CN105330258B - A kind of degradable golf ball nail and preparation method thereof - Google Patents
A kind of degradable golf ball nail and preparation method thereof Download PDFInfo
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- CN105330258B CN105330258B CN201510722643.1A CN201510722643A CN105330258B CN 105330258 B CN105330258 B CN 105330258B CN 201510722643 A CN201510722643 A CN 201510722643A CN 105330258 B CN105330258 B CN 105330258B
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- golf ball
- ball nail
- flyash
- accelerator
- water
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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Abstract
The present invention relates to a kind of degradable golf ball nail, it is made up of following raw material：Flyash 80 ~ 120, clay 10 ~ 30, sodium citrate 2 ~ 5, water reducer 1 ~ 5, air-entrainment 8 ~ 15, accelerator 1 ~ 5 and water 120 ~ 200.This method, which prepares degradable golf ball nail, can sufficiently and reasonably utilize flyash, reduce pollution problem of the flyash to air, production cost is set greatly to reduce simultaneously, for the golf ball nail of Plastic secondary pollution may be caused to environment during recycling, and the problem of consideration recycles is not being had to after using completion for the golf ball nail of flyash, flyash golf ball nail can degrade in grassland, so as to conserve fertilizer as good grassland.
Description
Technical field
The invention belongs to fine coal dirt processing reutilization technology field, and in particular to a kind of degradable golf ball nail and its system
Preparation Method.
Background technology
Flyash causes very big pollution to the environment in China, and the flyash being discharged into air has dust dirty to air
Contaminate and be drained into the flyash in water and water is polluted, and toxic chemical substance therein can also do harm to huamn body, close
Reason is sufficiently a very important thing using flyash, and China is fully sharp by flyash by all means at present
With it has been widely used in cement raw material, cement mixture, Large Hydro-Junction engineering, advanced filler etc..
At present, the conventional golf ball nail of in the market is mainly made up of plastic material and ironwork, due to golf
The particularity that ball nail uses, fly to be difficult to find once beating, while the ball of plastic material and ironwork pattern nail is scattered in lawn
Lawn can be damaged, because they have degradation characteristic, once be lost in lawn understand to golf course lawn and
Environment is polluted, and coal ash for manufacturing is utilized in the present invention into the loose golf ball nail capable of being fast degraded of high intensity quality.
At present, the member that the fertilizer of golf course lawn mainly contains is known as nitrogen, phosphorus, potassium, calcium, magnesium, sulphur, micro member
Element mainly has iron, manganese, boron, zinc, chlorine, aluminium etc., and the main oxides of power plants flyash composition is:SiO2、Al2O3、
FeO、Fe2O3、CaO、TiO2、 MgO 、K2O、 Na2O、SO3、MnO2Deng.
The content of the invention
It is an object of the invention to provide a kind of degradable golf ball nail and preparation method thereof, this method prepares degradable height
Golf ball nail can sufficiently and reasonably utilize flyash, reduce pollution problem of the flyash to air, while make production cost significantly
Reduction, secondary pollution may be caused to environment during recycling for the golf ball nail of Plastic, and
The problem of consideration recycles, flyash golf are not being had to after using completion for the golf ball nail of flyash
Nail can degrade in grassland, so as to conserve fertilizer as good grassland.
In order to achieve the above object, the present invention adopts the following technical scheme that：
The invention provides a kind of degradable golf ball nail, it is made up of following raw material：Flyash 80 ~ 120, stick
Soil 10 ~ 30, sodium citrate 2 ~ 5, water reducer 1 ~ 5, air-entrainment 8 ~ 15, accelerator 1 ~ 5 and water 120 ~ 200.
According to above-mentioned degradable golf ball nail, it is made up of following raw material：Flyash 90 ~ 100, clay 15 ~
25th, sodium citrate 2 ~ 4, water reducer 1 ~ 3, air-entrainment 12 ~ 15, accelerator 1 ~ 3 and water 150 ~ 180.
According to above-mentioned degradable golf ball nail, it is made up of following raw material：Flyash 100, clay 15, lemon
Sour sodium 2, water reducer 3, air-entrainment 10, accelerator 2 and water 150.
The water reducer is naphthalene series high-efficiency water-reducing agent, polycarboxylic acid salt's water reducer or melamine based water reducer.
The air-entrainment is rosin acid sodium or sodium naphthenate.
The accelerator is formed by three kinds of bauxite, quick lime and soda ash components through burning till, wearing into 20 ~ 40 mesh powder, and three
The weight ratio of person is 1：（0.05~0.1）：（0.01~0.1）.
The content of the oxide of iron need to be less than 12% or less than 7% in the flyash selected in the present invention, ideally for
Less than 4%.
The preparation method of described degradable golf ball nail, is comprised the following steps that：A. formula content of starting materials powder is weighed first
Coal ash, clay, sodium citrate, water reducer, air-entrainment, which add to be added in stirring container with water, is uniformly mixed so as to obtain mixing wet feed a1；B. it is molded
Formula ratio accelerator is added in forward direction mixing wet feed a1 to be sufficiently stirred to obtain castable；C. castable is poured into die cavity, waits to be full of
Untill die cavity, solidified by 5 ~ 10min, the demoulding can obtain product.
Compared with prior art：The beneficial effect that the present invention obtains：
1. the composition of raw material clay of the present invention is similar to the chemical composition of flyash, the main component of clay is kaolinite,
The clay minerals such as montmorillonite and quartz etc., the main function of clay are the stability of the shaped object in order to ensure, make shaping
Golf ball nail there is certain shape stability；Sodium citrate is added in the present invention, sodium citrate is acid additives,
The addition of sodium citrate makes the early strength of flyash increase but have no effect on stability, due to wherein flyash golf ball nail
In alkalescence, the easy aquation of this golf ball nail produces substantial amounts of calcium hydroxide in wet environment, so as to receive reaction with citric acid
And promote to decompose.Sodium citrate has good water soluble characteristic, and can be reacted with Fe2O3, CaO, MgO in flyash makes
Golf ball nail occurs biodegradable；Water reducer is a kind of surfactant, belongs to anionic surfactant, can make particle
Unnecessary moisture between being disperseed and discharging particle, while can also make the growth of flyash crystal more perfect, improve flyash
Hardness；Flyash golf ball nail in patent of the present invention has the characteristics of low-density and high-strength, wherein low-density be due to
It with the addition of air-entrainment in flyash, the main function of wherein air-entrainment is that to have made golf ball nail relatively low close
Degree, and intensity does not change；The addition of raw material accelerator is in order to improve the production efficiency of flyash golf ball nail, in solvent
Quick dry agent or accelerator are added before injection, this material can be such that flyash is molded with speed quickly, add the production of mould
Efficiency.
2. can adequately and reasonably utilize flyash using golf ball nail made from flyash in the present invention, reduce powder
Pollution problem of the coal ash to air, while production cost is greatly reduced, reclaimed for the golf ball nail of Plastic
Secondary pollution may be caused during utilization to environment, and completion is being used for the golf ball nail of flyash
Do not have to consider that flyash golf ball nail can degrade in grassland, so as to as good grassland the problem of recycling afterwards
Conserve fertilizer.Production cost can be made to reduce by more than 50% during golf ball nail is made using flyash.
Embodiment
With reference to embodiment to further description of the present invention, but it is not intended to limit present disclosure.
Embodiment 1
A kind of degradable golf ball nail, is made up of following raw material：Flyash 80 ~ 120, clay 10 ~ 30, lemon
Sour sodium 2 ~ 5, water reducer 1 ~ 5, air-entrainment 8 ~ 15, accelerator 1 ~ 5 and water 120 ~ 200.
The water reducer is naphthalene series high-efficiency water-reducing agent, polycarboxylic acid salt's water reducer or melamine based water reducer.
The air-entrainment is rosin acid sodium or sodium naphthenate.
The accelerator is formed by three kinds of bauxite, quick lime and soda ash components through burning till, wearing into 20 ~ 40 mesh powder, and three
The weight ratio of person is 1：（0.05~0.1）：（0.01~0.1）.
The preparation method of described degradable golf ball nail, is comprised the following steps that：A. formula content of starting materials powder is weighed first
Coal ash, clay, sodium citrate, water reducer, air-entrainment, which add to be added in stirring container with water, is uniformly mixed so as to obtain mixing wet feed a1；B. it is molded
Formula ratio accelerator is added in forward direction mixing wet feed a1 to be sufficiently stirred to obtain castable；C. castable is poured into die cavity, waits to be full of
Untill die cavity, solidified by 5 ~ 10min, the demoulding can obtain product.
Embodiment 2
A kind of degradable golf ball nail, is made up of following raw material：Flyash 100, clay 15, sodium citrate 2,
Melamine based water reducer 3, rosin acid sodium 10, accelerator 2 and water 150；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 40 mesh powder, and the weight ratio of three is 1： 0.05：0.05.
The preparation method of the present embodiment is same as Example 1.
Embodiment 3
A kind of degradable golf ball nail, is made up of following raw material：Flyash 80, clay 20, sodium citrate 3,
Naphthalene series high-efficiency water-reducing agent 2, rosin acid sodium 10, accelerator 4 and water 130；The accelerator is by three kinds of bauxite, quick lime and soda ash
Component forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.06：0.07.
The preparation method of the present embodiment is same as Example 1.
Embodiment 4
A kind of degradable golf ball nail, is made up of following raw material：Flyash 90, clay 25, sodium citrate 4,
Melamine based water reducer 2, sodium naphthenate 12, accelerator 4 and water 150；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1： 0.07： 0.1.
The preparation method of the present embodiment is same as Example 1.
Embodiment 5
A kind of degradable golf ball nail, is made up of following raw material：Flyash 110, clay 15, sodium citrate 3,
Polycarboxylic acid salt's water reducer 3, rosin acid sodium 12, accelerator 3 and water 160；The accelerator is by bauxite, quick lime and soda ash three
Kind component forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1： 0.05：0.08.
The preparation method of the present embodiment is same as Example 1.
Embodiment 6
A kind of degradable golf ball nail, is made up of following raw material：Flyash 120, clay 30, sodium citrate 5,
Melamine based water reducer 5, rosin acid sodium 10, accelerator 4 and water 180；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.05：0.02.
The preparation method of the present embodiment is same as Example 1.
Embodiment 7
A kind of degradable golf ball nail, is made up of following raw material：Flyash 105, clay 19, sodium citrate 3,
Naphthalene series high-efficiency water-reducing agent 4, sodium naphthenate 11, accelerator 3 and water 170；The accelerator is by three kinds of bauxite, quick lime and soda ash
Component forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.08：0.1.
The preparation method of the present embodiment is same as Example 1.
Embodiment 8
A kind of degradable golf ball nail, is made up of following raw material：Flyash 95, clay 22, sodium citrate 4,
Polycarboxylic acid salt's water reducer 5, sodium naphthenate 13, accelerator 4 and water 130；The accelerator is by bauxite, quick lime and soda ash three
Kind component forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.09：0.1.
The preparation method of the present embodiment is same as Example 1.
Embodiment 9
A kind of degradable golf ball nail, is made up of following raw material：Flyash 85, clay 10, sodium citrate 3,
Melamine based water reducer 2, rosin acid sodium 14, accelerator 5 and water 160；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 40 mesh powder, and the weight ratio of three is 1：0.08：0.01.
The preparation method of the present embodiment is same as Example 1.
Embodiment 10
A kind of degradable golf ball nail, is made up of following raw material：Flyash 110, clay 20, sodium citrate 2,
Melamine based water reducer 4, rosin acid sodium 10, accelerator 4.5 and water 180；The accelerator is by three kinds of bauxite, quick lime and soda ash
Component forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.08：0.09.
The preparation method of the present embodiment is same as Example 1.
Embodiment 11
A kind of degradable golf ball nail, is made up of following raw material：Flyash 115, clay 15, sodium citrate 2,
Melamine based water reducer 4, rosin acid sodium 12, accelerator 4 and water 130；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 40 mesh powder, and the weight ratio of three is 1：0.1:0.06.
The preparation method of the present embodiment is same as Example 1.
Embodiment 12
A kind of degradable golf ball nail, is made up of following raw material：Flyash 120, clay 10, sodium citrate 3,
Melamine based water reducer 4, rosin acid sodium 14, accelerator 4 and water 170；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.05：0.04.
:The preparation method of the present embodiment is same as Example 1.
Embodiment 13
A kind of degradable golf ball nail, is made up of following raw material：Flyash 90, clay 20, sodium citrate 4,
Melamine based water reducer 1, rosin acid sodium 9, accelerator 1 and water 120；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.09：0.1.
The preparation method of the present embodiment is same as Example 1.
Embodiment 14
A kind of degradable golf ball nail, is made up of following raw material：Flyash 95, clay 25, sodium citrate 3,
Naphthalene series high-efficiency water-reducing agent 3, rosin acid sodium 14, accelerator 2.5 and water 160；The accelerator is by bauxite, quick lime and soda ash three
Kind component forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.07：0.08.
The preparation method of the present embodiment is same as Example 1.
Embodiment 15
A kind of degradable golf ball nail, is made up of following raw material：Flyash 110, clay 20, sodium citrate 3,
Polycarboxylic acid salt's water reducer 4, rosin acid sodium 12, accelerator 4 and water 140；The accelerator is by bauxite, quick lime and soda ash three
Kind component forms through burning till, wearing into 40 mesh powder, and the weight ratio of three is 1：0.06：0.09.
The preparation method of the present embodiment is same as Example 1.
Embodiment 16
A kind of degradable golf ball nail, is made up of following raw material：Flyash 115, clay 30, sodium citrate 5,
Melamine based water reducer 5, sodium naphthenate 15, accelerator 5 and water 200；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.1：0.1.
The preparation method of the present embodiment is same as Example 1.
Embodiment 17
A kind of degradable golf ball nail, is made up of following raw material：Flyash 120, clay 30, sodium citrate 2,
Naphthalene series high-efficiency water-reducing agent 5, rosin acid sodium 12, accelerator 4 and water 140；The accelerator is by three kinds of bauxite, quick lime and soda ash
Component forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.08：0.03.
The preparation method of the present embodiment is same as Example 1.
Embodiment 18
A kind of degradable golf ball nail, is made up of following raw material：Flyash 110, clay 25, sodium citrate 2,
Melamine based water reducer 3, sodium naphthenate 13, accelerator 4 and water 190；The accelerator is by three kinds of bauxite, quick lime and soda ash groups
Part forms through burning till, wearing into 20 mesh powder, and the weight ratio of three is 1：0.09：0.02.
The preparation method of the present embodiment is same as Example 1.
Claims (7)
1. a kind of degradable golf ball nail, it is characterised in that be made up of following raw material：Flyash 80 ~ 120, clay 10
~ 30, sodium citrate 2 ~ 5, water reducer 1 ~ 5, air-entrainment 8 ~ 15, accelerator 1 ~ 5 and water 120 ~ 200.
2. degradable golf ball nail according to claim 1, it is characterised in that be made up of following raw material：Fine coal
Ash 90 ~ 100, clay 15 ~ 25, sodium citrate 2 ~ 4, water reducer 1 ~ 3, air-entrainment 12 ~ 15, accelerator 1 ~ 3 and water 150 ~ 180.
3. degradable golf ball nail according to claim 1, it is characterised in that be made up of following raw material：Fine coal
Ash 100, clay 15, sodium citrate 2, water reducer 3, air-entrainment 10, accelerator 2 and water 150.
4. degradable golf ball nail according to claim 1, it is characterised in that：The water reducer is naphthalene series high-efficiency diminishing
Agent, polycarboxylic acid salt's water reducer or melamine based water reducer.
5. degradable golf ball nail according to claim 1, it is characterised in that：The air-entrainment is rosin acid sodium or ring
Alkanoic acid sodium.
6. degradable golf ball nail according to claim 1, it is characterised in that：The accelerator is by bauxite, raw stone
Ash and three kinds of components of soda ash form through burning till, wearing into 20 ~ 40 mesh powder, and the weight ratio of three is 1：（0.05~0.1）：（0.01~
0.1）.
7. the preparation method of the degradable golf ball nail described in a kind of claim 1, it is characterised in that comprise the following steps that：a.
Formula content of starting materials flyash, clay, sodium citrate, water reducer, air-entrainment are weighed first add to be added in stirring container with water mix
Obtain mixing wet feed a1；B. into mixing wet feed a1, addition formula ratio accelerator is sufficiently stirred to obtain castable before injection；C. will
Castable pours into die cavity, untill die cavity to be full of, is solidified by 5 ~ 10min, the demoulding can obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510722643.1A CN105330258B (en) | 2015-10-31 | 2015-10-31 | A kind of degradable golf ball nail and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510722643.1A CN105330258B (en) | 2015-10-31 | 2015-10-31 | A kind of degradable golf ball nail and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105330258A CN105330258A (en) | 2016-02-17 |
| CN105330258B true CN105330258B (en) | 2017-12-08 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510722643.1A Expired - Fee Related CN105330258B (en) | 2015-10-31 | 2015-10-31 | A kind of degradable golf ball nail and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115710101A (en) * | 2023-01-10 | 2023-02-24 | 廊坊师范学院 | Degradable golf tee and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1923323A (en) * | 2006-08-08 | 2007-03-07 | 姜东源 | Environment-friendly type golf holder |
| CN101297996A (en) * | 2008-06-19 | 2008-11-05 | 胡大川 | Method using plant stalks for preparing golf ball nails |
| CN102091402B (en) * | 2009-12-11 | 2013-09-04 | 黑龙江省林科木业有限公司 | Controllable full-degradable golf tee and manufacture method thereof |
| CN102350044A (en) * | 2011-10-21 | 2012-02-15 | 杨大可 | Wood-plastic environment-friendly golf ball nail and manufacturing method thereof |
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