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CN105070851B - A kind of polymer Li-ion battery packs high-barrier dedicated film - Google Patents

A kind of polymer Li-ion battery packs high-barrier dedicated film Download PDF

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Publication number
CN105070851B
CN105070851B CN201510500240.2A CN201510500240A CN105070851B CN 105070851 B CN105070851 B CN 105070851B CN 201510500240 A CN201510500240 A CN 201510500240A CN 105070851 B CN105070851 B CN 105070851B
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China
Prior art keywords
layer
ion battery
polymer
film
ultra
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CN201510500240.2A
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Chinese (zh)
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CN105070851A (en
Inventor
章结兵
谢凤秀
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Zhejiang Lidun Energy Storage Material Technology Co.,Ltd.
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Suzhou Lidun Energy Storage Material Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/116Primary casings; Jackets or wrappings characterised by the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/116Primary casings; Jackets or wrappings characterised by the material
    • H01M50/124Primary casings; Jackets or wrappings characterised by the material having a layered structure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Laminated Bodies (AREA)

Abstract

High-barrier dedicated film is packed the present invention relates to a kind of polymer Li-ion battery.The dedicated film has layer structure, and it is followed successively by modified polypropene layer, ultra-low ash content polypropylene layer, PUR film layer, aluminium foil, gluing oxidant layer, nylon layer from inside to outside.Utilized in the present invention increases by one layer of ultra-low ash content polypropylene layer material in aluminium foil layer internal layer; ultra-low ash content polypropylene material has the excellent ability for obstructing gas and liquid; so that the dedicated film has excellent barrier property; the lithium ion battery packaging dedicated film invented simultaneously has easy-formation, high-barrier, excellent ductility and high heat sealability; it is suitably adapted for the packaging applications of polymer Li-ion battery; to polymer Li-ion battery formation safeguard protection, the service life of lithium ion battery is lifted.

Description

A kind of polymer Li-ion battery packs high-barrier dedicated film
Technical field
The present invention relates to battery packaging material field, more particularly to a kind of polymer Li-ion battery packaging high-barrier is special Film.
Background technology
1992, Sony corporation of Japan invention made the lithium battery of positive pole with the compound containing lithium using Carbon Materials as negative pole, In charge and discharge process, exist without lithium metal, only lithium ion, started the lithium ion battery epoch, it has reformed mobile electron The looks of consumer products, it has also become the main power source of moving device.
Meanwhile, the history of battery development is combed, the characteristics of our times battery industry develops is:1. environmental protection battery is fast Speed development, such as lithium ion battery, Ni-H cell;2. one-shot battery is converted to battery;3. battery is sent out to small, light, thin direction Exhibition.In commercialization rechargeable battery, lithium ion battery can be realized due to its specific energy highest, special polymer Li-ion battery The thin type of chargeable battery.Just because of lithium ion battery energy density per unit volume and specific energy are high, and it is chargeable and pollution-free, possess The big feature of present battery industrial development three, the application to lithium ion battery brings mass market opportunity, in mobile electricity Words and notebook computer are largely used, and the market share also increases very fast.
In addition, polymer Li-ion battery in lithium ion battery is with its unique advantage in terms of security, can by having Liquid electrolyte lithium ion battery can be progressively substituted, the main flow as 21 century lithium ion battery opens up the new opplication of battery Epoch, development prospect is very optimistic.In polymer Li-ion battery application process, the stability of its discharge and recharge is maintained to weigh very much Will, among these in addition to positive and negative electrode material, polymer dielectric, the packaging film of battery outer layer is to influence its performance most important One of factor, the packaging film needs good barrier property and decay resistance, in processing encapsulation process, also needed excellent Heat sealability and ductility can just meet requirement of the polymer Li-ion battery to wrapping film, be a multinomial pass of set Key matter of science and technology, how to break through solution, the combination property of upgrading lifting wrapping film is lithium battery particularly polymer lithium Ion battery factory and the packaging film enterprise very concern that forms a complete production network.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of polymer Li-ion battery packaging high-barrier dedicated film.Should Dedicated film has excellent barrier property, heat sealability and ductility, can meet lithium ion battery to wrapping film material It can require, the packaging of polymer Li-ion battery can be suitably applied.
The technical scheme is that:A kind of polymer Li-ion battery packs high-barrier dedicated film, including modified poly- third Alkene layer, ultra-low ash content polypropylene layer, PUR film layer, aluminium foil layer, adhesive layer, nylon layer, the dedicated film from inside to outside according to The secondary stacking modified polypropene layer, ultra-low ash content polypropylene layer, PUR film layer, aluminium foil layer, adhesive layer, nylon layer, institute The ash content of coal stated in ultra-low ash content polypropylene layer is less than 10ppm.
As a preferred embodiment of the present invention, the material of the modified polypropene layer is polypropylene, low grey polypropylene, low One or both of density polyethylene, ultra-low density polyethylene or ethylene-octene copolymer combination of the above, the low ash poly- third The ash content of coal of alkene should be less than 100ppm.
As a preferred embodiment of the present invention, the ultra-low ash content polypropylene layer thickness is 10-70 μm.
As a preferred embodiment of the present invention, the optional EVA adhesive film of hot melt adhesive film material, PA glue in the PUR film layer One or both of film, PES glued membranes, PO glued membranes, TPU glued membranes, PE or POE materials combination of the above.
As a preferred embodiment of the present invention, the optional butadiene-styrene rubber of adhesive, polyurethane, nitric acid are fine in the gluing oxidant layer Dimension element, the solvent type adhesive of polyvinyl acetate, ethylene-vinyl acetate copolymer, the water-soluble of ethylene-acrylic acid copolymer glue One or more in mixture, vinyl acetate resin, the Emulsion Adhesive of acrylic resin.
After adopting the above technical scheme, the beneficial effects of the invention are as follows:
First, the present invention increases by one layer of ultra-low ash content polypropylene layer material in aluminium foil layer internal layer, adds the dedicated film Barrier;Secondly, the present invention is using dry method and Re Fa complex technique productions altogether, and processing is simple, and product also has excellent extension Property and heat sealability.
Brief description of the drawings
Fig. 1 is structural representation of the invention.
Wherein, 1 is modified polypropene layer;2 be ultra-low ash content polypropylene layer;3 be PUR film layer;4 be aluminium foil layer;5 are Adhesive layer;6 be nylon layer.
Embodiment
In order that objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further Describe in detail.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit this hair It is bright.
Embodiment
As shown in figure 1, the present invention improves a kind of polymer Li-ion battery packaging high-barrier dedicated film, including it is modified poly- Propylene layer 1, ultra-low ash content polypropylene layer 2, PUR film layer 3, aluminium foil layer 4, adhesive layer 5, nylon layer 6;The dedicated film by It is interior to be followed successively by modified polypropene layer 1, ultra-low ash content polypropylene layer 2, PUR film layer 3, aluminium foil layer 4, adhesive layer 5, Buddhist nun to outer Imperial layer 6.
The material of the modified polypropene layer 1 is polypropylene, low grey polypropylene, low density polyethylene (LDPE), the poly- second of extremely-low density One or both of alkene or ethylene-octene copolymer combination of the above.Low grey polyacrylic ash in the modified polypropene layer Content should be less than 100ppm, and temperature limit is at 80 DEG C~350 DEG C, and thickness is 10~100 μm.
The ash content of coal in the ultra-low ash content polypropylene layer 2 is less than 10ppm, and thickness is 10-70 μm.
The optional EVA adhesive film of hot melt adhesive film material, PA glued membranes, PES glued membranes, PO glued membranes, TPU glue in the PUR film layer 3 One or both of film, PE or POE materials combination of the above, temperature limit is 80 DEG C~300 DEG C, and thickness is 10~80 μ m。
Material carries out chromaking processing in the aluminium foil layer 4, and thickness is 30~60 μm.
The optional butadiene-styrene rubber of adhesive, polyurethane, nitrocellulose, the solvent-borne type of polyvinyl acetate in the adhesive layer 5 Adhesive, ethylene-vinyl acetate copolymer, the aqueous type adhesive of ethylene-acrylic acid copolymer, vinyl acetate resin, propylene One or more in the Emulsion Adhesive of acid resin.
The thickness of nylon layer 6 is 10~50 μm.
It is a kind of to prepare the method that polymer Li-ion battery packs high-barrier dedicated film, comprise the following steps:
1)It is right to modified polypropene one side, nylon one side and the two-sided carry out plasma sided corona treatment of ultra-low ash content polypropylene The two-sided carry out chromaking processing of aluminium foil;
2)Hot pressing is carried out between modified polypropene layer and ultra-low ash content polypropylene layer to be combined;
3)Heated in above-mentioned composite correspondence ultra-low ash content outer layer of polypropylene, hot melt adhesive film and aluminium foil, laminated heat Method is combined;
4)The compound aluminium foil surface, adhesive, nylon carry out dry laminating, form first product;
5)Curing is dried to the first product, polymer Li-ion battery packaging dedicated film finished product is obtained.
The product of the present invention reaches following index by measure:
1. peel strength test:Electrolyte soaks 85 DEG C, 7 days, and film interlaminar strength is more than or equal to 8N/15mm;
2. permeability resistance is tested:Soaked 14 days in 60 DEG C of water, no layering, weight change is less than 0.05 gram.
3. deep drawability is tested, deep-draw depth reaches more than 6mm.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (6)

1. a kind of polymer Li-ion battery packs high-barrier dedicated film, it is characterised in that including modified polypropene layer, ultra low-ash Part polypropylene layer, PUR film layer, aluminium foil layer, adhesive layer, nylon layer;The dedicated film is followed successively by modified poly- third from inside to outside Alkene layer, ultra-low ash content polypropylene layer, PUR film layer, aluminium foil layer, adhesive layer, nylon layer, the ultra-low ash content polypropylene layer In the ash content of coal be less than 10ppm.
2. the polymer Li-ion battery packaging high-barrier dedicated film according to claim 1, it is characterised in that described to change Property polypropylene layer material be polypropylene, low grey polypropylene, low density polyethylene (LDPE), ultra-low density polyethylene or ethylene-octene it is common One or both of polymers combination of the above, the low grey polyacrylic the ash content of coal should be less than 100ppm.
3. the polymer Li-ion battery packaging high-barrier dedicated film according to claim 1, it is characterised in that described super Low ash polypropylene layer thickness is 10-70 μm.
4. the polymer Li-ion battery packaging high-barrier dedicated film according to claim 1, it is characterised in that the heat In melten gel film layer in the optional EVA adhesive film of hot melt adhesive film material, PA glued membranes, PES glued membranes, PO glued membranes, TPU glued membranes, PE or POE materials One or more kinds of combinations.
5. the polymer Li-ion battery packaging high-barrier dedicated film according to claim 1, it is characterised in that described viscous Tie the optional butadiene-styrene rubber of adhesive, polyurethane, nitrocellulose, the solvent type adhesive of polyvinyl acetate, ethyl vinyl acetate in oxidant layer The aqueous type adhesive of ethylene copolymer, ethylene-acrylic acid copolymer, vinyl acetate resin, the emulsion-type of acrylic resin glue One or more in mixture.
6. a kind of method that polymer Li-ion battery prepared described in any one of Claims 1 to 5 packs high-barrier dedicated film, It is characterised in that it includes following steps:
Step 1, it is right to modified polypropene one side, nylon one side and the two-sided carry out plasma sided corona treatment of ultra-low ash content polypropylene The two-sided carry out chromaking processing of aluminium foil;
Step 2, hot pressing is carried out between modified polypropene layer and ultra-low ash content polypropylene layer to be combined;
Step 3, heated in above-mentioned composite correspondence ultra-low ash content outer layer of polypropylene, hot melt adhesive film and aluminium foil, laminated heat Method is combined;
Step 4, the compound aluminium foil surface, binding agent, nylon carry out dry laminating, form first product;
Step 5, curing is dried to the first product, obtains polymer Li-ion battery packaging dedicated film finished product.
CN201510500240.2A 2015-08-16 2015-08-16 A kind of polymer Li-ion battery packs high-barrier dedicated film Active CN105070851B (en)

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109397823A (en) * 2017-08-18 2019-03-01 刘立健 A kind of battery case encapsulating material and preparation method thereof
CN109037499A (en) * 2018-07-27 2018-12-18 杭州中齐新材料科技有限公司 A kind of new-energy automobile lithium battery flexible packing material
CN110400892A (en) * 2019-06-19 2019-11-01 华富(江苏)锂电新技术有限公司 Lithium ion battery flexible package plastic film of embedded heating function and preparation method thereof
CN110311165A (en) * 2019-06-19 2019-10-08 华富(江苏)锂电新技术有限公司 A kind of rectangular lithium ion battery and its preparation process with heating function
CN110311166A (en) * 2019-06-19 2019-10-08 华富(江苏)锂电新技术有限公司 A kind of column lithium ion battery and its preparation process with heating function
CN110615181B (en) * 2019-10-14 2021-05-28 宁波瑞成包装材料有限公司 High-temperature-resistant lithium battery packaging film and preparation method thereof
JP2023540727A (en) * 2021-04-15 2023-09-26 エルジー エナジー ソリューション リミテッド secondary battery

Family Cites Families (7)

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WO2001045183A1 (en) * 1999-12-17 2001-06-21 Dai Nippon Printing Co., Ltd Packaging material for polymer cell and method for producing the same
JP2001229885A (en) * 2000-02-16 2001-08-24 Dainippon Printing Co Ltd Packaging material for polymer battery and method of manufacturing the same
CN201278351Y (en) * 2008-08-20 2009-07-22 沈道付 Lithium ion battery packaging film
CN101640255B (en) * 2009-08-10 2013-04-03 沈道付 Lithium ion battery packaging film and manufacturing method thereof
JP5999674B2 (en) * 2010-02-12 2016-09-28 興人フィルム&ケミカルズ株式会社 Biaxially stretched nylon film for cold forming
CN102328779B (en) * 2011-06-14 2014-01-29 刘继福 High-barrier layer flexible packaging film for isolating contents of polymer lithium battery
CN205004358U (en) * 2015-08-16 2016-01-27 苏州锂盾储能材料技术有限公司 Polymer lithium ion battery packing high resistant separates special membrane

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Address after: No. 759, Zhizhou Avenue, Huaxi Street, Changxing County, Huzhou City, Zhejiang Province 313000

Patentee after: Zhejiang Lidun Energy Storage Material Technology Co.,Ltd.

Address before: No. 6, Anmin Road, East Bridge, Huangdai Town, Xiangcheng District, Suzhou City, Jiangsu Province, 215152

Patentee before: SUZHOU LIDUN ENERGY STORAGE MATERIAL TECHNOLOGY Co.,Ltd.