CN105482587B - A kind of environment-friendly aqueous nanostructured woodcare paint and preparation method thereof - Google Patents
A kind of environment-friendly aqueous nanostructured woodcare paint and preparation method thereof Download PDFInfo
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- CN105482587B CN105482587B CN201511008661.XA CN201511008661A CN105482587B CN 105482587 B CN105482587 B CN 105482587B CN 201511008661 A CN201511008661 A CN 201511008661A CN 105482587 B CN105482587 B CN 105482587B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, including following components：20 30 parts of self-crosslinking acrylic nanoemulsions, 20 35 parts of aqueous polyurethane resin emulsion, 37 parts of silver ion solution, nano-TiO225 parts of slurry, 13 parts of coalescents, 24 parts of emulsifying agent, 12 parts of dispersant, 0.5 1 parts of crosslinking agent, 1 1.5 parts of defoamer, 13 parts of other auxiliary agents, 20 30 parts of deionized water.The invention also discloses the preparation method of the woodcare paint.The woodcare paint has no irritating odor, nontoxic, non-environmental-pollution, non-ignitable, easy to use, and stability is good, and hardness is big, and stain resistant performance is good, and solid content is high, and prepares simply, and cost is low.
Description
Technical field：
The present invention relates to house ornamentation technical field of coatings, a kind of environment-friendly aqueous nanostructured woodenware is specifically related to
Paint.
Background technology：
Woodcare paint is seen everywhere in daily life, and it does not only have decoration effect, and timber is played well
Protective effect.But the woodcare paint used at present is mostly solvent-borne type, developed into from the phenolic paint, alkyd paint, nitrate paint of early stage
The polyurethane paint largely used at present, these woodcare paints all containing a large amount of poisonous organic volatile compounds, seriously endanger life
Production is healthy with workmen's, and pollution atmospheric environment.In recent years, the enhancing with environmental consciousness and the anxiety of the energy,
Aqueous woodware paint is increasingly by the concern and favor of people.
Water-based acrylic resin and waterborne polyurethane resin are compared with solvent based product, with safe, non-ignitable, nontoxic, no
The advantages of polluting environment, acrylic resin has the advantages that quick-drying, the good transparency, protects light colour retention, and adhesive force, light
Pool, hardness and weather resistance are also preferable, and it has the disadvantage that MFT is high, and film forming and pliability are poor.Water-fast solvent resistant
The poor, hot sticky cold crisp of property.The segmented structure that there is hard segment and soft chain segment to constitute in polyurethane molecular structure, determines that it was both hard
And flexible special performance, its two phase structure makes aqueous polyurethane have excellent film formation at low temp, levelability and pliability, resist
Hot after tack is good, due to the presence of hydrogen bond, makes it have wear-resisting, high rigidity, but stability, from thickening property, solid content, protect light
Shortcomings in terms of property.Therefore, there is certain complementarity in waterborne acrylic paint and waterborne polyurethane resin, utilize two
Person organically combines to improve the combination property of material, it has also become the important channel of new generation aqueous woodware paint.Due to nanometer
The excellent properties of material, can greatly improve the combination property of coating.
Chinese patent (03113622.2) discloses a kind of moisture and dissipates environmentally friendly nanostructured woodcare paint, and the paint is with breast
The moisture that micelle footpath is less than 100nm dissipates environmentally friendly (methyl) acroleic acid polyurethane, and moisture dissipates environmentally friendly drying oil and changed
Property (methyl) acroleic acid polyurethane nanometer polymer emulsion be base-material, be engaged with pigment, filler, drier and other auxiliary agents,
The process such as ground, scattered is processed.The nanostructured aqueous woodware paint is nontoxic, environmentally safe, to workmen's body
Body health is harmless, safe and convenient to use, and dried coating film is fast, high mechanical strength, and good decorative property, barrier propterty is excellent.But the painting
Expect that film solid content is low, stability is poor.
The content of the invention：
It is an object of the invention to provide a kind of environment-friendly aqueous nanostructured woodcare paint, it has no irritating odor, nothing
Malicious harmless, non-environmental-pollution, it is non-ignitable, it is easy to use, and stability is good, hardness is big, and stain resistant performance is good, and solid content is high.
It is a further object to provide the preparation method of the woodcare paint.
To achieve the above object, the present invention uses following technical scheme：
A kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, including following components：
20-30 parts of self-crosslinking acrylic nanoemulsions,
20-35 parts of aqueous polyurethane resin emulsion,
3-7 parts of silver ion solution,
Nano-TiO22-5 parts of slurry,
1-3 parts of coalescents,
2-4 parts of emulsifying agent,
1-2 parts of dispersant,
0.5-1 parts of crosslinking agent,
1-1.5 parts of defoamer,
1-3 parts of other auxiliary agents,
20-30 parts of deionized water.
As the preferred of above-mentioned technical proposal, a kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, bag
Include following components：
30 parts of self-crosslinking acrylic nanoemulsions,
22 parts of aqueous polyurethane resin emulsion,
3.5 parts of silver ion solution,
Nano-TiO24 parts of slurry,
2 parts of coalescents,
3 parts of emulsifying agent,
2 parts of dispersant,
0.7 part of crosslinking agent,
1 part of defoamer,
1.5 parts of other auxiliary agents,
25 parts of deionized water.
As the preferred of above-mentioned technical proposal, the Tg of the self-crosslinking acrylic nanoemulsions is 40-50 DEG C.
As the preferred of above-mentioned technical proposal, the aqueous polyurethane resin emulsion is by tung oil-modified polyurethane resin breast
Change is obtained.
As the preferred of above-mentioned technical proposal, the silver ion is that quaternary ammonium silver chlorate, quaternary ammonium silver sulfate, quaternary ammonium silver nitrate are molten
One kind in liquid.
As the preferred of above-mentioned technical proposal, the nano-TiO2The preparation method of slurry is：By nano-TiO2And deionization
Water is mixed evenly, and adds surfactant, and ultrasonic 20-50min is produced.
As the preferred of above-mentioned technical proposal, the surface dispersant is APES, octyl phenol polyoxy second
One or more mixing in alkene ether, polyacrylamide, polyvinyl alcohol.
As the preferred of above-mentioned technical proposal, the nano-TiO2, deionized water, surfactant mass ratio be 5-
10:15:1。
A kind of preparation method of environment-friendly aqueous nanostructured woodcare paint, comprises the following steps：
(1) self-crosslinking acrylic nanoemulsions, aqueous polyurethane resin emulsion and deionized water are mixed evenly, plus
Enter crosslinking agent, dispersant and nano-TiO2Slurry, is warming up to 70-80 DEG C, reacts 2-3h, is cooled to room temperature, obtains mixed liquor；
(2) in the mixed liquor obtained to step (1), add silver ion solution, emulsifying agent, coalescents, defoamer, other
Auxiliary agent, is mixed evenly rear grinder grinding, obtains environment-friendly aqueous nanostructured woodcare paint.
As the preferred of above-mentioned technical proposal, in step (1), the temperature of the reaction is 80 DEG C, the time of the reaction
For 2.5h.
The invention has the advantages that：
The present invention adds nano-TiO in acrylate/nano emulsion and tung oil-modified ester-polyurethane resin emulsion2Slurry, and
In the presence of crosslinking agent and dispersant, crosslinked in certain temperature so that stably dispersing of the nano pulp in emulsion, from
Prepared by woodcare paint excellent performance；
The present invention adds silver ion solution in woodcare paint, and it is good with emulsion compatibility, prepares obtained woodcare paint
With certain anti-microbial property；
Woodcare paint prepared by the present invention has no irritating odor, nontoxic, non-environmental-pollution, non-ignitable, easy to use, and surely
Qualitative good, hardness is big, and stain resistant performance is good, and solid content is high.
Embodiment：
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solution
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, including following components：
20 parts of self-crosslinking acrylic nanoemulsions,
20 parts of aqueous polyurethane resin emulsion,
3 parts of silver ion solution, nano-TiO22 parts of slurry,
1 part of coalescents, 2 parts of emulsifying agent,
1 part of dispersant, 0.5 part of crosslinking agent,
1 part of defoamer, 1 part of other auxiliary agents,
20 parts of deionized water.
Its preparation method comprises the following steps：
(1) self-crosslinking acrylic nanoemulsions, aqueous polyurethane resin emulsion and deionized water are mixed evenly, plus
Enter crosslinking agent, dispersant and nano-TiO2Slurry, is warming up to 70-80 DEG C, reacts 2h, is cooled to room temperature, obtains mixed liquor；
(2) in the mixed liquor obtained to step (1), add silver ion solution, emulsifying agent, coalescents, defoamer, other
Auxiliary agent, is mixed evenly rear grinder grinding, obtains environment-friendly aqueous nanostructured woodcare paint.
Embodiment 2
A kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, including following components：
30 parts of self-crosslinking acrylic nanoemulsions,
35 parts of aqueous polyurethane resin emulsion,
7 parts of silver ion solution, nano-TiO25 parts of slurry,
3 parts of coalescents, 4 parts of emulsifying agent,
2 parts of dispersant, 1 part of crosslinking agent,
1.5 parts of defoamer, 3 parts of other auxiliary agents,
30 parts of deionized water.
Its preparation method comprises the following steps：
(1) self-crosslinking acrylic nanoemulsions, aqueous polyurethane resin emulsion and deionized water are mixed evenly, plus
Enter crosslinking agent, dispersant and nano-TiO2Slurry, is warming up to 70-80 DEG C, reacts 3h, is cooled to room temperature, obtains mixed liquor；
(2) in the mixed liquor obtained to step (1), add silver ion solution, emulsifying agent, coalescents, defoamer, other
Auxiliary agent, is mixed evenly rear grinder grinding, obtains environment-friendly aqueous nanostructured woodcare paint.
Embodiment 3
A kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, including following components：
30 parts of self-crosslinking acrylic nanoemulsions,
22 parts of aqueous polyurethane resin emulsion,
3.5 parts of silver ion solution, nano-TiO24 parts of slurry,
2 parts of coalescents, 3 parts of emulsifying agent,
2 parts of dispersant, 0.7 part of crosslinking agent,
1 part of defoamer, 1.5 parts of other auxiliary agents,
25 parts of deionized water.
Its preparation method comprises the following steps：
(1) self-crosslinking acrylic nanoemulsions, aqueous polyurethane resin emulsion and deionized water are mixed evenly, plus
Enter crosslinking agent, dispersant and nano-TiO2Slurry, is warming up to 70-80 DEG C, reacts 2.2h, is cooled to room temperature, obtains mixed liquor；
(2) in the mixed liquor obtained to step (1), add silver ion solution, emulsifying agent, coalescents, defoamer, other
Auxiliary agent, is mixed evenly rear grinder grinding, obtains environment-friendly aqueous nanostructured woodcare paint.
Embodiment 4
A kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, including following components：
24 parts of self-crosslinking acrylic nanoemulsions,
24 parts of aqueous polyurethane resin emulsion,
4 parts of silver ion solution, nano-TiO23 parts of slurry,
1.5 parts of coalescents, 2.5 parts of emulsifying agent,
1.2 parts of dispersant, 0.6 part of crosslinking agent,
1.1 parts of defoamer, 1.5 parts of other auxiliary agents,
22 parts of deionized water.
Its preparation method comprises the following steps：
(1) self-crosslinking acrylic nanoemulsions, aqueous polyurethane resin emulsion and deionized water are mixed evenly, plus
Enter crosslinking agent, dispersant and nano-TiO2Slurry, is warming up to 70-80 DEG C, reacts 2.4h, is cooled to room temperature, obtains mixed liquor；
(2) in the mixed liquor obtained to step (1), add silver ion solution, emulsifying agent, coalescents, defoamer, other
Auxiliary agent, is mixed evenly rear grinder grinding, obtains environment-friendly aqueous nanostructured woodcare paint.
Embodiment 5
A kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, including following components：
26 parts of self-crosslinking acrylic nanoemulsions,
28 parts of aqueous polyurethane resin emulsion,
5 parts of silver ion solution, nano-TiO23.5 parts of slurry,
2 parts of coalescents, 3 parts of emulsifying agent,
1.4 parts of dispersant, 0.7 part of crosslinking agent,
1.2 parts of defoamer, 2 parts of other auxiliary agents,
24 parts of deionized water.
Its preparation method comprises the following steps：
(1) self-crosslinking acrylic nanoemulsions, aqueous polyurethane resin emulsion and deionized water are mixed evenly, plus
Enter crosslinking agent, dispersant and nano-TiO2Slurry, is warming up to 70-80 DEG C, reacts 2.6h, is cooled to room temperature, obtains mixed liquor；
(2) in the mixed liquor obtained to step (1), add silver ion solution, emulsifying agent, coalescents, defoamer, other
Auxiliary agent, is mixed evenly rear grinder grinding, obtains environment-friendly aqueous nanostructured woodcare paint.
Embodiment 6
A kind of environment-friendly aqueous nanostructured woodcare paint, in parts by weight, including following components：
28 parts of self-crosslinking acrylic nanoemulsions,
32 parts of aqueous polyurethane resin emulsion,
6 parts of silver ion solution, nano-TiO24.5 parts of slurry,
2.5 parts of coalescents, 3.5 parts of emulsifying agent,
1.6 parts of dispersant, 0.8 part of crosslinking agent,
1.4 parts of defoamer, 2.5 parts of other auxiliary agents,
28 parts of deionized water.
Its preparation method comprises the following steps：
(1) self-crosslinking acrylic nanoemulsions, aqueous polyurethane resin emulsion and deionized water are mixed evenly, plus
Enter crosslinking agent, dispersant and nano-TiO2Slurry, is warming up to 70-80 DEG C, reacts 2.8h, is cooled to room temperature, obtains mixed liquor；
(2) in the mixed liquor obtained to step (1), add silver ion solution, emulsifying agent, coalescents, defoamer, other
Auxiliary agent, is mixed evenly rear grinder grinding, obtains environment-friendly aqueous nanostructured woodcare paint.
Performance test is carried out to woodcare paint prepared by the present invention below.
Aqueous woodware paint is sampled by GB3186 regulations, then by national standard《Paint film is typically prepared method (GB-T1727-
1992)》Operating method, prepares paint film test specimen.It is coated, is pressed by film thickness regulation requirement using paint film spreader (80 μm)
45% is solid containing calculating, and theoretical thickness of dry film is 36 μm.The paint film of preparation is placed in it is dried for a week under conditions of constant temperature and humidity lucifuge,
It is positioned over shady and cool, dry storage.
(1) antibacterial tests
For nanometer waterborne woodware paint paint film antibiotic property according to Nippon Standard《Antibacterial fabricated product-antibacterial activity test side
Method antibacterial effect (JISZ2801:2000)》To detect, this standard is that hand over the antibacterial antibacterial effect of product surface is evaluated
's.Two kinds of bacterium of gram yin, yang are used respectively：Staphylococcus aureus and Escherichia coli are detected, than being more comprehensively demonstrated by
The anti-microbial property of body surface.Antibacterial tests the results are shown in Table 1：
Table 1
From the point of view of table 1, woodcare paint produced by the present invention has obvious surface bacteriostasis.
(2) film adhesive
The adhesive force of film is tested with cross-hatching, is specifically in level by test plate (panel) film square by GB/T9286 regulation
Platform on, draw lattice guarded blade utility knife in film coated surface respectively to mark laterally and vertically the square net of one group of fine uniform, see
Film damaged condition is examined, is as a result represented with 0-5 grades, 0 grade represents that adhesive force is best.Test result is as shown in table 2：
Table 2
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | |
| Adhesive force | 0 grade | 0 grade | 0 grade | 0 grade | 0 grade | 0 grade |
From table 1, woodcare paint adhesion performance produced by the present invention is good.
Claims (6)
1. a kind of environment-friendly aqueous nanostructured woodcare paint, it is characterised in that in parts by weight, including following components：
20-30 parts of self-crosslinking acrylic nanoemulsions,
20-35 parts of aqueous polyurethane resin emulsion,
3-7 parts of silver ion solution,
Nano-TiO22-5 parts of slurry,
1-3 parts of coalescents,
2-4 parts of emulsifying agent,
1-2 parts of dispersant,
0.5-1 parts of crosslinking agent,
1-1.5 parts of defoamer,
1-3 parts of other auxiliary agents,
20-30 parts of deionized water；
Wherein, the nano-TiO2The preparation method of slurry is：By nano-TiO2It is mixed evenly with deionized water, adds table
Face activating agent, ultrasonic 20-50min is produced；Nano-TiO2, deionized water, surfactant mass ratio be 5-10:15:1；Institute
It is one or more mixing in APES, polyacrylamide, polyvinyl alcohol to state surfactant；
The preparation method of the woodcare paint comprises the following steps：
(1) self-crosslinking acrylic nanoemulsions, aqueous polyurethane resin emulsion and deionized water are mixed evenly, add and hand over
Join agent, dispersant and nano-TiO2Slurry, is warming up to 70-80 DEG C, reacts 2-3h, is cooled to room temperature, obtains mixed liquor；
(2) in the mixed liquor obtained to step (1), silver ion solution, emulsifying agent are added, coalescents, defoamer, other help
Agent, is mixed evenly rear grinder grinding, obtains environment-friendly aqueous nanostructured woodcare paint.
2. a kind of environment-friendly aqueous nanostructured woodcare paint as claimed in claim 1, it is characterised in that with parts by weight
Meter, including following components：
30 parts of self-crosslinking acrylic nanoemulsions,
22 parts of aqueous polyurethane resin emulsion,
3.5 parts of silver ion solution,
Nano-TiO24 parts of slurry,
2 parts of coalescents,
3 parts of emulsifying agent,
2 parts of dispersant,
0.7 part of crosslinking agent,
1 part of defoamer,
1.5 parts of other auxiliary agents,
25 parts of deionized water.
3. a kind of environment-friendly aqueous nanostructured woodcare paint as claimed in claim 1, it is characterised in that the self-crosslinking
The Tg of acrylate/nano emulsion is 40-50 DEG C.
4. a kind of environment-friendly aqueous nanostructured woodcare paint as claimed in claim 1, it is characterised in that described aqueous poly-
Urethane resin emulsion is obtained by the emulsification of tung oil-modified polyurethane resin.
5. a kind of environment-friendly aqueous nanostructured woodcare paint as claimed in claim 1, it is characterised in that the silver ion
For one kind in quaternary ammonium silver chlorate, quaternary ammonium silver sulfate, quaternary ammonium silver nitrate solution.
6. a kind of environment-friendly aqueous nanostructured woodcare paint as claimed in claim 1, it is characterised in that in step (1),
The temperature of the reaction is 80 DEG C, and the time of the reaction is 2.5h.
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| CN108285702A (en) * | 2016-12-02 | 2018-07-17 | 青岛瑞利特新材料科技有限公司 | Anti- formaldehyde aqueous woodware paint |
| CN106833204A (en) * | 2017-02-21 | 2017-06-13 | 程艳青 | A kind of indoor formaldehyde-removing antibiotic environmental protection sealing wax and preparation method thereof |
| CN107841222A (en) * | 2017-11-21 | 2018-03-27 | 广东华兹卜新材料科技有限公司 | A kind of self-crosslinking aqueous wood lacquer emulsion and its synthetic method |
| CN110305509A (en) * | 2019-07-12 | 2019-10-08 | 武汉同发科技有限公司 | A kind of water-based paint and preparation method thereof |
| CN112409872A (en) * | 2020-12-03 | 2021-02-26 | 鲁嘉涂料（福建）有限公司 | Environment-friendly water-based wood paint and preparation method thereof |
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| CN102051096A (en) * | 2009-11-05 | 2011-05-11 | 紫荆花制漆(上海)有限公司 | Environmentally-friendly high-performance water-based woodware paint and using method thereof |
| CN103881500A (en) * | 2014-03-27 | 2014-06-25 | 中华制漆（深圳）有限公司 | High-weather-resistance high-stain-resistance white paint for outdoor woodware and preparation method of paint |
| CN104098961A (en) * | 2013-04-12 | 2014-10-15 | 四川远见实业有限公司 | Self-crosslinking aqueous woodenware primer |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051096A (en) * | 2009-11-05 | 2011-05-11 | 紫荆花制漆(上海)有限公司 | Environmentally-friendly high-performance water-based woodware paint and using method thereof |
| CN104098961A (en) * | 2013-04-12 | 2014-10-15 | 四川远见实业有限公司 | Self-crosslinking aqueous woodenware primer |
| CN103881500A (en) * | 2014-03-27 | 2014-06-25 | 中华制漆（深圳）有限公司 | High-weather-resistance high-stain-resistance white paint for outdoor woodware and preparation method of paint |
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