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CN1050012C - 铅酸蓄电瓶增效复原添加剂 - Google Patents

铅酸蓄电瓶增效复原添加剂 Download PDF

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Publication number
CN1050012C
CN1050012C CN94101871A CN94101871A CN1050012C CN 1050012 C CN1050012 C CN 1050012C CN 94101871 A CN94101871 A CN 94101871A CN 94101871 A CN94101871 A CN 94101871A CN 1050012 C CN1050012 C CN 1050012C
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CN1107617A (zh
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施铭德
周爱芝
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Wuhan Colleges & Univs New Tech Inst
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Wuhan Colleges & Univs New Tech Inst
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

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Abstract

铅酸蓄电瓶增效复原添加剂是由乙二胺四乙酸二钠、硫酸镁、硫酸铝、酒石酸、硫酸镉、纯水组成。具有防止和消除电瓶极板硫酸化、减少电瓶的内阻和放电次数,减少电解液中的蒸馏水蒸发;防止自放电和过充电;降低过充电温度,提高电瓶的充电接受能力和起动性能,提高电压和电能化学能的转换效率,络合掩蔽在电瓶内部的锰、铁、砷、铜等破坏性离子,减少电瓶的正负极板的脱粉,使硫酸化报废的电瓶“起死复生”,重新投入正常使用,并延长新旧电瓶使用寿命。

Description

铅酸蓄电瓶增效复原添加剂
本发明涉及一种铅酸蓄电瓶增效复原添加剂。
铅酸蓄电瓶具有电动势较高,使用温度范围宽,放电可逆性好、干态贮存寿命长等优点,广泛应用于汽车、火车、轮船、摩托车、矿山等行业。但是,铅酸蓄电瓶也存在一些不足之处,比如电能较低,活性物质的利用率不高(最低速率放电不超过60%),使用寿命有限等。影响铅酸蓄电瓶寿命的主要因素有正极活性物质的软化脱落、板棚变形腐蚀和正负极板的不可逆硫酸化。为了解决上述存在的不足,美、日、英等国先后研究了各种类型的铅酸蓄电瓶电解液添加剂,但这类添加剂如美国的VX-6、日本的TCL等主要防止硫酸化,至于正极活性物质的软化脱落仍然未得到解决。
本发明的目的就是克服上述现有技术的不足,进而提供一种铅酸蓄电瓶增效复原添加剂,这种增效复原添加剂不仅可防止电瓶极板硫化(硫酸化),而且可抑制正负极板活性物质的脱落。
本发明的目的可以通过以下措施来达到:铅酸蓄电瓶增效复原添加剂由乙二胺四乙酸二钠、硫酸镁、硫酸铝、酒石酸、硫酸镉、纯水组成。其成份范围(重量百分比)为乙二胺四乙酸二钠0.5~3%、硫酸镁2~12%、硫酸铝10~25%、酒石酸12~24%、硫酸镉4~10%、其余为纯水,各组的总和为100%,其制造方法是按选定的比例称好原材料依次加入所需的纯水中,经搅拌溶解后即为产品。
本发明可防止、消除电瓶极板硫化(硫酸化),减少电瓶的内阻和充电次数、减少电解液中的蒸馏水蒸发,防止自放电和过充电、降低过充电温度、提高电瓶的充电接受能力和起动性能、提高电压和电能化学能的转换效率、络合掩蔽在电瓶内部的锰、铁、砷、铜等破坏性离子,同时还可抑制正负极板活性物质的脱落。提高了硫酸的活度,并改善了电瓶的低温性能。
因此,本发明有以下的优点:一是新旧电瓶使用本发明可延长使用寿命;二是提高了活性物质的利用率;三是提高充电效率,减少自放电。延长带电搁置时间,四是提高电瓶输出功率,改善电的低温起动性能,五是抑制了氧和氢的析出,减少蒸馏水的挥发。
下面结合实施例对本发明作进一步详述:本发明可根据需要在前述给出的比例范围内任意取一组,如选用乙二胺四乙酸二钠1.2克,硫酸镁6.8克,硫酸铝22.4克,酒石酸14.5克,硫酸镉4.6克,纯水50.5克,总和为100克,经过混合充分搅拌溶解即为产品。本产品经使用单位试用效果优异,能使硫酸化失效的铅酸电瓶继续使用半年以上。

Claims (1)

1.铅酸蓄电瓶增效复原添加剂,其特征在于由乙二胺四乙酸二钠、硫酸镁、硫酸铝、酒石酸、硫酸镉、纯水组成,其各组份的比例为(重量百分比):乙二胺四乙酸二钠0.5~3%、硫酸镁2~12%、硫酸铝10~25%、酒石酸12~24%、硫酸镉4~10%,其余为纯水,各组份的总和为100%。
CN94101871A 1994-03-07 1994-03-07 铅酸蓄电瓶增效复原添加剂 Expired - Fee Related CN1050012C (zh)

Priority Applications (1)

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CN94101871A CN1050012C (zh) 1994-03-07 1994-03-07 铅酸蓄电瓶增效复原添加剂

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CN94101871A CN1050012C (zh) 1994-03-07 1994-03-07 铅酸蓄电瓶增效复原添加剂

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CN1050012C true CN1050012C (zh) 2000-03-01

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101552355B (zh) * 2008-04-01 2012-02-29 于冬远 电瓶增强剂及其制备方法
CN105914416A (zh) * 2016-05-18 2016-08-31 山西嘉禾兴节能技术有限公司 一种废旧铅酸蓄电池修复活化剂及其使用方法
CN106025360A (zh) * 2016-05-25 2016-10-12 江苏帕维电动科技有限公司 一种电瓶增强剂及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1049427A (zh) * 1990-04-12 1991-02-20 韶关市通力化工合成材料厂 铅蓄电池电解液添加剂
CN1088713A (zh) * 1992-12-19 1994-06-29 李泽强 铅蓄电池的添加剂

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1049427A (zh) * 1990-04-12 1991-02-20 韶关市通力化工合成材料厂 铅蓄电池电解液添加剂
CN1088713A (zh) * 1992-12-19 1994-06-29 李泽强 铅蓄电池的添加剂

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