CN105001765A - High temperature resistant coating - Google Patents
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- CN105001765A CN105001765A CN201510373506.1A CN201510373506A CN105001765A CN 105001765 A CN105001765 A CN 105001765A CN 201510373506 A CN201510373506 A CN 201510373506A CN 105001765 A CN105001765 A CN 105001765A
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Abstract
The invention discloses a high temperature resistant coating, which comprises the following raw materials by weight: 25-50 parts of silicone modified acrylate, 20-45 parts of epoxy acrylate resin, 2-8 parts of methyl phenyl organic siliconresin, 5-15 parts of carboxy nitrile rubber, 5-10 parts of nanographite, 3-10 parts of nano-silica, 3-10 parts of aluminum powder, 2-8 parts of zinc phosphate, 1-5 parts of magnesium hydroxide, 3-10 parts of hollow glass microspheres, 2-10 parts of expanded vermiculite, 1-5 parts of polyvinyl alcohol, 5-10 parts of polyamide resin, 1-5 parts of PESA, 5-10 parts of xylene, 1-5 parts of dilauryl thiodipropionate, 2-6 parts of aramid fiber, 2-4 parts of m-phenylenediamine, 3-8 parts of trimethylene tetramine, 1-3 parts of a coupling, 20-40 parts of water and 1-2 parts of an additive. The high temperature resistant coating provided by the invention has excellent high temperature resistance, good flame resistance and good adhesive force.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of high-temperature resistant coating.
Background technology
Coating is applied to body surface can be formed and have protection, the class I liquid I of solid-state film of decoration or property (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprises oil (property) paint, water-miscible paint, powder coating.
High-temperature resistant coating is the one of space energy-saving heat-insulating thermal insulation coatings, effectively can suppress and shield the conduction of ultrared radiant heat and heat, heat insulation suppression efficiency can reach about 90%, the thermal radiation of high temp objects and the lost of heat can be suppressed, can effective cold insulation environmental radiation heat can be suppressed and the loss of refrigeration capacity that causes to cryogenic object, also can prevent the generation of object condensation, be widely used in the industrial circles such as metallurgy, petroleum industry, Natural gas extraction, aerospace at present.
Along with the fast development of modern industry and national defense construction industry, more and more higher to the requirement of high-temperaure coating, require high-temperature resistant coating at high temperature paint film nondiscoloration, do not come off, still can keep good physical and mechanical properties and antiseptic property.Although, a lot of to the report of high-temperature resistant coating at present, and the heat resistance of existing high-temperature resistant coating can reach service requirements substantially, but still all there are some shortcomings, the poor adhesive force of such as film, heat-resistant fireproof is bad.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of high-temperature resistant coating, its resistance to elevated temperatures is excellent, flame retardant resistance and sticking power good.
A kind of high-temperature resistant coating that the present invention proposes, its raw material comprises following component by weight: organosilicon-modified acrylate 25-50 part, epoxy acrylic resin 20-45 part, methylphenylsiloxane 2-8 part, carboxy nitrile rubber 5-15 part, nano-graphite 5-10 part, nano silicon 3-10 part, aluminium silicate powder 3-10 part, zinc phosphate 2-8 part, magnesium hydroxide 1-5 part, hollow glass microbead 3-10 part, expanded vermiculite 2-10 part, polyvinyl alcohol 1-5 part, polyamide resin 5-10 part, poly-epoxy succinic acid 1-5 part, dimethylbenzene 5-10 part, Tyox B 1-5 part, aramid fiber 2-6 part, mphenylenediamine 2-4 part, triethylene tetramine 3-8 part, coupling agent 1-3 part, water 20-40 part, auxiliary agent 1-2 part.
In a particular embodiment, a kind of high-temperature resistant coating that the present invention proposes, in its raw material, the weight part of organosilicon-modified acrylate can be 25,26,27,28,29.5,30,31,34,35,37,38,39.3,43,45,46,47,48.3,49,49.3,50 parts; The weight part of epoxy acrylic resin can be 20,23,24,25,26,27,28.6,29,30,32,34,35,36,36.8,38,39,41,42,42.6,43,44,44.6,45 parts; The weight part of methylphenylsiloxane can be 2,2.3,2.8,3,3.4,4,4.8,5,6,7,7.4,8 parts; The weight part of carboxy nitrile rubber can be 5,6,7,7.4,8,8.5,9,9.5,10,11,11.4,12,12.5,13,13.7,14,14.6,15 parts; The weight part of nano-graphite can be 5,6,7,7.5,8,8.6,9,9.3,10 parts; The weight part of nano silicon can be 3,4,5,6,6.7,7,7.8,8,8.6,9,9.3,10 parts; The weight part of aluminium silicate powder can be 3,4,5,6,6.4,7,7.5,8,8.6,9,9.4,10 parts; The weight part of zinc phosphate can be 2,2.3,3,3.5,4,5,6,6.4,7,7.5,8 parts; The weight part of magnesium hydroxide can be 1,2,2.4,3,3.6,4,4.3,4.8,5 part; The weight part of hollow glass microbead can be 3,4,5,6,6.5,7,7.6,8,8.9,9,9.3,10 parts; The weight part of expanded vermiculite can be 2,3,4,5,5.6,6,6.7,7,7.8,8,8.7,9,9.4,10 parts; The weight part of polyvinyl alcohol can be 1,2,3,3.4,4,4.5,5 part; The weight part of polyamide resin can be 5,6,7,7.5,8,8.6,9,9.4,10 parts; The weight part of poly-epoxy succinic acid can be 1,1.2,1.8,2,2.3,2.8,3,3.4,3.8,4,4.5,4.8,5 part; The weight part of dimethylbenzene can be 5,6,7,7.5,8,8.6,9,9.5,10 parts; The weight part of Tyox B can be 1,1.2,1.6,1.86,2,2.3,2.8,3,3.5,4,4.5,5 part; The weight part of aramid fiber can be 2,2.3,2.5,2.8,3,4,4.5,5,5.5,6 parts; The weight part of mphenylenediamine can be 2,2.3,2.6,2.86,3,3.2,3.5,3.86,4 parts; The weight part of triethylene tetramine can be 3,4,5,5.6,6,6.5,7,7.5,8 parts; The weight part of coupling agent can be 1,1.2,1.6,1.8,2,2.3,2.6,2.85,3 part; The weight part of water can be 20,22,23,24,25,25.6,28,29,32,35,36,37,37.5,39,39.4,40 parts; The weight part of auxiliary agent can be 1,1.2,1.45,1.6,1.86,1.96,2 part.
Preferably, in its raw material, the weight ratio of organosilicon-modified acrylate, epoxy acrylic resin, methylphenylsiloxane is 32-45:26-40:3-8.
Preferably, in its raw material, the weight ratio of nano-graphite, nano silicon, aluminium silicate powder, zinc phosphate, magnesium hydroxide, hollow glass microbead, expanded vermiculite is 6-9:5-9:4-10:3-8:2-4:6-9:4-9.
Preferably, its raw material comprises following component by weight: organosilicon-modified acrylate 35-40 part, epoxy acrylic resin 33-38 part, methylphenylsiloxane 5-7 part, carboxy nitrile rubber 8-12 part, nano-graphite 7-8 part, nano silicon 7-9 part, aluminium silicate powder 6-8 part, zinc phosphate 5-7 part, magnesium hydroxide 2.5-4 part, hollow glass microbead 7-8 part, expanded vermiculite 6-7 part, polyvinyl alcohol 3-4.5 part, polyamide resin 8-9 part, poly-epoxy succinic acid 3-4.5 part, dimethylbenzene 8-9 part, Tyox B 3-4.5 part, aramid fiber 3-5 part, mphenylenediamine 3-3.6 part, triethylene tetramine 6-6.5 part, coupling agent 2-2.6 part, water 34-38 part, auxiliary agent 1.6-1.9 part.
Preferably, its raw material comprises following component by weight: organosilicon-modified acrylate 39 parts, epoxy acrylic resin 36 parts, methylphenylsiloxane 6 parts, carboxy nitrile rubber 10 parts, nano-graphite 7.6 parts, nano silicon 8.3 parts, aluminium silicate powder 7 parts, zinc phosphate 6 parts, magnesium hydroxide 3 parts, hollow glass microbead 7.6 parts, expanded vermiculite 6.2 parts, polyvinyl alcohol 4 parts, polyamide resin 8.5 parts, poly-epoxy succinic acid 4 parts, dimethylbenzene 8.6 parts, Tyox B 4 parts, aramid fiber 3.9 parts, mphenylenediamine 3.3 parts, triethylene tetramine 6.2 parts, coupling agent 2.1 parts, 36 parts, water, auxiliary agent 1.8 parts.
Preferably, described epoxy acrylic resin is modified epoxy acrylate resin; Described modified epoxy acrylate resin is prepared according to following technique: add in reaction unit by 20-35 part Hydroxyethyl acrylate, 3-15 part 2-hydroxyethyl methacrylic acid phosphoric acid ester, 5-20 part MALEIC ANHYDRIDE, 0.3-1 part MEHQ, 0.2-0.8 part Resorcinol and 0.1-0.5 part trolamine by weight, be warming up to 75-85 DEG C, 5-10 part epoxy resin is added after reaction 20-50min, stopped reaction when to react to acid number after being heated to 100-110 DEG C be 5-7mgKOH/g, obtains modified epoxy acrylate resin after cooling.
Preferably, described epoxy acrylic resin is modified epoxy acrylate resin; Described modified epoxy acrylate resin is prepared according to following technique: add in reaction unit by 30 parts of Hydroxyethyl acrylates, 12 parts of 2-hydroxyethyl methacrylic acid phosphoric acid ester, 13 parts of MALEIC ANHYDRIDE, 0.6 part of MEHQ, 0.7 part of Resorcinol and 0.26 part of trolamine by weight, be warming up to 79 DEG C, 8 parts of epoxy resin are added after reaction 43min, stopped reaction when to react to acid number after being heated to 106 DEG C be 5.8mgKOH/g, obtains modified epoxy acrylate resin after cooling.
Preferably, described coupling agent is one or more the combination in silane coupling agent KH560, silane coupling agent KH570, Silane coupling agent KH550, stearic acid.
High-temperature resistant coating of the present invention can Paint preparation technology conveniently be prepared from.
Epoxy resin and silicone resin have higher fire resistant melting performance, in the present invention, have selected the main film forming substance of organosilicon-modified acrylate, epoxy acrylic resin and methylphenylsiloxane cooperation as coating, and with the addition of carboxy nitrile rubber, organosilicon, acrylate and epoxy resin are combined as a whole, give the high thermal resistance of coating excellence, ultraviolet resistance, cohesiveness, stability, snappiness and high temperature corrosion; In optimal way, in the preparation process of modified epoxy acrylate resin, with the addition of the phosphoric acid ester function monomer 2-hydroxyethyl methacrylic acid phosphoric acid ester of methacrylic esterification, phosphoric is introduced in epoxy acrylic resin matrix, add in coating, improve the sticking power of coating, and coordinate with coupling agent, improve the consistency of each raw material in system; Aluminium silicate powder, zinc phosphate, magnesium hydroxide is with the addition of in coating, further increase the flame retardant properties of coating, in coating, with the addition of nano-graphite, nano silicon, hollow glass microbead, expanded vermiculite four kinds of particles simultaneously, increase substantially the high thermal resistance of coating; In coating system, add aramid fiber, the network structure that itself and coating are formed is blended, further promotes bridging property and the snappiness of coating, makes coating also have good snappiness while having higher hardness.
In the present invention, by selecting various raw material, and optimize the ratio of each raw material, the high-temperature resistant coating obtained has excellent high thermal resistance, snappiness, flame retardant resistance and good sticking power.
Carry out Performance Detection to high-temperature resistant coating of the present invention, its detected result is as follows: surface drying time is 4-5min; The time of doing solid work is 8-10h; Appearance of film flat smooth; 800 DEG C, 10h thermotolerance film do not chap, do not come off; Sticking power is 1 grade; Shock strength is 50-55kg.cm; Store 8-13 month to stablize; Salt spray resistance 800-1000h; Oxygen index is greater than 40.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of high-temperature resistant coating that the present invention proposes, its raw material comprises following component by weight: organosilicon-modified acrylate 25 parts, epoxy acrylic resin 45 parts, methylphenylsiloxane 2 parts, carboxy nitrile rubber 15 parts, nano-graphite 5 parts, nano silicon 10 parts, aluminium silicate powder 3 parts, zinc phosphate 8 parts, magnesium hydroxide 1 part, hollow glass microbead 10 parts, expanded vermiculite 2 parts, polyvinyl alcohol 5 parts, polyamide resin 5 parts, poly-epoxy succinic acid 5 parts, dimethylbenzene 5 parts, Tyox B 5 parts, aramid fiber 2 parts, mphenylenediamine 4 parts, triethylene tetramine 3 parts, coupling agent 3 parts, 20 parts, water, auxiliary agent 2 parts.
Embodiment 2
A kind of high-temperature resistant coating that the present invention proposes, its raw material comprises following component by weight: organosilicon-modified acrylate 50 parts, epoxy acrylic resin 20 parts, methylphenylsiloxane 8 parts, carboxy nitrile rubber 5 parts, nano-graphite 10 parts, nano silicon 3 parts, aluminium silicate powder 10 parts, zinc phosphate 2 parts, magnesium hydroxide 5 parts, hollow glass microbead 3 parts, expanded vermiculite 10 parts, polyvinyl alcohol 1 part, polyamide resin 10 parts, poly-epoxy succinic acid 1 part, dimethylbenzene 10 parts, Tyox B 1 part, aramid fiber 6 parts, mphenylenediamine 2 parts, triethylene tetramine 8 parts, silane coupling agent KH5600.3 part, silane coupling agent KH5700.2 part, Silane coupling agent KH550 0.2 part, stearic acid 0.3 part, 40 parts, water, auxiliary agent 1 part,
Wherein, described epoxy acrylic resin is modified epoxy acrylate resin; Described modified epoxy acrylate resin is prepared according to following technique: add in reaction unit by 20 parts of Hydroxyethyl acrylates, 15 parts of 2-hydroxyethyl methacrylic acid phosphoric acid ester, 5 parts of MALEIC ANHYDRIDE, 1 part of MEHQ, 0.2 part of Resorcinol and 0.5 part of trolamine by weight, be warming up to 75 DEG C, 5 parts of epoxy resin are added after reaction 50min, stopped reaction when to react to acid number after being heated to 110 DEG C be 5mgKOH/g, obtains modified epoxy acrylate resin after cooling.
Embodiment 3
A kind of high-temperature resistant coating that the present invention proposes, its raw material comprises following component by weight: organosilicon-modified acrylate 35 parts, epoxy acrylic resin 38 parts, methylphenylsiloxane 5 parts, carboxy nitrile rubber 12 parts, nano-graphite 7 parts, nano silicon 9 parts, aluminium silicate powder 6 parts, zinc phosphate 7 parts, magnesium hydroxide 2.5 parts, hollow glass microbead 8 parts, expanded vermiculite 6 parts, polyvinyl alcohol 4.5 parts, polyamide resin 8 parts, poly-epoxy succinic acid 4.5 parts, dimethylbenzene 8 parts, Tyox B 4.5 parts, aramid fiber 3 parts, mphenylenediamine 3.6 parts, triethylene tetramine 6 parts, stearic acid 2.6 parts, 34 parts, water, auxiliary agent 1.9 parts,
Wherein, described epoxy acrylic resin is modified epoxy acrylate resin; Described modified epoxy acrylate resin is prepared according to following technique: add in reaction unit by 35 parts of Hydroxyethyl acrylates, 3 parts of 2-hydroxyethyl methacrylic acid phosphoric acid ester, 20 parts of MALEIC ANHYDRIDE, 0.3 part of MEHQ, 0.8 part of Resorcinol and 0.1 part of trolamine by weight, be warming up to 85 DEG C, 10 parts of epoxy resin are added after reaction 20min, stopped reaction when to react to acid number after being heated to 100 DEG C be 7mgKOH/g, obtains modified epoxy acrylate resin after cooling.
Embodiment 4
A kind of high-temperature resistant coating that the present invention proposes, its raw material comprises following component by weight: organosilicon-modified acrylate 40 parts, epoxy acrylic resin 33 parts, methylphenylsiloxane 7 parts, carboxy nitrile rubber 8 parts, nano-graphite 8 parts, nano silicon 7 parts, aluminium silicate powder 8 parts, zinc phosphate 5 parts, magnesium hydroxide 4 parts, hollow glass microbead 7 parts, expanded vermiculite 7 parts, polyvinyl alcohol 3 parts, polyamide resin 9 parts, poly-epoxy succinic acid 3 parts, dimethylbenzene 9 parts, Tyox B 3 parts, aramid fiber 5 parts, mphenylenediamine 3 parts, triethylene tetramine 6.5 parts, silane coupling agent KH5701.3 part, Silane coupling agent KH550 0.7 part, 38 parts, water, auxiliary agent 1.6 parts,
Wherein, described epoxy acrylic resin is modified epoxy acrylate resin; Described modified epoxy acrylate resin is prepared according to following technique: add in reaction unit by 30 parts of Hydroxyethyl acrylates, 12 parts of 2-hydroxyethyl methacrylic acid phosphoric acid ester, 13 parts of MALEIC ANHYDRIDE, 0.6 part of MEHQ, 0.7 part of Resorcinol and 0.26 part of trolamine by weight, be warming up to 79 DEG C, 8 parts of epoxy resin are added after reaction 43min, stopped reaction when to react to acid number after being heated to 106 DEG C be 5.8mgKOH/g, obtains modified epoxy acrylate resin after cooling.
Embodiment 5
A kind of high-temperature resistant coating that the present invention proposes, its raw material comprises following component by weight: organosilicon-modified acrylate 39 parts, epoxy acrylic resin 36 parts, methylphenylsiloxane 6 parts, carboxy nitrile rubber 10 parts, nano-graphite 7.6 parts, nano silicon 8.3 parts, aluminium silicate powder 7 parts, zinc phosphate 6 parts, magnesium hydroxide 3 parts, hollow glass microbead 7.6 parts, expanded vermiculite 6.2 parts, polyvinyl alcohol 4 parts, polyamide resin 8.5 parts, poly-epoxy succinic acid 4 parts, dimethylbenzene 8.6 parts, Tyox B 4 parts, aramid fiber 3.9 parts, mphenylenediamine 3.3 parts, triethylene tetramine 6.2 parts, silane coupling agent KH5602.1 part, 36 parts, water, auxiliary agent 1.8 parts.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. a high-temperature resistant coating, it is characterized in that, its raw material comprises following component by weight: organosilicon-modified acrylate 25-50 part, epoxy acrylic resin 20-45 part, methylphenylsiloxane 2-8 part, carboxy nitrile rubber 5-15 part, nano-graphite 5-10 part, nano silicon 3-10 part, aluminium silicate powder 3-10 part, zinc phosphate 2-8 part, magnesium hydroxide 1-5 part, hollow glass microbead 3-10 part, expanded vermiculite 2-10 part, polyvinyl alcohol 1-5 part, polyamide resin 5-10 part, poly-epoxy succinic acid 1-5 part, dimethylbenzene 5-10 part, Tyox B 1-5 part, aramid fiber 2-6 part, mphenylenediamine 2-4 part, triethylene tetramine 3-8 part, coupling agent 1-3 part, water 20-40 part, auxiliary agent 1-2 part.
2. high-temperature resistant coating according to claim 1, it is characterized in that, in its raw material, the weight ratio of organosilicon-modified acrylate, epoxy acrylic resin, methylphenylsiloxane is 32-45:26-40:3-8.
3. high-temperature resistant coating according to claim 1 or 2, it is characterized in that, in its raw material, the weight ratio of nano-graphite, nano silicon, aluminium silicate powder, zinc phosphate, magnesium hydroxide, hollow glass microbead, expanded vermiculite is 6-9:5-9:4-10:3-8:2-4:6-9:4-9.
4. high-temperature resistant coating according to any one of claim 1-3, it is characterized in that, its raw material comprises following component by weight: organosilicon-modified acrylate 35-40 part, epoxy acrylic resin 33-38 part, methylphenylsiloxane 5-7 part, carboxy nitrile rubber 8-12 part, nano-graphite 7-8 part, nano silicon 7-9 part, aluminium silicate powder 6-8 part, zinc phosphate 5-7 part, magnesium hydroxide 2.5-4 part, hollow glass microbead 7-8 part, expanded vermiculite 6-7 part, polyvinyl alcohol 3-4.5 part, polyamide resin 8-9 part, poly-epoxy succinic acid 3-4.5 part, dimethylbenzene 8-9 part, Tyox B 3-4.5 part, aramid fiber 3-5 part, mphenylenediamine 3-3.6 part, triethylene tetramine 6-6.5 part, coupling agent 2-2.6 part, water 34-38 part, auxiliary agent 1.6-1.9 part.
5. high-temperature resistant coating according to any one of claim 1-4, it is characterized in that, its raw material comprises following component by weight: organosilicon-modified acrylate 39 parts, epoxy acrylic resin 36 parts, methylphenylsiloxane 6 parts, carboxy nitrile rubber 10 parts, nano-graphite 7.6 parts, nano silicon 8.3 parts, aluminium silicate powder 7 parts, zinc phosphate 6 parts, magnesium hydroxide 3 parts, hollow glass microbead 7.6 parts, expanded vermiculite 6.2 parts, polyvinyl alcohol 4 parts, polyamide resin 8.5 parts, poly-epoxy succinic acid 4 parts, dimethylbenzene 8.6 parts, Tyox B 4 parts, aramid fiber 3.9 parts, mphenylenediamine 3.3 parts, triethylene tetramine 6.2 parts, coupling agent 2.1 parts, 36 parts, water, auxiliary agent 1.8 parts.
6. high-temperature resistant coating according to any one of claim 1-5, is characterized in that, described epoxy acrylic resin is modified epoxy acrylate resin; Described modified epoxy acrylate resin is prepared according to following technique: add in reaction unit by 20-35 part Hydroxyethyl acrylate, 3-15 part 2-hydroxyethyl methacrylic acid phosphoric acid ester, 5-20 part MALEIC ANHYDRIDE, 0.3-1 part MEHQ, 0.2-0.8 part Resorcinol and 0.1-0.5 part trolamine by weight, be warming up to 75-85 DEG C, 5-10 part epoxy resin is added after reaction 20-50min, stopped reaction when to react to acid number after being heated to 100-110 DEG C be 5-7mgKOH/g, obtains modified epoxy acrylate resin after cooling.
7. high-temperature resistant coating according to any one of claim 1-6, is characterized in that, described epoxy acrylic resin is modified epoxy acrylate resin; Described modified epoxy acrylate resin is prepared according to following technique: add in reaction unit by 30 parts of Hydroxyethyl acrylates, 12 parts of 2-hydroxyethyl methacrylic acid phosphoric acid ester, 13 parts of MALEIC ANHYDRIDE, 0.6 part of MEHQ, 0.7 part of Resorcinol and 0.26 part of trolamine by weight, be warming up to 79 DEG C, 8 parts of epoxy resin are added after reaction 43min, stopped reaction when to react to acid number after being heated to 106 DEG C be 5.8mgKOH/g, obtains modified epoxy acrylate resin after cooling.
8. high-temperature resistant coating according to any one of claim 1-7, is characterized in that, described coupling agent is one or more the combination in silane coupling agent KH560, silane coupling agent KH570, Silane coupling agent KH550, stearic acid.
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| CN106118467A (en) * | 2016-07-29 | 2016-11-16 | 江苏仁通节能科技有限公司 | A kind of aqueous thermal-resistant thermal insulation coatings and its preparation method and application |
| CN108006333A (en) * | 2017-11-29 | 2018-05-08 | 大连新光管道制造有限公司 | High-temperature water pipe network system, pipeline and the pipe fitting of a kind of long-distance delivery |
| CN109370363A (en) * | 2018-10-12 | 2019-02-22 | 南京悠谷知识产权服务有限公司 | A kind of high temperature resistant aviation coating and preparation method thereof |
| CN113717637A (en) * | 2021-09-07 | 2021-11-30 | 河南三棵树新材料科技有限公司 | High-temperature-resistant anticorrosive paint and preparation method thereof |
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| CN113717637A (en) * | 2021-09-07 | 2021-11-30 | 河南三棵树新材料科技有限公司 | High-temperature-resistant anticorrosive paint and preparation method thereof |
| CN113717637B (en) * | 2021-09-07 | 2022-08-02 | 河南三棵树新材料科技有限公司 | High-temperature-resistant anticorrosive paint and preparation method thereof |
| CN113897119A (en) * | 2021-11-03 | 2022-01-07 | 鲁东大学 | Ultraviolet light curing nano composite coating and preparation method thereof |
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Application publication date: 20151028 |
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