CN104927536A - Anti-pollution self-cleaning coating and preparation method thereof - Google Patents
Anti-pollution self-cleaning coating and preparation method thereof Download PDFInfo
- Publication number
- CN104927536A CN104927536A CN201510346128.8A CN201510346128A CN104927536A CN 104927536 A CN104927536 A CN 104927536A CN 201510346128 A CN201510346128 A CN 201510346128A CN 104927536 A CN104927536 A CN 104927536A
- Authority
- CN
- China
- Prior art keywords
- parts
- self
- cleaning
- cleaning coating
- dirt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an anti-pollution self-cleaning coating and a preparation method thereof. The anti-pollution self-cleaning coating comprises, by weight, 25-35 parts of modified acrylate resin, 15-25 parts of glycerin alkyd resin, 5-12 parts of zinc oxide, 2-8 parts of silicon nitride, 3-9 parts of hydroxyl-contained fluorine silicon additive, 1-5 parts of butyl acrylate resin, 5-14 parts of anti-pollution self-cleaning non-adhesive, 2-7 parts of defoamers, 1-6 parts of plasticizers and 30-40 parts of solvents. The anti-pollution self-cleaning coating is small in surface tension, high in pollution resistance, capable of reaching the self-cleaning effect through washing of rainwater, high in coating stability and cohesiveness, good in resistance to acid and alkali and weather resistance and suitable for the exterior wall decoration field of buildings, dwellings and commercial buildings.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of anti-soil self-cleaning coating and preparation method thereof.
Background technology
Building, house and business premises are scrawled and puted up etc. and pollute environment, destroy the problem of improving looks in city and be not yet resolved, once wall is by scribble colored drawing, just be difficult to eliminate, unless with the solvent of high abrasiveness, but can affect to buildings again like this.
Self-cleaning coating is a kind of novel functional paint, is coated in glass, ceramic tile surface, can reach clean effect by rain-out.
But, the function imperfection that has of self-cleaning coating on the market at present, existing defects; main drawback is can not the intensity of available protecting wall plaster bottom, thus produces metope cracking, comes off, and not only affects buildings attractive in appearance; and metope cracking, cause metope to leak.
Summary of the invention
The object of the invention is to overcome the deficiency that above-mentioned prior art exists, provide a kind of anti-soil and self-cleaning property is excellent, the anti-soil self-cleaning coating of good weatherability.
Meanwhile, present invention also offers a kind of preparation method of anti-soil self-cleaning coating.
For achieving the above object, the present invention is achieved by the following technical solutions:
A kind of anti-soil self-cleaning coating, meter comprises following component by weight: modified acrylic ester resin 25 ~ 35 parts, glyptal 15 ~ 25 parts, 5 ~ 12 parts, zinc oxide, silicon nitride 2 ~ 8 parts, hydroxyl fluorine silicon additive 3 ~ 9 parts, butyl polyacrylate 1 ~ 5 part, the self-cleaning not stick of anti-dirt 5 ~ 14 parts, defoamer 2 ~ 7 parts, 1 ~ 6 part, softening agent, solvent 30 ~ 40 parts.
Preferably, described modified acrylic ester resin is any one in silane-modified acrylate resin, epoxy modification acrylate resin, polyester modification acrylate resin.
Preferably, the self-cleaning not stick of described anti-dirt is any one in clorafin, white oil, naphthenic oil.
Preferably, described defoamer is any one in tributyl phosphate, dimethyl silicone oil, silicone emulsion.
Preferably, described softening agent is any one in dioctyl phthalate (DOP), dibutyl phthalate, dimethyl phthalate.
Preferably, described solvent is any one in propyl alcohol, ethyl acetate, butylacetate.
Above-mentioned anti-soil self-cleaning coating, its step of preparation process is as follows:
(1) mark takes the material in composition of raw materials by weight;
(2) solvent, modified acrylic ester resin, glyptal are mixed and heated to 70 ~ 90 DEG C and form emulsion, add zinc oxide, hydroxyl fluorine silicon additive dispersed with stirring again after 10 ~ 20 minutes, reduce temperature at 40 ~ 60 DEG C, add the self-cleaning not stick of anti-dirt and continue stirring 20 ~ 40 minutes;
(3) butyl polyacrylate, silicon nitride are added in reactor and mix, be heated to 70 ~ 90 DEG C, stir 30 ~ 50 minutes under the rotating speed of 400 ~ 600 revs/min; Add remaining raw material, stir with the rotating speed of 500 ~ 800 revs/min, filter, obtain dirt-resistant self-cleaning coating.
Beneficial effect of the present invention:
Anti-soil self-cleaning coating prepared by the present invention, surface tension is little, and stain resistance is strong, can reach self-cleaning effect by rainwash, coating stability is strong, and cohesiveness is strong, resistance to acids and bases and good weatherability, be applicable to the exterior wall finishing field of building, house and business premises.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.Following examples will contribute to those skilled in the art and understand the present invention further, but not limit the present invention in any form.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, some distortion and improvement can also be made.These all belong to protection scope of the present invention.
A kind of anti-soil self-cleaning coating, meter comprises following component by weight: modified acrylic ester resin 25 ~ 35 parts, glyptal 15 ~ 25 parts, 5 ~ 12 parts, zinc oxide, silicon nitride 2 ~ 8 parts, hydroxyl fluorine silicon additive 3 ~ 9 parts, butyl polyacrylate 1 ~ 5 part, the self-cleaning not stick of anti-dirt 5 ~ 14 parts, defoamer 2 ~ 7 parts, 1 ~ 6 part, softening agent, solvent 30 ~ 40 parts.
Its step of preparation process is as follows:
(1) mark takes the material in composition of raw materials by weight;
(2) solvent, modified acrylic ester resin, glyptal are mixed and heated to 70 ~ 90 DEG C and form emulsion, add zinc oxide, hydroxyl fluorine silicon additive dispersed with stirring again after 10 ~ 20 minutes, reduce temperature at 40 ~ 60 DEG C, add the self-cleaning not stick of anti-dirt and continue stirring 20 ~ 40 minutes;
(3) butyl polyacrylate, silicon nitride are added in reactor and mix, be heated to 70 ~ 90 DEG C, stir 30 ~ 50 minutes under the rotating speed of 400 ~ 600 revs/min; Add remaining raw material, stir with the rotating speed of 500 ~ 800 revs/min, filter, obtain dirt-resistant self-cleaning coating.
Anti-soil self-cleaning coating prepared by the present invention, has anti-soil and self-cleaning property is excellent, the advantage of good weatherability.
Embodiment 1
Anti-soil self-cleaning coating of the present invention, meter comprises following component by weight: silane-modified acrylate resin 35 parts, glyptal 15 parts, 5 parts, zinc oxide, silicon nitride 8 parts, hydroxyl fluorine silicon additive 9 parts, butyl polyacrylate 1 part, clorafin 14 parts, tributyl phosphate 2 parts, dioctyl phthalate (DOP) 1 part, propyl alcohol 30 parts.
Embodiment 2
Anti-soil self-cleaning coating of the present invention, meter comprises following component by weight: epoxy modification acrylate resin 25 parts, glyptal 25 parts, 12 parts, zinc oxide, silicon nitride 2 parts, hydroxyl fluorine silicon additive 3 parts, butyl polyacrylate 5 parts, white oil 5 parts, dimethyl silicone oil 7 parts, dibutyl phthalate 6 parts, ethyl acetate 40 parts.
Embodiment 3
Anti-soil self-cleaning coating of the present invention, meter comprises following component by weight: polyester modification acrylate resin 29 parts, glyptal 18 parts, 8 parts, zinc oxide, silicon nitride 5 parts, hydroxyl fluorine silicon additive 6 parts, butyl polyacrylate 3 parts, naphthenic oil 10 parts, silicone emulsion 4 parts, dimethyl phthalate 4 parts, butylacetate 35 parts.
Embodiment 4
Anti-soil self-cleaning coating of the present invention, meter comprises following component by weight: epoxy modification acrylate resin 22 parts, glyptal 17 parts, 7 parts, zinc oxide, silicon nitride 3 parts, hydroxyl fluorine silicon additive 4 parts, butyl polyacrylate 2 parts, white oil 7 parts, dimethyl silicone oil 3 parts, dibutyl phthalate 2 parts, ethyl acetate 32 parts.
Embodiment 5
Anti-soil self-cleaning coating of the present invention, meter comprises following component by weight: polyester modification acrylate resin 32 parts, glyptal 23 parts, 10 parts, zinc oxide, silicon nitride 6 parts, hydroxyl fluorine silicon additive 7 parts, butyl polyacrylate 4 parts, naphthenic oil 12 parts, silicone emulsion 6 parts, dimethyl phthalate 5 parts, butylacetate 37 parts.
Embodiment 6
Anti-soil self-cleaning coating of the present invention, meter comprises following component by weight: silane-modified acrylate resin 25 parts, glyptal 17 parts, 9 parts, zinc oxide, silicon nitride 2 parts, hydroxyl fluorine silicon additive 9 parts, butyl polyacrylate 5 parts, clorafin 8 parts, tributyl phosphate 6 parts, dioctyl phthalate (DOP) 4 parts, propyl alcohol 33 parts.
Above specific embodiments of the invention are described.It is to be appreciated that the present invention is not limited to above-mentioned particular implementation, those skilled in the art can make various distortion or amendment within the scope of the claims, and this does not affect flesh and blood of the present invention.
Claims (7)
1. an anti-soil self-cleaning coating, it is characterized in that, meter comprises following component by weight: modified acrylic ester resin 25 ~ 35 parts, glyptal 15 ~ 25 parts, 5 ~ 12 parts, zinc oxide, silicon nitride 2 ~ 8 parts, hydroxyl fluorine silicon additive 3 ~ 9 parts, butyl polyacrylate 1 ~ 5 part, the self-cleaning not stick of anti-dirt 5 ~ 14 parts, defoamer 2 ~ 7 parts, 1 ~ 6 part, softening agent, solvent 30 ~ 40 parts.
2. anti-soil self-cleaning coating according to claim 1, is characterized in that: described modified acrylic ester resin is any one in silane-modified acrylate resin, epoxy modification acrylate resin, polyester modification acrylate resin.
3. anti-soil self-cleaning coating according to claim 1, is characterized in that: the self-cleaning not stick of described anti-dirt is any one in clorafin, white oil, naphthenic oil.
4. anti-soil self-cleaning coating according to claim 1, is characterized in that: described defoamer is any one in tributyl phosphate, dimethyl silicone oil, silicone emulsion.
5. dirt-resistant self-cleaning coating according to claim 1, is characterized in that: described softening agent is any one in dioctyl phthalate (DOP), dibutyl phthalate, dimethyl phthalate.
6. anti-soil self-cleaning coating according to claim 1, is characterized in that: described solvent is any one in propyl alcohol, ethyl acetate, butylacetate.
7. a preparation method for anti-soil self-cleaning coating as claimed in claim 1, is characterized in that, comprise the following steps:
(1) mark takes the material in composition of raw materials by weight;
(2) solvent, modified acrylic ester resin, glyptal are mixed and heated to 70 ~ 90 DEG C and form emulsion, add zinc oxide, hydroxyl fluorine silicon additive dispersed with stirring again after 10 ~ 20 minutes, reduce temperature at 40 ~ 60 DEG C, add the self-cleaning not stick of anti-dirt and continue stirring 20 ~ 40 minutes;
(3) butyl polyacrylate, silicon nitride are added in reactor and mix, be heated to 70 ~ 90 DEG C, stir 30 ~ 50 minutes under the rotating speed of 400 ~ 600 revs/min; Add remaining raw material, stir with the rotating speed of 500 ~ 800 revs/min, filter, obtain dirt-resistant self-cleaning coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510346128.8A CN104927536A (en) | 2015-06-23 | 2015-06-23 | Anti-pollution self-cleaning coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510346128.8A CN104927536A (en) | 2015-06-23 | 2015-06-23 | Anti-pollution self-cleaning coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104927536A true CN104927536A (en) | 2015-09-23 |
Family
ID=54114972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510346128.8A Pending CN104927536A (en) | 2015-06-23 | 2015-06-23 | Anti-pollution self-cleaning coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104927536A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199527A (en) * | 2015-10-30 | 2015-12-30 | 桂林市和鑫防水装饰材料有限公司 | Stain-resistant acrylic ester waterproof coating |
| CN105482597A (en) * | 2016-01-07 | 2016-04-13 | 上海华谊（集团）公司 | Ultra-stain-resistant self-cleaning paint and preparation method thereof |
| CN108504210A (en) * | 2018-03-01 | 2018-09-07 | 广东至诚化学工业有限公司 | A kind of self-cleaning coating and preparation method thereof |
| CN108840720A (en) * | 2018-08-01 | 2018-11-20 | 广东金意陶陶瓷集团有限公司 | Self-cleaning ceramic brick and preparation method thereof |
| CN108912981A (en) * | 2018-08-01 | 2018-11-30 | 广东金意陶陶瓷集团有限公司 | For the coating paste on porous ceramics surface, coating and Unglazed ceramic ceramic tile and preparation method thereof |
| CN110214196A (en) * | 2017-01-27 | 2019-09-06 | 日本制铁株式会社 | Steel plate and coated steel sheet |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4366300A (en) * | 1980-06-03 | 1982-12-28 | Pcuk - Produits Chimiques Ugine Kuhlmann | Composition and process for the protection of materials against spots or stains |
| JP2000144013A (en) * | 1998-11-17 | 2000-05-26 | Takenaka Komuten Co Ltd | Stain-resistant matte coating composition |
| CN102796429A (en) * | 2012-09-05 | 2012-11-28 | 珠海市美筑化工有限公司 | Water-soluble paint, preparation method and spraying technique thereof |
| CN104356826A (en) * | 2014-11-14 | 2015-02-18 | 珠海市澜诺新材料科技有限公司 | Surface self-cleaning coating and preparation method thereof |
| CN104356841A (en) * | 2014-10-23 | 2015-02-18 | 安徽省金盾涂料有限责任公司 | Self-cleaning acrylic coating |
| CN104356822A (en) * | 2014-10-23 | 2015-02-18 | 安徽省金盾涂料有限责任公司 | Weather-proof self-cleaning paint |
-
2015
- 2015-06-23 CN CN201510346128.8A patent/CN104927536A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4366300A (en) * | 1980-06-03 | 1982-12-28 | Pcuk - Produits Chimiques Ugine Kuhlmann | Composition and process for the protection of materials against spots or stains |
| JP2000144013A (en) * | 1998-11-17 | 2000-05-26 | Takenaka Komuten Co Ltd | Stain-resistant matte coating composition |
| CN102796429A (en) * | 2012-09-05 | 2012-11-28 | 珠海市美筑化工有限公司 | Water-soluble paint, preparation method and spraying technique thereof |
| CN104356841A (en) * | 2014-10-23 | 2015-02-18 | 安徽省金盾涂料有限责任公司 | Self-cleaning acrylic coating |
| CN104356822A (en) * | 2014-10-23 | 2015-02-18 | 安徽省金盾涂料有限责任公司 | Weather-proof self-cleaning paint |
| CN104356826A (en) * | 2014-11-14 | 2015-02-18 | 珠海市澜诺新材料科技有限公司 | Surface self-cleaning coating and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105199527A (en) * | 2015-10-30 | 2015-12-30 | 桂林市和鑫防水装饰材料有限公司 | Stain-resistant acrylic ester waterproof coating |
| CN105482597A (en) * | 2016-01-07 | 2016-04-13 | 上海华谊（集团）公司 | Ultra-stain-resistant self-cleaning paint and preparation method thereof |
| CN110214196A (en) * | 2017-01-27 | 2019-09-06 | 日本制铁株式会社 | Steel plate and coated steel sheet |
| CN110214196B (en) * | 2017-01-27 | 2021-10-01 | 日本制铁株式会社 | Steel sheet and plated steel sheet |
| CN108504210A (en) * | 2018-03-01 | 2018-09-07 | 广东至诚化学工业有限公司 | A kind of self-cleaning coating and preparation method thereof |
| CN108840720A (en) * | 2018-08-01 | 2018-11-20 | 广东金意陶陶瓷集团有限公司 | Self-cleaning ceramic brick and preparation method thereof |
| CN108912981A (en) * | 2018-08-01 | 2018-11-30 | 广东金意陶陶瓷集团有限公司 | For the coating paste on porous ceramics surface, coating and Unglazed ceramic ceramic tile and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104927536A (en) | Anti-pollution self-cleaning coating and preparation method thereof | |
| CN102002298A (en) | Aqueous antifouling adhesive preventing coating and production method thereof | |
| CN102559053B (en) | Elastomeric gigging paint and preparation method thereof | |
| CN105542602B (en) | A kind of two-component coating of outdoor tile renovation | |
| CN105086823A (en) | Organosilicone room-temperature-cured anticorrosive coating material | |
| CN105838169A (en) | Universal high-performance water-borne glass ceramic glaze and preparation method thereof | |
| CN105176211A (en) | Organic-inorganic composite thermal insulation paint and preparation method thereof | |
| CN101851450A (en) | Waterborne fluorocarbon texture coating and preparation method and application thereof | |
| CN112266663A (en) | Quick-drying primer for renovating exterior wall tiles and preparation method thereof | |
| CN111138961A (en) | Finish paint and preparation method thereof | |
| CN106883688A (en) | A kind of wear-resisting automatically cleaning emulsion paint of safe environment protection type and preparation method thereof | |
| CN110713760A (en) | Water-based acrylic floor paint and preparation method thereof | |
| CN111019453A (en) | Environment-friendly waterproof coating and preparation method thereof | |
| CN105754427B (en) | A kind of self-cleaning colored solar heat reflection paint | |
| CN111777907A (en) | Waterproof coating and preparation method thereof | |
| CN107189604A (en) | A kind of environment-friendly type building construction finishing paint and preparation method thereof | |
| CN110845953A (en) | Exterior wall environment-friendly coating and preparation method thereof | |
| CN102976706B (en) | Composite mortar | |
| CN106752827B (en) | High-adhesion coating on low-surface-energy base material | |
| KR102060601B1 (en) | Water proof painting composition for concrete structure and painting method | |
| CN103173075A (en) | Aqueous paint and preparation method thereof | |
| CN108822636A (en) | A kind of glass dirt resistance coatings and preparation method thereof | |
| CN113956731B (en) | Primer for aluminum plate curtain wall, preparation method of primer, composite paint for aluminum plate curtain wall and preparation method of aluminum plate curtain wall | |
| CN104087238A (en) | Antifouling sealing material and preparation method thereof | |
| CN114479585B (en) | Rain mark resistant high-color-retention high-polymer exterior wall coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150923 |
|
| WD01 | Invention patent application deemed withdrawn after publication |