A kind of biological growth promoter and preparation method
Technical field:
The invention belongs to biochemical treatment of industrial wastewater technical field, be specifically related to a kind of new bio growth-promoting agent with long preservation period and preparation method.
Technical background:
The mechanism of action of biochemical treatment of industrial wastewater system is: the material that some in trade effluent was not easily degraded by microorganism in trade effluent originally, be decomposed into small organic molecule or the inorganics of easily degraded, thus the organic concentration in reduction waste water, remove or reduce waste water to the toxicity of environment and harm.Biochemical treatment is the main technique that industry is applied with municipal wastewater process.This method is lower than physical chemistry method cost, widely applicable, its shortcoming be exactly influent quality or the water yield fluctuation time, or contain the material compared with difficult degradation at trade effluent, as phenyl ring class, solvent based organism, oils, cellulose family etc., biosystem easily breaks down, the effect of impact process, for the process of trade effluent, water inlet poor stability, causes biochemical system fluctuation of service, and the decubation of biochemical system continues the impact being subject to various change, biochemical system is made to be in the large state of Long-term Fluctuation.For above problem, just need a kind of biological growth promoter to strengthen the resistibility of microorganism in biochemical system, alleviate variation water quality to the impact of biochemical system.
The existing product for biochemical treatment of wastewater extra-nutrition, mainly contains solid and liquid two kinds of forms.The nutritional formulation that solid form is mainly compound, as various nitrogenous fertilizer or phosphate fertilizer, although these materials can be preserved for a long time, directly can add when variation water quality and not need now to buy existing use, but this kind of biological growth promoter solvability is poor, nutritive ingredient is single, and the degree of absorption of microorganism is limited, and the nutritive ingredient of supplementing is also limited, liquid form mainly adds the carbon source nitrogenous source trace element and somatomedin that microorganism can directly utilize, diversification of varieties and nutrition relative abundance, because this type of growth-promoting agent is equivalent to microbiological culture media, can produce well and the microorganism that amount reproduction is useless in transit, consume considerable nutrition in growth-promoting agent, and useless microorganism joins in biochemical system can bring new impact to system, therefore, this type of biological growth promoter is not easily preserved, can only be now with the current, but the variation water quality of upstream water inlet is sewage disposal operation, and factory is uncontrollable, therefore biological growth promoter cannot be added timely when running into variation water quality, biological growth promoter can be caused to add increase and other unnecessary loss of consumption, therefore, need now a kind of biological growth promoter badly, not only containing abundant nutritive ingredient, and can preserve for a long time in warehouse, can use at any time when needed.
Summary of the invention:
In order to solve the problem, the invention provides a kind of biological growth promoter, be made up of the raw material of following mass percent: starch 40-45%, caseinhydrolysate 10-12%, yeast extract 8-10%, EDTA3.5-4.0%, NaCl4.0-4.5%, vitamin H 1.5-2.0%, surplus is distilled water;
It is as follows that described Raw material processing prepares biological growth promoter method:
(1) raw material prepares as follows: starch 40-45%, caseinhydrolysate 10-12%, yeast extract 8-10%, EDTA3.5-4.0%, NaCl4.0-4.5%, vitamin H 1.5-2.0%, and surplus is distilled water;
(2) distilled water is joined in reactor, add caseinhydrolysate, yeast extract, EDTA, NaCl, vitamin H subsequently, stir 15-20 minute;
(3) temperature of reaction kettle is warming up to 60-70 DEG C, starch is added in reactor after stirring 30-60min and temperature of reaction kettle is warming up to 121 DEG C, stir 20-30min;
(4) when question response still temperature is down to about 40-45 DEG C, biological growth promoter will be obtained;
(5) get the biological growth promoter of step (4) when using, conventionally use after adding the water dilution of growth-promoting agent quality 8 times of volumes;
Raw material described in the present invention is commercially available prod.
Beneficial effect:
1, biological growth promoter of the present invention not only rich in nutrition content, in water, solvability is good, owing to have employed new growth-promoting agent proportioning, this growth-promoting agent can preserve more than 180 days, undergo no deterioration and affect growth-promoting agent effect, can use at any time when needs use, and the present invention is concentrated biological growth promoter, can certain transportation cost be saved.
2, starch containing high level in raw material of the present invention, Starch Hydrolysis is maltose to the disaccharides stage, monose (glucose) is obtained after complete hydrolysis, in Raw material processing process, Starch Hydrolysis can be become the micromolecular sugar such as disaccharides, this type of micromolecular sugared solvability is better, can be utilized fast by microorganism, in this formula, starch concentration is higher, in biological growth promoter of the present invention, the micromolecular sugared concentration such as disaccharides is higher after hydrolyzing, not only in use provide a large amount of carbon sources to microorganism, and rot-resistant effect is played in the breeding of osmotic pressure anti-bacteria that the soluble sugar of high density also can increase in water before use, by extended shelf-life.
3, starch is added in raw material of the present invention, the amylolytic polysaccharide having short chain, and disaccharides and monose, the microbe species contained in active sludge is more, although monose is beneficial to most to provide energy, but in the process of disposing of sewage, the organism of a lot of macromole difficult degradation is had in sewage, if be only to provide glucose some can be allowed to compare be easy to utilize the bacterium amount reproduction of glucose to become dominant microflora, but these floras can not play a role when degraded larger molecular organics, if provide the polysaccharide of a part, biochemical system is not impacted at last, and be beneficial to macromolecular microorganism of can degrading occupy in active sludge part advantage, can to degrade in the process of disposing of sewage the macromolecular organism of some difficult degradations, the processing efficiency of biochemical system will inevitably be promoted like this.
4, caseinhydrolysate with crude milk albumen for raw material, through the product of hydrolysis, decolouring, desalination, spraying dry, containing 18 kinds of total free aminoacidss, amino acid is the basis of synthetic protein, be one of the most basic nutritive ingredient of microorganism, adding caseinhydrolysate can provide the amino acid that can utilize fast to accelerate the reproduction speed of microorganism to microorganism on the one hand;
Yeast extract is rich in complete protein, balanced indispensable amino acid and vitamin B group, Nucleotide, trace element etc., it is the main raw material in ideal biological culture medium raw material and fermentation industry, the Yeast Phase of its effect and 8 times is worked as, and greatly can improve throughput rate and the leavened prod yield of bacterial classification;
NaCl adds in biological growth promoter not only can play rot-resistant effect, and can adjust the osmotic pressure in biochemical system when putting in biochemical system, accelerates the accretion rate of microorganism;
EDTA is common complexone, full name is disodium salt, owing to there is more heavy metal ion and dyestuff in dyeing and printing sewage, microorganism can be caused poisoning, reduce the total amount of active flora in active sludge, thus reduction wastewater purification efficiency, EDTA can heavy metal ion in complexing sewage, reduces the poisoning risk of microorganism;
Vitamin H is one of vitamin B group, and be microbial growth and breathing promotive factor, vitamin H is the coenzyme of multiple carboxylase, in carboxylase reaction, play CO2 carrier;
Because growth-promoting agent of the present invention is nutritious and persistence is effective, the ammonia nitrogen removal frank in waste water can be made after using to improve 154.5%, and nitrogen removal rate improves 154.6%, and total tp removal rate improves 75.7%.
Embodiment:
Below in conjunction with embodiment, the present invention is described in further detail and completely:
Embodiment 1. 1 kinds of biological growth promoters and preparation method thereof
A kind of biological growth promoter, is prepared from by the following raw material formed:
1. starch: 45kg
2. caseinhydrolysate: 12kg
3. yeast extract: 10kg
④EDTA:4kg
⑤NaCl:4.5kg
6. vitamin H: 2kg
7. distilled water: 22.5kg
To 7. add in reactor, add respectively and 2., 3., 4., 5., 6. stir 15min, subsequently temperature of reaction kettle is heated to 70 DEG C, add and 1. stir 30min afterwards, temperature of reaction kettle is risen to 121 DEG C, stir 20min, reactor is cooled to about 40 DEG C, the growth-promoting agent prepared is loaded in bucket stand-by.
Embodiment 2. 1 kinds of biological growth promoters and preparation method thereof
A kind of biological growth promoter, is prepared from by the following raw material formed:
1. starch: 40kg
2. caseinhydrolysate: 10kg
3. yeast extract: 8kg
④EDTA:3.5kg
⑤NaCl:4kg
6. vitamin H: 1.5kg
7. distilled water: 33kg
To 7. add in reactor, add respectively and 2., 3., 4., 5., 6. stir 20min, subsequently temperature of reaction kettle is heated to 60 DEG C, add and 1. stir 60min afterwards, temperature of reaction kettle is risen to 121 DEG C, stir 30min, reactor is cooled to about 45 DEG C, the growth-promoting agent prepared is loaded in bucket stand-by.
Embodiment 3, effect experimental
Certain dyeing and printing sewage treatment plant, the average influent COD in waste water mesophytization pond: 900mg/L, ammonia nitrogen: 76.52mg/L, the average removal rate of biochemical system COD is 78%, and the average removal rate of ammonia nitrogen is 60%.Because fluctuation appears in influent quality, the ability of biochemical section of printing and dyeing opposing fluctuation is more weak, therefore the sewage treatment capacity of biochemical section is significantly reduced, effect is started better when using conventional biological growth promoter, but effect has and significantly weakens after for some time is deposited in warehouse, and there is the smelly taste that turns sour, the situation of some blackening that even occurred becoming mildewed, health and the air in warehouse are had a strong impact on, in order to verify the superiority of preservative effect of the present invention and growth-promoting effect, this Sewage Plant is bought a collection of for this Sewage Plant standard biologic growth-promoting agent of 60 days and product of the present invention simultaneously, add respectively in two biochemical sections of this Sewage Plant and carry out detailed data logging, carry out simultaneously
After the biological growth promoter that embodiment 1 is produced dilutes 8 times by mass volume ratio in use, proportionally add, dosage is as follows:
60 days are used continuously altogether in systems in which according to the dosage that adds above.Test is recorded and is analyzed system in detail and uses the removal effect of COD before and after biological growth promoter, ammonia nitrogen and formed with the biological growth promoter used before and contrast.Experimental data being carried out detailed record, seeing the following form through arranging:
Results and analysis: biological growth promoter of the present invention effectively can be alleviated and remove in sewage disposal because variation water quality is to the impact of biochemical system, and biochemical system can be promoted processing efficiency is obtained to sewage, can find out according in contrast, in first 15 days, biological growth promoter effect of the present invention is slightly better than the biological growth promoter of other producer, the biological growth promoter of other producers is seriously putrid and deteriorated after warehouse storage starts putrid and deteriorated 30 days in 20 days, embodiments of the invention 1 were when warehouse storage 60 days and find no corrupt phenomenon occurs, can find out from upper table, corrupt biological growth promoter occurs, and in use effect is worse and worse, before the processing power of biochemical system has been got back to again and has been added biological growth promoter, biological growth promoter of the present invention can not go bad in storage process, sustainablely effectively provide nutritive substance to biochemical system, promote the processing efficiency of biochemical system.
Embodiment 4, result of use are tested
Certain Industrial Waste Water Treatments factory, because upstream process technique goes wrong, waste water quality fluctuating range is larger, the organism of microorganism difficult degradation in water increases, due to the impact to biochemical system, the processing power of biochemical system declines, and biochemical section effluent quality exceeds standard, because the servicing time of upstream process technique is indefinite, therefore need to alleviate the impact of variation water quality to biochemical system by adding biological growth promoter.
Using method: biological growth promoter embodiment 2 produced, after diluting 8 times, adds continuously by mass volume ratio in biochemical system.Add dosage as following table:
Duration of service |
Growth-promoting agent kind |
Every day adds ratio |
1-4 days (Chi Rongji) |
Embodiment 2 (diluting 8 times) |
3ppm |
5-10 days (water meter) |
Embodiment 2 (diluting 8 times) |
2ppm |
11-20 days (water meter) |
Embodiment 2 (diluting 8 times) |
2ppm |
21-30 days (water meter) |
Embodiment 2 (diluting 8 times) |
2ppm |
The removal effect that system uses COD, ammonia nitrogen, total nitrogen, total phosphorus before and after biological growth promoter is recorded and analyzes in test in detail:
Result shows, this biological growth promoter significantly can alleviate the impact of variation water quality to sewage disposal mesophytization system, and can promote the processing efficiency of biochemical system to sewage, makes ammonia nitrogen removal frank improve 154.5%, nitrogen removal rate improves 154.6%, and total tp removal rate improves 75.7%.