode of action is contact toxicity, does not have absorbability.To various crop
A variety of chewing types and sucking pest have control efficiency.So the two reasonably compounds or mixture has expansion desinsection
Spectrum improves control efficiency, extension optimum period for applying fertilizer, reduces dosage, reduce phytotoxicity, reduce residual, delaying pest resistance and resist
The positive features such as the generation and development of pharmacological property.
Summary of the invention
In view of this, the present invention provides a kind of Pesticidal combination, the composition includes hydroprene and amide insecticides
One or more of.Wherein amide insecticides are Tolfenpyrad, ethiprole or butene-fipronil.
The mass ratio of hydroprene and amide insecticides is 90: 1~1: 90, preferably 80: 1~1: 80, further excellent
It is selected as 70: 1~1: 70.
Composition provided by the invention further may include oil component, be selected from vegetable oil, animal oil, mineral oil, essence
It is oily and other, wherein the vegetable oil be selected from peanut oil, soya-bean oil, linseed oil, castor oil, sunflower oil, sesame oil, tea-seed oil,
Coconut oil, rosin base oil etc., the animal oil are selected from lard, butter, sheep oil etc..The oil component is further selected from gasoline, bavin
Oil, paraffin, kerosene etc..
Wherein the mass ratio of the gross mass and oil component of hydroprene and amide insecticides is 0.0001~1000:
1, preferably 0.001-100: 1, particularly preferred 0.001-80: 1.
Composition provided by the invention further may include alcohols, be selected from ethylene glycol, glycerine, polyethylene glycol 200, poly- second
Glycol 400, polyethylene glycol-800, Macrogol 600.
The ratio of the composition and alcohol component is 0.0001~1000: 1, preferably 0.01~100: 1, particularly preferably
0.01~80: 1.
Hydroprene and Tolfenpyrad in composition, the content and ratio of ethiprole or butene-fipronil compounding can be according to prevention and treatments pair
Change as the difference with dosage form, the total content of composition accounts for the 0.0001~99% of total formulation weight in institute's preparaton, preferably
0.01~93%, particularly preferred 0.5~70%.
The Pesticidal combination, it is characterised in that: composition can be made into wettable powder, water dispersible granules, suspending agent,
Suspoemulsion, aqueous emulsion, microemulsion.
Wherein the auxiliary element include wetting agent, dispersing agent, disintegrating agent, emulsifier, binder, stabilizer, defoaming agent,
One or both of antifreezing agent, preservative, light stabilizer, antioxidant, solvent, encapsulating agent, warning coloration, filler, film forming agent
More than.
Wherein, solvent includes dimethylbenzene, toluene, chlorobenzene, dichlorotoleune, paraffin, hexamethylene, mineral oil, vegetable oil, alcohol
One or more of class, acetone, cyclohexanone, methyl iso-butyl ketone (MIBK), dimethylformamide, dimethyl sulfoxide, water etc.
Mixture.
Filler includes but is not limited to the days such as kaolin, clay, talcum, chalk, quartz, attapulgite, montmorillonite, diatomite
The synthetic minerals powder such as right mineral powder, silica, aluminium oxide, silicate；Calcite, marble, float stone, sepiolite and white clouds
The natural rock that stone etc. is crushed and is classified, the particle of the organic substances such as sawdust, coconut husk, corncob and tobacco stem；Ammonium sulfate, sulphur
Sour potassium, sodium sulphate, ammonium chloride, potassium chloride, sodium chloride, ammonium hydrogen carbonate, saleratus, sodium bicarbonate, ammonium carbonate, potassium carbonate, carbon
Sour sodium, sodium pyrophosphate, tertiary sodium phosphate, precipitated calcium carbonate inorganic salts；
Film forming agent include but is not limited to Arabic gum, acrylic acid polymer, oxidized starch acetic acid vinegar, Macrogol 600,
Ethylene-vinyl acetate copolymer, Pioloform, polyvinyl acetal, methyl acrylate-methyl acrylic copolymer, povidone.
Adhesive includes but is not limited to carboxymethyl cellulose (CMC), hydroxypropyl cellulose, polyvinyl alcohol, polyvinyl acetate
Ester, natural phospholipid, synthetic phospholipid.
Antioxidant includes but is not limited to butylhydroxy anisole (BHA), dibutyl hydroxy toluene (BHT), tert-butyl
Hydroquinone (TBHQ), propylgallate (PG), ascorbyl palmitate (AP), thiodipropionic acid dilauryl cinnamic acid ester
(DLTP), the artificial synthesized class such as 4- hexyl resorcin (4-HR), tocopherol (vitamin E), L-AA (vitamin C),
D-araboascorbic acid sodium (sodium isoascorbate), tea polyphenols (TP), Rosmarinus officinalis extract, phytic acid (phytic acid), ginger extract
Object.
Light stabilizer includes but is not limited to phenyl salicylate, 3,5- dichlorosalicylic acid phenyl ester, the double 4 (benzene of 4,4 '-isopropylidenes
Phenol salicylate), p-t-butylphenyl salicylate, the salicylic acids esters such as p-octylphenyl salicylate, resorcinol list benzene potassium acid
The benzoate light stabilizers such as ester, 3,5- di-tert-butyl-4-hydroxybenzoic acid -2,4- 6- di-tert-butyl phenyl ester, UV-2908, N-
539, the cyanoacrylates light stabilizer such as N-35,2,4-DihydroxyBenzophenone (UV-0), 2- hydroxyl -4- methoxyl group hexichol
Ketone (UV-9), 2- hydroxyl -4- n-octyloxy-benzophenone (UV-531), 2- hydroxyl -4- (2 '-second are for hexyloxy)-hexichol first
The benzophenones such as ketone (UV-242), UV-39, UV-21, UV-207, DOBP, HBBP, UV-P, UV-320, UV-327, UV-
328, the benzotriazoles such as UV-510, UV5411, the nickel compound containings such as NBC, UV-1084, AM-101, UV-3034, light stabilizer
744, the hindered amines such as light stabilizer LA-57, light stabilizer LA-68, light stabilizer LA-63, light stabilizer LA-67.
The dispersing agent is selected from alkylnaphthalene sulfonate, bis- (alkyl) naphthalenesulfonate formaldehyde condensation compounds, naphthalenesulfonateformaldehyde formaldehyde contracting
Close object, arylphenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, sulfomethylated lignin
The phonetic formaldehyde condensation products sulfate of hydrochlorate, alkyl aryl polyoxyethylene ether, fatty alcohol polyoxyethylene ether, alkylphenol-polyethenoxy,
Alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy are phonetic, aliphatic amine polyoxyethylene is phonetic, fatty acid
Polyoxyethylene ester, ester polyoxyethylene are one of phonetic or a variety of.
The wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent
F, one of spaonin powder, sldium lauryl sulfate, tea seed cake, silkworm excrement, spaonin powder or a variety of.
The disintegrating agent is selected from: sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, in aluminium chloride
It is one or more.
The thickener is selected from: hydroxymethyl cellulose, hydroxyethyl cellulose, aluminum magnesium silicate, gelatin, guar gum, Arab
Glue, xanthan gum, sodium tripolyphosphate, phenolic resin, sodium alginate, white dextrin, methylcellulose, sodium acrylate, polyvinyl pyrrole
One of alkanone, crosslinked polyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol are a variety of.
The antifreeze is selected from: glycerol, ethylene glycol, propylene glycol, glycerine, diethylene glycol (DEG), triethylene glycol, in polyethylene glycol
It is one or more.
The solvent is selected from: n,N-Dimethylformamide, 3-methyl cyclohexanol ketenes, n-octylpyrrolidone, N- pyrroles
Alkanone, toluene, propyl alcohol, cyclohexanone, acetone, methanol, ethyl alcohol, butanol, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil, second
Nitrile is one or more.
The defoaming agent is selected from: the fatty alcohols of silicone, C8~10, the saturated fat acids of C0~20 (such as capric acid) and acyl
One of amine, silicone oil, silicone compound are a variety of.
The emulsifier is selected from: agriculture breast 500# (alkyl benzene calcium sulfonate), OP series phosphate (nonylphenol polyoxyethylene ether
Phosphate), 600# phosphate (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl
Ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400# (benzyl dimethyl phenol polyoxyethyl ether), agriculture breast 600# (phenyl phenol polyoxy
Ethylether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxyethyl ether), agriculture breast 36# (phenethyl phenol formaldehyde resin polyoxyethanyl
Ether), agriculture breast 1600# (phenethyl phenol polyoxyethanyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series
(nonylphenol polyoxyethylene ether), By series (castor oil polyoxyethylene ether), agriculture breast 33# (alkylaryl polyoxyethylene polyoxypropylene
Ether), agriculture breast 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitan monostearate), TWEEN Series
One of (sorbitan fatty acid ester polyoxyethylene ether), AEO series (fatty alcohol polyoxyethylene ether) is a variety of.
The PH regulator is selected from one of sodium hydroxide, hydrochloric acid, citric acid, sorbic acid or a variety of.
The filler is selected from: kaolin, diatomite, bentonite, attapulgite, white carbon black, starch, in precipitated calcium carbonate
It is one or more.
The crop pests can be Lepidoptera, Diptera, coleoptera, Homoptera, Hymenoptera, Semiptera, Orthoptera,
Diptera, Acarina, Anoplura, Siphonaptera, Neuroptera, Collembola, Thysanoptera, including but not limited to striped rice borer, beet armyworm, apple
The vertical volume of heart-eating worm, olethreutid, bollworm, cabbage butterfly, diamondback moth, pear psyllid, Bemisia tabaci, scale insect, aphid, thrips, rice
Leaf snout moth's larva, pink bollworm, lopper worm, arrowhead scales, mite, aphid, pine moth, rice leaf roller, plant hopper, green bugs, Mai Changguan
Aphid, rhopalosiphum padi, aleyrodid, thrips, prodenia litura, cabbage caterpillar, flea beetle, bean-pod borer, liriomyza bryoniae, red spider, white spider.
The sanitary insect pest refers mainly to mosquito, horsefly, midge, buffalo gnat, sand fly, fly, cockroach (blattaria), bedbug.The fly includes but not
Be limited to housefly, torsalo, stomach fly, yellow fly, band fork yellow-fever mosquito, Aedes harinasutai, Aedes japonicus, intellectual with a senior professional title yellow-fever mosquito, aedes luteocephalus, Mans she
Mosquito, black yellow-fever mosquito, Aedes poicilius, Pori Ni Xi yellow-fever mosquito, Samoa yellow-fever mosquito, aedes scapularis, aedes scutellaris, aedes taeniorhynchus, safe formula
Yellow-fever mosquito, aedes togoi, aedes triseriatus, Aedes vexans, vigilance yellow-fever mosquito, rhizome of Chinese monkshood yellow-fever mosquito, anopheles albimanus, anopheles albitarsis, ring grain anopheles,
It must also anopheles, anopheles aquasalis etc.
The storage pest can be coleoptera, Lepidoptera, Blattaria, Corrodentia, Thysanoptera and Arachnoidea Acarina, packet
Include but be not limited to curculionid class, ancient moth, saw-toothed grain beetle, Cryptolestes pusillus, red flour beetle, gelechiid, Indian meal moth, the thermophilic junket of corruption, pea weevil,
Grain peat, lasioderma serricorne beetle, tobacco powder sp, short foot attagenus piceus.
The parasitic pest can be flea, louse, dust mite, follicle mites, crab louse, head louse, culex, gamasid, trombiculid, scabies
Worm, pinworm, chicken tapeworm, shaft louse, chicken mite, tick worm etc..
When the present composition is used as crop pests prevention and treatment, effective dose is 0.01~100 milli gram/m, excellent
Select 0.6~100 milli gram/m, particularly preferred 0.6~30 milli gram/m.
The present composition serve as storage pest prevention and treatment when, effective dose be 0.1~100 mg/kg, preferably 1
~100 mg/kgs, particularly preferred 1~60 mg/kg.
When the present composition is used as health pest control, effective dose is 0.001~100 gram/cubic metre, preferably
0.01~100 gram/cubic metre, particularly preferred 0.01~30 gram/cubic metre.
When the present composition serves as parasitic pest prevention and treatment, effective dose is 0.01~100 mg/kg, preferably
0.1~100 mg/kg, particularly preferred 0.05~60 mg/kg.
Inventive composition includes alcohol component, is conducive to the absorption of active constituent, prevents or slows down the volatilization of hydroprene,
Active constituent is improved, the dosage of unit area is reduced, drug cost is reduced, also can preferably promote the steady of complex composition
It is fixed.This composition is especially obvious particularly with the control efficiency of crop pests.
Specific embodiment
Specific description is done to present aspect below by embodiment, it is necessary to which indicated herein is that following embodiment is served only for
Invention is further explained, should not be understood as limiting the scope of the invention, the person skilled in the art in the field
Nonessential modifications and adaptations can be made according to the present invention.
In example, the effect for being individually administered the composition of the invention that is far to the effect of target pest is good, this medicine synergy
Degree be also not only it is that both activities ingredient is simply added as a result, and drug effect is faster more efficient shows, verified
Example nor be only limitted to following examples.The experiment of experimental design composition test target pest drug effect, suitable temperature strip
It is cultivated under part, after required time, calculates the death rate.In terms of %.100% indicates to kill all bodyguard pest larvas；0% indicates
No target pest larva is killed.The identified death rate is substituted into Colby formula.
Colby calculation formula is as follows:
E=X+Y- (X × Y)/100, wherein
The death rate of the X=when using reactive compound A with the rate of application of m ppm, is expressed as the hundred of untreated control group
Divide ratio,
The death rate of the Y=when using reactive compound B with the rate of application of n ppm, is expressed as the hundred of untreated control group
Divide ratio,
The death rate of the E=when using reactive compound A and B with the rate of application of m+n ppm, is expressed as untreated control group
Percentage.
Embodiment 1: agricultural crops pest efficacy testing
Test method: when test each ingredients mother liquor is diluted to preparation using concentration respectively in proportion, is respectively placed in burning
It is taken out after cup, it, will be not in contact with food (such as Rice Leaf of the same size of any medicament using insect is accessed after first impregnating food
Piece, wild rice stem, cotton tender leaf) impregnate 1min after take out, naturally dry, be put into insect box, then connect for examination adult or
Larva is raised under the conditions of 25 DEG C, 3 repetitions of each processing, and test worm number used in every repetition is 50, while setting blank control,
After required time, the death rate is determined, in terms of %.100% indicates to kill all pests；0% indicates that no pest is killed.
The identified death rate is substituted into Colby formula.
1 agricultural crops pest effect experiment result of table
Embodiment 2: storage pest efficacy testing
Storage pest food (mung bean, rice etc.) 100g is weighed, is fitted into can, three repetitions of each experiment.Green
First uniform spraying is each on beans prepares the dosing (as shown in table 2) after mother liquor dilutes, after allowing medicament to volatilize 2 days, each
Adult 25 is right in test bottle, and observation adult sensitivity reflection, adult contacting foodstuff surfactant determines 1d, the death rate after 3d, 5d
Or without emergence number.Blank control is set simultaneously, after required time, the death rate is counted, in terms of %.100% indicates to kill institute
There is pest；0% indicates that no pest is killed.
The identified death rate is substituted into Colby formula.
2 storage pest effect experiment result of table
Embodiment 3: sanitary insect pest efficacy testing
Compound preparation distilled water is diluted 100 times, is then tested by GB 13917.8, GB/T17322.1 method,
Release test worm each 100.Using manual sprayer station in simulation field central, it is small to carry out spraying Culex pipiens pallens, housefly, Germany
Lian, to mosquito, upward 45 ° of fly it is spraying, 45 ° downward to blattaria are spraying, and simulation scene is entered after 1h, and observation calculates rate of knockdown.It will examination
Normally raised in worm income cleaning ware, 6,12, observation calculates mosquito, the fly death rate afterwards for 24 hours, 24,48, observation calculates moral after 72h
The small Lian death rate of state.This experiment in triplicate, after required time, counts the death rate, in terms of %.100% indicates to kill institute
There is pest；0% indicates that no pest is killed.The identified death rate is substituted into Colby formula.
3 sanitary insect pest effect experiment result of table
Embodiment 4: parasitic pests efficacy testing
Weight and the roughly the same piglet of physical condition are selected, while suffering from the trouble of pig mustard mite (haematopinus suis, pig flea) disease
Sick pig bull, each pharmacy test selects 100 affected pigs, and (such as 100 body growing ways of selection are consistent in doing hydroprene experiment
Affected pig), optionally select 20 be used as controlled observation onset states.Medicament is imposed on into disease sites and possible site of pathological change, when
Disease sites skin becomes ruddy, linen scab block purulence sample tubercle occurs in affected part and gradually subsides, also starts to grow at depilation
New hair, and clinical symptoms also disappear, and affected pig no longer recurs during observation, and restoring normal person is to cure.Conversely, then
Morbidity is serious, and pig mustard mite, haematopinus suis, the breeding of pig flea are more and more, and medicament is invalid.It is calculated and is cured according to the number for curing sick pig
Rate.Each pharmacy test in triplicate, after required time, counts cure rate, in terms of %.100% indicates to cure all trouble
Sick individual (killing all pests)；0% indicates that no diseased individuals are cured (no pest is killed).By identified cure rate generation
Enter Colby formula.
Claims (26)
1. a kind of Pesticidal combination, which is characterized in that including hydroprene and amide insecticides, wherein the amides desinsection
Agent is selected from one or more of Tolfenpyrad, ethiprole or butene-fipronil；The quality of the hydroprene and Tolfenpyrad
Than for 5.6:5.5~3:2；The hydroprene and the mass ratio of ethiprole are 3:5~3:1；The hydroprene and butene-fipronil
Mass ratio be 3:4.3~3:1.
2. Pesticidal combination as described in claim 1, which is characterized in that the Pesticidal combination further comprises oils group
Point.
3. Pesticidal combination as claimed in claim 2, which is characterized in that the oil component is vegetable oil, animal oil, mineral
Oil or essential oil；The mineral oil is selected from gasoline, diesel oil, paraffin or kerosene, and the vegetable oil is selected from peanut oil, soya-bean oil, flax
At least one of oil, castor oil, sunflower oil, sesame oil, tea-seed oil, coconut oil or rosin base oil, the animal oil are selected from pig
At least one of oil, butter, sheep oil.
4. Pesticidal combination as described in claim 1, which is characterized in that the Pesticidal combination further comprises alcohol.
5. Pesticidal combination as claimed in claim 4, which is characterized in that the alcohol is selected from ethylene glycol, glycerine, polyethylene glycol
200, at least one of polyethylene glycol 400, polyethylene glycol-800 or Macrogol 600.
6. Pesticidal combination as claimed in claim 4, which is characterized in that total matter of the hydroprene and amide insecticides
The mass ratio of amount and alkoxide component is 11.1:1.3~5:3.
7. a kind of insecticidal preparation, which is characterized in that including the Pesticidal combination and pesticide as described in one of claim 1-6
Acceptable auxiliary agent, the Pesticidal combination account for the 0.0001~99% of the quality of the pharmaceutical preparations.
8. insecticidal preparation as claimed in claim 7, which is characterized in that the Pesticidal combination account for the quality of the pharmaceutical preparations 0.01~
93%.
9. insecticidal preparation as claimed in claim 8, which is characterized in that the Pesticidal combination account for the quality of the pharmaceutical preparations 0.5~
70%.
10. insecticidal preparation as claimed in claim 7, which is characterized in that the auxiliary agent include wetting agent, dispersing agent, disintegrating agent,
Emulsifier, binder, stabilizer, defoaming agent, antifreezing agent, preservative, light stabilizer, antioxidant, solvent, encapsulating agent, warning
One or both of color, filler or film forming agent or more.
11. a kind of for preventing and treating parasitic, health, storage or the method for crop pests, which is characterized in that utilize claim 1-
Insecticidal preparation described in one of Pesticidal combination described in one of 6 or claim 7-10 is direct or applies after solvent dilutes,
Be sprayed, atomizing, dust, smear, fumigate, spread fertilizer over the fields, dress seed or irrigation method processing；
The parasitic pest is dust mite, flea or louse.
12. method as claimed in claim 11, which is characterized in that the crop pests are Lepidoptera, coleoptera or half wing
Mesh.
13. method as claimed in claim 11, which is characterized in that the sanitary insect pest is mosquito, fly or Groton bug.
14. method as claimed in claim 11, which is characterized in that the storage pest is curculionid class or grain peat.
15. method as claimed in claim 11, which is characterized in that when being used as crop pests prevention and treatment, effective dose is
0.01~100 milli gram/m.
16. method as claimed in claim 15, which is characterized in that when being used as crop pests prevention and treatment, effective dose 0.6
~100 millis gram/m.
17. the method described in claim 16, which is characterized in that when being used as crop pests prevention and treatment, effective dose 0.6
~30 millis gram/m.
18. method as claimed in claim 11, which is characterized in that be used as storage pest prevention and treatment when, effective dose be 0.1~
100 mg/kgs.
19. method as claimed in claim 18, which is characterized in that be used as storage pest prevention and treatment when, effective dose be 1~
100 mg/kgs.
20. method as claimed in claim 19, which is characterized in that when being used as storage pest prevention and treatment, effective dose is 1~60
Mg/kg.
21. method as claimed in claim 11, which is characterized in that when being used as health pest control, effective dose 0.001
~100 grams/cubic metre.
22. method as claimed in claim 21, which is characterized in that when being used as health pest control, effective dose 0.01
~100 grams/cubic metre.
23. method as claimed in claim 22, which is characterized in that when being used as health pest control, effective dose 0.01~
30 grams/cubic metre.
24. method as claimed in claim 11, which is characterized in that when for parasitic pest prevention and treatment, effective dose 0.01
~100 mg/kgs.
25. method as claimed in claim 24, which is characterized in that for parasitic pest prevention and treatment when, effective dose be 0.1~
100 mg/kgs.
26. method as claimed in claim 25, which is characterized in that when for parasitic pest prevention and treatment, effective dose 0.05
~60 mg/kgs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510880481.4A CN105494408B (en) | 2015-11-30 | 2015-11-30 | A kind of Efficient insecticidal composition and its application method containing hydroprene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510880481.4A CN105494408B (en) | 2015-11-30 | 2015-11-30 | A kind of Efficient insecticidal composition and its application method containing hydroprene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105494408A CN105494408A (en) | 2016-04-20 |
| CN105494408B true CN105494408B (en) | 2019-03-01 |
Family
ID=55703021
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510880481.4A Active CN105494408B (en) | 2015-11-30 | 2015-11-30 | A kind of Efficient insecticidal composition and its application method containing hydroprene |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105494408B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110495420B (en) * | 2019-08-01 | 2021-08-17 | 安佑生物科技集团股份有限公司 | Method for preventing and treating red mites of poultry |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101203135A (en) * | 2005-04-28 | 2008-06-18 | 拜尔农作物科学股份公司 | Combinations of pesticidal active substance combinations |
| CN103068235A (en) * | 2010-06-18 | 2013-04-24 | 拜耳知识产权有限责任公司 | Active substance combinations with insecticide and acaricide properties |
| CN104798798A (en) * | 2014-01-26 | 2015-07-29 | 沈阳化工研究院有限公司 | Binary composition and application thereof |
| CN104968201A (en) * | 2012-10-01 | 2015-10-07 | 巴斯夫欧洲公司 | Pesticidally active mixtures comprising anthranilamide compounds |
-
2015
- 2015-11-30 CN CN201510880481.4A patent/CN105494408B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101203135A (en) * | 2005-04-28 | 2008-06-18 | 拜尔农作物科学股份公司 | Combinations of pesticidal active substance combinations |
| CN103068235A (en) * | 2010-06-18 | 2013-04-24 | 拜耳知识产权有限责任公司 | Active substance combinations with insecticide and acaricide properties |
| CN104968201A (en) * | 2012-10-01 | 2015-10-07 | 巴斯夫欧洲公司 | Pesticidally active mixtures comprising anthranilamide compounds |
| CN104798798A (en) * | 2014-01-26 | 2015-07-29 | 沈阳化工研究院有限公司 | Binary composition and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105494408A (en) | 2016-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105379749B (en) | A kind of long-acting, less toxic, efficient Pesticidal combination | |
| CN105532714A (en) | Safe, environment-friendly and efficient insecticidal composition and use thereof | |
| CN102125044A (en) | Imidacloprid and cypermethrin synergic compound | |
| CN105145663A (en) | Botanical pesticide composition containing azadirachtin and eucalyptus oil | |
| CN105123699A (en) | Miticide and insecticide composite containing thymol and pyriproxyfen | |
| CN105284917B (en) | A kind of plant pesticide composition containing nimbin and caryophyllus oil | |
| CN103053569A (en) | Tolfenpyrad-containing insecticidal composition | |
| CN102187869A (en) | Composition containing avermectin and chlorfenapyer, and application thereof | |
| CN105494408B (en) | A kind of Efficient insecticidal composition and its application method containing hydroprene | |
| CN104106593A (en) | Insecticide acaricidal composition containing xiaochongthion and etoxazole | |
| CN104082300A (en) | Insecticide acaricide composition containing pyriproxyfen and spirodiclofen | |
| CN105494389B (en) | A kind of synergistic complex composition of two-element active component | |
| CN102210317B (en) | Insecticidal compounded composition containing chlorbenzuron | |
| CN102657216A (en) | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler | |
| CN103070186B (en) | Insecticidal composition containing thiamethoxam and application of insecticidal composition | |
| CN106561656B (en) | A kind of Pesticidal combination containing Celastrus angulatus and multiple killing teichomycin | |
| CN104522006B (en) | A kind of preventing and treating Lepidoptera and homoptera pest compositions | |
| CN104115850A (en) | Insect and mite killing composition containing etoxazole and spirotetramat | |
| CN102792972A (en) | Insecticide compound comprising guadipyr and metarrhizium anisopliae | |
| CN103404531A (en) | Biological compound insecticide containing toosedarin and imidacloprid and preparation method and application thereof | |
| CN105994275A (en) | Pesticide composition containing chromafenozide and biogenic sources | |
| CN103053600B (en) | Insecticidal composition of indoxacarb and efficient cyfluthrin | |
| CN104115833A (en) | Insect and mite killing composition containing pyriproxyfen and cyflumetofen | |
| CN101180961A (en) | Insecticide compounding with buprofezin and pymtrozine as well as method for preventing and controlling pest thereof | |
| CN106973949B (en) | A kind of Pesticidal combination and application thereof comprising bitter pueraria root extract and matrine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |