CN104986991B - Artificial special-shaped aggregate is applied to the preparation method of artificial hilllock stone - Google Patents
Artificial special-shaped aggregate is applied to the preparation method of artificial hilllock stone Download PDFInfo
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- CN104986991B CN104986991B CN201510364655.1A CN201510364655A CN104986991B CN 104986991 B CN104986991 B CN 104986991B CN 201510364655 A CN201510364655 A CN 201510364655A CN 104986991 B CN104986991 B CN 104986991B
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- special
- shaped aggregate
- artificial
- hilllock stone
- aggregate
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- 239000004575 stone Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 23
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000000049 pigment Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 239000004576 sand Substances 0.000 claims abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 9
- 239000000853 adhesive Substances 0.000 claims abstract description 8
- 230000001070 adhesive effect Effects 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000003999 initiator Substances 0.000 claims abstract description 7
- 235000013312 flour Nutrition 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 description 13
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N Methyl ethyl ketone Natural products CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000002969 artificial stone Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 239000011265 semifinished product Substances 0.000 description 4
- 229920006305 unsaturated polyester Polymers 0.000 description 4
- 229920006337 unsaturated polyester resin Polymers 0.000 description 4
- 239000010977 jade Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- -1 methyl ethyl ketone peroxides Chemical class 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 206010023126 Jaundice Diseases 0.000 description 1
- 241000003857 Parmelia saxatilis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- XFBXDGLHUSUNMG-UHFFFAOYSA-N alumane;hydrate Chemical compound O.[AlH3] XFBXDGLHUSUNMG-UHFFFAOYSA-N 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Road Paving Structures (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The special-shaped aggregate of the present invention is applied to the preparation method of artificial hilllock stone, it is characterised in that：Including following processing steps：1) by calcium carbonate silty sand or other function flour sands, after being stirred with pigment in mixer, the adhesive containing initiator and curing agent is added, the bulk with stickiness is stirred into.2) mixture that step 1 is stirred is put into mould, compressing under vacuum, cold curing is stripped after 4~6 hours, then natural solidify afterwards obtain special-shaped aggregate in 5 hours.3) the special-shaped aggregate for obtaining step 2, material making artificial hilllock stone is optimized according to the material tests method of prior art；With simple and easy to apply, and the rich color of special-shaped aggregate, the diversified advantage of specification shape.
Description
Technical field
It is applied to the present invention relates to a kind of preparation technology of artificial hilllock hardcore, more particularly to a kind of artificial special-shaped aggregate
The preparation method of artificial hilllock stone, belongs to building decoration field.
Background technology
Artificial hilllock stone various creates the rich and varied of hilllock stone with the changeable and filler of its pattern.Hilllock stone is typically using U.S.
Beautiful natural jade and shell as aggregate, and such aggregate price it is high it is even have mix ugly impurity, and the aggregate of jade class
It can crack in process of production, greatly have impact on the attractive in appearance of waste flitch.If but being given birth to using hilllock stone raw material and pigment
Aggregate is produced, natural jade aggregate can be not only copied, and can create the aggregate of more varied by the mould of different patterns,
The style of aggregate hilllock stone had so both been added, hilllock stone cost can be reduced again, has increased production efficiency.In addition, we utilize transparent
The characteristic of powder and luminescent powder is made containing transparent aggregate and luminous artificial hilllock stone.
The content of the invention
It is an object of the invention to：Propose that a kind of artificial special-shaped aggregate is applied to the preparation method of artificial hilllock stone.
The special-shaped aggregate of the present invention is applied to the preparation method of artificial hilllock stone, it is characterised in that：Including following processing steps：
1) by calcium carbonate silty sand or other function flour sands, after being stirred with pigment in mixer, add and contain initiator
With the adhesive of curing agent, the bulk with stickiness is stirred into.
2) mixture that step 1 is stirred is put into mould, compressing under vacuum, cold curing 4~6 is small
When after be stripped, then natural solidify afterwards obtain special-shaped aggregate in 5 hours.
3) the special-shaped aggregate for obtaining step 2, material making artificial hilllock is optimized according to the material tests method of prior art
Stone.
The special-shaped aggregate is applied to the preparation method of artificial hilllock stone, it is characterised in that：1. the adhesive is its step
Unsaturated polyester (UP) tree, by weight percentage, addition are the 5%~8% of calcium carbonate silty sand.
The special-shaped aggregate is applied to the preparation method of artificial hilllock stone, it is characterised in that：2. the curing agent is its step
Methyl ethyl ketone peroxide, by weight percentage, addition are 1.2.0%~2.0% of unsaturated polyester resin consumption.
The special-shaped aggregate is applied to the preparation method of artificial hilllock stone, it is characterised in that：1. the pigment is iron to its step
Series pigments, addition is depending on special-shaped aggregate color is adjusted.
The special-shaped aggregate is applied to the preparation method of artificial hilllock stone, it is characterised in that：2. the mould is spy to its step
The one side compacting of system or two-sided compacting.
The special-shaped aggregate is applied to the preparation method of artificial hilllock stone, it is characterised in that：The artificial hilllock stone, it was prepared
Cheng Wei：
Batch mixing, by weight percentage：
Processing step：
After 1 calcium carbonate silty sand and pigment stir in mixer, appropriate initiator and curing agent have been added in addition
Adhesive and stir into the bulk with stickiness.
2 by the mixture being stirred be put into mould be placed in it is compressing under vacuum condition, after cold curing 4~6 hours
The demoulding, natural solidify afterwards can obtain special-shaped aggregate in 5 hours.
The 3 special-shaped aggregates for obtaining step 2 optimize material making artificial hilllock stone according to material tests method.
The good result of the present invention is embodied in：Artificial hilllock stone is applied to it is an object of the invention to provide a kind of special-shaped aggregate
Preparation process, the inventive method prepare special-shaped aggregate there is flexible and changeable, rich color, can be according to hilllock parmelia saxatilis color and pattern
Come the figure colour and specification shape of special-shaped aggregate needed for selecting, and the preparation method is simple and easy to do.The method is greatly rich
The rich content of artificial hilllock stone decorative fillers, vast development prospect is suffered from whole artificial stone industry.
Special-shaped aggregate is obtained using the inventive method and prepares simple and easy to apply, and the rich color of special-shaped aggregate, specification shape
It is varied.
The special-shaped aggregate prepared using this method imparts the more decorative pattern patterns of artificial hilllock stone so that artificial hilllock stone has
The kind of more tinctorial patterns, meets different consumer demands.
Embodiment
Following non-limiting examples can make one of ordinary skill in the art be more fully understood the present invention, but not with
Any mode limits the present invention.
Embodiment 1
The special-shaped aggregate of the present invention is applied to the preparation method of artificial hilllock stone, including following processing steps：
After 1 calcium carbonate silty sand (or other function flour sands) and pigment stir in mixer, addition, which has been added, fits
The adhesive of amount initiator and curing agent simultaneously stirs into the bulk with stickiness.
2 by the mixture being stirred be put into mould be placed in it is compressing under vacuum condition, after cold curing 4~6 hours
Demoulding nature solidify afterwards can obtain special-shaped aggregate in 5 hours.
The 3 special-shaped aggregates for obtaining step 2 optimize material making artificial hilllock stone according to material tests method.
The special-shaped aggregate is applied to the preferred steps 1. gluing in all technical schemes of preparation method of artificial hilllock stone
Agent is unsaturated polyester (UP) tree, by weight percentage, and addition is the 5%~8% of calcium carbonate silty sand.
The special-shaped aggregate is applied to the preferred steps 1. solidification in all technical schemes of preparation method of artificial hilllock stone
Agent is methyl ethyl ketone peroxide, by weight percentage, and addition is followed successively by the 2.0%~3.0% of unsaturated polyester resin consumption.
The special-shaped aggregate is applied to the preferred steps 1. pigment in all technical schemes of preparation method of artificial hilllock stone
For iron pigment, addition is depending on special-shaped aggregate color is adjusted.
The special-shaped aggregate is applied to mould described in preferred steps 2 in all technical schemes of preparation method of artificial hilllock stone
Special one side compacting or two-sided compacting.
The special-shaped aggregate be applied to artificial hilllock stone all technical schemes of preparation method in preferred steps 3. in, the system
The component for making the following percentage by weight of batch mixing of artificial hilllock stone is made：
It is a further object of the present invention to provide the special-shaped aggregate materials prepared by the above method.
The special-shaped aggregate of the present invention is applied to the preparation method of artificial hilllock stone, including following processing steps：
After 1 calcium carbonate silty sand and pigment stir in mixer, appropriate initiator and curing agent have been added in addition
Adhesive and stir into the bulk with stickiness.
2 by the mixture being stirred be put into mould be placed in it is compressing under vacuum condition, after cold curing 4~6 hours
Demoulding nature solidify afterwards can obtain special-shaped aggregate in 5 hours.
The 3 special-shaped aggregates for obtaining step 2 optimize material making artificial hilllock stone according to material tests method.
The preparation method of artificial hilllock stone, the artificial hilllock stone product of different in nature aggregate of preparation are applied to by above-mentioned special-shaped aggregate.
Embodiment 2
1. the preparation method of the special-shaped aggregate of weak blue fluorescence spheroid, sphere diameter is 1cm.Specifically preparation process is：
5kg Paris whites (300 mesh and following), 0.05g ultramarine blue and 20g blue colour fluorescent powders are weighed in vertical mixer
In, 5~8min is stirred with 40r/min；After calcium powder and pigment stirring are almost abundant, 550g unsaturated-resins are weighed, in tree
1.65g cobalt naphthenates are added in fat simultaneously to stir evenly, after add 7.7g methyl ethyl ketone peroxides and stir；Handle well not
Saturated resin is added in calcium powder, until the dough of calcium powder and resin into moistening.
The material stirred is packed into spheroid mould, -0.098 is evacuated in the die press of populated material, and
5~10min is suppressed, the special-shaped aggregate of blue sphere can be removed from the molds after having suppressed；
The special-shaped aggregate of obtained blue-fluorescence spheroid is placed in clean flat board upper berth and drives row cold curing into.
2. the special-shaped aggregate of blue-fluorescence spheroid is applied to the preparation method of artificial hilllock stone：
Automatic material weighing system weighs 3500kg Paris whites, the white building stones of 5900kg (80 mesh), titanium dioxide 20kg, 1cm respectively
Blue sphere abnormity aggregate 1100kg is placed in blender, and 570kg unsaturated polyester resins are then weighed again, is added simultaneously
7.2kg methyl ethyl ketone peroxide, stirs；
Above-mentioned artificial stone premix is cast in mould under vacuum, a height of 2.75m of the die size length and width
It is compressing under × 1.85m × 1.25m, vacuum condition, obtain semi-finished product；
Semi-finished product cold curing 7-10 days, further cutting polishing obtains finished product.People can see the artificial hilllock slabstone at night
To not of uniform size and send out the circle of light blue light.
Embodiment 3
1. the preparation method of the special-shaped aggregate of jaundice color fluorescent transparent spheroid.Specifically preparation method is：
5kg aluminium hydrate powders (300 mesh) and 20g yellow fluorescent powders are weighed in vertical mixer, 5 are stirred with 40r/min
~8min；After calcium powder and fluorescent material stirring are almost abundant, 550g unsaturated-resins are weighed, 1.65g rings are added in resin
Alkanoic acid cobalt is simultaneously stirred evenly, after add 7.7g methyl ethyl ketone peroxides and stir；The unsaturated-resin handled well adds aluminium
In powder, until the dough of aluminium powder and resin into moistening.
The material stirred is packed into ellipsoid mould, -0.098 is evacuated in the die press of populated material,
And 5~10min is suppressed, the special-shaped aggregate of transparent spheroid can be removed from the molds after having suppressed；
The special-shaped aggregate of obtained blue-fluorescence spheroid is placed in clean flat board upper berth and drives row cold curing into.
2. the special-shaped aggregate of hair yellow fluorescence spheroid is applied to the preparation method of artificial hilllock stone：
Automatic material weighing system weighs 3500kg Paris whites, the white building stones of 5900kg (80 mesh), titanium dioxide 20kg, ellipsoid respectively
Body abnormity aggregate 1100kg is placed in blender, and 570kg unsaturated polyester resins are then weighed again, while adding 7.2kg mistake
MEKP, stirs；
Above-mentioned artificial stone premix is cast in mould under vacuum, a height of 2.75m of the die size length and width
It is compressing under × 1.85m × 1.25m, vacuum condition, obtain semi-finished product；
Semi-finished product cold curing 7-10 days, further cutting polishing obtains finished product.The artificial hilllock slabstone is transparent due to surface
Degree it is deep mixed and rich in stereovision, those ellipses not of uniform size of evening can also send out light fluorescence, give people a kind of
Dim sense rich in poetic atmosphere.
The artificial special-shaped aggregate of the present invention is applied to the preparation method of artificial hilllock stone：1 calcium carbonate silty sand (or other function powder
Sand) and after pigment stirs in mixer, add the adhesive for having added appropriate initiator and curing agent and stir into
Bulk with stickiness；The mixture being stirred is put into mould by 2 is placed in compressing under vacuum condition, cold curing 4~6
Demoulding nature solidify afterwards can obtain special-shaped aggregate in 5 hours after hour；The 3 special-shaped aggregates for 2. obtaining step are according to material tests
Method optimization material making artificial hilllock stone.Using different silty sands, different collocation of colour are adjusted, specific function powder is mixed
(such as fluorescent material) and the different patterns of replacing, the mould of shape, the special-shaped aggregate various colors produced, pattern are changeable, applicability
By force, expand the scope of the artificial hilllock stone of aggregate significantly, make hilllock stone that there is more preferable decorative effect；And it is this method cost, simple and easy to apply,
It can be mass-produced, had a wide range of applications in artificial stone field.
Claims (1)
1. a kind of method for applying special-shaped aggregate to prepare artificial hilllock stone, it is characterised in that：Including following processing steps：
1) by calcium carbonate flour sand or other function flour sands, after being stirred with pigment in mixer, add and contain initiator and solid
The adhesive of agent, stirs into the bulk with stickiness,
2) mixture that step 1 is stirred is put into mould, it is compressing under vacuum, after cold curing 4~6 hours
The demoulding, then natural solidify afterwards obtain special-shaped aggregate in 5 hours,
3) the special-shaped aggregate for obtaining step 2, material making artificial hilllock stone is optimized according to the material tests method of prior art.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510364655.1A CN104986991B (en) | 2015-06-26 | 2015-06-26 | Artificial special-shaped aggregate is applied to the preparation method of artificial hilllock stone |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510364655.1A CN104986991B (en) | 2015-06-26 | 2015-06-26 | Artificial special-shaped aggregate is applied to the preparation method of artificial hilllock stone |
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| Publication Number | Publication Date |
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| CN104986991A CN104986991A (en) | 2015-10-21 |
| CN104986991B true CN104986991B (en) | 2017-11-07 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109580624B (en) * | 2018-12-11 | 2021-02-09 | 广西利升石业有限公司 | Artificial stone aggregate simulation method |
| CN113459532A (en) * | 2021-06-28 | 2021-10-01 | 安徽宏耀石材有限公司 | Manufacturing process of environment-friendly granite |
| CN113666709A (en) * | 2021-09-03 | 2021-11-19 | 安庆仁创聚源生态环保科技有限公司 | Novel composite cement-based artificial stone and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101804660A (en) * | 2010-03-02 | 2010-08-18 | 刘建平 | Method for producing quartz granite by using yellow river sand and forming device thereof |
| CN102320779A (en) * | 2011-06-21 | 2012-01-18 | 云浮市新富云岗石有限公司 | Celik dark beige artificial granite and preparation method thereof |
| CN104446143A (en) * | 2014-11-19 | 2015-03-25 | 广西利升石业有限公司 | Preparation method of artificial stone from colored glass particles |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1097569C (en) * | 1997-02-17 | 2003-01-01 | 株式会社多佩尔 | Method for manufacturing artificial stone |
| US7727435B2 (en) * | 2006-04-18 | 2010-06-01 | Safas Corporation | Engineered stone |
| CN102701645B (en) * | 2011-03-28 | 2013-11-06 | 中冶宝钢技术服务有限公司 | Cement-based steel slag granite product and preparation method thereof |
| CN104556837A (en) * | 2013-10-29 | 2015-04-29 | 天津市恒伊源建筑材料有限公司 | Artificial stone and preparation method thereof |
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2015
- 2015-06-26 CN CN201510364655.1A patent/CN104986991B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101804660A (en) * | 2010-03-02 | 2010-08-18 | 刘建平 | Method for producing quartz granite by using yellow river sand and forming device thereof |
| CN102320779A (en) * | 2011-06-21 | 2012-01-18 | 云浮市新富云岗石有限公司 | Celik dark beige artificial granite and preparation method thereof |
| CN104446143A (en) * | 2014-11-19 | 2015-03-25 | 广西利升石业有限公司 | Preparation method of artificial stone from colored glass particles |
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Effective date of registration: 20170919 Address after: 542800 the Guangxi Zhuang Autonomous Region Hezhou Ping GUI management Industrial Zone Applicant after: GUANGXI LISHENG STONE Co.,Ltd. Address before: 542800 the Guangxi Zhuang Autonomous Region Hezhou Ping GUI management Industrial Zone Applicant before: Tang Xiongyue Applicant before: Liu Songjun |
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Denomination of invention: Preparation method of artificial irregular aggregate applied to artificial granite Granted publication date: 20171107 Pledgee: Guangxi SME Financing Guarantee Co.,Ltd. Pledgor: GUANGXI LISHENG STONE Co.,Ltd. Registration number: Y2024980001572 |