CN105273551B - Water-based marble-imitated coating and preparation method thereof - Google Patents
Water-based marble-imitated coating and preparation method thereof Download PDFInfo
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- CN105273551B CN105273551B CN201510795158.7A CN201510795158A CN105273551B CN 105273551 B CN105273551 B CN 105273551B CN 201510795158 A CN201510795158 A CN 201510795158A CN 105273551 B CN105273551 B CN 105273551B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 9
- 238000000576 coating method Methods 0.000 title abstract description 19
- 239000011248 coating agent Substances 0.000 title abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 38
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 31
- 239000002562 thickening agent Substances 0.000 claims abstract description 15
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 11
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 11
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 11
- 239000000080 wetting agent Substances 0.000 claims abstract description 11
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 9
- 239000003973 paint Substances 0.000 claims description 33
- 239000004579 marble Substances 0.000 claims description 32
- -1 coalescents Substances 0.000 claims description 13
- 239000013530 defoamer Substances 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 241001272567 Hominoidea Species 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical group O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 229920001661 Chitosan Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 238000001802 infusion Methods 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000012752 auxiliary agent Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 230000001408 fungistatic effect Effects 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical class COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- 241000228197 Aspergillus flavus Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 208000019155 Radiation injury Diseases 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical group O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000009422 growth inhibiting effect Effects 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002504 physiological saline solution Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses a water-based marble-imitated coating and belongs to the technical field of coatings. The water-based marble-imitated coating is prepared from, by weight, 3.5-5.5 parts of hydroxyethyl cellulose, 3.5-5.5 parts of a multifunctional additive, 0.5-2.0 parts of a wetting agent, 1.5-2.5 parts of a defoaming agent, 8.5-10.5 parts of ethanediol, 18-20 parts of a coalescing agent, 6-10 parts of a thickening agent, 350-450 parts of a silicone acrylic emulsion, 2.5-4.5 parts of a flatting agent, 2.0-3.0 parts of an anti-precipitant, 10-20 parts of a bacteriostatic agent, 15-30 parts of a moss-resistant agent, 200-300 parts of colorful slices and 200-300 parts of water. The water-based marble-imitated coating is excellent in antibacterial effect and obvious in moss-resistant effect.
Description
Technical field
The invention belongs to technical field of coatings, it is more particularly related to a kind of aqueous imitation marble paint and its
Preparation method.
Background technology
Granite, marble are favored with its serious texture, durable quality, various color by owner.But
Granite, marmorean shortcoming are also evident from, and one is expensive price, and two is that construction is complicated, and three is the safety for causing that comes off
Problem, makes many users hang back, and aqueous imitation marble paint arises at the historic moment, but, general aqueous imitation marble paint, because
Not have fungistatic effect, anti-moss is undesirable, causes to affect attractive in appearance after mould and moss growth, can also affect the durable of coating
Property.At present, the research for water paint expansion is more, and patent document also to this more disclosure.
A kind of aqueous, environmental protective imitation marble paint is disclosed such as Chinese invention patent application CN103709846 A, including with
Lower raw material is constituted：Water, synthetic resin emulsion, color stuffing, auxiliary agent；Described raw material proportioning (W/W) is：12.4～19.7 parts of water,
8～20 parts of synthetic resin emulsion, 65～70 parts of color stuffing, 2.3～2.6 parts of auxiliary agent；The auxiliary agent include preservative, dispersant,
One or more mixing in wetting agent, defoamer, antifreeze, coalescents, cellulose, thickener；Color stuffing is
Filler and mill base, also including titanium dioxide.There is the marble decoration effect true to nature that common coating is incomparable after application of the present invention
Really；Realize that seamless application, protectiveness are good, damage the characteristics of easily repairing, overcome wallpaper decoration and there is piece, damage, make moist
Come off the shortcoming for being difficult to repair；Solve the problems, such as that natural marble has radiation injury to human body simultaneously, storage period is more than 36
The moon, excellent storage stability, health environment-friendly.The invention also discloses the preparation method of the aqueous, environmental protective imitation marble paint and construction
Method.
As Chinese invention patent application CN101967329 B discloses a kind of imitation marble paint, and in particular to Yi Zhongshui
Property colorful imitation marble paint, in order to solve existing aqueous imitation marble paint, it is impossible to ensure coating particle during long-distance transport
Stability and be difficult to the problem of industrialized production, present invention employs and be added into labile functional groups in coating constitutive material
Ionic compound and the suspending agent that is made up of halogenation metasilicic acid salt form thixotropic agent, using physics, chemical bistable mechanism, thoroughly
Solve the problems, such as Product transport, long term storage stability..
But, with the development of economic society, people for the requirement more and more higher of aqueous imitation marble paint, for water
Property imitation marble paint the impact for how causing for germ and moss in actual use propose new requirement.
The content of the invention
In order to solve the problems referred to above existing for prior art, the present invention proposes a kind of aqueous imitation marble paint, should
Not only fungistatic effect is excellent for coating, and anti-moss effect is obvious.
Technical solution of the present invention is as follows：
A kind of aqueous imitation marble paint, by hydroxyethyl cellulose, multifunctional assistant, wetting agent, defoamer, ethylene glycol,
Coalescents, thickener, silicone acrylic emulsion, levelling agent, antisettling agent, bacteriostatic agent, anti-moss agent, colored sliver and water composition, its
In the weight portion of each component be：Hydroxyethyl cellulose 3.5-5.5 parts, multifunctional assistant 3.5-5.5 parts, wetting agent 0.5-2.0
Part, defoamer 1.5-2.5 parts, ethylene glycol 8.5-10.5 parts, coalescents 18-20 parts, thickener 6-10 parts, silicone acrylic emulsion 350-
450 parts, levelling agent 2.5-4.5 parts, antisettling agent 2.0-3.0 parts, bacteriostatic agent 10-20 parts, anti-moss agent 15-30 parts, colored rock
Piece 200-300 parts and water 200-300 parts.
The further preferred scheme of above-mentioned technical proposal of the present invention is as follows：The bacteriostatic agent is modification of chitosan.
The further preferred scheme of above-mentioned technical proposal of the present invention is as follows：The anti-moss agent is rare earth compound.
The further preferred scheme of above-mentioned technical proposal of the present invention is as follows：The wetting agent is APES,
The defoamer is polysiloxane-polyether copolymer, and the coalescents are propylene glycol monomethyl ethers, and the thickener is polyurethane
Thick dose, the levelling agent is with 2 by organically-modified silica alkane levelling agent, fluorine-carbon modified ammonium polyacrylate salt levelling agent:3 ratio
Mix, the antisettling agent is organic modified bentonite.
A kind of preparation method of aqueous imitation marble paint, comprises the steps：
(1) in order successively by hydroxyethyl cellulose 3.5-5.5 parts of above-mentioned dosage, multifunctional assistant 3.5-5.5 parts,
Wetting agent 0.5-2.0 parts, defoamer 1.5-2.5 parts, ethylene glycol 8.5-10.5 parts, coalescents 18-20 parts, thickener 6-10
Part, silicone acrylic emulsion 350-450 parts, levelling agent 2.5-4.5 parts, antisettling agent 2.0-3.0 parts, colored sliver 200-300 parts and water
200-300 parts are added in material-compound tank, are carried out with mixer pre-dispersed, are ground after material dispersion is uniform, and head product is obtained.
(2) remaining bacteriostatic agent 10-20 parts, anti-moss agent 15-30 parts are added in grinding pot, viscosity, the spray of paint is adjusted
Performance and gloss are applied, filtered after stirring, packed.
Further, the mixing speed in step (1) is 1200 revs/min, is stirred 20～40 minutes.
For compared with prior art, the present invention has advantages below：
(1) not only fungistatic effect is beneficial for the present invention, extends the durability of coating.
(2) the also anti-moss effect of the present invention substantially, saves later maintenance cost.
Specific embodiment
In order that those skilled in the art more fully understand technical scheme, with reference to embodiment to this
Bright product is described in further detail.
A kind of preparation method of aqueous imitation marble paint, comprises the steps：
(1) in order successively by hydroxyethyl cellulose 3.5-5.5 parts of above-mentioned dosage, multifunctional assistant 3.5-5.5 parts,
Wetting agent 0.5-2.0 parts, defoamer 1.5-2.5 parts, ethylene glycol 8.5-10.5 parts, coalescents 18-20 parts, thickener 6-10
Part, silicone acrylic emulsion 350-450 parts, levelling agent 2.5-4.5 parts, antisettling agent 2.0-3.0 parts, colored sliver 200-300 parts and water
200-300 parts are added in material-compound tank, are carried out with mixer pre-dispersed, are ground after material dispersion is uniform, and head product is obtained.
(2) remaining bacteriostatic agent 10-20 parts, anti-moss agent 15-30 parts are added in grinding pot, viscosity, the spray of paint is adjusted
Performance and gloss are applied, filtered after stirring, packed.
Further, the mixing speed in step (1) is 1200 revs/min, is stirred 20～40 minutes.
In order to further to the present invention aqueous imitation marble paint study, using aqueous imitative Dali of the present invention
The preparation method of stone coating prepares respectively embodiment 1- embodiment 3 and carries out the research of correlation, and specific embodiment is as follows：
Embodiment 1,
A kind of aqueous imitation marble paint, is made up of the component of following weight portion：3.5 parts of hydroxyethyl cellulose, it is multi-functional
3.5 parts of auxiliary agent, 0.5 part of APES, 1.5 parts of polysiloxane-polyether copolymer, 8.5 parts of ethylene glycol, propane diols first
18 parts of ether, 6 parts of polyurethane thickener, 350 parts of silicone acrylic emulsion, 2.5 parts of levelling agent, 2.0 parts of organic modified bentonite, the shell that is modified gathers
200 parts of 10 parts of sugar, 15 parts of rare earth compound, 200 parts of colored sliver and water.
Embodiment 2,
A kind of aqueous imitation marble paint, is made up of the component of following weight portion：4.0 parts of hydroxyethyl cellulose, it is multi-functional
4.5 parts of auxiliary agent, 1.0 parts of APES, 2.0 parts of polysiloxane-polyether copolymer, 9.5 parts of ethylene glycol, propane diols first
19 parts of ether, 8 parts of polyurethane thickener, 400 parts of silicone acrylic emulsion, 3.0 parts of levelling agent, 2.5 parts of organic modified bentonite, the shell that is modified gathers
250 parts of 15 parts of sugar, 20 parts of rare earth compound, 250 parts of colored sliver and water.
Embodiment 3,
A kind of aqueous imitation marble paint, is made up of the component of following weight portion：5.5 parts of hydroxyethyl cellulose, it is multi-functional
5.5 parts of auxiliary agent, 2.0 parts of APES, 2.5 parts of polysiloxane-polyether copolymer, 10.5 parts of ethylene glycol, propane diols
20 parts of methyl ether, 10 parts of polyurethane thickener, 450 parts of silicone acrylic emulsion, 4.5 parts of levelling agent, 3.0 parts of organic modified bentonite is modified
300 parts of 20 parts of shitosan, 30 parts of rare earth compound, 300 parts of colored sliver and water.
The evaluation of implementation result
Below by specific experiment, the excellent effect that the present invention is reached is further illustrated.
Model will be respectively prepared according to coating made by above-mentioned specific embodiment, and performance survey will be carried out to above-mentioned model
Examination.As a result display as follows：
Below by specific experiment, the excellent effect that the present invention is reached is further illustrated.
Model will be respectively prepared according to coating made by above-mentioned specific embodiment, and antibacterial survey will be carried out to above-mentioned model
Examination.Aspergillus flavus is spread evenly across on the slide for scribbling above-mentioned coating, bacterium is gently stained with swab stick Jing after 0h, 30h, 60h, 120h
It is placed in after liquid in physiological saline, vibrates, take 0.5ml in culture dish, add culture medium, cultivate 48 hours in incubator, takes
Go out several clump counts, with general aqueous imitation marble paint as blank, the results are shown in Table 1：
The bacteriostasis property of table 1 is tested
Understand above, this coating antibiosis excellent performance, environmental friendliness.
Model will be respectively prepared according to coating made by above-mentioned specific embodiment, and anti-moss survey will be carried out to above-mentioned model
Examination.Moss kind liquid is inoculated with sample upper surface with spray-on process, postvaccinal sample is put into into constant temperature and humidity illumination box (temperature
25 DEG C ± 2 DEG C, relative humidity >=85%, intensity of illumination 1000lx～3000lx), daily illumination 14 hours, inspection in the 21st day connects
Kind of surface moss growth area, finally accounts for the percentage of inoculation surface area to weigh the life of moss with the area for having moss to grow
Long situation, the less inhibition level of the percentage is higher, is that 0 expression does not grow completely.
With general aqueous imitation marble paint as blank, 2 are the results are shown in Table.
The anti-moss performance test of table 2
Understand above, this coating is obvious to moss growth inhibitory effect.
The above, only presently preferred embodiments of the present invention not makees any pro forma restriction to the present invention；It is all
The those of ordinary skill of the industry can shown in by specification and the above and swimmingly implement the present invention；But, it is all to be familiar with
Professional and technical personnel makes in the range of without departing from technical solution of the present invention using disclosed above technology contents
A little change, modification with develop equivalent variations, be the present invention Equivalent embodiments；Meanwhile, all realities according to the present invention
Change, modification and differentiation of any equivalent variations that matter technology is made to above example etc., still fall within the technology of the present invention
Within the protection domain of scheme.
Claims (8)
1. a kind of aqueous imitation marble paint, it is characterised in that：By hydroxyethyl cellulose, multifunctional assistant, wetting agent, froth breaking
Agent, ethylene glycol, coalescents, thickener, silicone acrylic emulsion, levelling agent, antisettling agent, bacteriostatic agent, anti-moss agent, colored sliver and
Water is constituted, and the weight portion of wherein each component is：Hydroxyethyl cellulose 3.5-5.5 parts, multifunctional assistant 3.5-5.5 parts, wetting
Agent 0.5-2.0 parts, defoamer 1.5-2.5 parts, ethylene glycol 8.5-10.5 parts, coalescents 18-20 parts, thickener 6-10 parts, silicon
Acrylic emulsion 350-450 parts, levelling agent 2.5-4.5 parts, antisettling agent 2.0-3.0 parts, bacteriostatic agent 10-20 parts, anti-moss agent 15-30
Part, colored sliver 200-300 parts and water 200-300 parts；
The bacteriostatic agent is modification of chitosan, and the anti-moss agent is rare earth compound.
2. aqueous imitation marble paint according to claim 1, the wetting agent is APES, described to disappear
Infusion is polysiloxane-polyether copolymer.
3. aqueous imitation marble paint according to claim 1, the thickener is polyurethane thickener.
4. aqueous imitation marble paint according to claim 1, it is characterised in that the levelling agent is by organic modified silicas
Oxygen alkane levelling agent, fluorine-carbon modified ammonium polyacrylate salt levelling agent are with 2:3 ratio is mixed.
5. aqueous imitation marble paint according to claim 1, it is characterised in that described antisettling agent is organically-modified
Bentonite.
6. aqueous imitation marble paint according to claim 1, it is characterised in that the coalescents are propane diols first
Ether.
7. the preparation method of aqueous imitation marble paint according to claim 1, it is characterised in that comprise the steps：
(1) in order successively by hydroxyethyl cellulose 3.5-5.5 parts of above-mentioned dosage, multifunctional assistant 3.5-5.5 parts, wetting
Agent 0.5-2.0 parts, defoamer 1.5-2.5 parts, ethylene glycol 8.5-10.5 parts, coalescents 18-20 parts, thickener 6-10 parts, silicon
Acrylic emulsion 350-450 parts, levelling agent 2.5-4.5 parts, antisettling agent 2.0-3.0 parts, colored sliver 200-300 parts and water 200-
300 parts are added in material-compound tank, are carried out with mixer pre-dispersed, are ground after material dispersion is uniform, and head product is obtained；
(2) remaining bacteriostatic agent 10-20 parts, anti-moss agent 15-30 parts are added in grinding pot, viscosity, the sprayability of paint is adjusted
Energy and gloss, filter after stirring, pack.
8. the preparation method of aqueous imitation marble paint according to claim 7, it is characterised in that stirring in step (1)
Speed is mixed for 1200 revs/min, is stirred 20～40 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510795158.7A CN105273551B (en) | 2015-11-18 | 2015-11-18 | Water-based marble-imitated coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510795158.7A CN105273551B (en) | 2015-11-18 | 2015-11-18 | Water-based marble-imitated coating and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105273551A CN105273551A (en) | 2016-01-27 |
| CN105273551B true CN105273551B (en) | 2017-05-10 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221275A (en) * | 2016-08-26 | 2016-12-14 | 山东天汇防水材料有限公司 | A kind of waterproof roll with clean-keeping function and preparation method thereof |
| CN107446444A (en) * | 2017-09-20 | 2017-12-08 | 芜湖县双宝建材有限公司 | A kind of water-fast sliver paint of parian |
| CN109092421B (en) * | 2018-08-07 | 2020-07-10 | 进彩涂料科技(上海)有限公司 | Production method of high-molecular water-based paint |
| CN110183924A (en) * | 2019-07-13 | 2019-08-30 | 安徽星光标识系统有限公司 | Imitation marble paint and preparation method thereof |
| CN110349496A (en) * | 2019-07-13 | 2019-10-18 | 安徽星光标识系统有限公司 | Parian identification label and its processing method |
| CN115109484A (en) * | 2022-04-25 | 2022-09-27 | 安徽盛城新型材料有限公司 | Preparation method and construction process of water-based colorful stone-like paint |
| CN116463020A (en) * | 2023-05-04 | 2023-07-21 | 浙江古品新材料科技有限公司 | Colorful imitation marble paint and preparation process thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102531495B (en) * | 2011-12-30 | 2013-06-05 | 重庆暄洁环保产业（集团）股份有限公司 | Concrete road edge stones capable of preventing moss from growing |
| CN102617071A (en) * | 2012-03-23 | 2012-08-01 | 尚怀兴 | High-gloss real stone lacquer and marble simulation lacquer |
| CN104830184A (en) * | 2015-05-20 | 2015-08-12 | 田雪 | Water-based imitated marble multi-color paint and preparation and construction method thereof |
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