CN105432656B - A kind of Pesticidal combination - Google Patents
A kind of Pesticidal combination Download PDFInfo
- Publication number
- CN105432656B CN105432656B CN201410481941.1A CN201410481941A CN105432656B CN 105432656 B CN105432656 B CN 105432656B CN 201410481941 A CN201410481941 A CN 201410481941A CN 105432656 B CN105432656 B CN 105432656B
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- Prior art keywords
- reactive compound
- pesticidal combination
- chlorine fluorine
- insect amide
- cyanogen insect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of Pesticidal combination, and containing reactive compound I and reactive compound II, reactive compound I is chlorine fluorine cyanogen insect amide, and reactive compound II is phenthoate dimephenthoate cidial, and reactive compound I and reactive compound II weight ratio is 100:1‑1:100.The present invention has reached synergistic effect by the way that reactive compound I and reactive compound II are carried out into binary built on pest control, and reduces the dosage of two active ingredients, combines quick-acting and lasting effect, has delayed the generation of resistance, has expanded preventing and treating spectrum.
Description
Technical field
The present invention relates to agriculture field, and in particular to a kind of Pesticidal combination.
Background technology
It is in the urgent demand that field of pest control occurs：Need to provide a kind of Pesticidal combination, it is being reduced
The rate of application of active component and reduction avoid remaining to provide effective insect while unfavorable environment or toxicological effects
Preventing and treating；And the Pesticidal combination also needs to combine the snap action and long-acting to insect.
It is to repeat using another difficulty of insecticide and uniquely uses single Pesticidal compound in many cases
Cause to produce the reactive compound quick selection that is natural or adapting to drug-fast insect.It is therefore desirable to have help overcome
Drug-fast Pesticidal combination.
It is an object of the invention to provide a kind of Pesticidal combination, and it solve at least a kind of above-mentioned problem：Such as reduce administration
Rate, improve activity profile, with reference to quick-acting and lasting effect, delaying drug resistance.
Chlorine fluorine cyanogen insect amide (ZJ4042, Cas.NO：1262605-53-7) be Zhejiang Provincial Chemical Engineering Research Inst develop adjacent benzene
Diformamide insecticides, it is the unique novel pesticide of a kind of efficient, low toxicity and mechanism of action, it acts on insect ryania
Acceptor, promote the endogenous calcium ion release of insect cell, influence contraction of muscle, and then cause insect death；To Lepidoptera, elytrum
Mesh, Diptera and the larva of Homoptera have very high activity, but main effect model has certain interior suction based on stomach toxicity
Property, the primary pest available for rice, vegetables, fruit tree, cotton prevents and treats.Chlorine fluorine cyanogen insect amide has the characteristics of lasting effect is long, but
It is that also there is the defects of quick-acting is poor.
Phenthoate dimephenthoate cidial（Phenthoate）, chemical name：The S of 0,0- dimethyl one (the ethoxy carbonyl benzyls of α mono-）Two thio phosphorus
Acid esters.Phenthoate dimephenthoate cidial is a kind of efficient, broad spectrum organic phosphorus Insecticidal and acaricidal agent；Its mechanism of action is to suppress the acetyl courage in insect bodies
Alkali esterase.Phenthoate dimephenthoate cidial is a kind of low toxicity, based on tagging, have certain stomach poison function, quick-acting preferably, can prevent and treat chewing type,
The medicament of sucking pest.Fruit tree, vegetables, the various pests on rice can be prevented and treated, particularly prevent and treat two changes on rice
Snout moth's larva, yellow rice borer, rice leaf roller, leafhopper, aphid, scotellaris, locust and other effects are fine.
The content of the invention
The present invention seeks to provide a kind of Pesticidal combination for above-mentioned weak point.
The present inventor have passed through long-term research, and is found surprisingly that on the basis of many experiments, by reactive compound I
After being compounded with reactive compound II, synergistic function is generated, reactive compound I is chlorine fluorine cyanogen insect amide, reactive compound
II is phenthoate dimephenthoate cidial.
The present invention is it has unexpectedly been discovered that chlorine fluorine cyanogen insect amide and phenthoate dimephenthoate cidial combination can effectively be prevented or control harmful life
Thing.It is surprising that the activity of the combination control harmful organism of reactive compound of the present invention is much higher than single activation
Compound activity of the combination.The unexpected effect is really to act synergistically, rather than just addition.
A kind of Pesticidal combination, it is chlorine fluorine containing reactive compound I and reactive compound II, the reactive compound I
Cyanogen insect amide, reactive compound II is phenthoate dimephenthoate cidial, and the reactive compound I and reactive compound II weight ratio is 100:
1-1:100。
A kind of Pesticidal combination, reactive compound I and reactive compound II weight ratio is 50:1-1:50.
A kind of Pesticidal combination, reactive compound I and reactive compound II weight ratio is 20:1-1:20.
A kind of Pesticidal combination, reactive compound I and reactive compound II weight ratio is 10:1-1:10.
A kind of Pesticidal combination, reactive compound I and reactive compound II weight ratio is 5:1-1:5.
A kind of Pesticidal combination, include reactive compound I and reactive compound II, the reactive compound I and activity
Compound II accounts for the 5%-90% of the composition by weight altogether.
A kind of Pesticidal combination, include reactive compound I and reactive compound II, the reactive compound I and activity
Compound II accounts for the 10%-80% of the composition by weight altogether.
A kind of Pesticidal combination, include reactive compound I and reactive compound II, the reactive compound I and activity
Compound II accounts for the 20%-60% of the composition by weight altogether.
A kind of Pesticidal combination, also comprising surfactant and/or extender.
The Pesticidal combination of the present invention, formulation is missible oil, suspending agent, seed coat agent, water dispersible granules, wettable powder, outstanding
Emulsion, smoke agent, aqueous emulsion, ultra low volume liquids.
The Pesticidal combination of the present invention, also comprising one or more other active components.
On the other hand, the purposes for preventing or controlling harmful organism is used for present invention also offers a kind of Pesticidal combination, its
Middle harmful organism is Insecta, Arachnoidea.
Preferably, the Pesticidal combination is used for the purposes for preventing and treating Lepidoptera and homoptera pest.
It is furthermore preferred that the Pesticidal combination is used to prevent and treat diamondback moth, cabbage caterpillar, beet armyworm, lopper worm, cigarette bud night
Moth, black peach aphid, cotten aphid, apple aphid, grain aphid, brown back rice plant hopper, small brown rice planthopper, Bemisia tabaci, Trialeurodes vaporariorum Westwood, leafhopper, rice green leafhopper, rice
The purposes of leaf-roller, bollworm, striped rice borer, yellow rice borer etc..
On the other hand, present invention also offers a kind of method prevented or control harmful organism, by the desinsection group of the present invention
Compound acts on target useful plant, object noxious livings or its environment, the propagating materials of target useful plant；The plant is numerous
It is seedling, rhizome, garden seedling, cutting or seed to grow material.
A kind of cover crop including makes crop and I containing reactive compound and activation to prevent the method for pest infestation
Compound II Pesticidal combination contact.
A kind of method prevented or control harmful organism, including separate, sequentially or simultaneously apply reactive compound I, activity
Compound II.
The present invention by by reactive compound I and reactive compound II combination, on the one hand combine lasting effect with it is quick-acting
Property；On the other hand, there is provided a kind of synergistic effect significantly I containing reactive compound and reactive compound II pharmaceutical agent combinations, can be bright
The aobvious dosage for reducing by two active ingredients.
Embodiment
Present invention discover that：Reactive compound I and reactive compound II combinations can not only be brought into adding for insecticidal spectrum
Improved with property, but also realize amazing synergy.
The insecticidal effect that term " synergy " used herein refers to active compound of the present invention is more than each activity
Compound effect sum, in other words, its effect is superadditivity.
The invention provides a kind of Pesticidal combination, is active component comprising reactive compound I and reactive compound II,
Reactive compound I is chlorine fluorine cyanogen insect amide, and reactive compound II is phenthoate dimephenthoate cidial.
The invention provides a kind of Pesticidal combination, includes reactive compound I and reactive compound II, the activation
Compound I and reactive compound II weight ratio are 100:1 to 1:100, preferably 50:1 to 1:50, preferably 20:1 to 1:20, it is more excellent
Choosing or 10:1 to 1:10, further preferably 5:1 to 1:Acted synergistically when 5.
The present invention solves by the way that the good chlorine fluorine cyanogen insect amide of the lasting effect reactive compound II good with quick-acting is combined
The problem of lasting effect and quick-acting.On the other hand, there is provided a kind of obvious containing chlorine fluorine cyanogen insect amide of synergistic effect and activation
Compound II pharmaceutical agent combinations, the dosage of two compositions can be reduced.
The Pesticidal combination of the present invention, has good plant compatibility and favourable homeothermal animal toxicity, suitable for preventing and treating
The harmful organism run into agricultural, forestry, Stored Product and material and health field, especially Insecta and Arachnoidea.
The Pesticidal combination of the present invention is active for generally sensitive and resistance species, and for all or single stage of development
It is respectively provided with activity.
Term " harmful organism " used herein means any organism that can be caused damage to the normal condition of plant：
Lepidoptera pest is included for example：Striped rice borer（chilosuppressalis）, yellow rice borer
（Tryporyzaincertulas）, rice leaf roller（cnaphalocrocismedinalisGuenee）, cabbage heart snout moth's larva
（hellullaundalis）, dichocrocis punctiferalis（conogethespunctiferlis）, papilio xuthus Linnaeus（papilioxuthus）, white powder
Butterfly（pierisrapaecrucivora）, straight burr rice hesperiidae（parnaraguttata）, tent caterpillar（malacosoma
Neustria testacea）, gypsymoth（lymantriadispar）, fall webworms（hyphantriacunea）, east poison moth
（euproctissubflava）, black line slug moth（scopelodescontracus）, bollworm
（helicoverpaarmigera）, Pectinophora gossypiella（Pink bollworm）, cabbage looper（trichoplusiani）, wild cabbage night
Moth（mamestrabrassicae）, beet armyworm（spodopteraexigua）, prodenia litura（spodopteralitura）、
Tea olethreutid（adoxophyesoranafasciata）, leaf roller（adoxophyeshonmai）, apricot yellow volume moth
（archipsfuscocureanus）, Homonamagnanima（homonamagnanima）, diamondback moth（plutellaxylotella）, cotton
Pink bollworm（pectinophoragossypiella）.
Coleopteran pest is included for example：Rice weevil（sitophilusoryzaelinne）, citrus leaf mining first
（Podagricomela nigricollis Che）, sitophilus zea-mais（S.zeamails）, grain weevil（S.granarius）, big daikon leaf beetle
（Cabbageleafbeetle）, daicon leaf beetle（Daikon leaf beele）, flea beetle（fleabeetle）, grape flea beetle
（Alticachalybea）, cabbage flea beetle（phyllotretastriolata）, cucumber flea beetle（Epitrixcucumeris）, cigarette
Careless flea beetle（Ehirtipennis）, eggplant flea beetle（E.fuscula）, aulacophora femoralis（Aulacophoraindica（Gemlin）, leaf mustard
It is chrysomelid（Phaedon cochleariae）Deng.
Diptera pest is included for example：Rice leafminer（agromyzaoryzae）, hydrellia griseola
（hydrelliagriseola）, African Chrysanthemum liriomyza bryoniae（liriomyzatrifolii）, pea leaf dive fly
（chromatomyiahorticola）, Liriomyza brponiae（liriomyzabryoniae）, delia platura（deliaplatura）、
Green onion ground Hylemyia Platura Meigen（deliaantiqua）Mediterranean fruitfly（ceratitiscapiatawiedgman）, Rhagoletis pomonella
（Rhagoletispomonella）, cherry fruit fly（R.cingulata）.
Hemipteran pest is included for example：Smelly stinkbug（megacoptapunctatissimum）, cabbage bug
（eurydemarugosum）, big thorn white star stinkbug（eysarcorislewisi）, white star stinkbug（eysarcorisparvus）, rice it is green
Stinkbug（nezaraviridula）, Si Shi amber stinkbugs（plautiastali）, clerodendron trichotomum stinkbug（halymorphamista）, rice spiny coreid
（cletuspunctiger）, Chinese Leptocorisa spp（leptocorisachinensis）, azelea lace bug
（stephantispyrioides）, it is red must fleahopper（trigonotyluscoelestialium）.
Homoptera pest includes such as rice green leafhopper（nephotettixcincticeps）, small brown rice planthopper
（laodelphaxstriatellus）, brown plant-hopper（nilaparvatalugens）, white backed planthopper
（sogatellafurcifera）, pear sucker（psyllapyrisuga）, diaphorina citri（diaphorinatabaci）, Bemisia tabaci
（bemisiatabaci）, aphid（homoptera）, apple aphid（eriosomalanigerum）.
Hymenoptera（hymenoptera）In have, yellow-winged cabbage sawfly（athaliarosaeruficornis）, rose sawfly
（argepagana）, Black Hills ant（formica japonica）, chestnut gall wasp（dryocsmuskuriphilus）Deng.
Thysanoptera, such as thrips（HaplothripsChinensisPriesner）.
Arachnoidea（Arachnida）Insect.Such as panonychus citri（panonychus citri）, Tetranychus cinnabarinus
（Tetranychus cinnabarinus）, panonychus ulmi（panonychus ulmi）, T.urticae Koch（tetranychus
urticae）, tetranychus viennensis（tetranychus viennensis）, oligonychus ununguis（oligonychus ununguis）Mandarin orange
Tangerine beginning tetranychid（eotetranychus kankitus）, purplish red short hairs mite（brevipalpus phoenicis）, Bryobia praetiosa
（bryobiapraetiosa）, wheat leaf roll mite（aceria tulipae）, grape erineum mite (Eriophyes vitis)（colomerus vitis）, tealeaves
Goitre mite（calacarus carinatus）, yellow tea mite（polyphagotarsonemus latus）, long hair root mite
（rhizoglyphus rostochiensis）Deng.
Anoplura (Anoplura, Phthiraptera), such as Damalinia (Damalinia spp.), Haematopinus
(Haematopinus spp.), Linognathus (Linognathus spp.), Pediculus (Pediculus spp.), Trichodectes
(Trichodectes spp. )。
Isopoda（Isopoda）, for example, Cape jasmine beach louse（Oniscus asellus）, pillworm（Armadilliudium
vulgare）, ball pillworm（Porcellio scaber）.
Sufficient mesh (Diplopoda) again, for example, Blaniulus guttulatus.
Lip foot mesh (Chi lopoda), for example, ground Scolopendra (Geophilus carpophagusScutigera
spp.) 。
Comprehensive mesh (Symphyla), for example, kahikatea worm (Scutigerella immaculata).
Thysanoptera (Thysanura), for example, silverfish (Lepisma saccharina).
Collembola (Collembola), for example, arms Onychiurus arcticus (Onychiurus armatus).
Orthoptera (Orthoptera), for example, family Xi (Acheta domesticus), mqb category category kind
(Gryllotalpa spp.), Asiatic migratory locust (Locusta migratoriamigrator ioides), black locust category kind (
Melanopluss pp.), desert locust (Schistocercagregaria).
Blattaria (Blattaria), for example, oriental cockroach (Blattaorientalis), American cockroach
(Periplaneta americana), leucophaea maderae (Leucophaea maderae), Groton bug (Blattella
germanica) 。
Dermaptera (Dermaptera), for example, European earwig (Forficula auricularia).
Isoptera (lsoptera), for example, Reticulitermes kind (Reticulitermes spp.).
Nematoda（(Nematoda)）Representative biology have and form nematode, stem eelworm and leaf selected from root-knot nematode, cyst
The nematode of nematode.It is preferred that the soybean cyst nematode Heterodera glycines of following nematode（Heterodera）, globodera rostochiensis（golbodera
rostochiensis）, Meloidogyne incognita（meloidogyne incognita）Deng, lance line mesh（dorylaimida）In have,
Minute hand Turbatrix（longidorus sp.）Deng.
The Pesticidal combination of the present invention has prominent effect, particularly pickles for preventing and treating Lepidoptera and homoptera pest
Moth, cabbage caterpillar, beet armyworm, lopper worm, tobacco budworm, prodenia litura, black peach aphid, cotten aphid, apple aphid, grain aphid, brown rice
Lice, small brown rice planthopper, Bemisia tabaci, Trialeurodes vaporariorum Westwood, leafhopper, rice green leafhopper, rice leaf roller, bollworm, striped rice borer, yellow rice borer etc..
The Pesticidal combination of the present invention can change into general configuration agent, such as missible oil, suspending agent, seed coat agent, water-dispersible grain
Agent, wettable powder, suspension emulsion, microcapsules, smoke agent, aqueous emulsion, ultra low volume liquids.Type of service depends on specific mesh
's；Every kind of preparaton should ensure that being evenly distributed for the compounds of this invention.
Preparaton in a known way, by by active component with suitable for agrochemical formulation filler and/or table
Face activating agent is mixed and prepared.
According to the present invention, term " filler ", which refers to, can be combined with active component or combines to make it easier for being administered to pair
As（Such as plant, crop or careless class）Natural or synthetic organic or inorganic compound.Therefore, the filler is preferably lazy
Property, it is acceptable at least to should be agricultural.The filler can be solid or liquid.
Filler can be used to be solid or be liquid in the present invention, solid-filling agent can be used as to make
Have for example：Phyteral powdery type（Such as soy meal, starch, grain dust, wood powder, bark powder, sawdust, walnut shell powder, bran
Skin, cellulose powder, coconut husk, the particle of corncob and tobacco stem, extract residue after plant essence etc.）, paper, clay
Class（Such as kaolin, bentonite, acid china clay etc.）, talcum powder class, silica（Such as diatomite, silica sand, mica, aqueous silicic acid,
Calcium silicates）, activated carbon, natural mineral matter class（Float stone, attapulgite and zeolite etc.）, fire diatomite, sand, plastics medium etc.
（Such as polyethylene, polypropylene）, potassium chloride, calcium carbonate, the inorganic mineral powder of calcium phosphate etc., ammonium sulfate, ammonium phosphate, urine
Chemical fertilizer, the clay fertilizer of element, ammonium chloride etc., these materials can be used alone or two or more is mixed.
It can be selected as liquid media materials'use in llowing group of materials, for example, water, alcohol type（Such as first
Alcohol, ethanol, isopropanol, butanol, ethylene glycol etc.）, ketone（Such as acetone, methyl ethyl ketone, isobutyrone, cyclohexanone
Deng）, ethers（Such as ether, dioxanes, methylcellulose, tetrahydrofuran etc.）, aliphatic hydrocarbon class（Such as kerosene,
Mineral oil etc.）, aromatic hydrocarbons class（Such as benzene,toluene,xylene, solvent naphtha, alkylnaphthalene, chlorinated aromatic hydrocarbons, chloro fat
Fat hydrocarbon, chlorobenzene etc.）, halogenated hydrocarbon class, amide-type, sulfone class, mineral oil, vegetable oil, animal oil etc..
To make active component emulsification, scattered and/or wetting, the surfactant that can be used for example can be fat
Fat alcohol APEO, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, the phosphoric acid of polyoxyethylene alcohol or phenol
Ester, the fatty acid ester of polyalcohol, alkylaryl sulfonates, lignosulfonates, branch shape copolymer, the dibutyl naphthalene of macromolecule comb shape
Sulfonate, alkylaryl sulfonates, sodium alkylsulfosuccinates.
To make effective active composition dispersion stability, such as xanthans, aluminium-magnesium silicate, gelatin, starch, cellulose can be used
Methyl ether, polyvinyl alcohol, polyvinyl acetate and natural phospholipid（Such as cephalin and lecithin）It is and synthetic phospholipid, bentonite, wooden
The adjuvants such as plain sodium sulfonate.
The optional spent glycol of antifreezing agent, propane diols, glycerine, sorbierite.
Deflocculant as suspension product can use the auxiliary such as naphthalene sulfonic acid polymer, polymeric phosphate
Agent.
Organic silicon defoamer can be used as defoamer.
Optionally, can also include other annexing ingredients, for example, protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent,
Stabilizer, screening agent.
Preparaton generally comprises 5%-90%, preferably 10%-80%, further preferably 20%-60% active component.
The reactive compound I and reactive compound II active components of the present invention can also apply with other active ingredient combinations
With, such as expanding activity profile or preventing from forming resistance.Other active components such as fungicide, bactericide, draw
Lure, insecticide, acaricide, nematicide, growth regulator, herbicide, safener, fertilizer or semiochemical etc..
The reactive compound I and reactive compound II of the present invention can be combined/be administered in combination.Including separately, successively or together
When apply reactive compound I and reactive compound II.Preferably, the reactive compound I combines with reactive compound II
For the form of the composition comprising reactive compound I and reactive compound II.In the case of separate administration, order of administration is led to
Often the result of prophylactico-therapeutic measures is not influenceed.
A kind of cover crop including makes crop and I containing reactive compound and activation to prevent the method for pest infestation
Compound II Pesticidal combination contact.
Present invention also offers a kind of method prevented or control harmful organism, the Pesticidal combination of the present invention is acted on
Target useful plant, object noxious livings or its environment, the propagating materials of target useful plant.
The Pesticidal combination of the present invention handles insect or to be protected with protection against insect by using the active component of insecticidal effective dose
Plant, plant propagation material, soil, surface, material or the space of invasion and attack are carried out before by infestation by insect and later.
Pesticidal combination of the present invention prevent and treat various cultivated plants such as cereal, water fruits and vegetables, a large amount of on industrial crops have
Evil biology is especially important.
All gene-modified plants or genetically modified plants can be included with the plant that Pesticidal combination of the present invention is handled.
A kind of Pesticidal combination is used for the purposes for the plant organ protected plant propagation material and then grown.
Term " plant propagation material " is understood to mean that all generation parts of plant, including seed, root, fruit, block
Stem, napiform root, rhizome, branch, seedling bud and other plant part.It also is included in after germination or is moved after being emerged from soil
The rice shoot and young plant of plant.Plant propagation material can in plantation or transplanting or before use the preventative place of plant protection compound
Reason.
The present invention Pesticidal combination can be used for protection branch to prevent foliar pest and for seed and root processing with
Anti- soil pests.
Therefore, Pesticidal combination of the invention is applied to seed treatment to protect seed to prevent insect pest, especially
It is soil-borne insects insect, and plant roots and branch caused by protecting are to prevent the infringement of soil pests and foliar insect.
Preferably, plant propagation material is seed.The method of seed treatment, such as can there are, diluent liquid or solid
Seed is directly immersed in the method in liquid condition preparaton made medicament be impregnated with seed by the preparaton of shape without dilution；Will
Solid chemicals or liquid preparation mix with seed, and being coated processing makes the method for the surface of the seed attachment medicament；Planting
The methods of being sprayed while plant near seed.
The Pesticidal combination of the present invention can be applied according to the methods of pouring tank, injection, spraying, dusting, distribution or smoke, apply
Dosage changes with weather condition or crop condition.
- generally for leaf portion processing：0.1-10000g/ha, preferably 10-1000 g/ha, more preferably 50-800 g/ha；
- for seed treatment：2-1000g/100kg seeds, preferably 3-500g/100kg seeds；
- for soil treatment：0.1-10000g/ha, preferably 1-5000g/ha.
Above-mentioned dosage is only general exemplary dose, and those skilled in the art can be according to actual feelings when reality is applied
Condition and needs, rate of application is adjusted especially in accordance with the seriousness of the property and insect pest of pending plant or crop.
The present invention by the way that reactive compound I is combined with reactive compound II, on the one hand combine lasting effect with it is quick-acting
Property；On the other hand, there is provided a kind of synergistic effect significantly I containing reactive compound and reactive compound II insecticide composition,
It can obviously reduce the dosage of two active ingredients.
Control insect pest need to be in insect pest early period of origination medication, but this period is not easy to hold, the general insect pest until needing medication
Lay particular stress on there occurs.But reactive compound I quick-acting is very slow, just reach peak mortality within 15 days or so after medicine, at this moment insect pest is
Through causing infringement to plant；After reactive compound I and the outstanding reactive compound II of quick-acting are used in combination, after medicine
Reach peak mortality within 12 hours, the lasting period can be maintained by 45 days.
On the other hand, the generation of resistance has been delayed：Both mechanisms of action and the mode of action are entirely different, have after combination
Tag, stomach toxicity, ovicidal and the effect for reducing spawning rate and incubation rate.
Example of formulations
Embodiment 1：The phenthoate dimephenthoate cidial oil-suspending agent of 5% chlorine fluorine cyanogen insect amide+10%
Chlorine fluorine cyanogen insect amide 5%
Phenthoate dimephenthoate cidial 10%
Nonyl pheno polyethers 5%
Bentonite 1%
Glycerine 5%
Corn oil complements to 100%
The each components such as active component, dispersant, wetting agent and corn oil are well mixed according to the ratio of formula, it is ground
And/or the phenthoate dimephenthoate cidial oil-suspending agent of 5% chlorine fluorine cyanogen insect amide+10% is obtained after high speed shear.
The phenthoate dimephenthoate cidial wettable powder of 2 40% chlorine fluorine cyanogen insect amide of embodiment+50%
Chlorine fluorine cyanogen insect amide 40%
Phenthoate dimephenthoate cidial 50%
Lauryl sodium sulfate 1%
Sodium lignin sulfonate 1%
White carbon 1%
Kaolin complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the phenthoate dimephenthoate cidial wettable powder of 40% chlorine fluorine cyanogen insect amide+50%.
The phenthoate dimephenthoate cidial wettable powder of 3 40% chlorine fluorine cyanogen insect amide of embodiment+40%
Chlorine fluorine cyanogen insect amide 40%
Phenthoate dimephenthoate cidial 40%
Calcium dodecyl benzene sulfonate 1%
Sodium lignin sulfonate 1%
Sucrose complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the phenthoate dimephenthoate cidial wettable powder of 40% chlorine fluorine cyanogen insect amide+40%.
The phenthoate dimephenthoate cidial water-dispersible granules of 4 40% chlorine fluorine cyanogen insect amide of embodiment+20%
Chlorine fluorine cyanogen insect amide 40%
Phenthoate dimephenthoate cidial 20%
Sodium lignin sulfonate 3%
Lauryl sodium sulfate 3%
Urea 5%
Sucrose complements to 100%
Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, by air-flow powder
Wettable powder is broken into, a certain amount of water mixing extruding is added and makes material.Through dry sieve after obtain 40% chlorine fluorine cyanogen insect amide+
20% phenthoate dimephenthoate cidial water-dispersible granules.
The phenthoate dimephenthoate cidial missible oil of 5 2% chlorine fluorine cyanogen insect amide of embodiment+3%
Chlorine fluorine cyanogen insect amide 2%
Phenthoate dimephenthoate cidial 3%
Ethoxylated castor oil 3%
The % of calcium dodecyl benzene sulfonate 2
Dimethyl sulfoxide (DMSO) complements to 100%
Mentioned component is proportionally prepared, is uniformly mixing to obtain homogeneous phase.
The phenthoate dimephenthoate cidial seed coat agent of 6 2% chlorine fluorine cyanogen insect amide of embodiment+20%
Chlorine fluorine cyanogen insect amide 2%
Phenthoate dimephenthoate cidial 20%
AEO sulfosuccinic acid monoesters disodium 5%
Ethoxylated castor oil 3%
Bentonite 3%
PVP –K30 1%
Soybean oil complements to 100%
The each components such as active component, dispersant, wetting agent are well mixed according to the ratio of formula, it is ground and/or high
The phenthoate dimephenthoate cidial seed coat agent of 2% chlorine fluorine cyanogen insect amide+20% is obtained after speed shearing.
The phenthoate dimephenthoate cidial wettable powder of 7 10% chlorine fluorine cyanogen insect amide of embodiment+10%
Chlorine fluorine cyanogen insect amide 10%
Phenthoate dimephenthoate cidial 10%
Lauryl sodium sulfate 5%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
The phenthoate dimephenthoate cidial water dispersible granules of 8 10% chlorine fluorine cyanogen insect amide of embodiment+30%
Chlorine fluorine cyanogen insect amide 10%
Phenthoate dimephenthoate cidial 30%
MODIFIED LIGNOSULPHONATE 5%
Lauryl sodium sulfate 5%
Urea 1%
Kaolin complements to 100%
The components such as chlorine fluorine cyanogen insect amide, phenthoate dimephenthoate cidial active component, dispersant, wetting agent are mixed in the ratio of formula
It is even, by air-flow crushing into wettable powder；Add a certain amount of water mixing extruding and make material.10% is obtained after drying and sieving
The phenthoate dimephenthoate cidial water dispersible granules of chlorine fluorine cyanogen insect amide+30%.
The phenthoate dimephenthoate cidial suspension emulsion of 9 5% chlorine fluorine cyanogen insect amide of embodiment+10%
Chlorine fluorine cyanogen insect amide 5%
Phenthoate dimephenthoate cidial 10%
Methyl oleate 10%
Ethoxylated castor oil 4%
Naphthalene sulfonic acids-formaldehyde condensation products sodium salt 5%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 0.5%
Bentonite 1%
Glycerine 5%
Defoamer 0.1%
Water complements to 100%
Phenthoate dimephenthoate cidial is dissolved in methyl oleate, ethoxylated castor oil is added, obtains the oil phase of phenthoate dimephenthoate cidial；By chlorine fluorine cyanogen
Insect amide, naphthalene sulfonic acids-formaldehyde condensation products sodium salt, MODIFIED LIGNOSULPHONATE, xanthans, bentonite, glycerine, water etc. are above-mentioned each
Component mixes in proportion, and through being sanded, is prepared into chlorine fluorine cyanogen insect amide suspending agent；Phenthoate dimephenthoate cidial is added to chlorine fluorine cyanogen worm
In acid amides suspended phase, the phenthoate dimephenthoate cidial suspension emulsion of 5% chlorine fluorine cyanogen insect amide+10% is obtained.
The phenthoate dimephenthoate cidial coated granule of 10 2% chlorine fluorine cyanogen insect amide of embodiment+8%
Chlorine fluorine cyanogen insect amide 2%
Phenthoate dimephenthoate cidial 8%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In a mixer, by levigate active component even spread to the carrier soaked by polyethylene glycol.In this way
Dust-free coated granules agent can be obtained.
The phenthoate dimephenthoate cidial of 11 70% chlorine fluorine cyanogen insect amide of embodiment+30%
Chlorine fluorine cyanogen insect amide 70%
Phenthoate dimephenthoate cidial 30%
The phenthoate dimephenthoate cidial wettable powder of 12 1% chlorine fluorine cyanogen insect amide of embodiment+20%
Chlorine fluorine cyanogen insect amide 1%
Phenthoate dimephenthoate cidial 20%
Lauryl sodium sulfate 1%
Sodium lignin sulfonate 1%
White carbon 1%
Kaolin complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the phenthoate dimephenthoate cidial wettable powder of 1% chlorine fluorine cyanogen insect amide+20%.
The phenthoate dimephenthoate cidial wettable powder of 13 1% chlorine fluorine cyanogen insect amide of embodiment+50%
Chlorine fluorine cyanogen insect amide 1%
Phenthoate dimephenthoate cidial 50%
Lauryl sodium sulfate 1%
Sodium lignin sulfonate 1%
White carbon 1%
Kaolin complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain the phenthoate dimephenthoate cidial wettable powder of 1% chlorine fluorine cyanogen insect amide+50%.
The phenthoate dimephenthoate cidial of 14 0.1% chlorine fluorine cyanogen insect amide of embodiment+10% extrudes granule
Chlorine fluorine cyanogen insect amide 0.1%
Phenthoate dimephenthoate cidial 10%
Sodium lignin sulfonate 5%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed and ground with auxiliary agent, mixture is soaked with water.The mixture is extruded, then in air stream
Middle drying.
The phenthoate dimephenthoate cidial suspension emulsion of 15 10% chlorine fluorine cyanogen insect amide of embodiment+0.1%
Chlorine fluorine cyanogen insect amide 10%
Phenthoate dimephenthoate cidial 0.1%
Methyl oleate 10%
Ethoxylated castor oil 4%
Naphthalene sulfonic acids-formaldehyde condensation products sodium salt 5%
MODIFIED LIGNOSULPHONATE 5%
Xanthans 0.5%
Bentonite 1%
Glycerine 5%
Defoamer 0.1%
Water complements to 100%
Phenthoate dimephenthoate cidial is dissolved in methyl oleate, ethoxylated castor oil is added, obtains the oil phase of phenthoate dimephenthoate cidial；By chlorine fluorine cyanogen
Insect amide, naphthalene sulfonic acids-formaldehyde condensation products sodium salt, MODIFIED LIGNOSULPHONATE, xanthans, bentonite, glycerine, water etc. are above-mentioned each
Component mixes in proportion, and through being sanded, is prepared into chlorine fluorine cyanogen insect amide suspending agent；The oil phase of phenthoate dimephenthoate cidial is added into chlorine fluorine
In cyanogen insect amide suspended phase, the phenthoate dimephenthoate cidial suspension emulsion of 10% chlorine fluorine cyanogen insect amide+0.1% is obtained.
The phenthoate dimephenthoate cidial of 16 50% chlorine fluorine cyanogen insect amide of embodiment+1% extrudes granule
Chlorine fluorine cyanogen insect amide 50%
Phenthoate dimephenthoate cidial 1%
Sodium lignin sulfonate 5%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed and ground with auxiliary agent, mixture is soaked with water.The mixture is extruded, then in air stream
Middle drying.
The phenthoate dimephenthoate cidial wettable powder of 17 40% chlorine fluorine cyanogen insect amide of embodiment+2%
Chlorine fluorine cyanogen insect amide 40%
Phenthoate dimephenthoate cidial 2%
Lauryl sodium sulfate 5%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
The phenthoate dimephenthoate cidial wettable powder of 18 40% chlorine fluorine cyanogen insect amide of embodiment+4%
Chlorine fluorine cyanogen insect amide 40%
Phenthoate dimephenthoate cidial 4%
Lauryl sodium sulfate 5%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
The phenthoate dimephenthoate cidial wettable powder of 19 50% chlorine fluorine cyanogen insect amide of embodiment+10%
Chlorine fluorine cyanogen insect amide 50%
Phenthoate dimephenthoate cidial 10%
Lauryl sodium sulfate 5%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
Biological test example
Three kinds of situations occur after active compound：Antagonism, addition and synergistic effect, generally when activity
During the effect summation acted on when each reactive compound is administered alone of compound composition, you can think that active compound is deposited
In synergistic function.The predictive role of reactive compound is calculated by Colby formula（Calculating Synergistic
And Antagonistic Responses of Herbicide Combination ", Colby, S.R.；Weeds 15,20-
22,1967）：
X=is the killing rate when using active component A with m ppm amount of application, is expressed as the hundred of untreated control group
Divide ratio；
Y=is the killing rate when using active component B with n ppm amount of application, is expressed as the hundred of untreated control group
Divide ratio；
E=is the killing rate when using active component A and B with m and n ppm amount of application, is expressed as untreated control
The percentage of group.
If actual killing rate is higher than calculated value, the eradicative rate of conjugate has superadditivity, that is, synergy be present.
In this case, the killing rate actually observed, which must exceed, uses the counted expected killing rate (E) of above formula.Thus, if
It was observed that activity be more than active expected from Colby formula, then synergy be present.
The bollworm of biological test example 1 is tested
Material to be tested：Bollworm
Medicament is prepared：Chlorine fluorine cyanogen insect amide, phenthoate dimephenthoate cidial active compound are dissolved with dimethylformamide respectively, are made into mother liquor, it is standby
With.Used time, above-mentioned mother liquor is diluted to concentration with 10% lignin sulfonic acid sodium water solution.
Test method：50 test worms are often handled, are repeated three times, using infusion process by test worm in each concentration for the treatment of described in table 1
Decoction in up and down dipping 5s, then conventinal breeding, investigation result after one week, the results are shown in Table 1, wherein " observation killing rate " for see
The actual killing rate observed, " theoretical killing rate " are the killing rate being calculated using Colby formula.
The effect test of the present composition of table 1
In the present invention it can be seen from the data of table 1, chlorine fluorine cyanogen insect amide and phenthoate dimephenthoate cidial are compounded, bollworm is prevented
Manage property raw synergistic effect.
The striped rice borer of biological test example 2 is tested
Material to be tested：Striped rice borer
Medicament is prepared：Chlorine fluorine cyanogen insect amide, phenthoate dimephenthoate cidial active compound are dissolved with dimethylformamide respectively, are made into mother liquor, it is standby
With.Used time, above-mentioned mother liquor is diluted to concentration with 5% lignin sulfonic acid sodium water solution.
Test method：With various medicaments of the deionized water containing 5% sodium lignin sulfonate respectively with 2 concentration of tabulation.Will
The rice seedlings of 2-3 week old transplant into length, width and height be respectively 100cm × 100cm × 20cm pallet in, cellar culture.Treat rice seedlings
When length is to 6-8 leaf periods, 50 rice-stem borer larvas are inoculated with to each pallet, then spray various concentration shown in table 2 respectively
Medicament.Wherein, each concentration is a processing, often handles 3 repetitions.It is consistent respectively to handle each repetition spray amount.Each
After processing 7 days, death condition is investigated, finally calculates the death rate（Experiment is repeated 3 times, and is averaged）, the results are shown in Table 2.Wherein " see
Examine killing rate " it is the actual killing rate observed, " theoretical killing rate " is the killing rate being calculated using Colby formula.
Effect test of the present composition of table 2 to striped rice borer
In the present invention it can be seen from the data of table 2, chlorine fluorine cyanogen insect amide and phenthoate dimephenthoate cidial are compounded, striped rice borer is prevented
Manage property raw synergistic effect.
The cotten aphid of biological test example 3 is tested
Material to be tested：Cotten aphid
Medicament is prepared：Chlorine fluorine cyanogen insect amide, phenthoate dimephenthoate cidial active compound are dissolved with dimethylformamide respectively, are made into mother liquor, it is standby
With.Used time, above-mentioned mother liquor is diluted to concentration with 10% lignin sulfonic acid sodium water solution.
Test method：With various medicines of the deionized water containing 5% calcium dodecyl benzene sulfonate respectively with 3 concentration of tabulation
Agent.Choose healthy cotton seedling（6-8 piece leaves）, every plant of inoculation cotten aphid adult about 60.Pressed using micro- shape sprayer within 2 days after inoculation
Spraying treatment is carried out according to the concentration described in table 3（Per 3 repetitions of concentration）, it is defined by squirting leave dual sides.6 days after medicine, inspection
Death condition is looked into, and calculates the death rate（Experiment is repeated 3 times, and is averaged）.3 are the results are shown in Table, wherein " observation killing rate " is sight
The actual killing rate observed, " theoretical killing rate " are the killing rate being calculated using Colby formula.
Effect test of the present composition of table 3 to cotten aphid
In the present invention it can be seen from the data of table 3, chlorine fluorine cyanogen insect amide and phenthoate dimephenthoate cidial are compounded, the preventing and treating to cotten aphid
Produce synergistic effect.
The Pesticidal combination of the present invention is described by specific embodiment.But examples detailed above is only to this
Being explained further for invention, is not limitation of the invention, as simply adjust obtained from such scheme
Scheme, without departing from the spirit of the present invention, it is regarded as being included within the scope of the present invention.
Claims (13)
1. a kind of Pesticidal combination, it is characterised in that contain reactive compound I and reactive compound II, the reactive compound
I is chlorine fluorine cyanogen insect amide, and reactive compound II is phenthoate dimephenthoate cidial, and the reactive compound I and reactive compound II weight
Amount is than being 20:1-1:20.
2. Pesticidal combination according to claim 1, it is characterised in that：Reactive compound I and reactive compound II's
Weight ratio is 10:1-1:10.
3. Pesticidal combination according to claim 1, it is characterised in that：The reactive compound I and reactive compound II
Weight ratio be 5:1-1:5.
4. Pesticidal combination according to claim 1, it is characterised in that：The reactive compound I and reactive compound II are altogether
Account for the 5%-90% of the composition by weight.
5. Pesticidal combination according to claim 1, it is characterised in that：The reactive compound I and reactive compound II are altogether
Account for the 10%-80% of the composition by weight.
6. Pesticidal combination according to claim 1, it is characterised in that：The reactive compound I and reactive compound II are altogether
Account for the 20%-60% of the composition by weight.
7. Pesticidal combination according to claim 1, it is characterised in that：Also include surfactant and/or extender.
8. Pesticidal combination according to claim 7, it is characterised in that：The formulation be missible oil, suspending agent, seed coat agent,
Water dispersible granules, wettable powder, suspension emulsion, smoke agent, aqueous emulsion, ultra low volume liquids.
9. the Pesticidal combination described in claim 1 is used for the purposes for preventing or controlling harmful organism.
A kind of 10. method prevented or control harmful organism, it is characterised in that use the Pesticidal combination described in claim 1
In target useful plant, object noxious livings or its environment, the propagating materials of target useful plant.
A kind of 11. method prevented or control harmful organism according to claim 10, it is characterised in that：The plant is numerous
It is seedling, rhizome, garden seedling, cutting or seed to grow material.
A kind of 12. method prevented or control harmful organism according to claim 10, it is characterised in that：Harmful life
Thing is selected from Lepidoptera and homoptera pest.
A kind of 13. method prevented or control harmful organism according to claim 10, it is characterised in that：Including separating,
Sequentially or simultaneously apply reactive compound I, reactive compound II.
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| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | Cyano phthalic diamide compounds, preparation method thereof and use thereof as agricultural chemical pesticide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
| CN103039512A (en) * | 2013-01-05 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing chlorpyrifos and ZJ4042 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | Cyano phthalic diamide compounds, preparation method thereof and use thereof as agricultural chemical pesticide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
| CN103039512A (en) * | 2013-01-05 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing chlorpyrifos and ZJ4042 |
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